Purification of fluoroionomer compositions
    1.
    发明授权
    Purification of fluoroionomer compositions 有权
    氟代离聚物组合物的纯化

    公开(公告)号:US09217045B2

    公开(公告)日:2015-12-22

    申请号:US13132611

    申请日:2009-12-10

    IPC分类号: C08F6/02

    CPC分类号: C08F6/02 C08L27/22 C08L27/12

    摘要: A process for the purification from ionic impurities of a fluoroionomer liquid composition, comprising: providing a liquid composition comprising at least one fluoroionomer (I-1) in a liquid medium, the liquid composition comprising ionic impurities; contacting the liquid composition with a solid particulate comprising at least one fluoroionomer (I-2) having ion exchange groups, wherein H+ or OH− ions are bound to at least a fraction of such ion exchange groups, and separating the liquid composition from the solid particulate.

    摘要翻译: 一种用于从氟离子液体组合物的离子杂质中纯化的方法,包括:在液体介质中提供包含至少一种氟代离聚物(I-1)的液体组合物,所述液体组合物包含离子杂质; 使液体组合物与包含至少一种具有离子交换基团的氟代离聚物(I-2)的固体颗粒接触,其中H +或OH-离子与至少一部分这样的离子交换基团结合,并将液体组合物与固体 微粒。

    Process for operating a fuel cell in dry conditions
    3.
    发明授权
    Process for operating a fuel cell in dry conditions 有权
    在干燥条件下操作燃料电池的方法

    公开(公告)号:US08232012B2

    公开(公告)日:2012-07-31

    申请号:US12520017

    申请日:2007-12-20

    IPC分类号: H01M8/10

    摘要: The invention pertains to a process for operating a polymer electrolyte membrane fuel cell (PEMFC), said PEMFC comprising: (a) a membrane comprising at least one fluorinated ionomer [polymer (I)] comprising recurring units derived from tetrafluoroethylene (TFE) and from at least one monomer of formula (M): wherein m is an integer between 1 and 6 and X′ is chosen among halogens (Cl, F, Br, I), —O−M+, wherein M+ is a cation selected among H+, NH4+, K+, Li+, Na+, or mixtures thereof, said polymer (I) having an equivalent weight (EW) of from 700 to 850 g/eq.; (b) a cathode; (c) an anode; said process comprising: (i) feeding gaseous reactants at the electrodes at a relative humidity of at most 66%; (ii) maintaining an average current density between 0.05 and 1.5 A/cm2; and (iii) maintaining an average temperature of more than 65° C.

    摘要翻译: 本发明涉及一种操作聚合物电解质膜燃料电池(PEMFC)的方法,所述PEMFC包括:(a)包含至少一种氟化离聚物[聚合物(I)]的膜,其包含衍生自四氟乙烯(TFE)的重复单元和 至少一种式(M)的单体:其中m是1和6之间的整数,X'选自卤素(Cl,F,Br,I),-O-M +,其中M +是选自H +, NH 4 +,K +,Li +,Na +或其混合物,所述聚合物(I)的当量重量(EW)为700至850g / eq; (b)阴极; (c)阳极; 所述方法包括:(i)在至多66%的相对湿度下在电极处输入气态反应物; (ii)保持0.05至1.5A / cm2之间的平均电流密度; 和(iii)保持超过65℃的平均温度。

    CCM COMPOSITE
    5.
    发明申请
    CCM COMPOSITE 有权
    CCM复合材料

    公开(公告)号:US20110052798A1

    公开(公告)日:2011-03-03

    申请号:US12890473

    申请日:2010-09-24

    IPC分类号: H01M8/10 H01M8/00

    摘要: CCM formed of a membrane having on one of the two surfaces a first electrocatalytic layer containing a catalyst and on the other one a second electrocatalytic layer containing a catalyst, said electrocatalytic layers and said membrane containing (per)fluorinated ionomers, said CCM having the following characteristics: size variations, for both the orthogonal directions of the plane xy, lower than 15%, by dipping the CCM, after drying at 105° C. under vacuum for one hour in demineralized water at 100° C. for 30 minutes; the CCM remains substantially unchanged after having been subjected to treatments of 60 cycles by dipping in water at 80° C. for 8 hours and then in water at the temperature of 25° C. for 16 hours.

    摘要翻译: CCM由具有在两个表面中的一个表面上的含有催化剂的第一电催化剂层和另一个包含催化剂的第二电催化剂层,所述电催化层和所述膜含有(全)氟化离聚物,所述CCM具有以下 特性:在105℃下在100℃下在软化水中真空干燥1小时30分钟后,通过浸渍CCM,平面xy的正交方向,低于15%的尺寸变化,小于15% 在经过80℃的水中浸渍8小时,然后在25℃的水中浸渍16小时后,经过60个循环的处理后,CCM基本上保持不变。

    Process for manufacturing a tyre and tyre bead structure
    6.
    发明申请
    Process for manufacturing a tyre and tyre bead structure 审中-公开
    制造轮胎和轮胎胎圈结构的方法

    公开(公告)号:US20100276054A1

    公开(公告)日:2010-11-04

    申请号:US12311825

    申请日:2006-10-16

    摘要: Process for manufacturing a tyre, includes the following steps: (a) winding at least one metal wire so as to form a plurality of coils, the coils being radially superimposed and axially arranged side-by-side with respect to one another, so as to obtain a bead core; (b) applying at least one layer of a crosslinkable elastomeric material to the bead core obtained in step (a), so as to obtain a coated bead core; (c) partially crosslinking the at least one layer of crosslinkable elastomeric material, so as to obtain an amount of free sulfur of 30% by weight to 70% by weight, preferably of 40% by weight to 65% by weight, more preferably of 50% by weight to 60% by weight, with respect to the total weight of the sulfur present in the crosslinkable elastomeric material; and (d) applying a bead filler to the radial outer surface of the bead core obtained in step (c), so as to obtain a bead structure for a green tyre.

    摘要翻译: 制造轮胎的方法包括以下步骤:(a)卷绕至少一根金属线以形成多个线圈,所述线圈相对于彼此并排地径向重叠并且轴向布置,以便 获得珠芯; (b)将至少一层可交联弹性体材料施加到步骤(a)中获得的珠芯上,以获得涂覆的珠芯; (c)部分地交联至少一层可交联弹性体材料,以获得30重量%至70重量%,优选40重量%至65重量%的游离硫的量,更优选 相对于存在于可交联弹性体材料中的硫的总重量为50重量%至60重量%; 和(d)在步骤(c)中获得的胎圈芯的径向外表面上施加胎圈填料,以获得生胎的胎圈结构。

    FLEXIBLE SPACER FOR DOUBLE-GLAZING
    8.
    发明申请
    FLEXIBLE SPACER FOR DOUBLE-GLAZING 审中-公开
    灵活的间隔器双重玻璃

    公开(公告)号:US20160265265A1

    公开(公告)日:2016-09-15

    申请号:US15031411

    申请日:2014-10-21

    申请人: Luca MERLO

    发明人: Luca MERLO

    摘要: A description is made of a flexible spacer for double glazing made of Polyisobutylene elastomer or butyl rubber IIR (simple or halogenated), suitably loaded with both reinforcing and inert fillers. The spacer can be cross-linked with sulphur or peroxides. The spacer is impermeable to moisture and has high low thermal conductivity gas sealing capacity, and incorporates moisture absorbing material. In particular, the spacer features—on each side wall—at least a small wave (13a) positioned immediately above the accumulation area of the internal or primary sealant (15) so as to ensure an optimal adhesion to the glass of the double/triple glazing unit within which the spacer is fitted and features at least one recess (13b), with a configuration such as to allow the external sealant to penetrate and create a strong mechanical bond between the two materials.

    摘要翻译: 描述了由适用于加强和惰性填料的聚异丁烯弹性体或丁基橡胶IIR(简单或卤化)制成的双层玻璃的柔性间隔物。 间隔物可以与硫或过氧化物交联。 间隔物不透水,具有低导热气体密封能力,并含有吸湿材料。 特别地,间隔物特征在于每个侧壁 - 至少一个位于内部或主要密封剂(15)的积聚区域正上方的小波(13a),以便确保对双/三重玻璃的玻璃的最佳粘附 玻璃单元,其中安装有间隔件,并且具有至少一个凹部(13b),其具有允许外部密封剂穿透并在两种材料之间产生强力机械结合的构造。

    PROCESS FOR THE PREPARATION OF CROSS-LINKED FLUORINATED POLYMERS
    9.
    发明申请
    PROCESS FOR THE PREPARATION OF CROSS-LINKED FLUORINATED POLYMERS 有权
    制备交联氟化聚合物的方法

    公开(公告)号:US20140017599A1

    公开(公告)日:2014-01-16

    申请号:US14007117

    申请日:2012-04-04

    IPC分类号: B01J39/20

    摘要: A process for the preparation of cross-linked fluorinated polymers comprising sulfonic acid functional groups comprising the steps of: a) providing at least one fluorinated polymer (P) comprising at least one —SO3M functional group and less than 2% of —SO2F functional groups with respect to the total amount of —SO3M and —SO2F functional groups, wherein each M is selected from H and alkaline metals; and b) reacting said fluorinated polymer with at least one cross-linking agent of formula R(X)n under conditions that promote the formation of covalent bonds between the at least one functional group —SO3M of fluorinated polymer (P) and at least one functional group X of the cross-linking agent.

    摘要翻译: 一种制备包含磺酸官能团的交联氟化聚合物的方法,包括以下步骤:a)提供至少一种包含至少一个-SO 3 M官能团和少于2%的-SO 2 F官能团的氟化聚合物(P) 相对于-SO 3 M和-SO 2 F官能团的总量,其中每个M选自H和碱金属; 和b)使所述含氟聚合物与至少一种式R(X)n交联剂在促进氟化聚合物(P)的至少一种官能团-SO 3 M与至少一个 交联剂的官能团X。