公开(公告)号：US5374184A

公开(公告)日：1994-12-20

申请号：US222393

申请日：1994-04-04

申请人： Stephan J. W. Platzer ,  Gerhard Buhr ,  Manfred Michel ,  Andrea Buchmann

发明人： Stephan J. W. Platzer ,  Gerhard Buhr ,  Manfred Michel ,  Andrea Buchmann

IPC分类号： G03F3/10 ,  G03F7/004 ,  G03F7/027 ,  G03F7/028 ,  G03F7/105 ,  G03F7/11 ,  G03F7/34 ,  G03C11/12

CPC分类号： G03F3/106 ,  G03F7/34

摘要： A photopolymerizable material having(A) a flexible, transparent film support;(B) a colored, polymerizable layer containing an organic binder, a free-radical-polymerizable compound, containing at least one terminal ethylenically unsaturated group, and a dye or colored pigment;(C) an adhesion layer containing a thermoplastic polymer and having a T.sub.g of from 25.degree. to 100.degree. C.; and(D) an uncolored photopolymerizable layer which contains a polymeric organic binder, a free-radical-polymerizable compound containing at least one terminal ethylenically unsaturated group and a photopolymerization initiator between the film support (A) and the colored polymerizable layer (B),where the cohesion of layers (B), (C) and (D) and the adhesion of these layers to one another and to the film support (A) provides the relationship wherein the adhesion (a.sub.2) of the photopolymerizable layer (D) to the colored layer (B) in the unexposed state is lower than: (i) the adhesion (a.sub.3) of the colored layer (B) to the adhesion layer (C); (ii) the adhesion (a.sub.1) of the photopolymerizable layer (D) to the film support (A); and (iii) the cohesion (c.sub.1), (c.sub.2) and (c.sub.3) of layers (D), (B) and (C) and the adhesion (a.sub.3 ') of the colored layer (B) to the adhesion layer (C) in the exposed state is lower than: (i) the adhesion (a.sub.1 ') of the photopolymerized layer (D) to the film support (A); (ii) the adhesion (a.sub.2 ') of the photopolymerized layer (D) to the colored layer (B); and (iii) than the cohesion (c.sub.1 '), (c.sub.2 ') and (c.sub.3 ') of layers (D) , (B) and (C). The material is processed by "peel-apart" development and yields color images with lower background discoloration.

摘要翻译： 一种可光聚合材料，其具有（A）柔性透明膜载体; （B）含有有机粘合剂，含有至少一个末端烯属不饱和基团的自由基聚合性化合物和染料或着色颜料的着色聚合层; （C）含有热塑性聚合物的Tg为25〜100℃的粘合层。 和（D）含有聚合有机粘合剂，含有至少一个末端烯属不饱和基团的自由基聚合性化合物和薄膜载体（A）和着色聚合层（B）之间的光聚合引发剂的未着色光聚合层， 其中层（B），（C）和（D）的内聚力以及这些层彼此和膜载体（A）的粘附性提供了这样的关系，其中可光聚合层（D）的粘合力（a2） 未曝光状态下的着色层（B）低于（i）着色层（B）对粘合层（C）的粘合力（a3）。 （ii）可光聚合层（D）与膜载体（A）的粘合（a1）; 和（iii）层（D），（B）和（C）的层压（c1），（c2）和（c3）和着色层（B）对粘合层（C ）低于（i）光聚合层（D）与膜载体（A）的粘合力（a1'）; （ii）光聚合层（D）与着色层（B）的粘合（a2'）; 和（iii）层（D），（B）和（C）的内聚力（c1'），（c2'）和（c3'）。 通过“剥离”开发处理材料，并产生具有较低背景变色的彩色图像。

公开(公告)号：US4814246A

公开(公告)日：1989-03-21

申请号：US38972

申请日：1987-04-16

申请人： Peter Lehmann ,  Manfred Michel

发明人： Peter Lehmann ,  Manfred Michel

IPC分类号： H05K3/00 ,  G03F1/00 ,  G03F7/00 ,  G03G5/153 ,  G03G13/26 ,  H05K3/06 ,  G03G5/14

CPC分类号： G03F7/2018 ,  G03G13/26 ,  G03G5/153 ,  H05K3/065

摘要： The disclosed light-sensitive recording material is composed of an electrically conductive support, suitable for the production of printing forms or printed circuits, an a photoconductive layer system containing a photoconductor, a binder, a sensitizing dye and conventional additives. The photoconductive system comprises (A) a single photoconductive layer, or multiple layers, applied to the support and (B) a light-sensitive covering layer which contains at least one photochemically reactive compound. The use of the recording material in a process for the production of printing forms and printed circuits is also disclosed.

摘要翻译： 所公开的光敏记录材料由适用于生产印刷形式或印刷电路的导电支撑体，含有光电导体，粘合剂，增感染料和常规添加剂的光导层组成。 光导体系包括（A）施加到载体上的单个光电导层或多层，和（B）含有至少一种光化学反应性化合物的光敏覆盖层。 还公开了在生产印刷版和印刷电路的方法中使用记录材料。

公开(公告)号：US4687726A

公开(公告)日：1987-08-18

申请号：US731778

申请日：1985-05-08

申请人： Gunter Schlogl ,  Gerhard Mack ,  Manfred Michel

发明人： Gunter Schlogl ,  Gerhard Mack ,  Manfred Michel

IPC分类号： G03F7/30 ,  G03F7/00 ,  G03F7/115 ,  G03C1/60 ,  G03C1/76

CPC分类号： G03F7/115 ,  Y10S430/146 ,  Y10S430/151

摘要： Disclosed are a novel photosensitive recording material and a method for using the recording material in the production of planographic printing plates. The recording material comprises a support and a negative-working photosensitive layer that contains a diazonium salt polycondensation product as the photosensitive compound and, in addition, a colorless inorganic pigment which is insoluble in water and organic solvents and which has an average particle diameter from 1 to 20 .mu.m. The pigment is present in a quantity from 0.01 to 2% by weight, relative to the non-volatile constituents of the layer, and is evenly distributed in the layer. Due to the pigment content, a rough layer surface is formed, which has the effect of reducing the time required for creating a vacuum in a vacuum frame into which the recording material is mounted. The presence of the pigment in the layer also produces an improved tonal rendering in the print obtained.

摘要翻译： 公开了一种新颖的光敏记录材料和在制备平版印刷版中使用该记录材料的方法。 记录材料包括载体和负性感光层，其含有重氮盐缩聚产物作为感光性化合物，另外还含有不溶于水和有机溶剂的无色无机颜料，其平均粒径为1 至20亩。 相对于该层的非挥发性组分，颜料的存在量为0.01至2重量％，并且均匀分布在该层中。 由于颜料含量，形成粗糙层表面，其具有减少在安装记录材料的真空框架中产生真空所需的时间的效果。 颜料在层中的存在也会在所得印刷品中产生改善的色调渲染。

公开(公告)号：US4680244A

公开(公告)日：1987-07-14

申请号：US712660

申请日：1985-03-18

申请人： Peter Lehmann ,  Manfred Michel

发明人： Peter Lehmann ,  Manfred Michel

IPC分类号： H05K3/00 ,  G03F1/00 ,  G03F7/00 ,  G03G5/153 ,  G03G13/26 ,  H05K3/06 ,  G03C5/14 ,  G03C1/495 ,  G03C1/54

CPC分类号： G03F7/2018 ,  G03G13/26 ,  G03G5/153 ,  H05K3/065

摘要： The disclosed light-sensitive recording material is composed of an electrically conductive support, suitable for the production of printing forms or printed circuits, and a photoconductive layer system containing a photoconductor, a binder, a sensitizing dye and conventional additives. The photoconductive system comprises (A) a single photoconductive layer, or multiple layers, applied to the support and (B) a light-sensitive covering layer which contains at least one photochemically reactive compound. The use of the recording material in a process for the production of printing forms and printed circuits is also disclosed.

摘要翻译： 所公开的光敏记录材料由适用于生产印刷形式或印刷电路的导电支撑体以及含有光电导体，粘合剂，增感染料和常规添加剂的光电导层系统组成。 光导体系包括（A）施加到载体上的单个光电导层或多层，和（B）含有至少一种光化学反应性化合物的光敏覆盖层。 还公开了在生产印刷版和印刷电路的方法中使用记录材料。

公开(公告)号：US5348833A

公开(公告)日：1994-09-20

申请号：US939909

申请日：1992-09-04

申请人： Dieter Mohr ,  Martin Benzing ,  Juergen Mertes ,  Guenter Hultzsch ,  Ine Gramm ,  Manfred Michel ,  Andreas Elsaesser ,  Shane Hsieh ,  David L. Siegfried

发明人： Dieter Mohr ,  Martin Benzing ,  Juergen Mertes ,  Guenter Hultzsch ,  Ine Gramm ,  Manfred Michel ,  Andreas Elsaesser ,  Shane Hsieh ,  David L. Siegfried

IPC分类号： G03F3/10 ,  G03F7/023 ,  G03F7/105 ,  G03F7/11

CPC分类号： G03F7/0233 ,  G03F3/10

摘要： The invention relates to a positive-working colored photosensitive recording material for the production of a color test image, composed of a temporary layer carrier, a photosensitive layer containing dyestuff or pigment, binder and quinonediazide compound and an adhesive layer which can be activated by means of heat, wherein a release layer based on polyvinyl alcohol is present on the surface of the temporary layer carrier, the photosensitive layer comprises, as the quinonediazide compound, an esterification product of a compound containing one or more phenolic hydroxyl groups and o-quinonediazide-sulfonyl chloride, and, as the binder, a novolak-free phenolic polymer resin and/or a reaction product of the phenolic polymer resin with a monoisocyanate, and the adhesive layer compresses a alkali-insoluble organic polymer and an alkali-soluble polyester. The invention also relates to a process for the production of a color test image using the recording material described.

摘要翻译： 本发明涉及一种用于生产彩色试验图像的正色彩色光敏记录材料，由临时层载体，含有染料或颜料的感光层，粘合剂和醌二叠氮化合物组成，粘合剂层可通过手段 的热量，其中基于聚乙烯醇的剥离层存在于临时层载体的表面上，感光层包含作为醌二叠氮化合物的含有一个或多个酚羟基的化合物和邻醌二叠氮化物的酯化产物， 磺酰氯，作为粘合剂，不含酚醛清漆的酚醛聚合物树脂和/或酚醛聚合物树脂与单异氰酸酯的反应产物，并且粘合剂层压制碱不溶性有机聚合物和碱溶性聚酯。 本发明还涉及使用所述记录材料生产彩色测试图像的方法。

公开(公告)号：US6074798A

公开(公告)日：2000-06-13

申请号：US196742

申请日：1998-11-20

申请人： Jurgen Mertes ,  Manfred Michel

发明人： Jurgen Mertes ,  Manfred Michel

IPC分类号： G03F7/004 ,  G03F3/10 ,  G03F7/34 ,  G03C11/12

CPC分类号： G03F3/102 ,  G03F7/34

摘要： The invention relates to a radiation-sensitive material comprising A) a multilayer support material, B) a colored photopolymerizable layer, and C) an adhesive layer. The multilayer support material consists of at least two sheet-form materials, which are bonded to one another in such a way that the adhesion between the two sheet-form materials is less than the adhesion between the radiation-sensitive layer and the adjacent support material. The invention furthermore relates to a process in which a colored image, in particular a multicolored image comprising a plurality of primary-color images, is produced on an image-receiving material. The color images are produced by laminating a colored photopolymerizable layer onto the image-receiving material, exposing the material under the relevant master, in particular a color separation, developing the image by peeling-off the support film from the photopolymerizable layer together with the non-image areas, and, if desired, repeating the same steps with a photopolymerizable layer in a different color.

摘要翻译： 本发明涉及一种辐射敏感材料，其包括A）多层载体材料，B）着色的可光聚合层，和C）粘合剂层。 多层载体材料由至少两种片状材料组成，这两种片状材料彼此粘合，使两个片状材料之间的粘合力小于辐射敏感层和相邻载体材料之间的粘合性 。 本发明还涉及在图像接收材料上产生彩色图像，特别是包括多个原色图像的多色图像的过程。 彩色图像是通过将着色的可光聚合层层压到图像接收材料上，将相关母版下的材料曝光，特别是颜色分离，通过从支持膜与可光聚合层一起剥离来显影图像而产生的， 图像区域，如果需要，用不同颜色的可光聚合层重复相同的步骤。

公开(公告)号：US5436106A

公开(公告)日：1995-07-25

申请号：US273071

申请日：1994-07-11

申请人： Dieter Mohr ,  Martin Benzing ,  Juergen Mertes ,  Guenter Hultzsch ,  Ine Gramm ,  Manfred Michel ,  Andreas Elsaesser ,  Shane Hsieh ,  David L. Siegfried

发明人： Dieter Mohr ,  Martin Benzing ,  Juergen Mertes ,  Guenter Hultzsch ,  Ine Gramm ,  Manfred Michel ,  Andreas Elsaesser ,  Shane Hsieh ,  David L. Siegfried

IPC分类号： G03F3/10 ,  G03F7/023 ,  G03F7/105 ,  G03F7/30

CPC分类号： G03F7/0233 ,  G03F3/10

摘要： The invention relates to a positive-working colored photosensitive recording material for the production of a color test image, composed of a temporary layer carrier, a photosensitive layer containing dyestuff or pigment, binder and quinonediazide compound and an adhesive layer which can be activated by means of heat, wherein a release layer based on polyvinyl alcohol is present on the surface of the temporary layer carrier, the photosensitive layer comprises, as the quinonediazide compound, an esterification product of a compound containing one or more phenolic hydroxyl groups and o-quinonediazide-sulfonyl chloride, and, as the binder, a novolak-free phenolic polymer resin and/or a reaction product of the phenolic polymer resin with a monoisocyanate, and the adhesive layer comprises a alkali-insoluble organic polymer and an alkali-soluble polyester. The invention also relates to a process for the production of a color test image using the recording material described.

摘要翻译： 本发明涉及一种用于生产彩色试验图像的正色彩色光敏记录材料，由临时层载体，含有染料或颜料的感光层，粘合剂和醌二叠氮化合物组成，粘合剂层可通过手段 的热量，其中基于聚乙烯醇的剥离层存在于临时层载体的表面上，感光层包含作为醌二叠氮化合物的含有一个或多个酚羟基的化合物和邻醌二叠氮化物的酯化产物， 磺酰氯和作为粘合剂的无酚醛清漆的酚醛聚合物树脂和/或酚醛聚合物树脂与单异氰酸酯的反应产物，并且粘合剂层包含碱不溶性有机聚合物和碱溶性聚酯。 本发明还涉及使用所述记录材料生产彩色测试图像的方法。