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公开(公告)号：US11331623B2
公开(公告)日：2022-05-17
申请号：US17104644
申请日：2020-11-25
发明人： Michele Colozzi , Emma Palo , Palma Contaldo , Maria Rosaria Pepe , Vincenzo Palma , Vincenzo Vaiano
IPC分类号： B01D53/48 , B01J23/06 , B01J23/22 , B01J23/26 , B01J23/28 , B01J23/34 , B01J23/46 , B01J23/745 , B01J23/755 , B01D53/14 , B01J19/24 , C07C7/148 , C10L3/10
摘要： Disclosed is method for removing carbonyl sulphide and/or carbon disulphide from a sour gas stream. The method comprises subjecting the gas stream to simultaneous contact with an absorption liquid, such as an aqueous amine solution, and with a catalyst suitable for hydrolyzing carbonyl sulphide and/or carbon disulphide. To this end, the invention also provides a reactor system wherein both an absorption liquid and a catalyst are present. In a preferred embodiment, the catalyst is a heterogeneous catalyst present on or in an absorption column, either coated on the trays of a column with trays, or contained in the packing of a packed column.
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公开(公告)号：US10030636B2
公开(公告)日：2018-07-24
申请号：US14894300
申请日：2014-05-27
发明人： Adriano Barsi , Gaetano Iaquaniello
摘要： Disclosed is a thermal energy storage system for storing collected solar thermal energy. The system comprises a solar thermal energy collection facility in the form of a field of parabolic troughs, which is in thermal communication with a molten salt circuit. The molten salt circuit is in fluid communication with a molten salt storage facility comprising at least three storage tanks that are each in fluid communication with the molten salt circuit. The multiple tanks set-up allows using cheaper materials, and a more efficient storage of thermal energy.
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3.发明申请公开(公告)号：US20140249343A1
公开(公告)日：2014-09-04
申请号：US14118214
申请日：2012-06-28
发明人： Yvonne Traa , Daniel Geiss
IPC分类号： C07C2/66
CPC分类号： C07C2/66 , B01J29/068 , B01J29/44 , B01J37/08 , B01J37/18 , B01J2229/186 , C07C2/76 , C07C2529/06 , C07C2529/40 , C07C2529/44 , C07C2529/48 , C07C2529/65 , C07C2529/67 , C07C2529/69 , C07C2529/85 , C07C2531/22 , C07C15/02 , C07C15/27
摘要： Disclosed is a process for the direct alkylation of aromatic compounds with alkanes. To this end a judicious catalyst combination is provided. The composition comprises palladium as a catalytically active metal, and zinc as a promoter, or a metal such as tin having a comparable promoting action. The metals are contained in a zeolite support, or a similar support of a metal organic framework type or a silico alumino phosphate type.
摘要翻译： 公开了用烷烃直接烷基化芳族化合物的方法。 为此，提供了明智的催化剂组合。 组合物包含作为催化活性金属的钯，作为助催化剂的锌，或具有可比较的促进作用的金属如锡。 金属包含在沸石载体中，或类似的金属有机骨架型或硅铝型磷酸盐载体。
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4.发明申请公开(公告)号：US20140134096A1
公开(公告)日：2014-05-15
申请号：US14115831
申请日：2012-05-07
发明人： Fabio Angelini , Lucia Barbato
CPC分类号： C01B17/0495 , B01D53/8612 , B01D2251/102 , B01D2256/16 , B01J8/00 , C01B3/02 , C01B3/04 , C01B17/0404 , C01B17/0408 , C01B17/0426 , Y02E60/364 , Y02P20/129
摘要： Disclosed is a process for the concurrent production of hydrogen and sulphur from a H2S-containing gas stream, with reduced, and preferably zero, emissions. The method comprises the catalytic oxidative cracking of H2S so as to form H2 and S2. Preferably, the oxidation is conducted using oxygen-enriched air, preferably pure oxygen. The process is conducted in a reaction chamber comprising a bifunctional catalyst material, so as to favor both the partial oxidation of H2S and the dissociation thereof.
摘要翻译： 公开了一种从含H 2 S的气流同时生产氢和硫的方法，具有减少的，优选为零的排放。 该方法包括H2S的催化氧化裂化，形成H2和S2。 优选地，使用富氧空气，优选纯氧进行氧化。 该方法在包含双官能催化剂材料的反应室中进行，以有利于H2S的部分氧化和其解离。
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公开(公告)号：US20140105814A1
公开(公告)日：2014-04-17
申请号：US14118201
申请日：2012-06-15
CPC分类号： C01B3/505 , B01J7/00 , B01J19/245 , B01J2219/24 , C01B3/12 , C01B3/34 , C01B3/36 , C01B3/38 , C01B3/48 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/0283 , C01B2203/0288 , C01B2203/0294 , C01B2203/0405 , C01B2203/0415 , C01B2203/043 , C01B2203/047 , C01B2203/0475 , C01B2203/0894 , C01B2203/1047
摘要： The present invention relates to a method for hydrogen production and to a method of hydrogen and/or carbon dioxide production from syngas. The method comprises the steps of: (i) providing a gas stream comprising hydrogen and carbon monoxide, (ii) separating at least part of hydrogen from the stream yielding a hydrogen-depleted stream, (iii) subjecting the hydrogen-depleted stream to a water-gas shift reaction, and (iv) separating hydrogen from the stream resulting from step (iii). The method according to the invention improves the conversion of carbon monoxide in the water gas shift reaction and allows to increase the hydrogen production by 10-15% and to increase the overall energy efficiency of the system by 5-7%. The invention further relates to a plant for hydrogen and/or carbon dioxide production suitable for the method of the invention.
摘要翻译： 本发明涉及一种氢气生产方法和一种从合成气生产氢气和/或二氧化碳的方法。 该方法包括以下步骤：（i）提供包含氢气和一氧化碳的气流，（ii）从流中分离至少部分氢气，产生贫氢气流，（iii）将贫氢气流 水煤气变换反应，和（iv）从步骤（iii）产生的物流中分离氢气。 根据本发明的方法改善了水煤气变换反应中一氧化碳的转化，并允许将氢气产量提高10-15％，并将系统的整体能量效率提高5-7％。 本发明还涉及适用于本发明方法的氢和/或二氧化碳生产设备。
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公开(公告)号：US10654719B2
公开(公告)日：2020-05-19
申请号：US14757761
申请日：2015-12-23
发明人： Lucio Molinari , Fabio Angelini , Lucia Barbato
摘要： Disclosed is a process for the concurrent production of hydrogen and sulphur from a H2S-containing gas stream, with zero emissions. The method comprises the thermal oxidative cracking of H2S so as to form H2 and S2. Preferably, the oxidation is conducted using oxygen-enriched air, preferably pure oxygen. The ratio H2S/O2 in the feedstock is higher than 2:1, preferably in the range of 3:1-5:1.
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公开(公告)号：US20170106355A1
公开(公告)日：2017-04-20
申请号：US15395093
申请日：2016-12-30
发明人： Michele COLOZZI , Lucia BARBATO , Fabio ANGELINI , Emma PALO , Vincenzo PALMA , Vincenzo VAIANO
CPC分类号： B01J27/0515 , B01J23/881 , B01J35/08 , B01J37/0201 , B01J37/0207 , B01J37/0215 , B01J37/08 , B01J37/20 , C01B3/04 , C01B17/046 , C01B17/0465 , C01B17/0495 , Y02E60/364
摘要： Disclosed is a catalyst suitable for the catalytic oxidative cracking of a H2S-containing gas stream, particularly in the event that the stream also contains methane and/or ammonia. The catalyst comprises iron and molybdenum supported by a carrier comprising aluminium. The carrier preferably is alumina. The iron and molybdenum preferably are in the form of sulphides. Also disclosed is a method for the production of hydrogen from a H2S-containing gas stream, comprising subjecting the gas stream to catalytic oxidative cracking so as to form H2 and S2, using a catalyst in accordance with any one of the preceding claims.
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公开(公告)号：US09493350B2
公开(公告)日：2016-11-15
申请号：US14384138
申请日：2013-03-11
CPC分类号： C01B3/382 , B01J7/00 , B01J8/009 , B01J8/067 , B01J19/02 , B01J2208/00212 , B01J2219/0004 , B01J2219/0286 , C01B3/384 , C01B3/48 , C01B3/501 , C01B2203/0233 , C01B2203/0283 , C01B2203/0405 , C01B2203/0833 , C01B2203/143 , C01B2203/146 , C01B2203/82 , Y02P20/134
摘要： Disclosed is a process for the production of hydrogen in a reactor system comprising a steam reforming reaction zone comprising a reforming catalyst and a membrane separation zone comprising a hydrogen-selective membrane. The process involves a reaction system of so-called open architecture, wherein the reforming zone and the membrane separation zone operate independently of each other. The invention provides the heat for the reforming reaction through heat exchange from liquid molten salts, preferably heated by solar energy.
摘要翻译： 公开了一种在反应器系统中生产氢气的方法，其包括包含重整催化剂和包含氢选择性膜的膜分离区的蒸汽重整反应区。 该方法涉及所谓的开放结构的反应体系，其中重整区和膜分离区彼此独立地操作。 本发明通过液体熔融盐的热交换提供热重整反应，优选由太阳能加热。
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9.发明申请公开(公告)号：US20160115026A1
公开(公告)日：2016-04-28
申请号：US14989696
申请日：2016-01-06
发明人： Fabio ANGELINI , Lucia BARBATO
CPC分类号： C01B17/0495 , B01D53/8612 , B01D2251/102 , B01D2256/16 , B01J8/00 , C01B3/02 , C01B3/04 , C01B17/0404 , C01B17/0408 , C01B17/0426 , Y02E60/364 , Y02P20/129
摘要： Disclosed is a process for the concurrent production of hydrogen and sulphur from a H2S-containing gas stream, with reduced, and preferably zero, emissions. The method comprises the catalytic oxidative cracking of H2S so as to form H2 and S2. Preferably, the oxidation is conducted using oxygen-enriched air, preferably pure oxygen. The process is conducted in a reaction chamber comprising a bifunctional catalyst material, so as to favor both the partial oxidation of H2S and the dissociation thereof.
摘要翻译： 公开了一种从含H 2 S的气流同时生产氢和硫的方法，具有减少的，优选为零的排放。 该方法包括H2S的催化氧化裂化，形成H2和S2。 优选地，使用富氧空气，优选纯氧进行氧化。 该方法在包含双官能催化剂材料的反应室中进行，以有利于H2S的部分氧化和其解离。
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公开(公告)号：US20140170052A1
公开(公告)日：2014-06-19
申请号：US14118182
申请日：2012-06-25
IPC分类号： C01C1/04
CPC分类号： C01C1/04 , C01B3/025 , C01B3/386 , C01B3/48 , C01B2203/0261 , C01B2203/0283 , C01B2203/0288 , C01B2203/043 , C01B2203/0445 , C01B2203/047 , C01B2203/0475 , C01B2203/068 , C01B2203/1241 , C01B2203/127 , C01B2203/148 , C07C273/04
摘要： Disclosed is a process for the production of ammonia comprising a step wherein synthesis gas is formed by catalytic partial oxidation. Also disclosed is a process of producing urea, wherein ammonia is formed in a process involving a step of catalytic partial oxidation, and carbon dioxide formed in the same process is reacted with said ammonia so as to form urea.
摘要翻译： 公开了一种生产氨的方法，包括通过催化部分氧化形成合成气的步骤。 还公开了生产尿素的方法，其中在涉及催化部分氧化步骤的方法中形成氨，并且将在相同方法中形成的二氧化碳与所述氨反应以形成尿素。
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