公开(公告)号：US20080132647A1

公开(公告)日：2008-06-05

申请号：US12012811

申请日：2008-02-06

Applicant: Manoj Ajbani ,  Christopher Kiehl ,  Thierry Florent Edme Materne

Inventor： Manoj Ajbani ,  Christopher Kiehl ,  Thierry Florent Edme Materne

IPC: C08F8/00

CPC classification number: C08L23/16 ,  C08L9/02 ,  C08L9/06 ,  C08L15/00 ,  C08L15/005 ,  C08L21/00 ,  C08L23/10 ,  C08L23/12 ,  C08L23/14 ,  C08L25/00 ,  C08L53/005 ,  C08L53/02 ,  C08L53/025 ,  C08L71/12 ,  C08L91/00 ,  C08L2205/02 ,  C08L2205/03 ,  C08L2205/035 ,  C08L2312/00 ,  Y10T428/31826 ,  Y10T428/31931 ,  Y10T428/31935 ,  C08L2666/24 ,  C08L2666/06 ,  C08L2666/02 ,  C08L2666/08 ,  C08L2666/04

Abstract: The present invention relates to a polymeric composition which has an excellent combination of properties for use in making seals and gaskets for utilization in appliances, automotive applications, and building applications, such as window glazing gaskets. These polymeric compositions offer excellent dimensional stability, low compression set, outstanding sealing characteristics, low temperature flexibility, heat resistance and ultra-violet light resistance. The present invention more specifically discloses a polymeric composition having excellent characteristics for utilization in manufacturing seals and gaskets including dimensional stability, low compression set and outstanding sealing characteristics, said polymeric composition being comprised of a blend of (A) a thermoplastic resin selected from the group consisting of polypropylene, polyethylene, poly phenylene ether, polystyrene, and styrene containing copolymer resins, (B) an elastomeric polymer selected from the group consisting of block copolymer comprising a first polymeric block that is comprised of repeat units that are derived from a vinyl aromatic monomer and a second block that is comprised of repeat units that are derived from a conjugated diolefin monomer, wherein the repeat units in the second block are hydrogenated, and wherein the repeat units in the second block are elastomeric in nature, and a crosslinked olefinic elastomer, (C) a high molecular weight crosslinked diene elastomer comprised of repeat units that are derived from conjugated diene monomer selected from the group consisting of 1,3-butadiene and isoprene, wherein the high molecular weight diene elastomer has a weight average molecular weight of at least about 200,000, and (D) an oil.

Abstract translation: 本发明涉及一种聚合物组合物，其具有用于制造用于制造密封件的特性和用于家用电器，汽车应用以及建筑应用（例如窗玻璃垫片）的垫圈的优异组合。 这些聚合物组合物具有优异的尺寸稳定性，低压缩永久变形，优异的密封特性，低温柔韧性，耐热性和耐紫外光性。 本发明更具体地公开了一种聚合物组合物，其具有用于制造密封件和垫片的优异特性，包括尺寸稳定性，低压缩永久变形和优异的密封特性，所述聚合物组合物由（A）选自组 由聚丙烯，聚乙烯，聚苯醚，聚苯乙烯和含苯乙烯的共聚物树脂组成的弹性体聚合物，（B）弹性体聚合物，其选自由包含衍生自乙烯基芳族化合物的重复单元组成的第一聚合物嵌段的嵌段共聚物 单体和由衍生自共轭二烯烃单体的重复单元组成的第二嵌段，其中第二嵌段中的重复单元被氢化，并且其中第二嵌段中的重复单元本质上是弹性体，并且交联的烯属弹性体 ，（C）高分子量交联二 烯属弹性体由衍生自选自1,3-丁二烯和异戊二烯的共轭二烯单体的重复单元组成，其中高分子量二烯弹性体的重均分子量为至少约20万，（D） 一种油

公开(公告)号：US06753375B2

公开(公告)日：2004-06-22

申请号：US09897316

申请日：2001-07-02

Applicant: Giorgio Agostini ,  Thierry Florent Edme Materne

Inventor： Giorgio Agostini ,  Thierry Florent Edme Materne

IPC: C08J300

CPC classification number: C08K9/04 ,  C08K9/02 ,  C08K9/06 ,  C08L23/16

Abstract: This invention relates to preparation of a rubber composition by pre-mixing at least one functionalized carbon black with an organic solvent solution or aqueous emulsion of at least one host elastomer. Functionalized carbon blacks for the purposes of this invention preferably contain a functional moiety on their surface to aid in promoting covalent bonds between the functionalized carbon black and said host polymer. The invention also contemplates the use of such rubber composition, or blend of such rubber composition with at least one additional elastomer and/or rubber compounding ingredient, as a component of an article of manufacture. Such article of manufacture may be, for example, a tire. Such article may also be an industrial product such as, for example, a hose or belt such as a conveyor belt or power transmission belt.

Abstract translation: 本发明涉及通过将至少一种官能化炭黑与至少一种主体弹性体的有机溶剂溶液或水性乳液预混合来制备橡胶组合物。 用于本发明目的的官能化炭黑优选在其表面上含有官能部分以有助于促进官能化炭黑和所述主体聚合物之间的共价键。 本发明还考虑使用这种橡胶组合物或这种橡胶组合物与至少一种另外的弹性体和/或橡胶配混成分的共混物作为制品的组分。 这种制造品可以是例如轮胎。 这种制品也可以是工业产品，例如软管或皮带，例如输送带或动力传动带。

公开(公告)号：US06410625B1

公开(公告)日：2002-06-25

申请号：US09535484

申请日：2000-03-24

Applicant: Thierry Florent Edme Materne ,  Rene Jean Zimmer ,  Friedrich Visel ,  Uwe Ernst Frank ,  Giorgio Agostini

Inventor： Thierry Florent Edme Materne ,  Rene Jean Zimmer ,  Friedrich Visel ,  Uwe Ernst Frank ,  Giorgio Agostini

IPC: C08J320

CPC classification number: C08K5/548 ,  C07F7/1804 ,  C08L21/00

Abstract: The present invention relates to asymmetrical siloxy compounds of the formula wherein R1, R2 and R3 are independently selected from the group consisting of alkoxy radicals having from 1 to 8 carbon atoms; R4 is selected from the group consisting of alkylene groups having from 1 to 1.5 carbon atoms and arylene and alkyl-substituted arylene groups having from 6 to 10 carbon atoms; n is an integer of from 2 to 8 and X is selected from the group consisting of and R5 is selected from the group consisting of alkyl groups having from 1 to 15 carbon atoms, aryl and alkyl substituted aryl groups having 6 to 10 carbon atoms.

Abstract translation: 本发明涉及式R 1，R 2和R 3的不对称甲硅烷氧基化合物独立地选自具有1至8个碳原子的烷氧基; R 4选自具有1至1.5个碳原子的亚烷基和具有6至10个碳原子的亚芳基和烷基取代的亚芳基; n为2〜8的整数，X选自由以下组成的组，R 5选自碳原子数为1〜15的烷基，碳原子数为6〜10的芳基和烷基取代芳基。

公开(公告)号：US06255379B1

公开(公告)日：2001-07-03

申请号：US09397751

申请日：1999-09-16

Applicant: Bruce Raymond Hahn ,  Thierry Florent Edme Materne

Inventor： Bruce Raymond Hahn ,  Thierry Florent Edme Materne

IPC: C08K300

CPC classification number: C08K5/548 ,  B60C1/00 ,  B60C1/0016 ,  B60C1/0025 ,  C08K7/02 ,  C08L21/00 ,  C08L2666/08

Abstract: The invention relates to composites of rubber compositions reinforced with short, discontinuous fibers together with an anchoring agent. Preferably, the rubber composition is exclusive of amorphous silica. The invention also relates to articles, including industrial products and tires, which have at least one component thereof. The invention particularly relates to industrial rubber belts having at least one component of such rubber composite and to tires with at least one component of such rubber composite.

Abstract translation: 本发明涉及用短的不连续纤维与锚固剂一起增强的橡胶组合物的复合材料。 优选地，橡胶组合物不包括无定形二氧化硅。 本发明还涉及具有至少一种组分的制品，包括工业产品和轮胎。 本发明特别涉及具有这种橡胶复合材料的至少一种组分的工业橡胶带和具有这种橡胶复合材料的至少一种组分的轮胎。

公开(公告)号：US6084014A

公开(公告)日：2000-07-04

申请号：US33302

申请日：1998-03-02

Applicant: Thierry Florent Edme Materne ,  Rene Jean Zimmer ,  Friedrich Visel ,  Uwe Ernst Frank ,  Giorgio Agostini

Inventor： Thierry Florent Edme Materne ,  Rene Jean Zimmer ,  Friedrich Visel ,  Uwe Ernst Frank ,  Giorgio Agostini

IPC: C07F7/22 ,  C07F7/18 ,  C08K3/04 ,  C08K3/36 ,  C08K5/5419 ,  C08K5/548 ,  C08L9/00 ,  C08L7/00 ,  C08L11/00 ,  C08L23/00 ,  C08L25/00

CPC classification number: C07F7/1836 ,  C08K5/548

Abstract: The present invention relates to asymmetrical siloxy compounds of the formula ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are independently selected from the group consisting of alkoxy radicals having from 1 to 8 carbon atoms; R.sup.4 is selected from the group consisting of alkylene groups having from 1 to 15 carbon atoms and arylene and alkyl-substituted arylene groups having from 6 to 10 carbon atoms; n is an integer of from 2 to 8 and X is selected from the group consisting of ##STR2## and R.sup.5 is selected from the group consisting of alkyl groups having from 1 to 15 carbon atoms, aryl and alkyl substituted aryl groups having 6 to 10 carbon atoms.

Abstract translation: 本发明涉及下式的不对称甲硅烷氧基化合物，其中R 1，R 2和R 3独立地选自具有1至8个碳原子的烷氧基; R 4选自具有1至15个碳原子的亚烷基和具有6至10个碳原子的亚芳基和烷基取代的亚芳基; n为2〜8的整数，X选自由R 5选自具有1至15个碳原子的烷基，芳基和具有6至10个碳原子的烷基取代的芳基组成的组。

公开(公告)号：US5760110A

公开(公告)日：1998-06-02

申请号：US801426

申请日：1997-02-18

Applicant: Rene Jean Zimmer ,  Uwe Ernst Frank ,  Friedrich Visel ,  Thierry Florent Edme Materne ,  Giorgio Agostini

Inventor： Rene Jean Zimmer ,  Uwe Ernst Frank ,  Friedrich Visel ,  Thierry Florent Edme Materne ,  Giorgio Agostini

IPC: B60C1/00 ,  C08K3/04 ,  C08K3/06 ,  C08K3/22 ,  C08K3/36 ,  C08K5/44 ,  C08K5/548 ,  C08K9/04 ,  C08L9/00 ,  C09C1/28 ,  C09C1/40 ,  C09C1/56 ,  C08K5/46 ,  C08K3/08 ,  C08K3/34

CPC classification number: C08K5/548

Abstract: The invention relates to a process for the preparation of a rubber composition involving thermomechanically mixing in a preparatory mixing step at least one sulfur vulcanizable elastomer, a particulate filler and an unsymmetrical organosilicon disulfide compound of the formula ##STR1## wherein Z is selected from the group consisting of: ##STR2## wherein R.sup.2 may be the same or different and is independently selected from the group consisting of an alkyl group having 1 to 4 carbons and phenyl; R.sup.3 may be the same of different and is independently selected from the group consisting of alkoxy groups having 1 to 8 carbon atoms and cycloalkoxy groups with 5 to 8 carbon atoms; and R.sup.1 is selected from the group consisting of a substituted or unsubstituted alkylene group having a total of 1 to 18 carbon atoms and a substituted or unsubstituted arylene group having a total of 6 to 12 carbon atoms.

Abstract translation: 本发明涉及一种制备橡胶组合物的方法，所述橡胶组合物在制备混合步骤中热机械混合至少一种硫可硫化弹性体，颗粒填料和式“IMAGE”的不对称有机硅二硫化物化合物，其中Z选自 其组成为：其中R 2可以相同或不同，并且独立地选自具有1至4个碳原子的烷基和苯基; R3可以相同，不同，独立地选自碳原子数为1〜8的烷氧基和碳原子数为5〜8的环烷氧基。 并且R 1选自具有总共1至18个碳原子的取代或未取代的亚烷基和具有总共6至12个碳原子的取代或未取代的亚芳基。

公开(公告)号：US07825194B2

公开(公告)日：2010-11-02

申请号：US12287426

申请日：2008-10-10

Applicant: Lei Zheng ,  Eric Sean Castner ,  Thierry Florent Edme Materne

Inventor： Lei Zheng ,  Eric Sean Castner ,  Thierry Florent Edme Materne

IPC: C08F8/42 ,  C08F36/04 ,  C08F36/08 ,  C08F36/06

CPC classification number: C08F257/02 ,  C08C1/15 ,  C08F6/22 ,  C08F236/06 ,  C08L51/00

Abstract: This invention discloses a process for synthesizing a hairy polymer particle which comprises the steps of (1) polymerizing a vinyl aromatic monomer by emulsion polymerization in an aqueous medium to produce core particles, (2) recovering the core particles from the aqueous medium, (3) dispersing the core particles in an organic solvent, (4) adding an organo-lithium compound to the dried core particles in the organic solvent to produce the hairless core initiator, and (5) utilizing the hairless core initiator to initiate the anionic polymerization of a conjugated diolefin monomer in an organic solvent to produce a solution of the hairy polymer particles. The hairy polymer nanoparticles can then be recovered from the organic solvent. These hairy polymer particles are comprised of (1) a core which is comprised of a polymer of a vinyl aromatic monomer and (2) hairs which are polymer chains of a conjugated diolefin monomer, wherein the hairs are covalently bonded to the core. The core is typically spherical in shape, has a diameter of less than 1000 nm, and is comprised of a crosslinked polymer of a vinyl aromatic monomer. The hairy polymer particles of this invention are useful as fillers in rubber compositions used in making articles of manufacture, such as tires, hoses, power transmission belts, windshield wiper blades, and the like.

Abstract translation: 本发明公开了一种合成毛状聚合物颗粒的方法，其包括以下步骤：（1）通过乳液聚合在水性介质中聚合乙烯基芳族单体以产生核心颗粒，（2）从水介质中回收芯颗粒，（3 ）将核心颗粒分散在有机溶剂中，（4）将有机锂化合物加入到有机溶剂中的干燥芯颗粒中以制备无毛芯引发剂，和（5）利用无毛芯引发剂引发阴离子聚合 共轭二烯单体在有机溶剂中以产生毛状聚合物颗粒的溶液。 然后可以从有机溶剂中回收毛状聚合物纳米颗粒。 这些毛发聚合物颗粒包括（1）由乙烯基芳族单体的聚合物组成的芯和（2）作为共轭二烯烃单体的聚合物链的毛发，其中毛发共价键合到芯上。 芯通常为球形，直径小于1000nm，并且由乙烯基芳族单体的交联聚合物组成。 本发明的毛发聚合物颗粒可用作用于制造制品的橡胶组合物中的填料，例如轮胎，软管，动力传动带，挡风玻璃刮水器等。

公开(公告)号：US20090042719A1

公开(公告)日：2009-02-12

申请号：US12287426

申请日：2008-10-10

Applicant: Lei Zheng ,  Eric Sean Castner ,  Thierry Florent Edme Materne

Inventor： Lei Zheng ,  Eric Sean Castner ,  Thierry Florent Edme Materne

IPC: B01J31/12

CPC classification number: C08F257/02 ,  C08C1/15 ,  C08F6/22 ,  C08F236/06 ,  C08L51/00

Abstract: This invention discloses a process for synthesizing a hairy polymer particle which comprises the steps of (1) polymerizing a vinyl aromatic monomer by emulsion polymerization in an aqueous medium to produce core particles, (2) recovering the core particles from the aqueous medium, (3) dispersing the core particles in an organic solvent, (4) adding an organo-lithium compound to the dried core particles in the organic solvent to produce the hairless core initiator, and (5) utilizing the hairless core initiator to initiate the anionic polymerization of a conjugated diolefin monomer in an organic solvent to produce a solution of the hairy polymer particles. The hairy polymer nanoparticles can then be recovered from the organic solvent. These hairy polymer particles are comprised of (1) a core which is comprised of a polymer of a vinyl aromatic monomer and (2) hairs which are polymer chains of a conjugated diolefin monomer, wherein the hairs are covalently bonded to the core. The core is typically spherical in shape, has a diameter of less than 1000 nm, and is comprised of a crosslinked polymer of a vinyl aromatic monomer. The hairy polymer particles of this invention are useful as fillers in rubber compositions used in making articles of manufacture, such as tires, hoses, power transmission belts, windshield wiper blades, and the like.

Abstract translation: 本发明公开了一种合成毛状聚合物颗粒的方法，其包括以下步骤：（1）通过乳液聚合在水性介质中聚合乙烯基芳族单体以产生核心颗粒，（2）从水介质中回收芯颗粒，（3 ）将核心颗粒分散在有机溶剂中，（4）将有机锂化合物加入到有机溶剂中的干燥芯颗粒中以制备无毛芯引发剂，和（5）利用无毛芯引发剂引发阴离子聚合 共轭二烯单体在有机溶剂中以产生毛状聚合物颗粒的溶液。 然后可以从有机溶剂中回收毛状聚合物纳米颗粒。 这些毛发聚合物颗粒包括（1）由乙烯基芳族单体的聚合物组成的芯和（2）作为共轭二烯烃单体的聚合物链的毛发，其中毛发共价键合到芯上。 芯通常为球形，直径小于1000nm，并且由乙烯基芳族单体的交联聚合物组成。 本发明的毛发聚合物颗粒可用作用于制造制品的橡胶组合物中的填料，例如轮胎，软管，动力传动带，挡风玻璃刮水器等。

公开(公告)号：US07365131B2

公开(公告)日：2008-04-29

申请号：US11106977

申请日：2005-04-15

Applicant: Manoj Ajbani ,  Christopher Kiehl ,  Thierry Florent Edme Materne

Inventor： Manoj Ajbani ,  Christopher Kiehl ,  Thierry Florent Edme Materne

IPC: C08F8/00 ,  C08L33/04 ,  C08L9/00 ,  C08L23/00 ,  C08L23/04 ,  C08G18/42

CPC classification number: C08L53/025 ,  C08L21/00 ,  C08L23/06 ,  C08L23/12 ,  C08L25/06 ,  C08L35/06 ,  C08L53/00 ,  C08L53/02 ,  C08L71/12 ,  C08L91/00 ,  C08L2666/02 ,  C08L2666/24 ,  C08L2666/04 ,  C08L2666/14 ,  C08L2666/20

Abstract: A thermoplastic vulcanizate composition comprised of (a) thermoplastic resin selected from the group consisting of polyphenylene ether, polypropylene, polyethylene, and polystyrene, (b) at least one elastomer selected from the group consisting of butadiene-isoprene copolymer rubbers, copolymers of a conjugated diolefin monomer and an acrylate monomer, copolymers of a conjugated diolefin monomer and an methacrylate monomer, copolymers of a conjugated diolefin monomer and a vinyl aromatic monomer, copolymers of a conjugated diolefin monomer and an acrylonitrile monomer, blends of polyisoprene rubber with styrene-butadiene rubber, wherein the elastomer is at least partially crosslinked, wherein the repeat units in the elastomer are distributed throughout the elastomer in an essentially random manner, and (c) oil.

Abstract translation: 一种热塑性硫化胶组合物，其包含（a）选自聚苯醚，聚丙烯，聚乙烯和聚苯乙烯的热塑性树脂，（b）至少一种选自丁二烯 - 异戊二烯共聚物橡胶的共聚物，共轭 二烯烃单体和丙烯酸酯单体，共轭二烯烃单体和甲基丙烯酸酯单体的共聚物，共轭二烯烃单体和乙烯基芳族单体的共聚物，共轭二烯烃单体和丙烯腈单体的共聚物，聚异戊二烯橡胶与苯乙烯 - 丁二烯橡胶的共混物 ，其中弹性体至少部分交联，其中弹性体中的重复单元以基本上随机的方式分布在整个弹性体中，和（c）油。

公开(公告)号：US07264868B2

公开(公告)日：2007-09-04

申请号：US10672675

申请日：2003-09-26

Applicant: Manoj Ajbani ,  Christopher Kiehl ,  Thierry Florent Edme Materne

Inventor： Manoj Ajbani ,  Christopher Kiehl ,  Thierry Florent Edme Materne

IPC: B32B15/06 ,  B32B25/08

CPC classification number: C08L51/006 ,  B32B25/04 ,  C08C19/02 ,  C08K5/01 ,  C08L15/00 ,  C08L21/00 ,  C08L53/025 ,  C08L71/12 ,  C08L101/00 ,  Y10T428/24983 ,  Y10T428/31692 ,  Y10T428/31696 ,  Y10T428/31699 ,  Y10T428/31931 ,  Y10T428/31935 ,  C08L2666/02 ,  C08L2666/04

Abstract: The present invention discloses an article of manufacture comprising a soft thermoplastic elastomer composition overmolded onto a hard substrate, wherein the soft thermoplastic composition includes (a) 5 to 60 parts by weight of a thermoplastic resin, (b) 5 to 70 parts of a rubbery elastomer comprised of repeat units that are derived from a conjugated diene monomer, wherein the rubbery elastomer is optionally at least partially crosslinked, and wherein the rubbery polymer is a solution polymer, (c) 5 to 90 parts of a highly saturated elastomer selected from the group consisting of styrene-ethylene butylene-styrene polymers, styrene-ethylene propylene-styrene polymers, hydrogenated polybatadiene, hydrogenated polyisoprene, hydrogenated styrene-isoprene random copolymers, hydrogenated styrene-butadiene random copolymers, and (d) 15 to 200 parts by weight of an oil.

Abstract translation: 本发明公开了一种包含模塑在硬质基材上的软质热塑性弹性体组合物的制品，其中软质热塑性组合物包含（a）5-60重量份的热塑性树脂，（b）5-70重量份的橡胶状 弹性体由衍生自共轭二烯单体的重复单元构成，其中橡胶状弹性体任选地至少部分交联，其中橡胶状聚合物为溶液聚合物，（c）5-90份高度饱和的弹性体，其选自 由苯乙烯 - 乙烯 - 丁烯 - 苯乙烯聚合物组成的组，苯乙烯 - 乙烯丙烯 - 苯乙烯聚合物，氢化聚二
烯二烯，氢化聚异戊二烯，氢化苯乙烯 - 异戊二烯无规共聚物，氢化苯乙烯 - 丁二烯无规共聚物，和（d）15-200重量份 一种油