公开(公告)号：US06414087B1

公开(公告)日：2002-07-02

申请号：US09520733

申请日：2000-03-08

Applicant: Abdulmajid Hashemzadeh ,  Mihai Gurau ,  Rudolf Weissgerber ,  Walter Dobler

Inventor： Abdulmajid Hashemzadeh ,  Mihai Gurau ,  Rudolf Weissgerber ,  Walter Dobler

IPC: C08F800

CPC classification number: C08F265/04 ,  C08F220/12 ,  C08F285/00 ,  C08L51/003 ,  C09J151/003

Abstract: The invention relates to a process for preparing an aqueous polymer dispersion for removable pressure-sensitive adhesive films by means of free-radically initiated aqueous emulsion polymerization of one or more ethylenically unsaturated monomers from the group consisting of esters of acrylic acid and methacrylic acid with branched or unbranched alcohols having 1 to 12 carbon atoms, vinyl esters of branched or unbranched carboxylic acids having 1 to 12 carbon atoms, vinyl-aromatics, vinyl halides, olefins and dienes, which comprises copolymerizing from 0.01 to 2.0% by weight of polar, ionic or nonionic comonomers or mixtures thereof, and if polar ionic comonomers, alone or in a mixture, are copolymerized, the proportion thereof is not more than 1.0% by weight, and the amounts in % by weight are based in each case on the overall weight of the comonomers.

Abstract translation: 本发明涉及一种通过自由引发的一种或多种烯键式不饱和单体的水性乳液聚合制备用于可去除的压敏粘合剂膜的水性聚合物分散体的方法，所述单体由丙烯酸和甲基丙烯酸的酯与支链 或具有1至12个碳原子的非支链醇，具有1-12个碳原子的支链或非支链羧酸的乙烯基酯，乙烯基芳族化合物，乙烯基卤化物，烯烃和二烯，其包括共聚0.01至2.0重量％的极性离子 或非离子共聚单体或其混合物，如果单体或混合物中的极性离子共聚单体共聚，则其比例不超过1.0重量％，并且以重量计的量基于每种情况下的总重量 的共聚单体。

公开(公告)号：US5296532A

公开(公告)日：1994-03-22

申请号：US837553

申请日：1992-02-14

Applicant: Reinhard Haerzschel ,  Rudolf Weissgerber ,  Herbert Kaiser ,  Wilhelm Kaiser

Inventor： Reinhard Haerzschel ,  Rudolf Weissgerber ,  Herbert Kaiser ,  Wilhelm Kaiser

IPC: C08F261/00 ,  C08F261/04 ,  C09J151/00 ,  C08K5/09 ,  C08F6/00 ,  C08G63/91 ,  C08L29/04

CPC classification number: C09J151/003 ,  C08F261/04

Abstract: The invention relates to adhesive compositions for gluing wood containing aqueous vinyl ester graft copolymer dispersions and water-soluble acid metal salts or free acids, in which the adhesive compositions exhibit outstanding resistance to hot water and have high storage stability. The vinyl ester graft copolymer comprises from 2 to 12 percent by weight, based on the total weight of the graft copolymer, of one or more polyvinyl alcohols having a degree of hydrolysis of from 60 to 99 mol persent and 88 to 98 percent by weight, based on the total weight of the graft copolymer, of a grafting monomer mixture. The grafting monomer mixture contains from 5 to 50 percent by weight, based on the total weight of the monomer mixture, of vinyl esters of saturated, highly branched aliphatic monocarboxylic acids having 9 or 10 carbon atoms, vinyl pivalate, diisopropyl maleate, diisopropyl fumarate, vinyl chloride and mixtures thereof.

Abstract translation: 本发明涉及用于胶合木材的粘合剂组合物，其含有乙烯基酯水溶液接枝共聚物分散体和水溶性酸性金属盐或游离酸，其中粘合剂组合物显示出优异的耐热水性并且具有高储存稳定性。 乙烯基酯接枝共聚物包含2至12重量％的基于接枝共聚物的总重量的一种或多种水解度为60至99摩尔％的聚乙烯醇和88至98重量％ 基于接枝共聚物的总重量，接枝单体混合物。 接枝单体混合物含有5至50重量％，基于单体混合物的总重量，具有9或10个碳原子的饱和，高度支化的脂族一元羧酸的乙烯基酯，新戊酸乙烯酯，马来酸二异丙酯，富马酸二异丙酯， 氯乙烯及其混合物。

公开(公告)号：US06989191B2

公开(公告)日：2006-01-24

申请号：US10462505

申请日：2003-06-16

Applicant: Rudolf Weissgerber ,  Thomas Bastelberger

Inventor： Rudolf Weissgerber ,  Thomas Bastelberger

IPC: C09J7/04 ,  D21H17/34

CPC classification number: B32B29/00 ,  B32B27/30 ,  D21C5/02 ,  D21H19/20 ,  D21H19/824 ,  D21H23/34 ,  D21H23/52 ,  D21H23/56 ,  Y02W30/648 ,  Y10T428/14 ,  Y10T428/28 ,  Y10T428/2843 ,  Y10T428/2848 ,  Y10T428/2891 ,  Y10T428/31895 ,  Y10T428/31993

Abstract: The invention relates to a paper composite material with repulp-resistant adhesive coating, consisting of a paper carrier and an adhesive layer, characterized in that an intermediate coat of a dispersion polymer film containing a protective colloid and/or an emulsifying agent and with a glass transition temperature Tg of −20° to 40° is applied between the paper carrier and the adhesive coating. The invention also relates to a method for the production of paper composite material with repulp-resistant adhesive coating.

Abstract translation: 本发明涉及一种具有耐压粘合剂涂层的纸复合材料，由纸载体和粘合层组成，其特征在于，含有保护胶体和/或乳化剂和玻璃的分散聚合物膜的中间涂层 在纸载体和粘合剂涂层之间施加-20°至40°的转变温度Tg。 本发明还涉及一种生产具有耐压粘合剂涂层的纸复合材料的方法。

公开(公告)号：US06552115B1

公开(公告)日：2003-04-22

申请号：US09690422

申请日：2000-10-17

Applicant: Helmut Zecha ,  Rudolf Weissgerber ,  Frank Geiger

Inventor： Helmut Zecha ,  Rudolf Weissgerber ,  Frank Geiger

IPC: C08F216

CPC classification number: C08F218/04 ,  C08F261/04

Abstract: The present invention relates to a vinyl acetate based polymer latex composition obtained by emulsion polymerization, the polymer comprising PVOH, and a monomer mixture, said monomer mixture comprising vinyl acetate, and a pre-crosslinking monomer selected from one or more polyethylenically unsaturated compounds wherein said pre-crosslinking monomer is present in amount of less than 0.01% by weight based on the total monomer content and which pre-crosslinking monomer is initially charged to the polymerization reaction mixture. The invention further relates to use of the vinyl acetate based polymer latex in an adhesive, preferably a woodworking adhesive and to an adhesive, preferably a woodworking adhesive comprising said latex.

Abstract translation: 本发明涉及通过乳液聚合获得的乙酸乙烯酯基聚合物胶乳组合物，包含PVOH的聚合物和单体混合物，所述单体混合物包含乙酸乙烯酯和选自一种或多种多烯属不饱和化合物的预交联单体，其中所述 预交联单体的存在量小于基于单体总量的0.01重量％，并且哪些预交联单体最初加入到聚合反应混合物中。 本发明还涉及在粘合剂，优选木工粘合剂和粘合剂，优选包含所述胶乳的木工粘合剂中使用乙酸乙烯酯基聚合物胶乳。

公开(公告)号：US6140400A

公开(公告)日：2000-10-31

申请号：US68906

申请日：1998-05-20

Applicant: Reiner Figge ,  Rudolf Weissgerber

Inventor： Reiner Figge ,  Rudolf Weissgerber

IPC: C09J125/08 ,  C08L93/00 ,  C09J11/00 ,  C09J127/06 ,  C09J133/02 ,  C09J191/06 ,  C09J193/00 ,  C09J201/00 ,  C08J3/22 ,  C08L93/04 ,  C08K5/11 ,  C08K5/12 ,  C08K5/06

CPC classification number: C09J191/06 ,  C09J133/02 ,  C09J193/00 ,  C08L93/00

Abstract: Redispersible tackifier powder compositions which are redispersible in water are provided and which are comprised of one or more tackifying substances and from 2 to 50% by weight of one or more water-soluble low molecular weight homo or copolymers of olefinically unsaturated mono or dicarboxylic acids or their anhydrides. The copolymers also contain other free-radically polymerizable monomers. Antiblocking agents can also be present. Adhesives containing the compositions are also provided.

Abstract translation: PCT No.PCT / EP97 / 00172 Sec。 371日期：1998年5月20日 102（e）日期1998年5月20日PCT 1997年1月16日PCT PCT。 公开号WO97 / 26307 PCT 日期1997年7月24日提供可再分散在水中的可分散增粘剂粉末组合物，其由一种或多种增粘物质和2至50重量％的一种或多种水溶性低分子量烯属不饱和的共聚物 单或二羧酸或其酸酐。 共聚物还含有其他可自由基聚合的单体。 也可以存在防粘连剂。 还提供了含有组合物的粘合剂。

公开(公告)号：US4296017A

公开(公告)日：1981-10-20

申请号：US113259

申请日：1980-01-18

Applicant: Rudolf Weissgerber ,  Alois Stoll ,  Herbert Kandler ,  Hans-Herbert Nunner ,  Christine Eichelseder ,  Helmut Pangeri

Inventor： Rudolf Weissgerber ,  Alois Stoll ,  Herbert Kandler ,  Hans-Herbert Nunner ,  Christine Eichelseder ,  Helmut Pangeri

IPC: C08F255/00 ,  C08F255/02 ,  C08F263/04 ,  C09J151/00 ,  C09J151/06 ,  C08F261/04 ,  C08F263/02 ,  C08L39/06

CPC classification number: C09J151/06 ,  C08F255/026 ,  C08F263/04 ,  C09J151/003 ,  Y10T428/2878 ,  Y10T428/2887 ,  Y10T428/31649 ,  Y10T428/31667 ,  Y10T428/31699 ,  Y10T428/3192

Abstract: Pressure-sensitive adhesives which contain preferably from 60% to 85% by weight of graft copolymers for use as polymeric pressure-sensitive adhesives, and from 15% to 40% by weight of plasticizers such as phthalate or phosphate plasticizers. The graft copolymer consists of from 5% to 30% by weight of a graft base and from 70% to 95% by weight of grafted-on monomer units. The graft base is a copolymer with from 40% to 85% by weight of ethylene units and from 15% to 60% by weight of vinyl acetate units and optionally up to 10% by weight of monomer units of other unsaturated compounds. It may be replaced wholly or partially by other graft bases. The grafted-on monomer units consist of from 30% to 80% by weight of units of vinyl esters of short-chained carboxylic acids, especially vinyl acetate, from 20% to 70% by weight of units of vinyl esters of relatively long-chained carboxylic acids, for example vinyl laurate, and/or units of esters of .alpha.,.beta.-unsaturated carboxylic acids with relatively long-chained alcohols and/or units of esters of unsaturated dicarboxylic acids with relatively long-chained alcohols, from 0.5% to 15% by weight of N-vinyl-2-pyrrolidone units and from 0 to 20% by weight of other olefinically-unsaturated copolymerizable monomer units.

Abstract translation: 含有优选60％至85％重量的用作聚合物压敏粘合剂的接枝共聚物和15％至40％重量增塑剂如邻苯二甲酸酯或磷酸酯增塑剂的压敏粘合剂。 接枝共聚物由5％至30％重量的接枝基质和70％至95％重量的接枝单体组成。 接枝基质是具有40重量％至85重量％的乙烯单元和15重量％至60重量％的乙酸乙烯酯单元和任选至多10重量％的其它不饱和化合物的单体单元的共聚物。 它可以完全或部分地被其它移植物基质替代。 接枝的单体单元由30％至80％重量的短链羧酸乙烯基酯，特别是乙酸乙烯酯的单元，20％至70％重量的相对长链的乙烯基酯单元 羧酸，例如月桂酸乙烯酯，和/或α，β-不饱和羧酸与相对长链醇和/或不饱和二羧酸与相对长链醇的酯单元的酯的单元，为0.5〜15 重量％的N-乙烯基-2-吡咯烷酮单元和0至20％重量的其它烯属不饱和可共聚单体单元。

公开(公告)号：US06794466B2

公开(公告)日：2004-09-21

申请号：US10035373

申请日：2001-10-19

Applicant: Helmut Zecha ,  Rudolf Weissgerber ,  Francis Petrocelli

Inventor： Helmut Zecha ,  Rudolf Weissgerber ,  Francis Petrocelli

IPC: C08F238

CPC classification number: C08F18/08

Abstract: The present invention elates to a vinyl acetate based polymer latex composition obtained by emulsion polymerization of: (a) polyvinyl alcohol, (c) a monomer mixture comprising vinyl acetate, and (d) optionally one or more additional co-monomer(s), in presence of (c) 0.0001-0.05 wt. % of a chain transfer agent, based on total monomer weight, said vinyl acetate based polymer latex composition having a weight average particle size ≧400 nm and a higher shear thinning factor than the vinyl acetate based polymer latex composition (a), (b) and (d) obtained in the absence of the chain transfer agent (c). According to one embodiment, emulsion polymerization is carried out in presence of 0.001 to 0.05 wt. % of a chain transfer agent selected from the group consisting of aldehydes and chain transfer agents having a similar chain transfer constant with regard to vinyl acetate as the monomer. According to another embodiment, emulsion polymerization is carried out in presence of 0.0001 to 0.01 wt. % of a chain transfer agent selected from the group consisting of thiols, mercapto acids, and chain transfer agents having a similar chain transfer constant with regard to vinyl acetate as the monomer. The invention also relates to an adhesive comprising said vinyl acetate based polymer latex composition. Such adhesive is preferably used in paper and packaging applications or as a wood working adhesive or wood glue. The invention further relates to a process of manufacture of a vinyl acetate based polymer latex composition having a weight average particle size >400 nm, including emulsion polymerization of vinyl acetate in the presence of polyvinyl alcohol, optionally together with one or more additional co-monomer(s), wherein the emulsion polymerization is carried out in the presence of 0.0001 wt. % to 0.05 wt. % chain transfer agent, based on total monomer weight.

公开(公告)号：US06746555B1

公开(公告)日：2004-06-08

申请号：US09612166

申请日：2000-07-08

Applicant: Holger Künstle ,  Rudolf Weissgerber

Inventor： Holger Künstle ,  Rudolf Weissgerber

IPC: B32B3100

CPC classification number: C09J131/02 ,  C08F218/10 ,  C08L2666/28 ,  C09J4/00 ,  C09J123/08 ,  C08F218/08

Abstract: The invention provides low-emission adhesives based on an aqueous, protective-colloid-free polymer dispersion or water-redispersible dispersion powders, obtainable therefrom, of vinyl acetate-ethylene copolymers, obtainable by free-radically initiated emulsion polymerization, in aqueous medium and in the presence of one or more emulsifiers, of a comonomer mixture comprising a) from 5 to 50% by weight of ethylene, b) from 20 to 80% by weight of at least one vinyl ester from the group of vinyl esters of unbranched or branched carboxylic acids having 1 to 9 carbon atoms whose homopolymers have a glass transition temperature Tg >0° C., c) from 5 to 70% by weight of at least one vinyl ester from the group of vinyl esters of branched carboxylic acids having 8 to 13 carbon atoms whose homopolymers have a glass transition temperature Tg

Abstract translation: 本发明提供了基于由水性无保护胶体聚合物分散体或可从其获得的水分散体分散粉末的低发射粘合剂，其可通过自由引发的乳液聚合在水性介质中和在水性介质中获得的乙酸乙烯酯 - 乙烯共聚物 存在一种或多种乳化剂的共聚单体混合物，其包含a）5至50重量％的乙烯，b）20至80重量％的至少一种乙烯基酯，其来自无支链或支链羧酸的乙烯基酯 具有1至9个碳原子的酸，其均聚物具有玻璃化转变温度Tg> 0℃，c）5-70重量％的至少一种乙烯基酯，其具有8至13个支链羧酸的乙烯基酯 碳原子，其均聚物具有玻璃化转变温度Tg <0℃，d）0.5至10重量％的至少一种具有3或4个碳原子的烯属不饱和单羧酸或二羧酸，e）0至10％ 至少一种烯键式不饱和羟烷基官能共聚单体的重量，f）0至10重量％的另外的单或多烯属不饱和共聚单体，其重量百分比基于共聚单体的总重量和加入 最多100重量％，如果需要，由其获得的分散体干燥。

公开(公告)号：US06242512B1

公开(公告)日：2001-06-05

申请号：US09101661

申请日：1998-07-14

Applicant: Reiner Figge ,  Harald Zeh ,  Rudolf Weissgerber

Inventor： Reiner Figge ,  Harald Zeh ,  Rudolf Weissgerber

IPC: C08J312

CPC classification number: C09D5/34 ,  C04B40/0042 ,  C04B2103/0057 ,  C08L33/02 ,  C08L35/00 ,  Y10S524/904 ,  Y10S525/934 ,  C04B22/062 ,  C04B24/26 ,  C04B24/2641 ,  C04B2103/0094 ,  C04B24/2664 ,  C08L2666/04

Abstract: The invention provides a redispersible polymer powder based on a mixture of water-insoluble polymer and a water-soluble atomized protective colloid which can be de-activated through a pH change. In addition, the invention concerns aqueous dispersions that can be prepared with the polymer powder and the use of the polymer powder or its aqueous dispersions as a bonding agent in adhesives, plasters or paints.

Abstract translation: 本发明提供基于水不溶性聚合物和水溶性雾化保护胶体的混合物的可再分散的聚合物粉末，其可以通过pH变化而被去活化。 此外，本发明涉及可以用聚合物粉末制备的水性分散体以及聚合物粉末或其水分散体作为粘合剂，灰泥或油漆中的粘合剂的用途。

公开(公告)号：US4322516A

公开(公告)日：1982-03-30

申请号：US131785

申请日：1980-03-19

Applicant: Hubert Wiest ,  Rudolf Weissgerber ,  Erwin Lieb

Inventor： Hubert Wiest ,  Rudolf Weissgerber ,  Erwin Lieb

IPC: C08F20/00 ,  C08F20/10 ,  C08F218/00 ,  C08F218/02 ,  C08F218/08 ,  C08F220/00 ,  C08F220/10 ,  C08F220/18 ,  C09J131/04 ,  C08F210/02

CPC classification number: C08F220/18 ,  C08F218/08 ,  Y10T428/2878 ,  Y10T428/2887 ,  Y10T428/2891

Abstract: A copolymer having good properties for use as a pressure-sensitive adhesive from an aqueous dispersion comprising:(a) from 10% to 30% by weight of ethylene units,(b) from 29% to 69% by weight of acrylic ester units,(c) from 20% to 55% by weight of vinyl acetate units,(d) from 0.2% to 8% by weight of (meth)acrylamide units, and(e) from 0 to 12% of other olefinically-unsaturated monomer units copolymerizable with the above,said copolymer having a glass transition temperature of from -20.degree. C. to -60.degree. C. and a K-value according to Fikentscher, measured in tetrahydrofuran, of from 50 to 180; as well as processes to make the same and aqueous dispersions of the same for use as pressure-sensitive adhesives.

Abstract translation: 一种由水分散体用作压敏粘合剂的具有良好性能的共聚物，其包含：（a）10重量％至30重量％的乙烯单元，（b）29重量％至69重量％的丙烯酸酯单元， （c）20重量％至55重量％的乙酸乙烯酯单元，（d）0.2重量％至8重量％的（甲基）丙烯酰胺单元，和（e）0至12重量％的其它烯属不饱和单体单元 与上述共聚物，所述共聚物的玻璃化转变温度为-20℃至-60℃，根据Fikentscher测得的K值在四氢呋喃中为50至180; 以及制备相同的水性分散体并用作压敏粘合剂的方法。