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    Polymeric thickeners for aqueous compositions
    3.
    发明授权
    Polymeric thickeners for aqueous compositions 有权
    含水组合物的聚合增稠剂

    公开(公告)号：US6057388A

    公开(公告)日：2000-05-02

    申请号：US233514

    申请日：1999-01-20

    申请人： Michael Wiggins ,  Dipak Shah ,  Reuben H. Grinstein

    发明人： Michael Wiggins ,  Dipak Shah ,  Reuben H. Grinstein

    IPC分类号： C08G65/337 ,  C08J3/03 ,  C08J3/07 ,  C08L71/02 ,  C08J3/02

    CPC分类号： C08J3/07 ,  C08G65/337 ,  C08J3/03 ,  C08L71/02

    摘要： A process of preparing a concentrate which is useful as a thickener for aqueous compositions is provided. The process comprises obtaining a solution of an associative thickener compound in an organic solvent capable of forming a low boiling azeotrope with water. The solution is essentially free of water at this point and is at a temperature above the boiling point of said low boiling azeotrope. Water is added to said solution and an azeotrope of water and said organic solvent is distilled. The rate of addition of water is sufficient to replace said azeotrope with water, but is insufficient to cause a second phase to form in the resulting mixture of said solution and said water. The process yields a concentrate of an associative thickener in water, which concentrate is essentially free of volatile organic solvents.

    摘要翻译： 提供了制备可用作水性组合物的增稠剂的浓缩物的方法。 该方法包括获得缔合增稠剂化合物在能够与水形成低沸点共沸物的有机溶剂中的溶液。 该溶液在此点基本上不含水，并处于高于所述低沸点共沸物沸点的温度。 向所述溶液中加入水，蒸馏出水和所述有机溶剂的共沸物。 水的添加速度足以用水代替所述共沸物，但不足以在所得溶液和所述水的混合物中形成第二相。 该方法产生在水中缔合增稠剂的浓缩物，其浓缩物基本上不含挥发性有机溶剂。

    Polymeric thickeners for aqueous compositions
    4.
    发明授权
    Polymeric thickeners for aqueous compositions 失效
    含水组合物的聚合增稠剂

    公开(公告)号：US6002049A

    公开(公告)日：1999-12-14

    申请号：US873773

    申请日：1997-06-12

    申请人： Michael S. Wiggins ,  Reuben H. Grinstein ,  Stephen A. Fischer

    发明人： Michael S. Wiggins ,  Reuben H. Grinstein ,  Stephen A. Fischer

    IPC分类号： C08G83/00 ,  C09D7/00 ,  C09K3/00 ,  C07C43/30 ,  C08J5/02 ,  C08J3/03 ,  C08J3/07

    CPC分类号： C08G83/00 ,  C09D7/002 ,  C09K3/00 ,  Y10S526/932

    摘要： Latexes are thickened by compounds of the formula ##STR1## wherein R.sup.1 is an aliphatic, substituted aliphatic, aromatic, or substituted aromatic radical having a valence of from 2 to 8; each of B.sub.1 -B.sub.8 is independently an ester, amide, amine, ether, sulfide, disulfide, thiocarbamate, urea, thiourea, urethane, sulfate, phosphate, carbonyl, methylene, thioamide, carbonate, or imide linkage; each of X.sup.1 -X.sup.8 is independently --A.sub.1 --R.sup.2 --A.sub.2 -- or --A.sub.1 -- wherein each of A.sub.1 and A.sub.2 is independently an ester, amide, amine, ether, sulfide, disulfide, urethane, thiocarbamate, urea, thiourea, sulfate, phosphate, carbonyl, methylene, thioamide, carbonate, or imide linkage and R.sup.2 is a divalent aliphatic, substituted aliphatic, aromatic, or substituted aromatic radical with the proviso that only one of B.sub.1 -B.sub.8 is urethane and that when one of B.sub.1 -B.sub.8 is urethane, one of A.sub.1 and A.sub.2 is not urethane; each of d, g, j, m, p, s, v, y is independently 0 or 1, each of c, f, i, l, o, r, u, x is independently any integer or non-integer from 0 to about 200; each of J, K, L, M, N, P, Q, S is 0 or 1; each of e, h, k, n, q, t, w, z is independently any integer or non-integer from 0 to about 200; each of R.sup.3 -R.sup.10 is independently an aliphatic, substituted aliphatic, aromatic, or substituted aromatic radical having from 1 to about 50 carbon atoms; each of AG and AO is independently an ethyleneoxy, 1,2-propyleneoxy, 1,2-butyleneoxy unit or combinations thereof.

    摘要翻译： 乳化剂由下式化合物增稠，其中R1是2至8价的脂族，取代的脂族，芳族或取代的芳族基团; 每个B1-B8独立地是酯，酰胺，胺，醚，硫化物，二硫化物，硫代氨基甲酸酯，脲，硫脲，氨基甲酸酯，硫酸酯，磷酸酯，羰基，亚甲基，硫代酰胺，碳酸酯或酰亚胺键; X1-X8各自独立地为-A1-R2-A2-或-A1-，其中A1和A2各自独立地为酯，酰胺，胺，醚，硫醚，二硫化物，氨基甲酸酯，硫代氨基甲酸酯，脲，硫脲，硫酸酯，磷酸酯 ，羰基，亚甲基，硫代酰胺，碳酸酯或酰亚胺键，R 2是二价脂族，取代的脂族，芳族或取代的芳族基团，条件是B1-B8中只有一个是氨基甲酸酯，当B1-B8中的一个是氨基甲酸酯时 A1和A2之一不是氨基甲酸酯; d，g，j，m，p，s，v，y中的每一个独立地为0或1，c，f，i，l，o，r，u，x中的每一个独立地为0以上的整数或非整数 至约200; J，K，L，M，N，P，Q，S中的每一个为0或1; e，h，k，n，q，t，w，z中的每一个独立地为0至约200的任何整数或非整数; 每个R 3 -R 10独立地是具有1至约50个碳原子的脂族，取代的脂族，芳族或取代的芳族基团; AG和AO各自独立地为亚乙氧基，1,2-亚丙氧基，1,2-亚丁基氧基单元或其组合。

    Polymeric thickeners for aqueous compositions
    5.
    发明授权
    Polymeric thickeners for aqueous compositions 失效

    公开(公告)号：US5916935A

    公开(公告)日：1999-06-29

    申请号：US901579

    申请日：1997-07-28

    申请人： Michael Wiggins ,  Dipak Shah ,  Reuben H. Grinstein

    发明人： Michael Wiggins ,  Dipak Shah ,  Reuben H. Grinstein

    IPC分类号： C08G65/337 ,  C08J3/03 ,  C08J3/07 ,  C08L71/02 ,  C08J3/02

    CPC分类号： C08J3/07 ,  C08G65/337 ,  C08J3/03 ,  C08L71/02

    摘要： A process of preparing a concentrate which is useful as a thickener for aqueous compositions is provided. The process comprises obtaining a solution of an associative thickener compound in an organic solvent capable of forming a low boiling azeotrope with water. The solution is essentially free of water at this point and is at a temperature above the boiling point of said low boiling azeotrope. Water is added to said solution and an azeotrope of water and said organic solvent is distilled. The rate of addition of water is sufficient to replace said azeotrope with water, but is insufficient to cause a second phase to form in the resulting mixture of said solution and said water. The process yields a concentrate of an associative thickener in water, which concentrate is essentially free of volatile organic solvents.

    Polythiols and use as epoxy resin curing agents
    6.
    发明授权
    Polythiols and use as epoxy resin curing agents 失效
    聚硫醇并用作环氧树脂固化剂

    公开(公告)号：US4927902A

    公开(公告)日：1990-05-22

    申请号：US400057

    申请日：1989-08-29

    申请人： Grannis S. Johnson ,  Reuben H. Grinstein ,  Stuart J. Hartman ,  Raymond P. Dallago

    发明人： Grannis S. Johnson ,  Reuben H. Grinstein ,  Stuart J. Hartman ,  Raymond P. Dallago

    IPC分类号： C07C323/25 ,  C08G59/18 ,  C08G59/66

    CPC分类号： C08G59/66 ,  C07C323/25 ,  C08G59/182 ,  C07C2101/14

    摘要： Polythiols prepared by the reaction of hydrogen sulfide or organic dithiols with polyglycidyl substituted amines have been found to be outstanding curing agents for epoxy resins. Epoxy resins cured with these polythiols are characterized by not only improved gel times, but also improved cure rates, better heat resistance and greater resistance to absorption of water.A useful polythiol is the reaction product of N,N,N',N'-tetraglycidyl-m-xylylenediamine with hydrogen sulfide.

    摘要翻译： 已经发现通过硫化氢或有机二硫醇与聚缩水甘油基取代的胺的反应制备的聚硫醇是用于环氧树脂的杰出的固化剂。 用这些多硫醇固化的环氧树脂的特征在于不仅改善了凝胶时间，而且改进了固化速率，更好的耐热性和更强的耐水吸收能力。 有用的多硫醇是N，N，N'，N'-四缩水甘油基间苯二甲胺与硫化氢的反应产物。

    Polymeric thickeners for aqueous compositions
    8.
    发明授权
    Polymeric thickeners for aqueous compositions 失效
    含水组合物的聚合增稠剂

    公开(公告)号：US5880222A

    公开(公告)日：1999-03-09

    申请号：US933708

    申请日：1997-09-19

    申请人： Michael S. Wiggins ,  Reuben H. Grinstein

    发明人： Michael S. Wiggins ,  Reuben H. Grinstein

    IPC分类号： A61K8/86 ,  A61Q19/00 ,  C08G63/16 ,  C08G63/40 ,  C08G63/672 ,  C08G65/32 ,  C08G69/26 ,  C08G69/40 ,  C08G69/44 ,  C08K3/20 ,  C08K5/09 ,  C08L23/00 ,  C08L67/00 ,  C08L67/02 ,  C08L71/02 ,  C08L77/00 ,  C09D7/00 ,  C09D7/12 ,  C09D167/00 ,  C09D167/02 ,  C09D171/00 ,  C09D171/02 ,  C09D177/00 ,  C09K5/00 ,  C10M173/00 ,  C10M173/02

    CPC分类号： A61K8/86 ,  A61Q19/00 ,  C08G63/672 ,  C08G69/26 ,  C08G69/40 ,  C08G69/44 ,  C09D7/002 ,  C09K5/00

    摘要： Latexes are thickened by compounds of the formula:R.sup.1 -(O-A).sub.a -B.sup.1 -R.sup.2 -(B.sup.2 -R.sup.3).sub.d -(B.sup.3 -(A'-O).sub.b-f -(A'-B.sup.4).sub.f -R.sup.4 -(B.sup.5 -R.sup.5).sub.e).sub.n -B.sup.6 -(A"O).sub.c -R.sup.6wherein:R.sup.1 and R.sup.6 are monovalent hydrophobic groups independently selected from the group consisting of an aliphatic group, a substituted aliphatic group, an aromatic group, and a substituted aromatic group;R.sup.2 and R.sup.4 are independently selected from the group consisting of aliphatic, substituted aliphatic, aromatic, or substituted aromatic radicals, each radical being divalent or trivalent;R.sup.3 and R.sup.5 are independently selected from hydrogen, lower alkyl and lower aralkyl;B.sup.1, B.sup.2, B.sup.3, B.sup.4, B.sup.5, and B.sup.6 are linking groups independently selected from the group consisting of an oxygen atom (to form the ether linkage --O--), a carboxylate group (to form an ester linkage R.sup.2 --C(O)--O-- and/or R.sup.4 --C(O)--O--), an amino group (to form the amine linkage R.sup.2 --N(R)-- and or R.sup.4 --N(R)--, wherein R is hydrogen, lower alkyl, lower aralkyl, or lower acyl), and an amido group (to form the amide linkage R.sup.2 --N(R)--C(O)-- and/or R.sup.4 --N(R)--C(O)--, wherein R is hydrogen, lower alkyl, lower aralkyl, or lower acyl);each of a, b, c, d, e, f, and n are integers, wherein each of a and c are independently any integer from greater than 20 to about 200; b is any integer from greater than 20 to about 450; d, e, and f are zero or 1; and n is any integer from 1 to about 5; andeach of A, A', and A" is independently an ethylene, 1,2-propylene, 1,2-butylene unit or combinations thereof.

    摘要翻译： 通过下式化合物增强乳胶：R1-（OA）a-B1-R2-（B2-R3）d-（B3-（A'-O）bf-（A'-B4）f-R4-（B5 -R5）e）n-B6-（A''O）c-R6其中R1和R6是独立地选自脂族基团，取代脂族基团，芳族基团和取代芳族基团的一价疏水基团 组; R2和R4独立地选自脂族，取代的脂族，芳族或取代的芳族基团，每个基团是二价或三价的; R3和R5独立地选自氢，低级烷基和低级芳烷基; B1，B2，B3，B4，B5和B6是独立地选自氧原子（形成醚键-O-）的连接基团，羧酸酯基（形成酯键R2-C（O ）-O-和/或R 4 -C（O）-O-），氨基（形成胺键R2-N（R） - 和/或R4-N（R） - ），其中R是氢，低级 烷基，低级芳烷基或低级酰基）和酰胺基（形成酰胺键R2-N（R）-C（O） - 和/或R4-N（R）-C（O） - ），其中R 是氢，低级烷基，低级芳烷基或低级酰基）; a，b，c，d，e，f和n中的每一个为整数，其中a和c各自独立地为大于20至约200的任何整数; b是大于20至约450的任何整数; d，e和f为零或1; n为1〜5的整数; A，A'和A“各自独立地为乙烯，1,2-亚丙基，1,2-亚丁基单元或其组合。

    Method of preparing inorganic pigment dispersions
    9.
    发明授权
    Method of preparing inorganic pigment dispersions 失效
    制备无机颜料分散体的方法

    公开(公告)号：US5877253A

    公开(公告)日：1999-03-02

    申请号：US670969

    申请日：1996-06-26

    申请人： Bruce L. Matta ,  Samuel A. Firman ,  George A. Smith ,  Reuben H. Grinstein

    发明人： Bruce L. Matta ,  Samuel A. Firman ,  George A. Smith ,  Reuben H. Grinstein

    IPC分类号： C09D5/02 ,  C09D17/00 ,  C08L31/00

    CPC分类号： C09D17/004 ,  C09D5/028

    摘要： A method of preparing an inorganic pigment dispersion useful in the preparation of latex paints is provided. The method comprises dispersing an inorganic pigment in an aqueous medium further comprised of a dispersing polymer, said aqueous medium being essentially free of volatile organic solvents. The dispersing polymer is derived from monomers consisting essentially of an ethylenically unsaturated aromatic monomer having an unsubstituted ethylenic group, an ethylenically unsaturated aromatic monomer having an alkyl-substituted ethylenic group, and an ethylenically unsaturated acid monomer. The amount of the ethylenically unsaturated acid monomer is sufficient to permit the dispersing polymer to associate with an inorganic pigment in an aqueous medium in a manner which disperses the inorganic pigment in the aqueous medium to form a stable aqueous dispersion of said inorganic pigment. The total amount of the ethylenically unsaturated aromatic monomers is sufficient to reduce the water sensitivity of a dried coating of a latex paint comprised of said stable aqueous dispersion of said inorganic pigment. Use of the inorganic pigment dispersions to prepare latex paints, and latex paints resulting from such use, are also provided.

    摘要翻译： 提供了制备用于制备乳胶漆的无机颜料分散体的方法。 该方法包括将无机颜料分散在进一步包含分散聚合物的水性介质中，所述水性介质基本上不含挥发性有机溶剂。 分散聚合物衍生自主要由具有未取代的烯属基的烯属不饱和芳族单体，具有烷基取代的烯属基的烯属不饱和芳族单体和烯属不饱和酸单体组成的单体。 烯属不饱和酸单体的量足以允许分散聚合物以水性介质中的无机颜料与水性介质中的无机颜料缔合，以将无机颜料分散在水性介质中以形成稳定的无机颜料的水分散体。 烯键式不饱和芳族单体的总量足以降低由所述无机颜料的稳定水性分散体组成的乳胶漆的干燥涂层的水敏感性。 还提供了使用无机颜料分散体来制备乳胶漆，以及由这种使用产生的乳胶漆。