公开(公告)号：US09091433B2

公开(公告)日：2015-07-28

申请号：US13321388

申请日：2010-05-18

申请人： Godwind Tafara Peter Mabande ,  Soo Yin Chin ,  Goetz-Peter Schindler ,  Gerald Koermer ,  Dieter Harms ,  Burkhard Rabe ,  Howard Furbeck ,  Oliver Seel

发明人： Godwind Tafara Peter Mabande ,  Soo Yin Chin ,  Goetz-Peter Schindler ,  Gerald Koermer ,  Dieter Harms ,  Burkhard Rabe ,  Howard Furbeck ,  Oliver Seel

IPC分类号： F23C13/08 ,  B01J19/24 ,  B01J23/40 ,  B01J23/42 ,  B01J23/58 ,  B01J23/62 ,  B01J23/63 ,  B01J23/656 ,  B01J23/96 ,  B01J35/00 ,  B01J35/02 ,  B01J35/04 ,  B01J37/00 ,  B01J37/02 ,  C07C5/333 ,  C07C5/393 ,  B01J21/04 ,  B01J21/06 ,  B01J38/10 ,  B01J38/12

CPC分类号： F23C13/08 ,  B01J19/2485 ,  B01J21/04 ,  B01J21/06 ,  B01J21/066 ,  B01J23/40 ,  B01J23/42 ,  B01J23/58 ,  B01J23/624 ,  B01J23/63 ,  B01J23/6567 ,  B01J23/96 ,  B01J35/002 ,  B01J35/0026 ,  B01J35/023 ,  B01J35/04 ,  B01J37/0036 ,  B01J37/0045 ,  B01J37/0205 ,  B01J37/0228 ,  B01J37/0242 ,  B01J37/0248 ,  B01J38/10 ,  B01J38/12 ,  C07C5/3337 ,  C07C5/393 ,  C07C2523/42 ,  C07C2523/62 ,  F23C2900/9901 ,  Y02P20/52 ,  Y02P20/584 ,  C07C11/06 ,  C07C11/08 ,  C07C15/08

摘要： The invention relates to a catalyst comprising a monolith composed of a catalytically inert material with low BET surface area and a catalyst layer which has been applied to the monolith and comprises, on an oxidic support material, at least one noble metal selected from the group consisting of the noble metals of group VIII of the Periodic Table of the Elements, optionally tin and/or rhenium, and optionally further metals, wherein the thickness of the catalyst layer is 5 to 500 micrometers.

摘要翻译： 本发明涉及一种催化剂，其包含由具有低BET表面积的催化惰性材料构成的整料和已经施加到整料上的催化剂层，并且在氧化载体材料上包含至少一种选自以下的贵金属： 的元素周期表第Ⅷ族的贵金属，任选的锡和/或铼，以及任选的另外的金属，其中催化剂层的厚度为5至500微米。

公开(公告)号：US08642826B2

公开(公告)日：2014-02-04

申请号：US11829424

申请日：2007-07-27

申请人： Martin Dieterle ,  Catharina Klanner ,  Götz-Peter Schindler ,  Klaus Joachim Müller-Engel ,  Jens Scheidel ,  Christoph Adami

发明人： Martin Dieterle ,  Catharina Klanner ,  Götz-Peter Schindler ,  Klaus Joachim Müller-Engel ,  Jens Scheidel ,  Christoph Adami

IPC分类号： C07C5/333

CPC分类号： B01J8/0453 ,  B01J8/0496 ,  B01J8/062 ,  B01J8/067 ,  B01J19/0033 ,  B01J2208/00221 ,  B01J2208/00407 ,  B01J2208/00415 ,  B01J2208/00522 ,  B01J2208/025 ,  C07C5/3337 ,  C07C45/33 ,  C07C45/35 ,  C07C67/08 ,  C07C2523/42 ,  Y02P20/52 ,  C07C11/02 ,  C07C11/06 ,  C07C47/22 ,  C07C69/54

摘要： A process for long-term operation of a continuous heterogeneously catalyzed partial dehydrogenation of a hydrocarbon to be dehydrogenated, in which a reaction gas mixture stream comprising the hydrocarbon to be dehydrogenated in a molar starting amount KW is conducted through an overall catalyst bed comprising the total amount M of dehydrogenation catalyst and the deactivation of the overall catalyst bed is counteracted in such a way that, with increasing operating time, the contribution to the conversion in the first third of the total amount M of dehydrogenation catalyst in flow direction decreases, the contribution to the conversion in the last third of the total amount M of dehydrogenation catalyst in flow direction increases, and the contribution to the conversion in the second third of the total amount M of dehydrogenation catalyst in flow direction passes through a maximum.

摘要翻译： 一种用于长期运行待脱氢烃的连续不均匀催化的部分脱氢的方法，其中包含待脱氢的烃以摩尔起始量KW的反应气体混合物流通过包含总共的催化剂床 脱氢催化剂的量M和整个催化剂床的失活以这样的方式被抵消：随着操作时间的增加，在流动方向上对脱氢催化剂总量M的前三分之一转化的贡献减小，贡献 到脱氢催化剂流向总量M的最后三分之一的转化率增加，并且对流化方向的脱氢催化剂总量M的第二分之三转化率的影响最大。

公开(公告)号：US08481666B2

公开(公告)日：2013-07-09

申请号：US12663871

申请日：2009-01-23

申请人： William Michie ,  Mark Davis ,  Nathan Wiker ,  Debra Wilson ,  Peter Schindler ,  John Garnett

发明人： William Michie ,  Mark Davis ,  Nathan Wiker ,  Debra Wilson ,  Peter Schindler ,  John Garnett

IPC分类号： C08F10/02 ,  C08F4/6592

CPC分类号： C08F210/16 ,  B29K2023/06 ,  C08L2314/06 ,  C08F210/14 ,  C08F2500/09 ,  C08F2500/03 ,  C08F2500/17 ,  C08F2500/20 ,  C08F2500/11 ,  C08F2500/12

摘要： The instant invention is a polyethylene composition, method of producing the same, articles made therefrom, and method of making the same. The polyethylene composition according to the instant invention comprises (1) less than or equal to 100 percent by weight of the units derived from ethylene; and (2) less than 15 percent by weight of units derived from one or more α-olefin comonomers. The polyethylene composition according the instant invention has a density of equal to D g/cm3, wherein D=[(0.0034(Ln(I2))+0.9553], wherein I2 is melt index expressed in g/10 min, a molecular weight distribution (Mw/Mn) in the range of 1.70 to 3.62, a melt index (I2) in the range of 2 to 1000 g/10 minutes, a molecular weight distribution (Mz/Mw) in the range of less than 2.5, and a vinyl unsaturation of less than 0.06 vinyls per one thousand carbon atoms present in the backbone of the composition.

摘要翻译： 本发明是聚乙烯组合物，其制造方法，由其制成的制品及其制造方法。 根据本发明的聚乙烯组合物包含（1）小于或等于100重量％的衍生自乙烯的单元; 和（2）少于15重量％的衍生自一种或多种α-烯烃共聚单体的单元。 根据本发明的聚乙烯组合物具有等于D g / cm 3的密度，其中D = [（0.0034（Ln（I 2））+ 0.9553]，其中I 2是以g / 10分钟表示的熔体指数，分子量分布 （Mw / Mn）在1.70至3.62的范围内，熔体指数（I2）在2至1000g / 10分钟范围内，分子量分布（Mz / Mw）在小于2.5的范围内，以及 存在于组合物骨架中的每1000个碳原子的小于0.06个乙烯基的乙烯基不饱和度。

公开(公告)号：US08202814B2

公开(公告)日：2012-06-19

申请号：US12025448

申请日：2008-02-04

申请人： Martin Dieterle ,  Götz-Peter Schindler ,  Catharina Horstmann ,  Klaus Joachim Müller-Engel

发明人： Martin Dieterle ,  Götz-Peter Schindler ,  Catharina Horstmann ,  Klaus Joachim Müller-Engel

IPC分类号： B01J38/04

CPC分类号： B01J23/96 ,  B01J38/20 ,  C07C5/48 ,  C07C51/252 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2523/04 ,  C07C2523/63 ,  Y02P20/52 ,  Y02P20/584 ,  C07C11/06 ,  C07C57/04

摘要： A process for regenerating a catalyst bed deactivated in the course of a heterogeneously catalyzed partial dehydrogenation of a hydrocarbon, in which a gas comprising molecular oxygen is conducted at elevated temperature through the deactivated catalyst bed and, in the course of the regeneration, the content of molecular oxygen in the regeneration gas is increased repeatedly and the increase in the carbon oxide content of the regeneration gas as it flows through the deactivated catalyst bed is restricted to values of ≦5% by volume.

摘要翻译： 在烃的非均相催化部分脱氢过程中使催化剂床再生失活的方法，其中包含分子氧的气体在高温下通过失活的催化剂床进行，并且在再生过程中， 再生气体中的分子氧反复增加，并且再生气体在流过失活催化剂床时的碳氧化物含量的增加被限制为±10体积％的量。

公开(公告)号：US20120065443A1

公开(公告)日：2012-03-15

申请号：US13321388

申请日：2010-05-18

申请人： Godwind Tafara Peter Mabande ,  Soo Yin Chin ,  Goetz-Peter Schindler ,  Gerald Koermer ,  Dieter Harms ,  Burkhard Rabe ,  Howard Furbeck ,  Oliver Seel

发明人： Godwind Tafara Peter Mabande ,  Soo Yin Chin ,  Goetz-Peter Schindler ,  Gerald Koermer ,  Dieter Harms ,  Burkhard Rabe ,  Howard Furbeck ,  Oliver Seel

IPC分类号： C07C5/367 ,  C07C5/333

CPC分类号： F23C13/08 ,  B01J19/2485 ,  B01J21/04 ,  B01J21/06 ,  B01J21/066 ,  B01J23/40 ,  B01J23/42 ,  B01J23/58 ,  B01J23/624 ,  B01J23/63 ,  B01J23/6567 ,  B01J23/96 ,  B01J35/002 ,  B01J35/0026 ,  B01J35/023 ,  B01J35/04 ,  B01J37/0036 ,  B01J37/0045 ,  B01J37/0205 ,  B01J37/0228 ,  B01J37/0242 ,  B01J37/0248 ,  B01J38/10 ,  B01J38/12 ,  C07C5/3337 ,  C07C5/393 ,  C07C2523/42 ,  C07C2523/62 ,  F23C2900/9901 ,  Y02P20/52 ,  Y02P20/584 ,  C07C11/06 ,  C07C11/08 ,  C07C15/08

摘要： The invention relates to a catalyst comprising a monolith composed of a catalytically inert material with low BET surface area and a catalyst layer which has been applied to the monolith and comprises, on an oxidic support material, at least one noble metal selected from the group consisting of the noble metals of group VIII of the Periodic Table of the Elements, optionally tin and/or rhenium, and optionally further metals, wherein the thickness of the catalyst layer is 5 to 500 micrometers.

摘要翻译： 本发明涉及一种催化剂，其包含由具有低BET表面积的催化惰性材料构成的整料和已经施加到整料上的催化剂层，并且在氧化载体材料上包含至少一种选自以下的贵金属： 的元素周期表第Ⅷ族的贵金属，任选的锡和/或铼，以及任选的另外的金属，其中催化剂层的厚度为5至500微米。

公开(公告)号：US20110156383A1

公开(公告)日：2011-06-30

申请号：US12650223

申请日：2009-12-30

申请人： Urs BOBST ,  Markus Graf ,  Andreas Naef ,  Patrik Zeiter ,  Thomas Wullschleger ,  Peter Schindler ,  Kurt Gysin

发明人： Urs BOBST ,  Markus Graf ,  Andreas Naef ,  Patrik Zeiter ,  Thomas Wullschleger ,  Peter Schindler ,  Kurt Gysin

IPC分类号： F16L55/00

CPC分类号： F16L37/091 ,  F16L37/0925

摘要： A connection piece (111) for a plug-in connection of a fluid-carrying system of lines for distributing drinking water within stories is formed without a supporting nipple. The connection piece (111) has in the region of an inner lateral surface of the first tubular part a first peripheral guiding surface (122) and a second peripheral guiding surface (117), arranged behind the first guiding surface (122) with respect to an insertion opening of the connection piece (111), for the second tubular part (160). A first axial extent of the first guiding surface (122) and a second axial extent of the second guiding surface (117) respectively make up each at least one sixth of an inside diameter of the first tubular part (112, 120). The connection piece (111) may form part of a fitting or a faucet and is suitable in particular for use with solid plastic pipes, for example of crosslinked polyethylene.

摘要翻译： 形成用于在故障中分配饮用水的流体输送系统的插入式连接件的连接件（111），而没有支撑接头。 连接件（111）在第一管状部件的内侧表面的区域中具有相对于第一引导表面（122）布置在第一引导表面（122）的后面的第一外围引导表面（122）和第二外围引导表面（117） 用于第二管状部分（160）的连接件（111）的插入开口。 第一引导表面（122）的第一轴向范围和第二引导表面（117）的第二轴向范围分别构成第一管状部分（112,120）的内径的至少六分之一。 连接件（111）可以形成配件或水龙头的一部分，并且特别适用于固体塑料管，例如交联聚乙烯。

公开(公告)号：US07910766B2

公开(公告)日：2011-03-22

申请号：US10813010

申请日：2004-03-31

申请人： Goetz-Peter Schindler ,  Otto Machhammer ,  Klaus Joachim Mueller-Engel ,  Claus Hechler ,  Jochen Petzoldt ,  Christoph Adami ,  Klaus Harth

发明人： Goetz-Peter Schindler ,  Otto Machhammer ,  Klaus Joachim Mueller-Engel ,  Claus Hechler ,  Jochen Petzoldt ,  Christoph Adami ,  Klaus Harth

IPC分类号： C07C253/08 ,  C07C255/06 ,  C07C51/16

CPC分类号： B01J23/63 ,  B01J23/626 ,  C07C45/33 ,  C07C45/34 ,  C07C45/35 ,  C07C51/252 ,  C07C253/26 ,  Y02P20/52 ,  C07C47/22 ,  C07C57/04 ,  C07C255/08

摘要： A process for preparing at least one partial oxidation and/or ammoxidation product of a hydrocarbon by partially dehydrogenating at least one saturated hydrocarbon H under heterogeneous catalysis and using the resulting product gas mixture A, which comprises the partially dehydrogenated hydrocarbon H, as such or in modified form for heterogeneously catalyzed partial oxidation and/or ammoxidation of the partially dehydrogenated hydrocarbon present in the product gas mixture A, said process including at least one mechanical separating operation inserted between the product gas mixture A and the heterogeneously catalyzed partial oxidation and/or ammoxidation.

摘要翻译： 通过在非均相催化下部分脱氢至少一种饱和烃H并且使用所得到的产物气体混合物A（其包含部分脱氢的烃H）本身或其中的方法制备烃的至少一种部分氧化和/或氨氧化产物的方法 产物气体混合物A中存在的部分脱氢的烃的非均相催化部分氧化和/或氨氧化的改性形式，所述方法包括插入产物气体混合物A和非均相催化的部分氧化和/或氨氧化之间的至少一个机械分离操作 。

公开(公告)号：US20110042326A1

公开(公告)日：2011-02-24

申请号：US12990723

申请日：2009-04-30

申请人： Alexandra Seeber ,  Götz-Peter Schindler ,  Katrin Freitag ,  Reinhard Hess ,  Rudolf Piehl ,  Thilo Hahn ,  Thomas Hill ,  Michael Hesse ,  Piotr Makarczyk

发明人： Alexandra Seeber ,  Götz-Peter Schindler ,  Katrin Freitag ,  Reinhard Hess ,  Rudolf Piehl ,  Thilo Hahn ,  Thomas Hill ,  Michael Hesse ,  Piotr Makarczyk

IPC分类号： C02F1/32

CPC分类号： C02F1/725 ,  B01J21/063 ,  B01J23/02 ,  B01J23/10 ,  B01J23/12 ,  B01J23/75 ,  B01J27/24 ,  B01J35/004 ,  B01J35/026 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/0009 ,  B01J37/04 ,  B01J37/082 ,  C02F1/30 ,  C02F1/32 ,  C02F2103/10 ,  C02F2103/28 ,  C02F2103/32 ,  C02F2103/365 ,  C02F2305/10

摘要： The present invention relates to a method of purifying wastewater by contacting the wastewater which is to be purified with a rod-shaped TiO2 photocatalyst which has a BET surface area of 25 to 200 m2/g, a pore volume of 0.10 to 1.00 ml/g, and a median pore diameter of 0.005 to 0.050 μm, with irradiation by light, and to the use of such a rod-shaped TiO2 photocatalyst which has a BET surface area of 25 to 200 m2/g, a pore volume of 0.10 to 1.00 ml/g, and a median pore diameter of 0.005 to 0.050 μm, for purifying wastewater with irradiation by light.

摘要翻译： 本发明涉及一种净化废水的方法，该方法是将待纯化的废水与BET表面积为25〜200m 2 / g，孔体积为0.10〜1.00ml / g的棒状TiO 2光催化剂 ，中值孔径为0.005〜0.050μm，通过光照射，使用BET表面积为25〜200m 2 / g，孔体积为0.10〜1.00的棒状TiO 2光催化剂 ml / g，中值孔径为0.005〜0.050μm，用于通过光照射来净化废水。

公开(公告)号：US20110038763A1

公开(公告)日：2011-02-17

申请号：US12912127

申请日：2010-10-26

申请人： Claus Hechler ,  Wilhelm Ruppel ,  Götz-Peter Schindler ,  Catharina Klanner ,  Hans-Jürgen Bassler ,  Martin Dieterle ,  Karl-Heinrich Klappert ,  Klaus Joachim Müller-Engel

发明人： Claus Hechler ,  Wilhelm Ruppel ,  Götz-Peter Schindler ,  Catharina Klanner ,  Hans-Jürgen Bassler ,  Martin Dieterle ,  Karl-Heinrich Klappert ,  Klaus Joachim Müller-Engel

IPC分类号： B01J8/00

CPC分类号： C07C5/333 ,  B01J8/067 ,  B01J19/02 ,  B01J2219/0236 ,  C07C51/215 ,  C22C30/00 ,  C22C38/40 ,  Y02P20/52 ,  C07C11/06 ,  C07C11/02 ,  C07C57/04

摘要： A process for continuous heterogeneously catalyzed partial dehydrogenation of at least one hydrocarbon to be dehydrogenated in a reactor which is manufactured from a composite material which consists, on its side in contact with the reaction chamber, of a steel B with specific elemental composition which, on its side facing away from the reaction chamber, either directly or via an intermediate layer of copper, or of nickel, or of copper and nickel, is plated onto a steel A with specific elemental composition, and also partial oxidations of the dehydrogenated hydrocarbon and the reactor itself.

摘要翻译： 在反应器中连续不均匀催化的待脱氢烃的部分脱氢的方法，该反应器由复合材料制成，该复合材料在其与反应室接触的一侧由具有特定元素组成的钢B组成， 其直接或经由铜或镍或铜和镍的中间层离开反应室的一侧被镀在具有特定元素组成的钢A上，并且还将脱氢烃和 反应堆本身。

公开(公告)号：US20100298508A1

公开(公告)日：2010-11-25

申请号：US12663871

申请日：2009-01-23

申请人： William Michie ,  Mark Davis ,  Nathan Wiker ,  Debra Wilson ,  Peter Schindler ,  John Garnett

发明人： William Michie ,  Mark Davis ,  Nathan Wiker ,  Debra Wilson ,  Peter Schindler ,  John Garnett

IPC分类号： C08F210/02 ,  B29C45/00

CPC分类号： C08F210/16 ,  B29K2023/06 ,  C08L2314/06 ,  C08F210/14 ,  C08F2500/09 ,  C08F2500/03 ,  C08F2500/17 ,  C08F2500/20 ,  C08F2500/11 ,  C08F2500/12

摘要： The instant invention is a polyethylene composition, method of producing the same, articles made therefrom, and method of making the same. The polyethylene composition according to the instant invention comprises (1) less than or equal to 100 percent by weight of the units derived from ethylene; and (2) less than 15 percent by weight of units derived from one or more α-olefin comonomers. The polyethylene composition according the instant invention has a density in the range of 0.907 to 0.975 g/cm3, a molecular weight distribution (Mw/Mn) in the range of 1.70 to 3.62, a melt index (I2) in the range of 2 to 1000 g/10 minutes, a molecular weight distribution (Mz/Mw) in the range of less than 2.5, and a vinyl unsaturation of less than 0.06 vinyls per one thousand carbon atoms present in the backbone of the composition. The process for producing a polyethylene composition according to the instant invention comprises the steps of: (1) (co)polymerizing ethylene and at least one or more α-olefin comonomers in the presence of a hafnium based metallocene catalyst via a gas phase (co)polymerization process in a single stage reactor; and (2) thereby producing the inventive polyethylene composition, wherein the polyethylene composition has a density in the range of 0.907 to 0.975 g/cm3, a molecular weight distribution (Mw/Mn) in the range of 1.70 to 3.62, a melt index (I2) in the range of 2 to 1000 g/10 minutes, a molecular weight distribution (Mz/Mw) in the range of less than 2.5, and a vinyl unsaturation of less than 0.06 vinyls per one thousand carbon atoms present in the backbone of said composition. The injection molded articles according to the instant invention comprise a polyethylene composition comprising (1) less than or equal to 100 percent by weight of the units derived from ethylene; and (2) less than 15 percent by weight of units derived from one or more α-olefin comonomers; wherein the polyethylene composition has a density in the range of 0.907 to 0.975 g/cm3, a molecular weight distribution (Mw/Mn) in the range of 1.70 to 3.62, a melt index (I2) in the range of 2 to 1000 g/10 minutes, a molecular weight distribution (Mz/Mw) in the range of less than 2.5, vinyl unsaturation of less than 0.06 vinyls per one thousand carbon atoms present in the backbone of said composition. The process for making an injection molded article according to the instant invention comprises the steps of: (a) selecting a polyethylene composition comprising (1) less than or equal to 100 percent by weight of the units derived from ethylene; and (2) less than 15 percent by weight of units derived from one or more α-olefin comonomers; wherein the polyethylene composition has a density in the range of 0.907 to 0.975 g/cm3, a molecular weight distribution (Mw/Mn) in the range of 1.70 to 3.62, a melt index (I2) in the range of 2 to 1000 g/10 minutes, a molecular weight distribution (Mz/Mw) in the range of less than 2.5, vinyl unsaturation of less than 0.06 vinyls per one thousand carbon atoms present in the backbone of said composition; (b) injection molding said polyethylene composition; and (c) thereby forming the injection molded article.