SURFACE TREATMENT METHOD FOR ELECTRODES, ELECTRODE, AND PROCESS FOR PRODUCING ORGANIC ELECTROLUMINESCENT ELEMENT
    2.
    发明申请
    SURFACE TREATMENT METHOD FOR ELECTRODES, ELECTRODE, AND PROCESS FOR PRODUCING ORGANIC ELECTROLUMINESCENT ELEMENT 审中-公开
    用于生产有机电致发光元件的电极,电极和工艺的表面处理方法

    公开(公告)号:US20120068167A1

    公开(公告)日:2012-03-22

    申请号:US13321392

    申请日:2010-05-18

    CPC classification number: H01L51/5206 H01L2251/308 Y10T428/31663

    Abstract: [Problem] To provide a method for increasing a work function of an electrode by a simple operation and an organic EL element which has an anode of a high work function, exhibits excellent light emission properties (luminous efficiency, lifetime), has a good luminescent surface with small unevenness of luminance and few defects and has low leakage current.[Solution to Problem] A surface treatment method for electrodes, including a contact step of bringing an electrode made from a metal oxide into contact with a solution including a silane compound represented by the following formula (1) and/or a partially hydrolyzed condensate thereof and water, and an organic EL element having a luminescent layer and a cathode laminated in this order on a surface-treated surface of an anode made from a metal oxide, said anode having been surface-treated by the method. Si(OR)p(X)q(OH)4-p-q  (1) wherein in the formula (1), each OR is independently an alkoxy group or an aryloxy group, each X is independently a hydrolyzable group other than the above OR, p is an integer of 1 to 4, q is an integer of 0 to 3, and p+q≦4.

    Abstract translation: 为了提供通过简单的操作提高电极的功函数的方法和具有高功函功能的阳极的有机EL元件,具有优异的发光特性(发光效率,寿命),具有良好的发光性 表面亮度不均匀,缺陷少,漏电流低。 [问题的解决方案]电极的表面处理方法,包括将由金属氧化物制成的电极与包含下式(1)所示的硅烷化合物和/或其部分水解缩合物的溶液接触的接触步骤 和水,以及在由金属氧化物制成的阳极的表面处理表面上依次层叠有发光层和阴极的有机EL元件,所述阳极通过该方法进行表面处理。 Si(OR)p(X)q(OH)4-pq(1)其中在式(1)中,各OR独立地为烷氧基或芳氧基,X各自独立地为除上述OR之外的可水解基团 ,p为1〜4的整数,q为0〜3的整数,p + q≦̸ 4。

    Seamless steel pipe and manufacturing method thereof
    3.
    发明授权
    Seamless steel pipe and manufacturing method thereof 有权
    无缝钢管及其制造方法

    公开(公告)号:US07815755B2

    公开(公告)日:2010-10-19

    申请号:US12010459

    申请日:2008-01-25

    Abstract: The present invention relates to the following seamless steel pipes excellent in strength, toughness and weldability, particularly suitable for submarine flow lines, and a manufacturing method thereof. An as-quenched seamless steel pipe having a chemical composition consisting of, by mass%, C: 0.03 to 0.08%, Mn: 0.3 to 2.5%, Al: 0.001 to 0.10%, Cr: 0.02 to 1.0%, Ni: 0.02 to 1.0%, Mo: 0.02 to 0.8%, Ti: 0.004 to 0.010%, N: 0.002 to 0.008%, Ca: 0.0005 to 0.005%, and the balance Fe and impurities, with not more than 0.25% of Si, not more than 0.05% of P, not more than 0.005% of S, less than 0.005% Nb, and less than 0.0003% of B as the impurities, and having a microstructure consisting of not more than 20 volume% of polygonal ferrite, not more than 10 volume% of a mixed microstructure of martensite and retained austenite, and balance bainite. B can be 0.0003 to 0.001%. Mg and/or REM can be contained. The manufacturing method is characterized by the cooling rate during quenching.

    Abstract translation: 本发明涉及以下具有优异的强度,韧性和焊接性的无缝钢管,特别适用于海底流水线及其制造方法。 一种淬火后的无缝钢管,其组成为以质量%计含有C:0.03〜0.08%,Mn:0.3〜2.5%,Al:0.001〜0.10%,Cr:0.02〜1.0%,Ni:0.02〜 1.0%,Mo:0.02〜0.8%,Ti:0.004〜0.010%,N:0.002〜0.008%,Ca:0.0005〜0.005%,余量为Fe和杂质,不大于0.25% 0.05%的P,不大于0.005%的S,小于0.005%的Nb和小于0.0003%的作为杂质的B,并且具有由不大于20体积%的多边形铁素体组成的微结构,不大于10 马氏体和残留奥氏体的混合显微组织的体积%,以及平衡贝氏体。 B可以为0.0003〜0.001%。 可以含有Mg和/或REM。 制造方法的特征在于淬火时的冷却速度。

    Martensitic stainless steel
    4.
    发明授权
    Martensitic stainless steel 有权
    马氏体不锈钢

    公开(公告)号:US07767039B2

    公开(公告)日:2010-08-03

    申请号:US11335676

    申请日:2006-01-20

    CPC classification number: C22C38/42 C22C38/02 C22C38/04 C22C38/44

    Abstract: A martensitic stainless steel having a resistance to sulfide stress corrosion cracking superior to Super 13 Cr steel and having a strength and corrosion resistance comparable to dual phase stainless steels has a chemical composition consisting essentially of, in mass %, C: 0.001-0.1%, Si: 0.05-1.0%, Mn: 0.05-2.0%, P: at most 0.025%, S: at most 0.010%, Cr: 11-18%, Ni: 1.5-10%, sol. Al: 0.001-0.1%, N: at most 0.1%, O: at most 0.01%, Cu: 0-5%, solid solution Mo: 3.5-7%, the composition satisfying the following Equation (1), optionally at least one element selected from at least one of the following Groups A-C, and a remainder of Fe and impurities and undissolved Mo, if undissolved Mo is present. Ni-bal.=30(C+N)+0.5(Mn+Cu)+Ni+8.2−1.1(Cr+Mo+1.5Si)≧−4.5  Equation (1) Group A—W: 0.2-5% Group B—V: 0.001-0.50%, Nb: 0.001-0.50%, Ti: 0.001-0.50%, and Zr: 0.001-0.50% Group C—Ca: 0.0005-0.05%, Mg: 0.0005-0.05%, REM: 0.0005-0.05%, and B: 0.0001-0.01%.

    Abstract translation: 具有优于超级13Cr钢的具有耐硫化应力腐蚀开裂性且具有与双相不锈钢相当的强度和耐腐蚀性的马氏体不锈钢的化学成分基本上以质量%计含有C:0.001-0.1% Si:0.05〜1.0%,Mn:0.05〜2.0%,P:0.025%以下,S:0.010%以下,Cr:11〜18%,Ni:1.5〜10% Al:0.001-0.1%,N:0.1%以下,O:0.01%以下,Cu:0-5%,固溶Mo:3.5〜7%,满足下述式(1)的组成, 选自以下组AC中的至少一个的元素,以及余量的Fe和杂质以及未溶解的Mo,如果不溶解的Mo存在。 Ni-bal = 30(C + N)+0.5(Mn + Cu)+ Ni + 8.2-1.1(Cr + Mo + 1.5Si)≥-4.5等式(1)组A-W:0.2-5% -V:0.001-0.50%,Nb:0.001-0.50%,Ti:0.001-0.50%,Zr:0.001-0.50%C-Ca:0.0005-0.05%,Mg:0.0005-0.05%,REM: 0.05%,B:0.0001-0.01%。

    Martensitic stainless steel and method for manufacturing same
    5.
    发明授权
    Martensitic stainless steel and method for manufacturing same 有权
    马氏体不锈钢及其制造方法

    公开(公告)号:US07662244B2

    公开(公告)日:2010-02-16

    申请号:US10443821

    申请日:2003-05-23

    Abstract: A martensitic stainless steel provided includes C: 0.01-0.1% and Cr: 9-15%, and the retained austenite phase has a thickness not more than 100 nm in such a manner that the X-ray integral intensities of 111γ and 110α satisfy the following formula (a): 0.005≦111γ/(111γ+110α)≦0.05  (a) Such a metal structure can be obtained by the following procedure: the steel is heated at a temperature of the Ac3 point or more, and then cooled from 800° C. to 400° C. at a cooling rate of not less than 0.08° C./sec and further cooled down to 150° C. at a cooling rate of not more than 1° C./sec. The martensitic stainless steel according to the present invention has a relatively high carbon content and a greater toughness in spite of a high mechanical strength, and further exhibits an excellent corrosion resistance, so that it is particularly effective as the material for constructing a deep oil well.

    Abstract translation: 提供的马氏体不锈钢包括C:0.01-0.1%和Cr:9-15%,并且残留奥氏体相的厚度不大于100nm,使得111gamma和110alpha的X射线积分强度满足 下式(a):0.005 <= 111gamma /(111gamma + 110alpha)这样的金属结构可以通过以下步骤获得:将钢在Ac 3点以上的温度下加热,然后从800℃冷却。 至400℃,冷却速度不低于0.08℃/秒,并以不超过1℃/秒的冷却速度进一步冷却至150℃。 本发明的马氏体系不锈钢虽然具有较高的机械强度,但具有较高的碳含量和较高的韧性,并且还具有优异的耐腐蚀性,因此作为构成深油井的材料特别有效 。

    High strength seamless steel pipe excellent in hydrogen-induced cracking resistance
    6.
    发明授权
    High strength seamless steel pipe excellent in hydrogen-induced cracking resistance 有权
    高强度无缝钢管耐氢腐蚀性能优良

    公开(公告)号:US07416617B2

    公开(公告)日:2008-08-26

    申请号:US11088740

    申请日:2005-03-25

    Abstract: A high strength seamless steel pipe having mgh yield stress and excellent hydrogen-induced cracking resistance, comprises by mass %, C: 0.03-0.11%, Si: 0.05-0.5%, Mn: 0.8-1.6%, p: 0.025% or less, S: 0.003% or less, Ti: 0.002-0.017%, Al: 0.001-0.10%, Cr: 0.05-0.5%, Mo: 0.02-0.3%, V: 0.02-0.20%, Ca 0.0005-0.005%, N: 0.008% or less and O (Oxygen): 0.004% or less, the balance Fe and impurities. The steel microstructure is bainite and/or martensite and ferrite is precipitated at grain boundaries. The seamless steel pipe can contain at least one of Cu: 0.05-0.5% and Ni: 0.05-0.5%. To produce the pipe, it is desirable to limit a starting temperature of quenching after rolling, a cooling rate and a tempering temperature.

    Abstract translation: 具有mgh屈服应力和优异的氢诱发开裂性的高强度无缝钢管以质量%计含有C:0.03〜0.11%,Si:0.05〜0.5%,Mn:0.8〜1.6%,p:0.025%以下 ,S:0.003%以下,Ti:0.002〜0.017%,Al:0.001〜0.10%,Cr:0.05〜0.5%,Mo:0.02〜0.3%,V:0.02〜0.20%,Ca:0.0005〜0.005% :0.008%以下,O(氧):0.004%以下,余量为Fe和杂质。 钢组织为贝氏体和/或马氏体,铁素体在晶界析出。 无缝钢管可以含有Cu:0.05〜0.5%,Ni:0.05〜0.5%中的至少一种。 为了制造管,优选限制轧制后的淬火起始温度,冷却速度和回火温度。

    Martensitic stainless steel
    7.
    发明授权
    Martensitic stainless steel 有权
    马氏体不锈钢

    公开(公告)号:US07361236B2

    公开(公告)日:2008-04-22

    申请号:US10411186

    申请日:2003-04-11

    Abstract: A martensitic stainless steel having a C content of 0.01 to 0.1 mass %, a Cr content of 9 to 15 mass % and a N content of not more than 0.1 mass %, wherein the maximum length of the carbides in the steel is 10 to 200 nm in the direction of the minor axis, or wherein the ratio of the average Cr concentration [Cr] to the average Fe concentration [Fe] in carbides in the steel ([Cr]/[Fe]) is not more than 0.4, or wherein the content of M23C6 type carbides is not more than 1 volume %, the content of M3C type carbides is 0.01 to 1.5 volume % and the content of MN type or M2N type nitrides is not more than 0.3 volume % is provided. This stainless steel has a high toughness in spite of both a relatively more C content and a high strength, thereby providing a, wide applicability to pipe material for oil wells containing carbon dioxide and a small amount of hydrogen sulfide, in particular for oil wells having a much greater depth.

    Abstract translation: C含量为0.01〜0.1质量%,Cr含量为9〜15质量%,N含量为0.1质量%以下的马氏体系不锈钢,其中,碳的最大长度为10〜200 或其中钢中的碳化物中的平均Cr浓度[Cr]与平均Fe浓度[Fe]的比例([Cr] / [Fe]))不大于0.4,或者 其中M 23 C 6 C型碳化物的含量不超过1体积%,M 3 C型碳化物的含量为0.01〜 1.5体积%,并且MN型或M 2 N型氮化物的含量不大于0.3体积%。 该不锈钢虽然具有较高的C含量和较高的强度,但具有较高的韧性,从而为含有二氧化碳和少量硫化氢的油井的管道材料提供了广泛的应用,特别是对于具有 更深的深度

    Seamless steel tubes and method for producing the same
    8.
    发明授权
    Seamless steel tubes and method for producing the same 有权
    无缝钢管及其制造方法

    公开(公告)号:US07316143B2

    公开(公告)日:2008-01-08

    申请号:US11592782

    申请日:2006-11-03

    CPC classification number: C22C38/38 C21D8/105 C21D9/08 Y10S72/70

    Abstract: A seamless steel tube comprising, in mass %, C: 0.30 to 0.50%, Si: 0.5% or less, Mn: 0.3 to 2.0%, P: 0.025% or less, S: 0.005% or less, Cr: 0.15 to 1.0%, Al: 0.001 to 0.05%, Ti: 0.005 to 0.05%, N: 0.02% or less, B: 0.0005 to 0.01% and O (oxygen): 0.0050% or less, wherein Beff defined in following equation (a) or (b) takes a value of 0.0001 or more, where Beff=B−10.8×(N−14×Ti/47.9)/14—(a) when Neff=N−14×Ti/47.9≧0, and Beff=B—(b) when Neff=N−14×Ti/47.9

    Abstract translation: 1.一种无缝钢管,以质量%计含有C:0.30〜0.50%,Si:0.5%以下,Mn:0.3〜2.0%,P:0.025%以下,S:0.005%以下,Cr:0.15〜1.0 %,Al:0.001〜0.05%,Ti:0.005〜0.05%,N:0.02%以下,B:0.0005〜0.01%,O(氧):0.0050%以下, (b)取值为0.0001以上,当Neff = N-14xTi / 47.9> = 0时,Beff = B-10.8x(N-14xTi / 47.9)/ 14-(a),Beff = B- )当Neff = N-14xTi / 47.9 <0时,能够提供具有优异的冷加工性,淬透性,韧性和扭转疲劳强度的无缝钢管,并且最适合用于制造一体式中空驱动轴 以及。

    Boron-containing polymer compound and organic light emitting device using the same
    9.
    发明申请
    Boron-containing polymer compound and organic light emitting device using the same 有权
    含硼高分子化合物和使用其的有机发光装置

    公开(公告)号:US20070167588A1

    公开(公告)日:2007-07-19

    申请号:US10583389

    申请日:2004-12-10

    Abstract: The present invention provides a polymer material showing high luminous efficiency at a low voltage and suitable for increasing the emission area and for the mass production, and an organic light emitting device using the same. The present invention relates to a polymer compound comprising a boron-containing monomer unit represented by formula (1): [in the formula, A represents a triphenyl boron group in which the phenyl group may be substituted, R16 represents a hydrogen atom or an alkyl group having 1 to 12 carbon atoms. X represents a single bond, —O—, —S—, —SO—, —SO2— or a divalent hydrocarbon group having 1 to 20 carbon atoms which may have a hetero atom], a light-emitting polymer compound comprising the boron-containing monomer unit and a light-emitting monomer unit, a light-emitting composition comprising the boron-containing monomer unit and a light-emitting low-molecular compound or light-emitting polymer compound, and organic light-emitting device using the light-emit-ting polymer compound or the light-emitting composition.

    Abstract translation: 本发明提供了一种在低电压下显示高发光效率并且适合于增加发射面积和大规模生产的聚合物材料,以及使用其的有机发光器件。 本发明涉及包含由式(1)表示的含硼单体单元的高分子化合物:[式中,A表示苯基可被取代的三苯基硼基,R 16] >表示氢原子或碳原子数1〜12的烷基。 X表示单键,-O - , - S - , - SO - , - SO 2 - 或可具有杂原子的碳原子数1〜20的二价烃基],光 包含含硼单体单元和发光单体单元的发光组合物,包含含硼单体单元和发光低分子化合物或发光聚合物化合物的发光组合物和有机光 使用发光聚合物化合物或发光组合物的发光装置。

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