公开(公告)号：US20050130024A1

公开(公告)日：2005-06-16

申请号：US11007329

申请日：2004-12-09

申请人： Toshihiro Otsuki ,  Junji Kawai ,  Mayumi Kakuta ,  Nagayuki Kanaoka ,  Yoichi Asano ,  Ryoichiro Takahashi

发明人： Toshihiro Otsuki ,  Junji Kawai ,  Mayumi Kakuta ,  Nagayuki Kanaoka ,  Yoichi Asano ,  Ryoichiro Takahashi

IPC分类号： C08L71/12 ,  C08G65/40 ,  C08G85/00 ,  C08J5/22 ,  C08K3/00 ,  C08L71/10 ,  H01B1/06 ,  H01B1/12 ,  H01C1/00 ,  H01M8/02 ,  H01M8/10

CPC分类号： C08J5/2218 ,  H01B1/122 ,  H01M8/1004 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1032 ,  H01M8/1039 ,  H01M8/1051 ,  H01M2300/0082

摘要： The invention provides a proton conductive membrane which, even when reduced in thickness, does not allow penetration of an electrode to prevent a short circuit between electrodes and which permits sufficient generating performance. A proton conductive composition capable of forming the membrane is also provided. The proton conductive composition includes a nonconductive filler and a polyarylene having a sulfonic group. The proton conductive membrane, comprising the composition, contains the nonconductive filler in an amount of 3 to 50% by volume, and the nonconductive filler particles have diameters ranging from 3 to 90% the thickness of the membrane.

摘要翻译： 本发明提供了一种质子传导膜，其甚至在厚度减小时不允许电极穿透以防止电极之间的短路并且允许充分的发生性能。 还提供了能够形成膜的质子传导性组合物。 质子传导性组合物包括非导电填料和具有磺酸基的聚亚芳基。 包含该组合物的质子传导膜包含3至50体积％的非导电填料，非导电填料颗粒的直径范围为膜的厚度的3至90％。

公开(公告)号：US07449132B2

公开(公告)日：2008-11-11

申请号：US10995247

申请日：2004-11-24

申请人： Mayumi Kakuta ,  Toshihiro Otsuki ,  Nagayuki Kanaoka ,  Masaaki Nanaumi ,  Yoichi Asano ,  Ryoichiro Takahashi

发明人： Mayumi Kakuta ,  Toshihiro Otsuki ,  Nagayuki Kanaoka ,  Masaaki Nanaumi ,  Yoichi Asano ,  Ryoichiro Takahashi

IPC分类号： H01B1/00 ,  H01M8/10

CPC分类号： C08J5/2256 ,  C08J5/2262 ,  C08J2371/12 ,  H01B1/122 ,  H01M4/92 ,  H01M8/04197 ,  H01M8/04291 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/1032 ,  H01M8/1039 ,  H01M8/1051 ,  H01M2300/0082

摘要： The present invention provides a proton conductive membrane having capabilities of self-generating water and maintaining water, excellent ion conductivity and excellent effect of inhibiting crossover and usable for solid polymer electrolyte type fuel cells and also provides a proton conductive composition used for preparing the proton conductive membrane. The proton conductive composition comprises 100 parts by weight of a polyarylene having a sulfonic group and 0.01 to 80 parts by weight of at least one metal catalyst selected from the group consisting of platinum, gold, palladium, rhodium, iridium and ruthenium, or comprises 100 parts by weight of a polyarylene having a sulfonic group, 0.01 to 80 parts by weight of the metal catalyst, and 0.01 to 50 parts by weight of metal oxide fine particles and/or fibers in total.

摘要翻译： 本发明提供了具有自发水能力并保持水，优异的离子传导性和优异的抑制交叉的效果并且可用于固体聚合物电解质型燃料电池的质子传导膜，并且还提供了用于制备质子传导性的质子传导性组合物 膜。 质子传导性组合物包含100重量份具有磺酸基的聚亚芳基和0.01至80重量份的选自铂，金，钯，铑，铱和钌的至少一种金属催化剂，或包含100 重量份具有磺酸基的聚亚芳基，金属催化剂为0.01〜80重量份，总计为0.01〜50重量份的金属氧化物微粒和/或纤维。

公开(公告)号：US6084053A

公开(公告)日：2000-07-04

申请号：US60105

申请日：1998-04-15

申请人： Minoru Matsubara ,  Yasutake Inoue ,  Mayumi Kakuta ,  Igor Rozhanskii ,  Kohei Goto

发明人： Minoru Matsubara ,  Yasutake Inoue ,  Mayumi Kakuta ,  Igor Rozhanskii ,  Kohei Goto

IPC分类号： C08G73/10 ,  H01B3/30 ,  H05K1/03 ,  B32B27/00

CPC分类号： H01B3/306 ,  C08G73/10 ,  C08G73/1039 ,  H05K1/0346 ,  Y10S428/901

摘要： Electronic parts and a process for manufacturing the electronic parts are provided. The electronic parts comprise an electric insulating material exhibiting a high heat resistance and low dielectric constant as a structural component. The electric insulating material is formed of a polyimide containing a recurring unit represented by the following general formula (1). ##STR1##

摘要翻译： 提供了电子部件和用于制造电子部件的工艺。 电子部件包括表现出高耐热性和低介电常数作为结构部件的电绝缘材料。 电绝缘材料由含有由以下通式（1）表示的重复单元的聚酰亚胺形成。

公开(公告)号：US07001929B2

公开(公告)日：2006-02-21

申请号：US10641212

申请日：2003-08-15

申请人： Kohei Goto ,  Mayumi Kakuta ,  Fusazumi Masaka ,  Kiyonori Kita ,  Naoki Mitsuta ,  Masaru Iguchi ,  Hiroshi Soma ,  Nagayuki Kanaoka

发明人： Kohei Goto ,  Mayumi Kakuta ,  Fusazumi Masaka ,  Kiyonori Kita ,  Naoki Mitsuta ,  Masaru Iguchi ,  Hiroshi Soma ,  Nagayuki Kanaoka

IPC分类号： C08J5/20

CPC分类号： H01M10/0565 ,  H01M8/0289 ,  H01M8/1023 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1032 ,  H01M8/1039 ,  H01M8/1051 ,  H01M8/1081 ,  Y02P70/56

摘要： The invention provides a proton conductive membrane excellent in heat resistance, which has sulfonic acid as ion exchange groups. The proton conductive membrane comprises a nitrogen-containing compound that can be mixed with water in arbitrary proportions and has a boiling point of not lower than 100. degree. C. and a proton conductive resin which has sulfonic acid ion-exchange groups, wherein the nitrogen-containing compound is contained in an amount of 0.5 to 10 parts by weight based on 100 parts by weight of the proton conductive resin.

摘要翻译： 本发明提供了耐热性优异的质子传导膜，其具有作为离子交换基团的磺酸。 质子传导膜包含可与任意比例的水混合并且沸点不低于100.度的含氮化合物。 以及具有磺酸离子交换基团的质子传导性树脂，其中，相对于100重量份的质子传导性树脂，含氮化合物的含量为0.5〜10重量份。

公开(公告)号：US06812290B2

公开(公告)日：2004-11-02

申请号：US10303821

申请日：2002-11-26

申请人： Kohei Goto ,  Yoshitaka Yamakawa ,  Mayumi Kakuta ,  Igor Rozhanskii

发明人： Kohei Goto ,  Yoshitaka Yamakawa ,  Mayumi Kakuta ,  Igor Rozhanskii

IPC分类号： C08F836

CPC分类号： C08G61/12 ,  C07C45/46 ,  C07C49/84

摘要： A polyarylene copolymer which comprises (A) aromatic compound units having a main chain containing one or more electron-withdrawing groups therein and (B) aromatic compound units having a main chain containing no electron-withdrawing groups therein, and a proton-conductive membrane comprising the polyarylene copolymer having sulfonic acid groups.

摘要翻译： 一种聚亚芳基共聚物，其包含（A）具有含有一个或多个吸电子基团的主链的芳香族化合物单元和（B）具有不含吸电子基团的主链的芳香族化合物单元，以及质子传导性膜， 所述聚亚芳基共聚物具有磺酸基。

公开(公告)号：US20050116206A1

公开(公告)日：2005-06-02

申请号：US10995247

申请日：2004-11-24

申请人： Mayumi Kakuta ,  Toshihiro Otsuki ,  Nagayuki Kanaoka ,  Masaaki Nanaumi ,  Yoichi Asano ,  Ryoichiro Takahashi

发明人： Mayumi Kakuta ,  Toshihiro Otsuki ,  Nagayuki Kanaoka ,  Masaaki Nanaumi ,  Yoichi Asano ,  Ryoichiro Takahashi

IPC分类号： C08L71/10 ,  C08J5/22 ,  C08K3/08 ,  C08K3/22 ,  H01B1/06 ,  H01B1/12 ,  H01C1/00 ,  H01M4/92 ,  H01M8/02 ,  H01M8/04 ,  H01M8/10

CPC分类号： C08J5/2256 ,  C08J5/2262 ,  C08J2371/12 ,  H01B1/122 ,  H01M4/92 ,  H01M8/04197 ,  H01M8/04291 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/1032 ,  H01M8/1039 ,  H01M8/1051 ,  H01M2300/0082

摘要： The present invention provides a proton conductive membrane having capabilities of self-generating water and maintaining water, excellent ion conductivity and excellent effect of inhibiting crossover and usable for solid polymer electrolyte type fuel cells and also provides a proton conductive composition used for preparing the proton conductive membrane. The proton conductive composition comprises 100 parts by weight of a polyarylene having a sulfonic group and 0.01 to 80 parts by weight of at least one metal catalyst selected from the group consisting of platinum, gold, palladium, rhodium, iridium and ruthenium, or comprises 100 parts by weight of a polyarylene having a sulfonic group, 0.01 to 80 parts by weight of the metal catalyst, and 0.01 to 50 parts by weight of metal oxide fine particles and/or fibers in total.

摘要翻译： 本发明提供了具有自发水能力并保持水，优异的离子传导性和优异的抑制交叉的效果并且可用于固体聚合物电解质型燃料电池的质子传导膜，并且还提供了用于制备质子传导性的质子传导性组合物 膜。 质子传导性组合物包含100重量份具有磺酸基的聚亚芳基和0.01至80重量份的选自铂，金，钯，铑，铱和钌的至少一种金属催化剂，或包含100 重量份具有磺酸基的聚亚芳基，金属催化剂为0.01〜80重量份，总计为0.01〜50重量份的金属氧化物微粒和/或纤维。

公开(公告)号：US20050106469A1

公开(公告)日：2005-05-19

申请号：US10990879

申请日：2004-11-18

申请人： Junji Kawai ,  Toshihiro Otsuki ,  Mayumi Kakuta ,  Kohei Goto ,  Nagayuki Kanaoka ,  Yoichi Asano ,  Ryoichiro Takahashi

发明人： Junji Kawai ,  Toshihiro Otsuki ,  Mayumi Kakuta ,  Kohei Goto ,  Nagayuki Kanaoka ,  Yoichi Asano ,  Ryoichiro Takahashi

IPC分类号： B01D67/00 ,  B01D69/14 ,  B01D71/02 ,  B01D71/52 ,  B01D71/68 ,  B01D71/82 ,  C08J5/22 ,  C25B13/00 ,  C25C7/04 ,  H01M6/18 ,  H01M8/10

CPC分类号： C08J5/2256 ,  B01D67/0079 ,  B01D69/141 ,  B01D71/024 ,  B01D71/027 ,  B01D71/028 ,  B01D71/52 ,  B01D71/68 ,  B01D71/82 ,  C08J5/2275 ,  C08J2365/02 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/1032 ,  H01M8/1039 ,  H01M8/1048 ,  H01M8/1051 ,  H01M2300/0082 ,  H01M2300/0091

摘要： A proton conductive membrane exhibiting superior proton conductivity even at high temperatures of 100° C. or above, and a proton conductive composition capable of forming the membrane are provided. The invention also provides a proton conductive membrane showing excellent proton conductivity even if it does not have an increased amount of the sulfonic groups introduced therein, and a proton conductive composition capable of forming the membrane. The proton conductive composition includes (a) at least one compound selected from a metal oxide hydrate, a phyllosilicate and a hygroscopic inorganic porous compound, and (b) a polyarylene having a sulfonic group.

摘要翻译： 提供即使在100℃以上的高温也能表现出优异的质子传导性的质子传导性膜和能够形成膜的质子传导性组合物。 本发明还提供了即使不引入其中引入的磺酸基的量增加也显示出优异的质子传导性的质子传导膜，以及能够形成膜的质子传导性组合物。 质子传导性组合物包含（a）至少一种选自金属氧化物水合物，页硅酸盐和吸湿性无机多孔化合物的化合物，和（b）具有磺酸基的聚亚芳基。

公开(公告)号：US06555626B2

公开(公告)日：2003-04-29

申请号：US09818847

申请日：2001-03-28

申请人： Kohei Goto ,  Yoshitaka Yamakawa ,  Mayumi Kakuta ,  Igor Rozhanskii

发明人： Kohei Goto ,  Yoshitaka Yamakawa ,  Mayumi Kakuta ,  Igor Rozhanskii

IPC分类号： C08F836

CPC分类号： C08G61/12 ,  C07C45/46 ,  C07C49/84

摘要： A polyarylene copolymer which comprises (A) from 60 to 3 mol % aromatic compound units having a main chain containing one or more electron-withdrawing groups therein and (B) from 40 to 97 mol % aromatic compound units having a main chain containing no electron-withdrawing groups therein (provided that (A)+(B)=100 mol %), and a proton-conductive membrane comprising the polyarylene copolymer having sulfonic acid groups.

摘要翻译： 一种聚亚芳基共聚物，其包含（A）60〜3摩尔％的含有一个或多个吸电子基团的主链的芳族化合物单元和（B）40〜97摩尔％的不含电子的主链的芳族化合物单元 （A）+（B）= 100摩尔％）和包含具有磺酸基的聚亚芳基共聚物的质子传导膜。

公开(公告)号：US06376634B1

公开(公告)日：2002-04-23

申请号：US09585275

申请日：2000-06-02

申请人： Michinori Nishikawa ,  Kinji Yamada ,  Mayumi Kakuta ,  Yasutake Inoue ,  Masahiko Ebisawa ,  Satoko Hakamatsuka ,  Kentarou Tamaki

发明人： Michinori Nishikawa ,  Kinji Yamada ,  Mayumi Kakuta ,  Yasutake Inoue ,  Masahiko Ebisawa ,  Satoko Hakamatsuka ,  Kentarou Tamaki

IPC分类号： C09D18304

CPC分类号： H01B3/46

摘要： A composition for film formation which is useful as an interlayer insulating film material in the production of semiconductor devices and the like, and gives a coating film having excellent uniformity, low dielectric constant, low leakage current and excellent storage stability; and a material for insulating film formation using the composition. The composition comprises (A) a product of hydrolysis and condensation obtained by hydrolyzing and condensing at least one compound selected from the group consisting of (A-1) compounds represented by the formula (1): R1aSi(OR2)4−a, and (A-2) compounds represented by the formula (2): R3b(R4O)3−bSi—(R7)d—Si(OR5)3−cR6c; and (B) a compound represented by the formula (3): R8O (CHCH3CH2O)eR9.

摘要翻译： 在半导体装置等的制造中，可用作层间绝缘膜材料的成膜用组合物，得到均匀性，低介电常数，低漏电流和优异的储存稳定性的涂膜; 以及使用该组合物的成膜绝缘材料。该组合物包含（A）通过水解和缩合至少一种选自（A-1）由式（1）表示的化合物的化合物 ）：R1aSi（OR2）4-a和（A-2）由式（2）表示的化合物：R3b（R4O）3-bSi-（R7）d-Si（OR5）3-cR6c; 和（B）由式（3）表示的化合物：R8O（CHCH 3 CH 2 O）e R 9。