摘要:
A sintered lithium complex oxide characterized in that the sintered lithium complex oxide is constituted by sintering fine particles of a lithium complex oxide, the peak pore size giving the maximum differential pore volume is 0.80-5.00 μm, the total pore volume is 0.10-2.00 mL/g, the average particle size is not less than the above-specified peak pore size but not more than 20 μm, there is a sub-peak giving a differential pore volume not less than 10% of the maximum differential pore volume on the smaller pore size side with respect to the above-specified peak pore size, the pore size corresponding to the sub-peak is more than 0.50 μm but not more than 2.00 μm, the BET specific surface area of the sintered lithium complex oxide is 1.0-10.0 m2/g, and the half width of the maximum peak among X-ray diffraction peaks in an X-ray diffraction measurement is 0.12-0.30 deg.
摘要翻译:一种烧结锂复合氧化物,其特征在于,烧结锂复合氧化物是通过烧结锂复合氧化物的细颗粒构成的,提供最大微孔容积的峰值孔径为0.80-5.00μm,总孔体积为0.10-2.00mL / g,平均粒径不小于上述规定的峰值孔径但不大于20μm,具有不小于最大微孔容积的10%的微孔容积的次峰值在较小的 相对于上述规定的峰值孔径的孔径侧,与亚峰对应的孔径大于0.50μm且不大于2.00μm,烧结的锂复合氧化物的BET比表面积为1.0〜10.0 m 2 / g,X射线衍射测定中的X射线衍射峰中的最大峰的半值宽度为0.12-0.30度。
摘要:
The present invention provides a composite material for positive electrodes of lithium batteries, which provides a lithium battery having excellent high rate electrical discharge characteristics, has a sufficiently secured diffusion passage for Li, and has high conductivity, a process for producing the same, as well as a positive electrode and a battery using the composite material for positive electrodes of lithium batteries. The present invention relates to a composite material for positive electrodes of lithium batteries, comprising composite particles containing positive electrode active material particles and fibrous carbons, wherein the composite particles have a form in which the positive electrode active material particles are supported by the fibrous carbons.
摘要:
A positive electrode for a non-aqueous electrolyte secondary battery of the present invention has: a current collector; and a positive electrode active material layer formed on the current collector. The positive electrode active material layer contains, as positive electrode active materials, spinel lithium manganate, and a composite oxide represented by the following formula (1): LiCovNixMnyMzO2 (1) where v+x+y+z=1, M is any one selected from the group consisting of aluminum, gallium and indium, 0≦v≦0.5, 0.3≦x≦1, 0≦y≦0.5 and 0≦z≦0.1. Further, an average particle diameter of the composite oxide is larger than an average particle diameter of the spinel lithium manganate.
摘要翻译:本发明的非水电解质二次电池用正极具有:集电体; 以及形成在集电体上的正极活性物质层。 正极活性物质层含有作为正极活性物质的尖晶石锰酸锂和由下式(1)表示的复合氧化物:<?在线式描述=“在线式”末端=“铅 (ⅰ)Ni Ni x x x x O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O )其中v + x + y + z = 1,M是从由铝,镓和铟组成的组中选择的任意一种, 0 <= v <= 0.5,0.3 <= x <=1,0,0≤y≤0.5且0≤z≤0.1。 此外,复合氧化物的平均粒径大于尖晶石锰酸锂的平均粒径。
摘要:
A cell electrode of the present invention has a current collector and an active material layer formed on the current collector. The active material layer contains: an active material in which a mean particle diameter is more than 1 μm to 5 μm or less and a BET specific surface area is 1 to 5 m2/g; and a conductive material of which content is 3 to 50 mass % with respect to 100 mass % of the active material.
摘要:
A secondary battery electrode of the present invention has an electrode active material composed of particles with an average particle size of not more than 3 μm, and a conductive material contained in an amount of not less than 3 and less than 50 parts by weight with respect to 100 parts by weight of the electrode active material. The secondary battery electrode is capable of extracting a maximum effect of using fine particles as a constituent material.
摘要:
A control device of a secondary battery has a current detection unit (103) that detects a charge current to the secondary battery (101) and a discharge current from the secondary battery (101); a calculation unit (107) that calculates, from the charge current and the discharge current, a charge-discharge efficiency and a discharge-charge efficiency when performing a charge operation and a discharge operation; a deterioration judgment unit (107) that judges a deterioration state of the secondary battery (101) from a temporal change rate of the charge-discharge efficiency and a temporal change rate of the discharge-charge efficiency; and a control unit (107) that sets a charge termination voltage of the secondary battery (101) in accordance with the deterioration state.
摘要:
The burned composite metal oxide of the present invention is a burned composite metal oxide which is porous and particulate and which is obtained by subjecting a slurry comprising at least one metal oxide (a), at least one metal compound (b) and a solvent to spray granulation to obtain granules, and burning the granules, the metal oxide (a) selected from the group consisting of a transition metal oxide and an oxide of a metal belonging to 3B, 4B and 5B of a periodic table, the metal compound (b) selected from the group consisting of an alkali metal compound and an alkali earth metal compound, wherein the metal oxide (a) and the metal compound (b) are sparingly soluble in the solvent; the burning is conducted after a heat-maintaining step of heating the granules obtained by the spray granulation at a temperature in a range of ±200° C. based on the decomposition temperature of the metal compound (b); and the metal compound (b) contains at least a nonmetallic element component desorbed in the heat-maintaining step.
摘要:
An anode with a multi-layer structure including a first layer (21) having carbon as a main component, and a second layer (22) having lithium-ion conductivity and including a material as a main component thereof which can insert and extract lithium ions, or a multi-layer structure including a third layer (23) containing lithium in addition to the first layer and the second layer, and a lithium secondary battery including the same. The lithium secondary battery can be provided in which the battery capacity is substantially enhanced in the voltage range where the battery is actually used while maintaining the higher charge-discharge efficiency and the excellent cycle performance.
摘要:
An object of the present invention is to provide a negative electrode for a secondary battery which has large capacity and restrains a rise in resistance inside the battery and reduction in capacity even after cycles and the secondary battery using the same. A first active material layer 2a comprising members occluding and releasing Li onto a collector 1a is formed and a second active material layer 3a as an alloy layer containing metal forming alloy with lithium or lithium and metal not-forming alloy with lithium is formed thereon. The secondary battery is constituted using the negative electrode.
摘要:
A vacuum deposition apparatus is used for deposit evaporated substance from evaporation sources (6a and 6b) on the desired position of a flexible substrate (1). While the flexible substrate (1) is carried using rollers in a vacuum, shutters (8a and 8b) are opened and closed to control the movement of the evaporated substance via openings. A film having a desired shape of pattern is formed on the flexible substrate (1) with higher controllability.