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公开(公告)号：US07902411B2
公开(公告)日：2011-03-08
申请号：US11499666
申请日：2006-08-07
申请人： Christian Kuhrs , Ruprecht Meissner
发明人： Christian Kuhrs , Ruprecht Meissner
IPC分类号： C07C17/08
CPC分类号： B01J27/138 , B01J21/04 , B01J23/8946 , B01J27/122 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J37/0201 , C07C17/156 , C07C19/045
摘要： The present invention relates to a catalyst composition for the oxychlorination of ethylene, comprising a mixture of metal salts on a support, where said metal salts are applied to the support in such ratios that the catalyst composition comprises a) from 3 to 12% by weight of copper as copper salt, b) from 0 to 3% by weight of an alkaline earth metal as alkaline earth metal salt, c) from 0 to 3% by weight of an alkaline metal as alkaline metal salt, d) from 0.001 to 0.1% by weight, preferably from 0.005 to 0.05% by weight, of at least one metal selected from the group consisting of ruthenium, rhodium, palladium, osmium, iridium and platinum, and/or from 0.0001 to 0.1% by weight, preferably from 0.001 to 0.05% by weight, of gold, as corresponding metal salt or tetrachloroauric acid, where all percentages by weight are based on the total weight of the catalyst including support material. The invention further provides a process for preparing 1,2-dichloroethane by oxychlorination of ethylene in the presence of the above catalyst composition as catalyst.
摘要翻译： 本发明涉及用于乙烯氧氯化的催化剂组合物，其包含在载体上的金属盐的混合物，其中所述金属盐以这样的比例施加到载体上，使得催化剂组合物包含a）3至12重量％ 的铜作为铜盐，b）0-3重量％的碱土金属作为碱土金属盐，c）0-3重量％的作为碱金属盐的碱金属，d）0.001至0.1 至少一种选自钌，铑，钯，锇，铱和铂的金属，和/或0.0001至0.1重量％，优选为0.001重量％，优选0.005至0.05重量％ 至0.05重量％的金，作为相应的金属盐或四氯月桂酸，其中所有的重量百分数都是基于包括载体材料的催化剂的总重量。 本发明还提供了在上述催化剂组合物作为催化剂存在下，通过乙烯氧氯化制备1,2-二氯乙烷的方法。
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公开(公告)号：US06278033B1
公开(公告)日：2001-08-21
申请号：US09726259
申请日：2000-11-30
申请人： Klemens Flick , Ruprecht Meissner , Werner Hefner , Rainer Feser , Fabian Kunz
发明人： Klemens Flick , Ruprecht Meissner , Werner Hefner , Rainer Feser , Fabian Kunz
IPC分类号： C07C7163
CPC分类号： C10G70/02 , B01J21/08 , B01J23/44 , B01J23/50 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J35/108 , C10G45/40
摘要： A catalyst which contains, in its active composition, from 0.05 to 1.0% by weight of at least one metal or compound of a metal of the 10th group of the Periodic Table of the Elements and from 0.05 to 1.0% by weight of at least one metal or compound of a metal of the 11th group of the Periodic Table of the Elements, with the weight ratio of the metal of the 11th group to the metal of the 10th group being from 0.95 to 1.05, and, as support, an SiO2 -containing catalyst support having a BET surface area of from 2 to 400 m2/g, wherein at least 20% of the total pore volume of the catalyst is made up by pores having a diameter greater than 100 nanometers, can be used in processes for removing alkynes, dienes and/or monounsaturated hydrocarbons from streams of materials.
摘要翻译： 一种催化剂，其活性组合物含有0.05-1.0重量％的元素周期表第十组金属的至少一种金属或化合物，以及0.05-1.0重量％的至少一种 元素周期表第11族金属的金属或化合物，第11族金属与第10族金属的重量比为0.95〜1.05，作为载体的SiO 2 - 含有BET表面积为2〜400m 2 / g的催化剂载体，其中催化剂总孔体积的至少20％由直径大于100纳米的孔构成，可用于除去 炔烃，二烯烃和/或单不饱和烃。
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3.发明授权Preparation of a catalyst for the oxidation of sulfur dioxide to sulfur trioxide 失效制备用于将二氧化硫氧化成三氧化硫的催化剂
公开(公告)号：US4539309A
公开(公告)日：1985-09-03
申请号：US624096
申请日：1984-06-25
申请人： Ruprecht Meissner , Norbert Neth
发明人： Ruprecht Meissner , Norbert Neth
IPC分类号： B01J23/22 , B01J27/055 , C01B17/79 , B01J23/04
摘要： Catalysts for the oxidation of sulfur dioxide to sulfur trioxide, consisting of a silica-based carrier and, applied on this, an active substance containing vanadium and alkali metal compounds, are prepared by dissolving vanadium pentoxide in an alkali solution, acidifying the solution with sulfuric acid, mixing the acidified solution with the carrier, molding the mixture and drying and calcining the molding. To obtain mechanically stable catalysts, a dissolved alkali metal silicate and/or silica sol are added to the alkaline solution before acidification, the latter process is carried out at below 35.degree. C. and the solution is then immediately incorporated into the carrier. The resulting moist crumbly material contains from 2 to 6% by weight of V.sub.2 O.sub.5, from 35 to 45% by weight of H.sub.2 O and from 15 to 50% by weight of SiO.sub.2. From 5 to 25% by weight of the total silica content originates from the dissolved alkali metal silicate and/or silica sol.
摘要翻译： 通过将二氧化硫氧化成三氧化硫的催化剂，由二氧化硅基载体组成，并在其上施用含有钒和碱金属化合物的活性物质，通过将五氧化二钒溶解在碱溶液中，用硫酸酸化该溶液来制备 将酸化溶液与载体混合，将混合物成型并干燥并煅烧成型。 为了获得机械稳定的催化剂，在酸化之前，将碱溶性碱金属硅酸盐和/或硅溶胶加入到碱性溶液中，后一过程在低于35℃下进行，然后将溶液立即并入载体中。 所得湿润的脆性材料含有2至6重量％的V 2 O 5，35至45重量％的H 2 O和15至50重量％的SiO 2。 总二氧化硅含量的5至25重量％来源于溶解的碱金属硅酸盐和/或硅溶胶。
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公开(公告)号：US20060270879A1
公开(公告)日：2006-11-30
申请号：US11499666
申请日：2006-08-07
申请人： Christian Kuhrs , Ruprecht Meissner
发明人： Christian Kuhrs , Ruprecht Meissner
CPC分类号： B01J27/138 , B01J21/04 , B01J23/8946 , B01J27/122 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J37/0201 , C07C17/156 , C07C19/045
摘要： The present invention relates to a catalyst composition for the oxychlorination of ethylene, comprising a mixture of metal salts on a support, where said metal salts are applied to the support in such ratios that the catalyst composition comprises a) from 3 to 12% by weight of copper as copper salt, b) from 0 to 3% by weight of an alkaline earth metal as alkaline earth metal salt, c) from 0 to 3% by weight of an alkaline metal as alkaline metal salt, d) from 0.001 to 0.1% by weight, preferably from 0.005 to 0.05% by weight, of at least one metal selected from the group consisting of ruthenium, rhodium, palladium, osmium, iridium and platinum, and/or from 0.0001 to 0.1% by weight, preferably from 0.001 to 0.05% by weight, of gold, as corresponding metal salt or tetrachloroauric acid, where all percentages by weight are based on the total weight of the catalyst including support material. The invention further provides a process for preparing 1,2-dichloroethane by oxychlorination of ethylene in the presence of the above catalyst composition as catalyst.
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公开(公告)号：US07126035B2
公开(公告)日：2006-10-24
申请号：US10502056
申请日：2003-02-04
申请人： Christian Kuhrs , Ruprecht Meissner
发明人： Christian Kuhrs , Ruprecht Meissner
CPC分类号： B01J27/138 , B01J21/04 , B01J23/8946 , B01J27/122 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J37/0201 , C07C17/156 , C07C19/045
摘要： The present invention relates to a catalyst composition for the oxychlorination of ethylene, comprising a mixture of metal salts on a support, where said metal salts are applied to the support in such ratios that the catalyst composition comprises a) from 3 to 12% by weight of copper as copper salt, b) from 0 to 3% by weight of an alkaline earth metal as alkaline earth metal salt, c) from 0 to 3% by weight of an alkaline metal as alkaline metal salt, d) from 0.001 to 0.1% by weight, preferably from 0.005 to 0.05% by weight, of at least one metal selected from the group consisting of ruthenium, rhodium, palladium, osmium, iridium and platinum, and/or from 0.0001 to 0.1% by weight, preferably from 0.001 to 0.05% by weight, of gold, as corresponding metal salt or tetrachloroauric acid, where all percentages by weight are based on the total weight of the catalyst including support material. The invention further provides a process for preparing 1,2-dichloroethane by oxychlorination of ethylene in the presence of the above catalyst composition as catalyst.
摘要翻译： 本发明涉及用于乙烯氧氯化的催化剂组合物，其包含在载体上的金属盐的混合物，其中所述金属盐以这样的比例施加到载体上，使得催化剂组合物包含a）3至12重量％ 的铜作为铜盐，b）0-3重量％的碱土金属作为碱土金属盐，c）0-3重量％的作为碱金属盐的碱金属，d）0.001至0.1 至少一种选自钌，铑，钯，锇，铱和铂的金属，和/或0.0001至0.1重量％，优选为0.001重量％，优选0.005至0.05重量％ 至0.05重量％的金，作为相应的金属盐或四氯月桂酸，其中所有的重量百分数都是基于包括载体材料的催化剂的总重量。 本发明还提供了在上述催化剂组合物作为催化剂存在下，通过乙烯氧氯化制备1,2-二氯乙烷的方法。
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6.发明授权Supported catalyst containing pseudo-boehmite and &ggr;-Al2O3, production of same and its use for producing 1,2-dichloroethane 失效含有假勃姆石和γ-Al2O3的负载催化剂，生产方法及其用于生产1,2-二氯乙烷公开(公告)号：US06680416B1
公开(公告)日：2004-01-20
申请号：US09646003
申请日：2000-09-11
IPC分类号： C07C1900
CPC分类号： B01J27/122 , C07C17/156 , C07C19/045
摘要： A process for preparing 1,2-dichloroethane by reacting about 2 mols of ethylene, about 4 mols of hydrogen chloride and about 1 mol of oxygen in the presence of a fixed bed of supported catalyst based on copper(II) chloride in only one reaction zone at a pressure of from 2 to 10 bar and at from 220 to 280° C., separating off 1,2-dichloroethane and water from the reaction mixture emerging from the reaction zone and passing most of the exhaust gas back into the reaction zone, where, prior to entry into the reaction zone, the exhaust gas is mixed with ethylene, hydrogen chloride and oxygen, and the oxygen content of the mixture does not exceed 7% by volume, and where the ethylene content of the gas mixture entering into the reaction zone is regulated so that the exhaust gas comprises less than 20% by volume of ethylene, where the supported catalyst used is obtained by tableting a mixture of pseudoboehmite and &ggr;-Al2O3 in a weight ratio from 4:1 to 1:4, if desired with addition of tableting auxiliaries, loading this support with the active components by saturating with a CuCl2/KCl solution so that the copper content is from 1 to 15% by weight and the potassium content is from 0.1 to 8% by weight, based in each case on the total weight of the catalyst, and then drying the catalyst at from 60 to 400° C.
摘要翻译： 在仅一次反应的基于氯化铜（II）的固定床的负载型催化剂存在下，使约2摩尔乙烯，约4摩尔氯化氢和约1摩尔氧气反应制备1,2-二氯乙烷的方法 在2至10巴的压力和220至280℃的压力范围内，从反应区中排出的反应混合物中分离出1,2-二氯乙烷和水，并将大部分废气送回反应区 ，其中在进入反应区之前，将废气与乙烯，氯化氢和氧气混合，并且混合物的氧含量不超过7体积％，并且其中气体混合物的乙烯含量进入 对反应区进行调节，以使废气中的乙烯的含量少于20体积％，其中使用的负载催化剂是通过将重量比为4:1至1:4的假勃姆石和γ-Al2O3的混合物压片而得到的， 如果需要添加表 丁基辅助剂，用CuCl 2 / KCl溶液饱和将活性组分负载该载体，使铜含量为1〜15重量％，钾含量为0.1〜8重量％，基于 催化剂的总重量，然后在60-400℃干燥催化剂。
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7.发明授权Method for producing oxidic catalysts containing copper with oxidation number>0 失效生产含氧化值> 0的铜的氧化催化剂的方法公开(公告)号：US06716789B1
公开(公告)日：2004-04-06
申请号：US09581988
申请日：2000-06-21
IPC分类号： B01J2108
CPC分类号： C07C45/002 , B01J23/72 , B01J37/0203 , C07C49/403
摘要： The disclosure is directed to a process for preparing an oxidic catalyst comprising copper in an oxidation state >0, which comprises treating a solid oxidic support material with an aqueous solution comprising at least one copper salt and at least one organic water soluble polymer which binds copper ions coordinatively in a concentration of from 0.1 to 100 g/l and then calcining, to the catalyst obtainable by this process and also to a process for dehydrogenating secondary alcohols to ketones using the catalysts, especially for dehydrogenating cyclohexanol.
摘要翻译： 本发明涉及制备氧化态> 0的铜的氧化催化剂的方法，该方法包括用包含至少一种铜盐和至少一种与铜结合的有机水溶性聚合物的水溶液处理固体氧化载体材料 离子以0.1至100g / l的浓度配位，然后煅烧至可通过该方法获得的催化剂，并且还涉及一种使用催化剂，特别是用于使环己醇脱氢来将仲醇脱氢成酮的方法。
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公开(公告)号：US06362384B1
公开(公告)日：2002-03-26
申请号：US09760711
申请日：2001-01-17
IPC分类号： C07C1700
摘要： A process for the preparation of 1,2-dichloroethane by oxychlorination of ethene in the presence of a copper-containing fixed-bed catalyst comprising a bed essentially consisting of catalyst particles which comprise, at least partially, support material impregnated with an active component and, if desired, a promoter, where the catalyst bed comprises essentially no separate inert material for dilution.
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公开(公告)号：US06204218B1
公开(公告)日：2001-03-20
申请号：US09385457
申请日：1999-08-30
申请人： Klemens Flick , Ruprecht Meissner , Werner Hefner , Rainer Feser , Fabian Kunz
发明人： Klemens Flick , Ruprecht Meissner , Werner Hefner , Rainer Feser , Fabian Kunz
IPC分类号： B01J2108
CPC分类号： C10G70/02 , B01J21/08 , B01J23/44 , B01J23/50 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J35/108 , C10G45/40
摘要： A catalyst comprising, in its active composition, from 0.05 to 1.0% by weight of at least one metal or compound of a metal of the 10th group of the Periodic Table of the Elements and from 0.05 to 1.0% by weight of at least one metal or compound of a metal of the 11th group of the Periodic Table of the Elements, with the weight ratio of the metal of the 11th group to the metal of the 10th group being from 0.95 to 1.05, and, as support, an SiO2-containing catalyst support having a BET surface area of from 2 to 400 m2/g, wherein at least 20% of the total pore volume of the catalyst is made up by pores having a diameter greater than 100 nanometers, can be used in processes for removing alkynes, dienes and/or monounsaturated hydrocarbons from streams of materials.
摘要翻译： 一种催化剂，其活性组合物含有0.05-1.0％（重量）元素周期表第十族金属的至少一种金属或化合物，以及0.05-1.0％重量的至少一种金属 或元素周期表第11族金属的化合物，第11族金属与第10族金属的重量比为0.95〜1.05，作为载体，含有SiO 2的 具有2至400m 2 / g的BET表面积的催化剂载体，其中催化剂的总孔体积的至少20％由直径大于100纳米的孔组成，可用于除去炔烃的方法 ，二烃类和/或单不饱和烃类。
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公开(公告)号：US5736076A
公开(公告)日：1998-04-07
申请号：US517841
申请日：1995-08-22
申请人： Ruprecht Meissner , Matthias Irgang , Knut Eger , Peter Weidlich , Heinz Dreyer
发明人： Ruprecht Meissner , Matthias Irgang , Knut Eger , Peter Weidlich , Heinz Dreyer
CPC分类号： C04B35/532 , B01J19/30 , B01J21/18 , B01J2219/30203 , B01J2219/30207 , B01J2219/30215 , B01J2219/30223 , B01J2219/30242 , B01J2219/304 , B01J2219/30475
摘要： Moldings which comprise from 30 to 100% by weight of graphite, prepared from graphite powders which comprise from 5 to 100% by weight of rhombohedral crystalline graphite and, if required, contain additives and/or binders, and a process for their preparation and their use as catalyst carriers, heat transfer material, column packing or diluent in catalyst beds.
摘要翻译： 包含30至100重量％石墨的模制品，由石墨粉末制备，所述石墨粉末包含5至100重量％的菱面体结晶石墨，并且如果需要，含有添加剂和/或粘合剂，及其制备方法及其制备方法 在催化剂床中用作催化剂载体，传热材料，柱填料或稀释剂。
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