摘要:
Catalyst solid for olefin polymerization comprising A) at least one calcined hydrotalcite and B) at least one organic transition metal compound, and also a catalyst system comprising the catalyst solid, the use of the catalyst solid for the polymerization or copolymerization of olefins and a process for preparing polyolefins by polymerization or copolymerization of olefins in the presence of the catalyst solid.
摘要:
The present invention relates to organometallic transition metal compounds of the formula (I) Z1AnZ2MXm (I) where Z1 is a coordinating group which comprises a six-π-electron central group which coordinates directly to M, A is a divalent bridge between the groups Z1 and Z2, Z2 is a coordinating group having the same meaning as Z1 or is a group comprising an open pentadienyl, a cyclopentadienyl-containing group or a heterocyclic, 5- or 6-membered group containing six π electrons, n=zero or 1, M is an element of group 3, 4, 5 or 6 of the Periodic Table of the Elements, the radicals X are identical or different and are each an organic or inorganic radical, m is 0, 1 or 2, and at least one of the three molecule fragments Z1, Z2 and A bears a monovalent organic radical.
摘要:
Catalyst system for olefin polymerization comprising A) at least one calcined hydrotalcite, B) at least one organic transition metal compound, C) optionally one or more cation-forming compounds and D) at least one organic magnesium compound.
摘要:
A continuous gas-phase process for the polymerization of alpha-olefins, in particular ethylene, comprising passing an alpha-olefin monomer stream through an oil filter in order to reduce the amount of oil to less than 8 ppm, and polymerizing the thus purified monomer feed in gas-phase reactor; the reduction of the amount of oil improves the operability of the plant over time.
摘要:
A continuous gas-phase process for the polymerization of alpha-olefins, in particular ethylene, comprising passing an alpha-olefin monomer stream through an oil filter in order to reduce the amount of oil to less than 8 ppm, and polymerizing the thus purified monomer feed in gas-phase reactor; the reduction of the amount of oil improves the operability of the plant over time.
摘要:
The present invention relates to organometallic transition metal compounds of the formula (I) Z1AnZ2MXm (I) where Z1 is a coordinating group which comprises a six-π-electron central group which coordinates directly to M, A is a divalent bridge between the groups Z1 and Z2, Z2 is a coordinating group having the same meaning as Z1 or is a group comprising an open pentadienyl, a cyclopentadienyl-containing group or a heterocyclic, 5- or 6-membered group containing six π electrons, n=zero or 1, M is an element of group 3, 4, 5 or 6 of the Periodic Table of the Elements, the radicals X are identical or different and are each an organic or inorganic radical, m is 0, 1 or 2, and at least one of the three molecule fragments Z1, Z2 and A bears a monovalent organic radical.
摘要翻译:本发明涉及式(I)Z1AnZ2MXm(I)的有机金属过渡金属化合物,其中Z1是包括与M直接配位的六元电子中心基团的配位基团,A是组之间的二价桥接 Z 1和Z 2中,Z 2是具有与Z1相同含义的配位基团,或者是包含开式戊二烯基,含环戊二烯基的基团或杂环基,含有6个碳原子的5或6元基团; 电子,n = 0或1,M是元素周期表第3,4,5或6族的元素,基团X相同或不同,各自为有机或无机基团,m为0,1 或2,并且三个分子片段Z1,Z2和A中的至少一个具有一价有机基团。
摘要:
The present invention relates to catalyst system containing at least one imidochrome compound and at least one activation compound. This invention also relates to imidochrome compounds, to a method for olefin polymerization and to methods for producing said imidochrome compounds.
摘要:
The present invention relates to catalyst system containing at least one imidochrome compound and at least one activation compound. This invention also relates to imidochrome compounds, to a method for olefin polymerization and to methods for producing said imidochrome compounds.