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公开(公告)号：US09115032B2
公开(公告)日：2015-08-25
申请号：US13702282
申请日：2012-02-23
CPC分类号： C04B35/50 , B22F1/0085 , C04B35/42 , C04B35/64 , C04B2235/3205 , C04B2235/3206 , C04B2235/3213 , C04B2235/3224 , C04B2235/3225 , C04B2235/3227 , C04B2235/3239 , C04B2235/3244 , C04B2235/3262 , C04B2235/3263 , C04B2235/3268 , C04B2235/3275 , C04B2235/3284 , C04B2235/443 , C04B2235/449 , C04B2235/5409 , C04B2235/6562 , C04B2235/6565 , C04B2235/6567 , C04B2235/77 , C04B2235/80
摘要： This disclosure relates to a method of densifying a lanthanide chromite ceramic or a mixture containing a lanthanide chromite ceramic. The method comprises mixing one or more lanthanide chromite ceramics with one or more sintering aids, and sintering the mixture. The one or more lanthanide chromite ceramics are represented by the formula (Ln1-xAEx)zCr1-yByO3-δ, wherein Ln is a lanthanide element or yttrium, AE is one or more alkaline earth elements, B is one or more transition metals, x is a value less than 1, y is a value less than or equal to 0.5, and z is a value from 0.8 to 1.2. The sintering aids comprise one or more spinel oxides. The one or more spinel oxides are represented by the formula AB2O4 or A2BO4 wherein A and B are cationic materials having an affinity for B-site occupancy in a lanthanide chromite ceramic structure, e.g., ZnMn2O4, MgMn2O4, MnMn2O4 and CoMn2O4. This disclosure also relates in part to products, e.g., dense ceramic structures produced by the above method.
摘要翻译： 本公开涉及致密化镧系铬铁矿陶瓷或含有镧系铬铁矿陶瓷的混合物的方法。 该方法包括将一种或多种镧系亚铬酸盐陶瓷与一种或多种烧结助剂混合，并烧结该混合物。 一种或多种镧系亚铬酸盐陶瓷由式（Ln1-xAEx）zCr1-yByO3-δ表示，其中Ln是镧系元素或钇，AE是一种或多种碱土金属元素，B是一种或多种过渡金属，x 是小于1的值，y是小于或等于0.5的值，z是0.8至1.2的值。 烧结助剂包括一种或多种尖晶石氧化物。 一种或多种尖晶石氧化物由式AB2O4或A2BO4表示，其中A和B是对镧系铬铁矿陶瓷结构中的B位占据的亲和性的阳离子材料，例如ZnMn 2 O 4，MgMn 2 O 4，MnMn 2 O 4和CoMn 2 O 4。 本公开还部分地涉及产品，例如通过上述方法制备的致密陶瓷结构。
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公开(公告)号：US07595127B2
公开(公告)日：2009-09-29
申请号：US10185496
申请日：2002-06-28
CPC分类号： H01M4/8621 , C04B35/016 , C04B35/2633 , C04B35/486 , C04B35/488 , C04B35/50 , C04B35/6261 , C04B35/6262 , C04B35/62625 , C04B35/6263 , C04B35/63 , C04B35/6303 , C04B41/009 , C04B41/5036 , C04B41/87 , C04B2111/00853 , C04B2235/3213 , C04B2235/3224 , C04B2235/3225 , C04B2235/3227 , C04B2235/3229 , C04B2235/3246 , C04B2235/3262 , C04B2235/3272 , C04B2235/3275 , C04B2235/3279 , C04B2235/405 , C04B2235/449 , C04B2235/5409 , C04B2235/77 , C04B2235/80 , C04B2235/96 , H01M4/0402 , H01M4/0407 , H01M4/0471 , H01M4/8652 , H01M4/8885 , H01M4/9016 , H01M4/9033 , H01M4/9066 , H01M8/1226 , H01M8/1231 , H01M8/1246 , H01M2008/1293 , Y02E60/525 , Y02P70/56 , C04B41/4539 , C04B41/4549 , C04B41/5045
摘要： A method of making ceramic electrode materials comprising intimate mixtures of two or more components, including at least one nanoscale ionically conducting ceramic electrolyte material (e.g., yttrium-stabilized zirconia, gadolinium-doped ceria, samarium-doped ceria, etc.) and at least one powder of an electrode material, which may be an electrically conducting ceramic electrode material (e.g., lanthanum strontium manganite, praseodymium strontium manganese iron oxide, lanthanum strontium ferrite, lanthanum strontium cobalt ferrite, etc.) or a precursor of a metallic electrode material (e.g., nickel oxide, copper oxide, etc.). The invention also includes anode and cathode coatings and substrates for solid oxide fuel cells prepared by this method.
摘要翻译： 制备包括两种或多种组分的紧密混合物的陶瓷电极材料的方法，包括至少一种纳米尺度的离子导电陶瓷电解质材料（例如，钇稳定的氧化锆，掺杂钆的二氧化铈，钐掺杂的氧化铈等）和至少 电极材料的一种粉末，其可以是导电陶瓷电极材料（例如锰酸镧锶锰氧化铁，镧铁酸锶铁氧体，镧钴锶钴铁氧体等）或金属电极材料的前体（ 例如氧化镍，氧化铜等）。 本发明还包括通过该方法制备的阳极和阴极涂层和用于固体氧化物燃料电池的衬底。
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公开(公告)号：US07261833B2
公开(公告)日：2007-08-28
申请号：US10889234
申请日：2004-07-12
IPC分类号： H01G9/02
CPC分类号： C04B41/5042 , B82Y30/00 , C04B35/016 , C04B35/486 , C04B35/626 , C04B35/6261 , C04B35/62625 , C04B35/6263 , C04B35/63 , C04B35/634 , C04B41/009 , C04B41/87 , C04B2111/00853 , C04B2235/3213 , C04B2235/3224 , C04B2235/3225 , C04B2235/3227 , C04B2235/3246 , C04B2235/3268 , C04B2235/442 , C04B2235/5409 , C04B2235/5445 , C04B2235/5454 , C04B2235/5472 , C04B2235/5481 , C04B2235/6025 , H01M8/1213 , H01M8/1246 , H01M8/1253 , H01M2300/0071 , Y02E60/525 , Y02P70/56 , C04B41/4539 , C04B41/4549 , C04B35/48 , C04B38/00
摘要： Aqueous coating slurries useful in depositing a dense coating of a ceramic electrolyte material (e.g., yttrium-stabilized zirconia) onto a porous substrate of a ceramic electrode material (e.g., lanthanum strontium manganite or nickel/zirconia) and processes for preparing an aqueous suspension of a ceramic electrolyte material and an aqueous spray coating slurry including a ceramic electrolyte material. The invention also includes processes for depositing an aqueous spray coating slurry including a ceramic electrolyte material onto pre-sintered, partially sintered, and unsintered ceramic substrates and products made by this process.
摘要翻译： 用于将陶瓷电解质材料（例如，钇稳定的氧化锆）的致密涂层沉积到陶瓷电极材料（例如，镧锶锰矿或镍/氧化锆）的多孔基材上的水性涂料浆料以及用于制备 陶瓷电解质材料和包含陶瓷电解质材料的水性喷涂浆料。 本发明还包括将包含陶瓷电解质材料的水性喷涂浆料沉积到预烧结的，部分烧结的和未烧结的陶瓷基底上的方法以及通过该方法制备的产品。
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公开(公告)号：US08192888B2
公开(公告)日：2012-06-05
申请号：US11109471
申请日：2005-04-19
IPC分类号： H01M8/12
CPC分类号： B01D67/0041 , B01D69/06 , B01D69/10 , B01D71/024 , B01D2325/08 , B01D2325/26 , C01B13/0255 , H01M4/8828 , H01M4/8839 , H01M4/8889 , H01M4/9033 , H01M4/9066 , H01M8/1226 , H01M8/1253 , H01M2300/0077 , H01M2300/0094 , Y02E60/525 , Y02P70/56
摘要： Self-supporting thin film membranes of ceramic materials and related electrochemical cells and cell stacks. The membrane structure is divided into a plurality of self-supporting thin membrane regions by a network of thicker integrated support ribs. The membrane structure may be prepared by laminating a thin electrolyte layer with a thicker ceramic layer that forms a network of support ribs.
摘要翻译： 陶瓷材料的自支撑薄膜和相关的电化学电池和电池堆。 膜结构通过较厚的整体支撑肋的网络分成多个自支撑薄膜区域。 膜结构可以通过层叠具有形成支撑肋网络的较厚陶瓷层的薄电解质层来制备。
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5.发明授权Supported ceramic membranes and electrochemical cells and cell stacks including the same 失效支持的陶瓷膜和电化学电池和电池堆包括它们公开(公告)号：US07767358B2
公开(公告)日：2010-08-03
申请号：US11141259
申请日：2005-05-31
CPC分类号： H01M8/1226 , B01D67/0041 , B01D69/02 , B01D69/12 , B01D69/125 , B01D71/024 , B01D2325/02 , C04B38/0675 , C04B38/068 , C04B2111/00612 , C04B2111/00801 , C04B2111/00853 , H01M8/124 , H01M8/1253 , H01M2008/1293 , H01M2300/0094 , Y02E60/525 , Y02P70/56 , C04B35/48 , C04B38/0054 , C04B38/0074
摘要： A dense ceramic electrolyte membrane supported by symmetrical porous ceramic electrolyte layers. The thin (t
摘要翻译： 由对称多孔陶瓷电解质层支撑的致密陶瓷电解质膜。 薄（t <100微米）电解质层被夹在两个在烧成后变得高度多孔的含有逸散剂的电解质支撑层。 经热处理的含挥发物的载体层形成具有强电解质的骨架结构，其具有总是从电解质表面良好延伸的孔的互穿网络。 多孔层可以用一系列电极材料或前体渗透以形成固体氧化物燃料电池或其它电化学电池以及电化学电池组。 与常规结构相比，支撑的陶瓷膜提供电化学性能优点并减少烧结过程中的翘曲。
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6.发明授权Ceramic membranes with integral seals and support, and electrochemical cells and electrochemical cell stacks including the same 有权具有整体密封和支撑的陶瓷膜，以及包括其的电化学电池和电化学电池堆公开(公告)号：US07736787B2
公开(公告)日：2010-06-15
申请号：US11220361
申请日：2005-09-06
CPC分类号： H01M8/1226 , H01M4/9033 , H01M8/0282 , H01M8/2435 , H01M2008/1293 , H01M2300/0074
摘要： Ceramic membranes with integral seals and support, and related electrochemical cells and cell stacks. The membrane comprises a thin electrolyte layer supported on a porous electrode layer which in turn is supported on a thick ceramic support layer, preferably a ceramic electrolyte support. The support layer is divided into a plurality of self-supporting thin membrane regions by a network of thicker integrated support ribs. The thin electrolyte layer and thick ceramic support layer preferably define a sealing perimeter surrounding the porous electrode layer.
摘要翻译： 具有整体密封和支撑的陶瓷膜，以及相关的电化学电池和电池组。 膜包括负载在多孔电极层上的薄电解质层，该多孔电极层又被支撑在厚的陶瓷支撑层上，优选陶瓷电解质载体上。 通过较厚的整体支撑肋的网络将支撑层分成多个自支撑薄膜区域。 薄电解质层和厚陶瓷支撑层优选限定围绕多孔电极层的密封周边。
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7.发明申请公开(公告)号：US20090148743A1
公开(公告)日：2009-06-11
申请号：US12001072
申请日：2007-12-07
CPC分类号： H01M4/8657 , C01G53/00 , C01G53/006 , C01G53/04 , C01P2002/52 , C01P2002/54 , C01P2002/72 , C01P2006/40 , C04B35/01 , C04B35/50 , C04B2235/3224 , C04B2235/3229 , C04B2235/3246 , C04B2235/3277 , C04B2235/3279 , C04B2235/5409 , H01M8/0236 , H01M8/0245 , H01M8/1213 , H01M8/126 , H01M2004/8689 , Y02E60/525 , Y02P70/56
摘要： Electrode materials systems for planar solid oxide fuel cells with high electrochemical performance including anode materials that provide exceptional long-term durability when used in reducing gases and cathode materials that provide exceptional long-term durability when used in oxygen-containing gases. The cathode materials comprise zinc-doped lanthanum strontium ferrite (LSZF) or an alternative ferrite, cobaltite or nickelate ceramic electrode material. The cathode material also may comprise a mixed-conducting ceria-based electrolyte material, a palladium dopant, or a combination of these. The cathode may have a bi-layer structure. A ceramic-based interfacial layer may be provided at the electrolyte/cathode interface. The multilayer cathode system and its palladium doped cathode material exhibit a high degree of tolerance to chromium contamination during operation with metallic interconnect materials.
摘要翻译： 用于具有高电化学性能的平面固体氧化物燃料电池的电极材料系统，包括当用于还原气体和阴极材料时提供卓越的长期耐用性的阳极材料，当在含氧气体中使用时，其具有特殊的长期耐用性。 阴极材料包括掺杂锌的镧锶铁氧体（LSZF）或替代铁氧体，钴酸盐或镍酸盐陶瓷电极材料。 阴极材料还可以包括混合导电的二氧化铈基电解质材料，钯掺杂剂或它们的组合。 阴极可以具有双层结构。 可以在电解质/阴极界面处提供陶瓷界面层。 多层阴极系统及其钯掺杂阴极材料在金属互连材料操作期间表现出对铬污染的高度的耐受性。
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公开(公告)号：US08828618B2
公开(公告)日：2014-09-09
申请号：US12001062
申请日：2007-12-07
IPC分类号： H01M4/58
CPC分类号： H01M8/1213 , H01M4/8621 , H01M4/8657 , H01M4/8807 , H01M4/8885 , H01M4/9066 , H01M8/124 , H01M8/126 , H01M8/22 , H01M2004/8684 , H01M2008/1293 , H01M2300/0074 , H01M2300/0077 , H01M2300/0091 , Y02E60/525 , Y02P70/56
摘要： Electrode materials systems for planar solid oxide fuel cells with high electrochemical performance including anode materials that provide exceptional long-term durability when used in reducing gases and cathode materials that provide exceptional long-term durability when used in oxygen-containing gases. The anode materials may comprise a cermet in which the metal component is a cobalt-nickel alloy. These anode materials provide exceptional long-term durability when used in reducing gases, e.g., in SOFCs with sulfur contaminated fuels. The cermet also may comprise a mixed-conducting ceria-based electrolyte material. The anode may have a bi-layer structure. A cerium oxide-based interfacial layer with mixed electronic and ionic conduction may be provided at the electrolyte/anode interface.
摘要翻译： 用于具有高电化学性能的平面固体氧化物燃料电池的电极材料系统，包括当用于还原气体和阴极材料时提供卓越的长期耐用性的阳极材料，当在含氧气体中使用时，其具有特殊的长期耐用性。 阳极材料可以包括其中金属组分是钴镍合金的金属陶瓷。 当用于还原气体时，这些阳极材料具有特殊的长期耐用性，例如在具有硫污染燃料的SOFC中。 金属陶瓷还可以包含混合导电的二氧化铈基电解质材料。 阳极可以具有双层结构。 可以在电解质/阳极界面处提供具有混合电子和离子传导的氧化铈基界面层。
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公开(公告)号：US20100167169A1
公开(公告)日：2010-07-01
申请号：US12633606
申请日：2009-12-08
CPC分类号： H01M8/0232 , H01M4/8657 , H01M4/881 , H01M4/8817 , H01M4/8828 , H01M4/8889 , H01M4/9066 , H01M8/0236 , H01M8/0241 , H01M2008/1293
摘要： A sulfur tolerant anode current collector material includes a mesh or foam that includes a cermet. The cermet includes a metallic component and a ceramic component. The metallic component includes nickel, an alloy including nickel and cobalt, or a mixture including a nickel compound and a cobalt compound. The ceramic component includes a mixed conducting electrolyte material.
摘要翻译： 耐硫阳极集电器材料包括包括金属陶瓷的网或泡沫。 金属陶瓷包括金属成分和陶瓷成分。 金属组分包括镍，包括镍和钴的合金，或包含镍化合物和钴化合物的混合物。 陶瓷部件包括混合的导电电解质材料。
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公开(公告)号：US06946213B2
公开(公告)日：2005-09-20
申请号：US10425191
申请日：2003-04-28
CPC分类号： H01M4/9016 , H01M4/8621 , H01M4/8885 , H01M4/9033 , Y10S502/525
摘要： The invention relates to perovskite oxide electrode materials in which one or more of the elements Mg, Ni, Cu, and Zn are present as minority components that enhance electrochemical performance, as well as electrode products with these compositions and methods of making the electrode materials. Such electrodes are useful in electrochemical system applications such as solid oxide fuel cells, ceramic oxygen generation systems, gas sensors, ceramic membrane reactors, and ceramic electrochemical gas separation systems.
摘要翻译： 本发明涉及一种钙钛矿氧化物电极材料，其中一种或多种元素Mg，Ni，Cu和Zn作为提高电化学性能的少数成分，以及具有这些组成的电极产品和制备电极材料的方法存在。 这种电极可用于电化学系统应用，例如固体氧化物燃料电池，陶瓷氧气发生系统，气体传感器，陶瓷膜反应器和陶瓷电化学气体分离系统。
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