摘要:
This invention relates to a method of preparing cellulose solution which is homogeneous at relatively low temperature, in which a small amount of cellulose powder or polyvinylalcohol is dissolved in the liquid-state, concentrated N-methylmorpholine-N-oxide (hereinafter, referred to as ‘NMMO’) so as to lower the solidifying temperature of NMMO, and then, the resulting solution and cellulose powder are fed into an extruder so as to be mixed, swollen and melted in the extruder.
摘要:
The present invention relates to a method for making highly homogenized cellulose solution, wherein the cellulose solution is obtained by obtaining a solidified N-methylmorphorine-N-oxide (hereinafter, referred to as ‘NMMO’) hydrates which is solidified a liquid-state NMMO hydrates comprising 10 to 18% by weight water by using a simple screw-type feeder and by controlling the temperature, feeding the solidified NMMO into a twin-screw type extruder continuously, obtaining a cellulose solution which is fully swelled in a few minutes by dispersing and mixing with cellulose powder in the twin-screw type extruder, and extruding a highly homogenized cellulose solution by feeding the obtained cellulose solution into a melting zone of the extruder to melting the cellulose solution in a few minutes by minimum heat and shear force.
摘要:
Disclosed is a lyocell multi-filament for a tire cord and a method of producing the same. The method includes i) dissolving mixed powder of cellulose and polyvinyl alcohol in a mixed solvent of N-methyl morpholine N-oxide and water to prepare a dope, ii) extruding the dope using a spinning nozzle including orifices through air gaps into a conical upper coagulation bath to solidify the dope to produce a multi-filament, iii) feeding the multi-filament through a lower coagulation bath to a washing bath, and washing the multi-filament, and iv) drying and oiling the washed multi-filament and winding the resulting multi-filament. At this time, the orifices each have a diameter (D) of 100 to 300 μm, a length (L) of 200 to 2400 μm, and a ratio of the length to the diameter (L/D) of 2 to 8, and are spaced apart from each other at intervals of 2.0 to 5.0 mm. The method provides a lyocell multi-filament having excellent physical properties useful as a tire cord, thereby producing a tire for an automobile having improved driving stability, dimensional stability, and uniformity using the tire cord.
摘要:
This invention relates to a method of preparing cellulose solution which is homogeneous at relatively low temperature, in which a small amount of cellulose powder or polyvinylalcohol is dissolved in the liquid-state, concentrated N-methylmorpholine-N-oxide (hereinafter, referred to as ‘NMMO’) so as to lower the solidifying temperature of NMMO, and then, the resulting solution and cellulose powder are fed into an extruder so as to be mixed, swollen and melted in the extruder.
摘要:
Disclosed is a lyocell multi-filament for a tire cord and a method of producing the same. The method includes i) dissolving mixed powder of cellulose and polyvinyl alcohol in a mixed solvent of N-methyl morpholine N-oxide and water to prepare a dope, ii) extruding the dope using a spinning nozzle including orifices through air gaps into a conical upper coagulation bath to solidify the dope to produce a multi-filament, iii) feeding the multi-filament through a lower coagulation bath to a washing bath, and washing the multi-filament, and iv) drying and oiling the washed multi-filament and winding the resulting multi-filament. At this time, the orifices each have a diameter (D) of 100 to 300 μm, a length (L) of 200 to 2400 μm, and a ratio of the length to the diameter (L/D) of 2 to 8, and are spaced apart from each other at intervals of 2.0 to 5.0 mm. The method provides a lyocell multi-filament having excellent physical properties useful as a tire cord, thereby producing a tire for an automobile having improved driving stability, dimensional stability, and uniformity using the tire cord.
摘要:
This invention relates to a method of preparing cellulose solution which is homogeneous at relatively low temperature, in which a small amount of cellulose powder or polyvinylalcohol is dissolved in the liquid-state, concentrated N-methylmorpholine-N-oxide (hereinafter, referred to as ‘NMMO’) so as to lower the solidifying temperature of NMMO, and then, the resulting solution and cellulose powder are fed into an extruder so as to be mixed, swollen and melted in the extruder.
摘要:
The present invention relates to a method for making highly homogenized cellulose solution, wherein the cellulose solution is obtained by obtaining a solidified N-methylmorphorine-N-oxide (hereinafter, referred to as ‘NMMO’) hydrates which is solidified a liquid-state NMMO hydrates comprising 10 to 18% by weight water by using a simple screw-type feeder and by controlling the temperature, feeding the solidified NMMO into a twin-screw type extruder continuously, obtaining a cellulose solution which is fully swelled in a few minutes by dispersing and mixing with cellulose powder in the twin-screw type extruder, and extruding a highly homogenized cellulose solution by feeding the obtained cellulose solution into a melting zone of the extruder to melting the cellulose solution in a few minutes by minimum heat and shear force.
摘要:
This invention relates to a method of preparing cellulose solution which is homogeneous at relatively low temperature, in which a small amount of cellulose powder or polyvinylalcohol is dissolved in the liquid-state, concentrated N-methylmorpholine-N-oxide (hereinafter, referred to as ‘NMMO’) so as to lower the solidifying temperature of NMMO, and then, the resulting solution and cellulose powder are fed into an extruder so as to be mixed, swollen and melted in the extruder.
摘要:
The present invention relates to a method for making highly homogenized cellulose solution, wherein the cellulose solution is obtained by obtaining a solidified N-methylmorphorine-N-oxide (hereinafter, referred to as ‘NMMO’) hydrates which is solidified a liquid-state NMMO hydrates comprising 10 to 18% by weight water by using a simple screw-type feeder and by controlling the temperature, feeding the solidified NMMO into a twin-screw type extruder continuously, obtaining a cellulose solution which is fully swelled in a few minutes by dispersing and mixing with cellulose powder in the twin-screw type extruder, and extruding a highly homogenized cellulose solution by feeding the obtained cellulose solution into a melting zone of the extruder to melting the cellulose solution in a few minutes by minimum heat and shear force.