Polymer blend electrolyte membrane for use at high temperature and manufacturing method thereof
    4.
    发明授权
    Polymer blend electrolyte membrane for use at high temperature and manufacturing method thereof 有权
    用于高温的聚合物共混电解质膜及其制造方法

    公开(公告)号:US08092952B2

    公开(公告)日:2012-01-10

    申请号:US12229302

    申请日:2008-08-20

    IPC分类号: H01M8/10 B01J49/00 C08J5/20

    摘要: The present invention relates to a polymer blend electrolyte membrane comprising an inorganic polymer having polydimethylsiloxane as a main chain, which has a pore structure at both ends formed by condensation reaction between 3-aminopropyltriethoxysilane and tetraethylorthosilicate, wherein phosphoric acid is chemically linked to an amino group of the pore structure; and a proton-conducting polymer having a cation exchange group at the side chain thereof, as well as a manufacturing method thereof. Generally, proton-conducting electrolyte membranes have significantly reduced ion conductivity at high temperatures. However, proton-conducting electrolyte membranes have advantages in terms of efficiency and cost, and thus it is needed to develop an electrolyte membrane, which has excellent ion conductivity even at high temperature. Accordingly, the present invention aims to provide a polymer blend electrolyte membrane for use at high temperature and a manufacturing method thereof.

    摘要翻译: 本发明涉及一种聚合物共混电解质膜,其包含具有聚二甲基硅氧烷作为主链的无机聚合物,其具有通过3-氨基丙基三乙氧基硅烷和原硅酸四乙酯之间的缩合反应形成的两端的孔结构,其中磷酸与氨基化学连接 的孔结构; 以及其侧链具有阳离子交换基团的质子传导性聚合物及其制造方法。 通常,质子传导电解质膜在高温下具有显着降低的离子传导性。 然而,质子传导性电解质膜在效率和成本方面具有优点,因此需要开发即使在高温下也具有优异的离子传导性的电解质膜。 因此,本发明的目的在于提供一种高温使用的高分子混合电解质膜及其制造方法。

    ELECTRODE CATALYST COMPOSITION FOR FUEL CELL AND METHOD OF MANUFACTURING THE SAME
    5.
    发明申请
    ELECTRODE CATALYST COMPOSITION FOR FUEL CELL AND METHOD OF MANUFACTURING THE SAME 审中-公开
    用于燃料电池的电极催化剂组合物及其制造方法

    公开(公告)号:US20110053051A1

    公开(公告)日:2011-03-03

    申请号:US12618868

    申请日:2009-11-16

    IPC分类号: H01M4/86 H01M4/88

    摘要: The present invention provides an electrode binder for a polymer electrolyte membrane fuel cell which includes a hydrocarbon-based polymer and a water-soluble polymer acting as a porogen, a porous hydrocarbon-based electrode catalyst layer including the electrode binder, and a method of manufacturing the same. Because of the use of the porogen, the pore size and porosity of the hydrocarbon-based binder catalyst layer are optimized, and bondability of a hydrocarbon-based membrane electrode assembly is enhanced. The present invention also features a fuel cell manufactured using the porogen.

    摘要翻译: 本发明提供了一种用于聚合物电解质膜燃料电池的电极粘合剂,其包括烃基聚合物和用作致孔剂的水溶性聚合物,包含电极粘合剂的多孔烃类电极催化剂层,以及制造方法 一样。 由于使用致孔剂,优化了烃类粘合剂催化剂层的孔径和孔隙率,并且提高了烃系膜电极接合体的结合性。 本发明还特征在于使用致孔剂制造的燃料电池。

    Polymer blend electrolyte membrane for use at high temperature and manufacturing method thereof
    6.
    发明申请
    Polymer blend electrolyte membrane for use at high temperature and manufacturing method thereof 有权
    用于高温的聚合物共混电解质膜及其制造方法

    公开(公告)号:US20090208848A1

    公开(公告)日:2009-08-20

    申请号:US12229302

    申请日:2008-08-20

    IPC分类号: H01M6/18

    摘要: The present invention relates to a polymer blend electrolyte membrane comprising an inorganic polymer having polydimethylsiloxane as a main chain, which has a pore structure at both ends formed by condensation reaction between 3-aminopropyltriethoxysilane and tetraethylorthosilicate, wherein phosphoric acid is chemically linked to an amino group of the pore structure; and a proton-conducting polymer having a cation exchange group at the side chain thereof, as well as a manufacturing method thereof. Generally, proton-conducting electrolyte membranes have significantly reduced ion conductivity at high temperatures. However, proton-conducting electrolyte membranes have advantages in terms of efficiency and cost, and thus it is needed to develop an electrolyte membrane, which has excellent ion conductivity even at high temperature. Accordingly, the present invention aims to provide a polymer blend electrolyte membrane for use at high temperature and a manufacturing method thereof.

    摘要翻译: 本发明涉及一种聚合物共混电解质膜,其包含具有聚二甲基硅氧烷作为主链的无机聚合物,其具有通过3-氨基丙基三乙氧基硅烷和原硅酸四乙酯之间的缩合反应形成的两端的孔结构,其中磷酸与氨基化学连接 的孔结构; 以及其侧链具有阳离子交换基团的质子传导性聚合物及其制造方法。 通常,质子传导电解质膜在高温下具有显着降低的离子传导性。 然而,质子传导性电解质膜在效率和成本方面具有优点,因此需要开发即使在高温下也具有优异的离子传导性的电解质膜。 因此,本发明的目的在于提供一种高温使用的高分子混合电解质膜及其制造方法。

    Electrode binder solution composition for polymer electrolyte fuel cell
    8.
    发明申请
    Electrode binder solution composition for polymer electrolyte fuel cell 审中-公开
    用于聚合物电解质燃料电池的电极粘合剂溶液组合物

    公开(公告)号:US20090280379A1

    公开(公告)日:2009-11-12

    申请号:US12288301

    申请日:2008-10-17

    IPC分类号: H01M8/00

    摘要: The present invention relates to an electrode binder solution composition for a polymer electrolyte fuel cell comprising a mixture of a solvent and a nonsolvent. The electrode binder solution composition can significantly improve electrode activity by maximizing formation of a three-phase interface of catalyst, binder and fuel at the electrode catalytic layer of the polymer electrolyte fuel cell. The present invention relates to a preparation method of an electrode binder solution for a polymer electrolyte fuel cell, the electrode binder solution for a polymer electrolyte fuel cell comprising a sulfonated proton exchange hydrocarbon-based polymer and a mixture of a solvent and a nonsolvent. The present invention also relates to a preparation method of an electrode catalyst slurry comprising the steps of: mixing an electrode binder solution composition for a polymer electrolyte fuel cell with a platinum catalyst and drying the mixture; and heat-treating the dried mixture to maximize interface between the electrode binder and the catalyst.

    摘要翻译: 本发明涉及一种包含溶剂和非溶剂的混合物的固体高分子型燃料电池用电极粘合剂溶液组合物。 电极粘合剂溶液组合物可以通过在聚合物电解质燃料电池的电极催化剂层处最大化催化剂,粘合剂和燃料的三相界面的形成来显着改善电极活性。 本发明涉及一种聚合物电解质燃料电池用电极粘合剂溶液的制备方法,包含磺化质子交换烃类聚合物和溶剂与非溶剂的混合物的固体高分子型燃料电池用电极粘合剂溶液。 本发明还涉及电极催化剂浆料的制备方法,包括以下步骤:将聚合物电解质燃料电池用电极粘合剂溶液组合物与铂催化剂混合并干燥该混合物; 并对干燥的混合物进行热处理以最大化电极粘合剂和催化剂之间的界面。

    POLYMERIC MEA FOR FUEL CELL
    9.
    发明申请
    POLYMERIC MEA FOR FUEL CELL 审中-公开
    用于燃料电池的聚合物MEA

    公开(公告)号:US20090278073A1

    公开(公告)日:2009-11-12

    申请号:US12272964

    申请日:2008-11-18

    IPC分类号: H01G9/028

    摘要: A polymeric electrolyte membrane for a polymer electrolyte membrane fuel cell comprises: (a) a sulfonated polysulfoneketone copolymer comprising an aromatic sulfone repeating unit, an aromatic ketone repeating unit and an aromatic compound repeating unit which connects said repeating units with an ether linkage, wherein the aromatic sulfone repeating unit, the aromatic ketone repeating unit or both have a sulfonic acid or sulfonate substituent; and (b) one or more polymers each comprising a monomer selected from the group consisting of vinylidene fluoride, hexafluoropropylene, trifluoroethylene and tetrafluoroethylene.

    摘要翻译: 一种用于聚合物电解质膜燃料电池的聚合物电解质膜包括:(a)包含芳族砜重复单元,芳族酮重复单元和将所述重复单元与醚键连接的芳族化合物重复单元的磺化聚砜酮共聚物,其中 芳香族砜重复单元,芳族酮重复单元或两者具有磺酸或磺酸盐取代基; 和(b)一种或多种各自包含选自偏二氟乙烯,六氟丙烯,三氟乙烯和四氟乙烯的单体的聚合物。

    Polymer electrolyte membrane and fuel cell comprising same
    10.
    发明申请
    Polymer electrolyte membrane and fuel cell comprising same 审中-公开
    聚合物电解质膜和包含其的燃料电池

    公开(公告)号:US20100279200A1

    公开(公告)日:2010-11-04

    申请号:US11999371

    申请日:2007-12-04

    申请人: Ki Yun Cho

    发明人: Ki Yun Cho

    IPC分类号: H01M8/10

    摘要: The present invention relates to an electrolyte membrane comprising an aluminum-based compound for a high-temperature fuel cell, and a polymer electrolyte membrane fuel cell comprising the electrolyte membrane. In particular, the present invention relates to an electrolyte membrane for a high-temperature fuel cell where an aluminum-based compound is added as an anionic-binding substance in the conventional electrolyte for a fuel cell, thereby improving electrochemical stability of a fuel cell and increasing cation yield of proton by preventing the elution of anions caused by water generation on electrodes, and a high-performance polymer electrolyte membrane fuel cell comprising the electrolyte membrane.

    摘要翻译: 本发明涉及包含用于高温燃料电池的铝基化合物和包含电解质膜的聚合物电解质膜燃料电池的电解质膜。 特别地,本发明涉及用于燃料电池的常规电解质中作为阴离子结合性物质添加铝系化合物的高温型燃料电池用电解质膜,能够提高燃料电池的电化学稳定性, 通过防止由电极产生的水分产生的阴离子的洗脱而提高质子的阳离子收率,以及包含电解质膜的高性能聚合物电解质膜燃料电池。