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1.发明授权Esterification process using extractive separation to produce feed for hydrogenolysis 有权酯化过程采用萃取分离法生产饲料用于氢解公开(公告)号：US09024089B2
公开(公告)日：2015-05-05
申请号：US13299821
申请日：2011-11-18
申请人： R. Jay Warner , Wei Qi , Tatiana H. Sonnenberg
发明人： R. Jay Warner , Wei Qi , Tatiana H. Sonnenberg
IPC分类号： C07C29/12 , C07C29/149 , C07C67/08 , C07C67/58
CPC分类号： C07C29/149 , C07C67/08 , C07C67/58 , C07C69/14 , C07C31/08
摘要： Disclosed herein are processes for alcohol production by reducing an esterification product, such as ethyl acetate. The processes comprise esterifying acetic acid and an alcohol such as ethanol to produce an esterification product. The esterification product may be recovered using an extractive separation. The esterification product is reduced with hydrogen in the presence of a catalyst to obtain a crude reaction mixture comprising the alcohol, in particular ethanol, which may be separated from the crude reaction mixture.
摘要翻译： 本文公开了通过还原酯化产物如乙酸乙酯生产醇的方法。 该方法包括酯化乙酸和醇如乙醇以产生酯化产物。 可以使用萃取分离回收酯化产物。 在催化剂存在下，用氢还原酯化产物，得到包含可与粗反应混合物分离的醇，特别是乙醇的粗反应混合物。
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公开(公告)号：US08853468B2
公开(公告)日：2014-10-07
申请号：US13299771
申请日：2011-11-18
申请人： R. Jay Warner , Wei Qi , Tatiana H. Sonnenberg
发明人： R. Jay Warner , Wei Qi , Tatiana H. Sonnenberg
IPC分类号： C07C27/04 , C07C27/00 , C07C67/08 , C07C29/149
CPC分类号： C07C29/149 , C07C67/08 , C07C69/14 , C07C31/08
摘要： Disclosed herein are processes for alcohol production by reducing an esterification product, such as ethyl acetate. The processes comprise esterifying, in the vapor phase, acetic acid and an alcohol such as ethanol to produce the esterification product. The esterification product is reduced with hydrogen in the presence of a catalyst to obtain a crude reaction mixture comprising the alcohol, in particular ethanol, which may be separated from the crude reaction mixture.
摘要翻译： 本文公开了通过还原酯化产物如乙酸乙酯生产醇的方法。 该方法包括在汽相中酯化乙酸和醇如乙醇以产生酯化产物。 在催化剂存在下，用氢还原酯化产物，得到包含可与粗反应混合物分离的醇，特别是乙醇的粗反应混合物。
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公开(公告)号：US08884052B2
公开(公告)日：2014-11-11
申请号：US13327401
申请日：2011-12-15
申请人： Joseph G. Duff , Stephen Kerlegon , Kien V. Phung , Daniel Rangel-Osalde , Tatiana H. Sonnenberg , Cathy L. Tway , Hang Wang
发明人： Joseph G. Duff , Stephen Kerlegon , Kien V. Phung , Daniel Rangel-Osalde , Tatiana H. Sonnenberg , Cathy L. Tway , Hang Wang
IPC分类号： C07C67/035
摘要： In one embodiment, the invention is to a process for producing a vinyl acetate composition by contacting a vinyl acetate stream with acetic acid, ethylene, and oxygen to form a reaction mixture and reacting the reaction mixture in a reactor under conditions effective to form a crude vinyl acetate composition comprising vinyl acetate, water, acetic acid and at least 0.1 wt % diacetoxyethylene.
摘要翻译： 在一个实施方案中，本发明涉及通过使乙酸乙烯酯流与乙酸，乙烯和氧接触以形成反应混合物并使反应混合物在有效形成粗品的条件下在反应器中反应制备乙酸乙烯酯组合物的方法 乙酸乙烯酯组合物，其包含乙酸乙烯酯，水，乙酸和至少0.1重量％的二乙酰氧基乙烯。
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公开(公告)号：US20130158289A1
公开(公告)日：2013-06-20
申请号：US13327401
申请日：2011-12-15
申请人： Joseph G. Duff , Stephen Kerlegon , Kien V. Phung , Daniel Rangel-Osalde , Tatiana H. Sonnenberg , Cathy L. Tway , Hang Wang
发明人： Joseph G. Duff , Stephen Kerlegon , Kien V. Phung , Daniel Rangel-Osalde , Tatiana H. Sonnenberg , Cathy L. Tway , Hang Wang
摘要： In one embodiment, the invention is to a process for producing a vinyl acetate composition by contacting a vinyl acetate stream with acetic acid, ethylene, and oxygen to form a reaction mixture and reacting the reaction mixture in a reactor under conditions effective to form a crude vinyl acetate composition comprising vinyl acetate, water, acetic acid and at least 0.1 wt % diacetoxyethylene.
摘要翻译： 在一个实施方案中，本发明涉及通过使乙酸乙烯酯流与乙酸，乙烯和氧接触以形成反应混合物并使反应混合物在有效形成粗品的条件下在反应器中反应制备乙酸乙烯酯组合物的方法 乙酸乙烯酯组合物，其包含乙酸乙烯酯，水，乙酸和至少0.1重量％的二乙酰氧基乙烯。
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公开(公告)号：US20130131398A1
公开(公告)日：2013-05-23
申请号：US13299816
申请日：2011-11-18
申请人： R. Jay Warner , Wei Qi , Tatiana H. Sonnenberg
发明人： R. Jay Warner , Wei Qi , Tatiana H. Sonnenberg
IPC分类号： C07C29/149
CPC分类号： C07C67/08 , C07C29/149 , C07C29/80 , C07C31/08 , C07C69/14
摘要： Disclosed herein are processes for alcohol production by reducing an esterification product, such as ethyl acetate. The processes comprise esterifying acetic acid and an alcohol such as ethanol to produce an esterification product. The esterification product is reduced with hydrogen in the presence of a catalyst to obtain a crude reaction mixture comprising ethyl acetate, ethanol, and at least one alcohol having at least 4 carbon atoms. The ethanol is recovered with a reduced amount of the alcohol having at least 4 carbon atoms.
摘要翻译： 本文公开了通过还原酯化产物如乙酸乙酯生产醇的方法。 该方法包括酯化乙酸和醇如乙醇以产生酯化产物。 酯化产物在催化剂存在下用氢还原，得到包含乙酸乙酯，乙醇和至少一种具有至少4个碳原子的醇的粗反应混合物。 用减少量的具有至少4个碳原子的醇回收乙醇。
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6.发明申请Esterification Process Using Extractive Separation To Produce Feed For Hydrogenolysis 有权采用萃取分离技术生产饲料用于氢解的酯化方法公开(公告)号：US20130131393A1
公开(公告)日：2013-05-23
申请号：US13299821
申请日：2011-11-18
申请人： R. Jay Warner , Wei Qi , Tatiana H. Sonnenberg
发明人： R. Jay Warner , Wei Qi , Tatiana H. Sonnenberg
IPC分类号： C07C29/149 , C07C29/84
CPC分类号： C07C29/149 , C07C67/08 , C07C67/58 , C07C69/14 , C07C31/08
摘要： Disclosed herein are processes for alcohol production by reducing an esterification product, such as ethyl acetate. The processes comprise esterifying acetic acid and an alcohol such as ethanol to produce an esterification product. The esterification product may be recovered using an extractive separation. The esterification product is reduced with hydrogen in the presence of a catalyst to obtain a crude reaction mixture comprising the alcohol, in particular ethanol, which may be separated from the crude reaction mixture.
摘要翻译： 本文公开了通过还原酯化产物如乙酸乙酯生产醇的方法。 该方法包括酯化乙酸和醇如乙醇以产生酯化产物。 可以使用萃取分离回收酯化产物。 在催化剂存在下，用氢还原酯化产物，得到包含可与粗反应混合物分离的醇，特别是乙醇的粗反应混合物。
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公开(公告)号：US08829251B2
公开(公告)日：2014-09-09
申请号：US13299798
申请日：2011-11-18
申请人： R. Jay Warner , Wei Qi , Tatiana H. Sonnenberg
发明人： R. Jay Warner , Wei Qi , Tatiana H. Sonnenberg
IPC分类号： C07C29/149 , C07C67/08 , C07C29/80
CPC分类号： C07C29/149 , C07C29/80 , C07C67/08 , C07C31/08 , C07C69/14
摘要： Disclosed herein are processes for alcohol production by reducing an esterification product, such as ethyl acetate. The processes comprise esterifying, in the liquid phase, acetic acid and an alcohol such as ethanol to produce an esterification product. The esterification product is reduced with hydrogen in the presence of a catalyst to obtain a crude reaction mixture comprising the alcohol, in particular ethanol, which may be separated from the crude reaction mixture.
摘要翻译： 本文公开了通过还原酯化产物如乙酸乙酯生产醇的方法。 该方法包括在液相中酯化乙酸和醇如乙醇以产生酯化产物。 在催化剂存在下，用氢还原酯化产物，得到包含可与粗反应混合物分离的醇，特别是乙醇的粗反应混合物。
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公开(公告)号：US20130131396A1
公开(公告)日：2013-05-23
申请号：US13299730
申请日：2011-11-18
申请人： R. Jay Warner , Wei Qi , Tatiana H. Sonnenberg
发明人： R. Jay Warner , Wei Qi , Tatiana H. Sonnenberg
IPC分类号： C07C29/149 , C07C29/84
CPC分类号： C07C29/82 , C07C29/149 , C07C67/08 , C07C69/14 , C07C31/08
摘要： Disclosed herein are processes for alcohol production by reducing an esterification product, such as ethyl acetate. The processes comprise esterifying an excess molar ratio of acetic acid with an alcohol, such as ethanol, to produce the esterification product. The esterification product is reduced with hydrogen in the presence of a catalyst to obtain a crude reaction mixture comprising the alcohol, in particular ethanol, which may be separated from the crude reaction mixture.
摘要翻译： 本文公开了通过还原酯化产物如乙酸乙酯生产醇的方法。 该方法包括将过量摩尔比的乙酸与醇如乙醇酯化以产生酯化产物。 在催化剂存在下，用氢还原酯化产物，得到包含可与粗反应混合物分离的醇，特别是乙醇的粗反应混合物。
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公开(公告)号：US08859827B2
公开(公告)日：2014-10-14
申请号：US13299730
申请日：2011-11-18
申请人： R. Jay Warner , Wei Qi , Tatiana H. Sonnenberg
发明人： R. Jay Warner , Wei Qi , Tatiana H. Sonnenberg
IPC分类号： C07C29/149 , C07C67/08 , C07C29/82
CPC分类号： C07C29/82 , C07C29/149 , C07C67/08 , C07C69/14 , C07C31/08
摘要： Disclosed herein are processes for alcohol production by reducing an esterification product, such as ethyl acetate. The processes comprise esterifying an excess molar ratio of acetic acid with an alcohol, such as ethanol, to produce the esterification product. The esterification product is reduced with hydrogen in the presence of a catalyst to obtain a crude reaction mixture comprising the alcohol, in particular ethanol, which may be separated from the crude reaction mixture.
摘要翻译： 本文公开了通过还原酯化产物如乙酸乙酯生产醇的方法。 该方法包括将过量摩尔比的乙酸与醇如乙醇酯化以产生酯化产物。 在催化剂存在下，用氢还原酯化产物，得到包含可与粗反应混合物分离的醇，特别是乙醇的粗反应混合物。
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10.发明申请COPOLYMERS OF 1,2-DIACETOXYETHYLENE AND VINYL ACETATE, PROCESS OF MAKING THE COPOLYMERS AND PROCESS OF MAKING A COPOLYMERIZED POLYVINYL ALCOHOL 审中-公开1,2-二乙氧基乙烯和乙酸乙烯酯的共聚物，制备共聚物的方法和制备共聚聚乙烯醇的方法公开(公告)号：US20140024766A1
公开(公告)日：2014-01-23
申请号：US13554599
申请日：2012-07-20
申请人： Joseph G. Duff , Stephen Kerlegon , Kien-Van Phung , Daniel Rangel-Osalde , Tatiana H. Sonnenberg , Cathy Tway , Hang Wang
发明人： Joseph G. Duff , Stephen Kerlegon , Kien-Van Phung , Daniel Rangel-Osalde , Tatiana H. Sonnenberg , Cathy Tway , Hang Wang
IPC分类号： C08F216/06 , C08L29/04 , C08F8/00
CPC分类号： C08F216/06 , C08F8/12 , C08F218/08 , C08F218/14
摘要： In one embodiment, the invention is to a vinyl acetate/diacetoxyethylene copolymer, processes of making the copolymer and processes of hydrolyzing said copolymer to form a copolymerized polyvinyl alcohol.
摘要翻译： 在一个实施方案中，本发明涉及一种乙酸乙烯酯/二乙酰氧基乙烯共聚物，制备共聚物的方法和水解所述共聚物以形成共聚的聚乙烯醇的方法。
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