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    Silver halide light sensitive emulsion layer having enhanced photographic sensitivity
    4.
    发明授权
    Silver halide light sensitive emulsion layer having enhanced photographic sensitivity 失效
    具有增强的照相感光度的卤化银感光乳剂层

    公开(公告)号：US6153371A

    公开(公告)日：2000-11-28

    申请号：US118552

    申请日：1998-07-17

    申请人： Samir Y. Farid ,  Ian R. Gould ,  Stephen A. Godleski ,  Jerome R. Lenhard ,  Annabel A. Muenter ,  Paul A. Zielinski

    发明人： Samir Y. Farid ,  Ian R. Gould ,  Stephen A. Godleski ,  Jerome R. Lenhard ,  Annabel A. Muenter ,  Paul A. Zielinski

    IPC分类号： G03C1/10 ,  G03C1/12 ,  G03C1/29

    CPC分类号： G03C1/12 ,  G03C1/10 ,  G03C1/29 ,  G03C2200/24

    摘要： This invention comprises a photographic element comprising a support and at least one silver halide emulsion layer in which the silver halide is sensitized with a compound of the formula:Q-XYwherein Q represents the atoms necessary to form a chromophore comprising an amidinium-ion, a carboxyl-ion or dipolar-amidic chromophoric system when conjugated with XY, and XY is a fragmentable electron donor moiety in which X is an electron donor group and Y is a leaving group other than hydrogen, and wherein:1) XY has an oxidation potential between 0 and about 1.4 V;2) the oxidized form of XY undergoes a bond cleavage reaction to give the radical X.sup..cndot. and the leaving fragment Y.In a preferred embodiment of the invention, the radical X.cndot. has an oxidation potential

    摘要翻译： 本发明包括一种照相元件，其包括载体和至少一个卤化银乳剂层，其中卤化银用下式化合物敏化：Q-XY，其中Q表示形成包含脒鎓离子的发色团所需的原子， 羧基离子或偶极 - 酰胺发色体系，XY为可裂解的电子给体部分，其中X为电子给体基团，Y为氢以外的离去基团，其中：1）XY具有氧化电位 介于0和约1.4 V之间; 2）XY的氧化形式经历键断裂反应，得到基团X.和离去片段Y.在本发明的优选实施方案中，基团X的氧化势<-0.7V。

    Process for the separation of oligomeric materials from a catalyst mixture
    5.
    发明授权
    Process for the separation of oligomeric materials from a catalyst mixture 失效
    从催化剂混合物中分离低聚材料的方法

    公开(公告)号：US5238889A

    公开(公告)日：1993-08-24

    申请号：US926421

    申请日：1992-08-10

    申请人： Stephen N. Falling ,  Stephen A. Godleski ,  Lynda W. McGarry

    发明人： Stephen N. Falling ,  Stephen A. Godleski ,  Lynda W. McGarry

    IPC分类号： B01J31/12 ,  B01J31/40 ,  C07D307/28

    CPC分类号： B01J31/0268 ,  B01J31/0239 ,  B01J31/122 ,  B01J31/4015 ,  B01J31/4053 ,  C07D307/28 ,  B01J2231/52 ,  Y02P20/584

    摘要： Disclosed is a process for the recovery of catalyst values from mixtures of catalyst compounds and oligomeric materials. The process provides for the separation of (i) an onium iodide compound, (ii) an organotin iodide compound, or (iii) a mixture thereof from a mixture thereof in an oligomer of a .gamma.,.delta.-epoxy-alkene by the steps of (1) intimately contacting the mixture with an extraction solvent selected from hydrocarbons having about 5 to 12 carbon atoms; (2) allowing the mixture of step (1) to separate into 2 phases; and (3) recovering the extraction solvent phase containing iodide compounds (i) and (ii). The oligomer mixture of compounds (i) and/or (ii) is formed during the manufacture of 2,5-dihydrofurans by the isomerization of .gamma.,.delta.-epoxyalkenes.

    摘要翻译： 公开了从催化剂化合物和低聚材料的混合物中回收催化剂值的方法。 该方法提供了（i）碘化iodide化合物，（ⅱ）有机锡碘化合物或（ⅲ）其混合物在γ，δ-环氧 - 烯烃的低聚物中的混合物，其步骤为 （1）使混合物与选自具有约5至12个碳原子的烃的萃取溶剂紧密接触; （2）使步骤（1）的混合物分离成2相; 和（3）回收含碘化合物（i）和（ii）的萃取溶剂相。 化合物（i）和/或（ii）的低聚物混合物是通过γ，δ-环氧乙烷的异构化在制造2,5-二氢呋喃期间形成的。

    Silver halide light sensitive emulsion layer having enhanced photographic sensitivity
    6.
    发明授权
    Silver halide light sensitive emulsion layer having enhanced photographic sensitivity 失效
    具有增强的照相感光度的卤化银感光乳剂层

    公开(公告)号：US06306570B1

    公开(公告)日：2001-10-23

    申请号：US09536300

    申请日：2000-03-27

    申请人： Anthony Adin ,  Jerome J. Looker ,  Samir Y. Farid ,  Ian R. Gould ,  Stephen A. Godleski ,  Jerome R. Lenhard ,  Annabel A. Muenter ,  Lal C. Vishwakarma ,  Paul A. Zielinski

    发明人： Anthony Adin ,  Jerome J. Looker ,  Samir Y. Farid ,  Ian R. Gould ,  Stephen A. Godleski ,  Jerome R. Lenhard ,  Annabel A. Muenter ,  Lal C. Vishwakarma ,  Paul A. Zielinski

    IPC分类号： G03C110

    CPC分类号： G03C1/10 ,  G03C1/12 ,  G03C2200/24

    摘要： A photographic element comprising at least one silver halide emulsion layer in which the silver halide is sensitized with a compound of the formula: wherein A is a silver halide adsorptive group that contains at least one atom of N, S, Se, or Te that promotes adsorption to silver halide, and Z is a light absorbing group including for example cyanine dyes, complex cyanine dyes, merocyanine dyes, complex merocyanine dyes, homopolar cyanine dyes, styryl dyes, oxonol dyes, hemioxonol dyes, and hemicyanine dyes, and XY is an fragmentable electron donor moiety in which X is an electron donor group and Y is a leaving group other than hydrogen, and wherein: 1) XY has an oxidation potential between 0 and about 1.4 V; and 2) the oxidized form of XY undergoes a bond cleavage reaction to give the radical X• and the leaving fragment Y. In a preferred embodiment of the invention, the radical X• has an oxidation potential ≦−0.7 V.

    摘要翻译： 一种照相元件，包括至少一个卤化银乳剂层，其中卤化银用下式化合物致敏：其中A是含有至少一个促进的N，S，Se或Te原子的卤化银吸附基团 Z为吸光性基团，例如为花青染料，复合花青染料，部花菁染料，复色部花青染料，单极花青染料，苯乙烯基染料，氧杂菁染料，半氧杂菁染料，半花青染料，XY为 其中X是电子给体基团，Y是除氢以外的离去基团，其中：1）XY具有介于0和约1.4V之间的氧化电位; 和2）XY的氧化形式经历键断裂反应以得到基团X.和离去片段Y.在本发明的优选实施方案中，基团X具有<= -0.7V的氧化电位。

    Silver halide light sensitive emulsion layer having enhanced photographic sensitivity
    9.
    发明授权
    Silver halide light sensitive emulsion layer having enhanced photographic sensitivity 失效
    具有增强的照相感光度的卤化银感光乳剂层

    公开(公告)号：US6054260A

    公开(公告)日：2000-04-25

    申请号：US118714

    申请日：1998-07-17

    申请人： Anthony Adin ,  Jerome J. Looker ,  Samir Y. Farid ,  Ian R. Gould ,  Stephen A. Godleski ,  Jerome R. Lenhard ,  Annabel A. Muenter ,  Lal C. Vishwakarma ,  Paul A. Zielinski

    发明人： Anthony Adin ,  Jerome J. Looker ,  Samir Y. Farid ,  Ian R. Gould ,  Stephen A. Godleski ,  Jerome R. Lenhard ,  Annabel A. Muenter ,  Lal C. Vishwakarma ,  Paul A. Zielinski

    IPC分类号： G03C1/09 ,  G03C1/10 ,  G03C1/12

    CPC分类号： G03C1/10 ,  G03C1/12 ,  G03C2200/24

    摘要： A photographic element comprising at least one silver halide emulsion layer in which the silver halide is sensitized with a compound of the formula: ##STR1## wherein A is a silver halide adsorptive group that contains at least one atom of N, S, Se, or Te that promotes adsorption to silver halide, and Z is a light absorbing group including for example cyanine dyes, complex cyanine dyes, merocyanine dyes, complex merocyanine dyes, homopolar cyanine dyes, styryl dyes, oxonol dyes, hemioxonol dyes, and hemicyanine dyes, and XY is an fragmentable electron donor moiety in which X is an electron donor group and Y is a leaving group other than hydrogen, and wherein:1) XY has an oxidation potential between 0 and about 1.4 V; and2) the oxidized form of XY undergoes a bond cleavage reaction to give the radical X.sup..cndot. and the leaving fragment Y.In a preferred embodiment of the invention, the radical X.sup..cndot. has an oxidation potential .ltoreq.-0.7 V.

    摘要翻译： 一种照相元件，包括至少一个卤化银乳剂层，其中卤化银用下式化合物致敏：其中A是含有至少一个促进的N，S，Se或Te原子的卤化银吸附基团 Z为吸光性基团，例如为花青染料，复合花青染料，部花菁染料，复色部花青染料，单极花青染料，苯乙烯基染料，氧杂菁染料，半氧杂菁染料，半花青染料，XY为 其中X是电子给体基团，Y是除氢以外的离去基团，其中：1）XY具有介于0和约1.4V之间的氧化电位; 和2）XY的氧化形式经历键断裂反应，得到基团X.和离去片段Y.在本发明的一个优选实施方案中，基团X的氧化电势为-0.7V。