利索-全球专利检索

  1. 登录
  2. 注册

搜索结果

23 条记录 (耗时 0.019 秒)

    Thermosetting composition and process for preparing fiber-reinforced composites
    3.
    发明授权
    Thermosetting composition and process for preparing fiber-reinforced composites 有权
    热固性组合物和制备纤维增强复合材料的方法

    公开(公告)号：US09309354B2

    公开(公告)日：2016-04-12

    申请号：US14117878

    申请日：2012-06-06

    申请人： Nigel Shields ,  Martin Reimers ,  Nikhil K. E. Verghese ,  Timothy A. Morley ,  Marty J. Null ,  Rajesh H. Turakhia

    发明人： Nigel Shields ,  Martin Reimers ,  Nikhil K. E. Verghese ,  Timothy A. Morley ,  Marty J. Null ,  Rajesh H. Turakhia

    IPC分类号： C08L63/00 ,  C08G59/62 ,  C08G59/56 ,  B29C70/40 ,  C08K7/06 ,  B29C70/44 ,  B29C70/48 ,  B29K63/00

    CPC分类号： C08G59/621 ,  B29C70/40 ,  B29C70/44 ,  B29C70/48 ,  B29K2063/00 ,  C08G59/56 ,  C08G59/623 ,  C08K7/06 ,  C08L63/00

    摘要： A two-component curable epoxy resin system is disclosed. The resin system includes an epoxy resin component containing at least 80% by weight of a polyglycidyl ether of a polyphenol that has an epoxy equivalent weight of up to about 200 and contains no more than 2% by weight of monohydrolyzed resin species. The system also includes a hardener mixture that has an amino hydrogen equivalent weight of from 35 to 90 and contains at least 90% by weight of a mixture of (i) from 5 to 75% of the combined weight of (i), (ii) and (iii) of one or more compounds that have at least two primary and/or secondary aliphatic amino groups and which have no phenolic groups; (ii) from 10 to 95% of the combined weight of (i), (ii) and (iii) of one or more aminophenol compounds that contain one or more primary and/or secondary aliphatic amino groups and at least one phenolic group and (iii) from 0 to 50% of the combined weight of (i), (ii) and (iii) of one or more phenolic compounds that contain two or more phenolic groups and do not contain primary or secondary amino groups. The epoxy resin component and hardener mixture are present in amounts sufficient to provide from 1.05 to 1.35 equivalents of aliphatic amine hydrogens per equivalent of epoxide groups provided by the epoxy resin component. The system has beneficial curing characteristics that make it useful for producing fiber-reinforced composites in a resin transfer molding process.

    摘要翻译： 公开了一种双组分可固化环氧树脂体系。 该树脂体系包含环氧树脂组分，其含有至少80重量％的多酚的多缩水甘油醚，其环氧当量为至多约200，并且含有不超过2重量％的单水解树脂种类。 该系统还包括具有35至90的氨基氢当量的固化剂混合物，并且含有至少90重量％的（i）（i），（i），（ii）的组合重量的5至75重量％ ）和（iii）一种或多种具有至少两个伯和/或仲脂族氨基并且不具有酚基的化合物; （ii）含有一个或多个伯和/或仲脂族氨基和至少一个酚基的一种或多种氨基苯酚化合物的（i），（ii）和（iii）的组合重量的10至95％ （iii）含有两个或多个酚基并且不含伯或仲氨基的一种或多种酚类化合物的（i），（ii）和（iii）的组合重量的0至50％。 环氧树脂组分和硬化剂混合物的存在量足以提供每环氧树脂组分提供的每当量环氧基团1.05-1.35当量的脂族胺氢。 该系统具有有益的固化特性，使其可用于在树脂传递模塑工艺中生产纤维增强复合材料。

    Polyfunctional Polyglycerine Initiated Polyether Polyols and High Resilience Polyurethane Slabstock Therefrom
    4.
    发明申请
    Polyfunctional Polyglycerine Initiated Polyether Polyols and High Resilience Polyurethane Slabstock Therefrom 审中-公开
    多官能聚甘油引发的聚醚多元醇和高弹性聚氨酯板坯

    公开(公告)号：US20140206787A1

    公开(公告)日：2014-07-24

    申请号：US13578658

    申请日：2011-02-25

    申请人： Francois M. Casati ,  Esther E. Quintanilla ,  Hanno R. Van der Wal ,  Timothy A. Morley ,  Peter Mullaert

    发明人： Francois M. Casati ,  Esther E. Quintanilla ,  Hanno R. Van der Wal ,  Timothy A. Morley ,  Peter Mullaert

    IPC分类号： C08G18/48 ,  C08G65/34

    CPC分类号： C08G18/4866 ,  C08G18/48 ,  C08G65/2609 ,  C08G65/34 ,  C08G65/48 ,  C08G2101/0025 ,  C08G2650/24 ,  C08G2650/54

    摘要： A polyglycerine initiated polyether polyol exhibiting a final functionality less than the nominal functionalities of the polyol initiator wherein the initiator is a polyglycerine formed by the polymerization of glycerin having an HEW less than about 35 and exhibiting a nominal functionality between 2 and 16 is provided. Also provided is a process for producing a polyfunctional polyurethane by the reaction of a mixture containing a polyol based on polyglycerine initiator wherein between 5 wt % and 100 wt % of the total initiator is polyglycerine having a nominal functionality between 2 and 16, at least one organic isocyanate, an amine and/or a metal salt catalyst, and optionally a blowing agent. Also provided is a flexible polyurethane foam comprising a reaction product of a polyglycerine or formed by the glycidol polymerization of glycerin, at least one organic isocyanate, and an amine catalyst.

    摘要翻译： 提供了最终官能度低于多元醇引发剂的标称官能度的聚甘油引发的聚醚多元醇，其中引发剂是通过HEW低于约35并表现出标称官能度在2和16之间的甘油的聚合形成的聚甘油。 还提供了通过含有基于聚甘油引发剂的多元醇的混合物的反应来制备多官能聚氨酯的方法，其中总引发剂的5重量％至100重量％是标称官能度为2至16的聚甘油，至少一种 有机异氰酸酯，胺和/或金属盐催化剂，以及任选的发泡剂。 还提供了包含聚甘油的反应产物或通过甘油的缩水甘油聚合形成的柔性聚氨酯泡沫，至少一种有机异氰酸酯和胺催化剂。

    Isocyanate trimerisation catalyst system, a precursor formulation, a process for trimerising isocyanates, rigid polyisocyanurate/polyurethane foams made therefrom, and a process for making such foams
    8.
    发明授权
    Isocyanate trimerisation catalyst system, a precursor formulation, a process for trimerising isocyanates, rigid polyisocyanurate/polyurethane foams made therefrom, and a process for making such foams 有权

    公开(公告)号：US10294322B2

    公开(公告)日：2019-05-21

    申请号：US15621171

    申请日：2017-06-13

    申请人： Phillip S. Athey ,  Nathan Wilmot ,  Richard J. Keaton ,  David A. Babb ,  Cecile Boyer ,  Timothy A. Morley

    发明人： Phillip S. Athey ,  Nathan Wilmot ,  Richard J. Keaton ,  David A. Babb ,  Cecile Boyer ,  Timothy A. Morley

    IPC分类号： C08G18/02 ,  C08G18/09 ,  C08G18/16 ,  C08G18/18 ,  C08G101/00

    摘要： The instant invention provides an isocyanate trimerization catalyst system, a precursor formulation, a process for trimerizing isocyanates, rigid foams made therefrom, and a process for making such foams. The trimerization catalyst system comprises: (a) a phosphatrane cation; and (b) an isocyanate-trimer inducing anion; wherein said trimerization catalyst system has a trimerization activation temperature in the range of equal to or less than 73° C. The precursor formulation comprises (1) at least 25 percent by weight of polyol, based on the weight of the precursor formulation; (2) less than 15 percent by weight of a trimerization catalyst system, based on the weight of the precursor formulation, comprising; (a) a phosphatrane cation; and (c) an isocyanate-trimer inducing anion; wherein said trimerization catalyst system has a trimerization activation temperature in the range of equal to or less than 73° C.; and (4) optionally one or more surfactants, one or more flame retardants, water, one or more antioxidants, one or more auxiliary blowing agents, one or more urethane catalysts, one or more auxiliary trimerization catalysts, or combinations thereof. The process for trimerization of isocyanates comprises the steps of: (1) providing one or more monomers selected from the group consisting of an isocyanate, a diisocyanate, a triisocyanate, oligomeric isocyanate, a salt of any thereof, and a mixture of any thereof; (2) providing a trimerization catalyst system comprising; (a) an phosphatrane cation; and (b) an isocyanate-trimer inducing anion; (c) wherein said trimerization catalyst system has a trimerization activation temperature in the range of equal to or less than 73° C.; (3) trimerizing said one or more monomers in the presence of said trimerization catalyst; (4) thereby forming an isocyanurate ring. The process for making the PIR foam comprises the steps of: (1) providing one or more monomers selected from the group consisting of an isocyanate, a diisocyanate, a triisocyanate, oligomeric isocyanate, a salt of any thereof, and a mixture of any thereof; (2) providing polyol; (3) providing a trimerization catalyst system comprising; (a) a phosphatrane cation; and (b) an isocyanate-trimer inducing anion; wherein said trimerization catalyst system has a trimerization activation temperature in the range of equal to or less than 73° C.; and (4) optionally providing one or more surfactants, one or more flame retardants, water, one or more antioxidants, one or more auxiliary blowing agents, one or more urethane catalysts, one or more auxiliary trimerization catalysts, or combinations thereof; (5) contacting said one or more monomers, and said polyol, and optionally said one or more surfactants, and optionally said one or more flame retardants, and optionally said water, and optionally said one or more antioxidants, and optionally said one or more auxiliary blowing agents in the presence of said trimerization catalyst system and optionally said one or more urethane catalysts, and optionally said one or more auxiliary trimerization catalysts; (6) thereby forming said polyisocyanurate/polyurethane rigid foam. The PIR foam comprises the reaction product of one or more monomers selected from the group consisting of an isocyanate, a diisocyanate, a triisocyanate, oligomeric isocyanate, a salt of any thereof, and a mixture of any thereof with polyol in the presence of a trimerization catalyst system comprising a phosphatrane cation, and an isocyanate-trimer inducing anion, and optionally one or more surfactants, optionally one or more flame retardants, optionally water, optionally one or more antioxidants, optionally one or more auxiliary blowing agents, optionally one or more additional urethane catalysts, and optionally one or more auxiliary trimerization catalysts, or optionally combinations thereof, wherein the trimerization catalyst system has a trimerization activation temperature in the range of equal to or less than 73° C.The PIR foam comprises the reaction product of one or more monomers selected from the group consisting of an isocyanate, a diisocyanate, a triisocyanate, oligomeric isocyanate, a salt of any thereof, and a mixture of any thereof with polyol in the presence of a trimerization catalyst system comprising a phosphatrane cation, and an isocyanate-trimer inducing anion, and optionally one or more surfactants, optionally one or more flame retardants, optionally water, optionally one or more antioxidants, optionally one or more auxiliary blowing agents, optionally one or more additional polyurethane catalysts, and optionally one or more auxiliary trimerization catalysts, or optionally combinations thereof, wherein the PIR foam has a polyisocyanurate trimer ratio (Abs1410/Abs1595) of at least 5 at a depth of 12 mm from the rising surface of the rigid foam, measured via ATR-FTIR spectroscopy.

    ISOCYANATE TRIMERISATION CATALYST SYSTEM, A PRECURSOR FORMULATION, A PROCESS FOR TRIMERISING ISOCYANATES, RIGID POLYISOCYANURATE/POLYURETHANE FOAMS MADE THEREFROM, AND A PROCESS FOR MAKING SUCH FOAMS
    9.
    发明申请
    ISOCYANATE TRIMERISATION CATALYST SYSTEM, A PRECURSOR FORMULATION, A PROCESS FOR TRIMERISING ISOCYANATES, RIGID POLYISOCYANURATE/POLYURETHANE FOAMS MADE THEREFROM, AND A PROCESS FOR MAKING SUCH FOAMS 审中-公开

    公开(公告)号：US20110201706A1

    公开(公告)日：2011-08-18

    申请号：US13125476

    申请日：2009-11-09

    申请人： Phillip S. Athey ,  Nathan Wilmot ,  Richard Keaton ,  Cecile Boyer ,  Timothy A. Morley

    发明人： Phillip S. Athey ,  Nathan Wilmot ,  Richard Keaton ,  Cecile Boyer ,  Timothy A. Morley

    IPC分类号： C08J9/00 ,  C07C53/00

    CPC分类号： C08G18/022 ,  C08G18/092 ,  C08G18/168 ,  C08G18/1858 ,  C08G18/1883 ,  C08G18/791 ,  C08G2101/0025 ,  C08G2105/02

    摘要： The instant invention provides an isocyanate trimerisation catalyst system, a precursor formulation, a process for trimerising isocyanates, rigid foams made therefrom, and a process for making such foams. The trimerisation catalyst system comprises: (a) a substituted iminium cation; and (b) an isocyanate-trimer inducing anion; wherein said trimerisation catalyst system has a trimerisation activation temperature in the range of equal to or less than 73° C. The precursor formulation comprises (1) at least 25 percent by weight of polyol, based on the weight of the precursor formulation; (2) less than 15 percent by weight of a trimerisation catalyst system, based on the weight of the precursor formulation, comprising; (a) a substituted iminium cation; and (c) an isocyanate-trimer inducing anion; wherein said trimerisation catalyst system has a trimerisation activation temperature in the range of equal to or less than 73° C.; and (4) optionally one or more surfactants, one or more flame retardants, water, one or more antioxidants, one or more auxiliary blowing agents, one or more urethane catalysts, one or more auxiliary trimerisation catalysts, or combinations thereof. The process for trimerisation of isocyanates comprises the steps of: (1) providing one or more monomers selected from the group consisting of an isocyanate, a diisocyanate, a triisocyanate, oligomeric isocyanate, a salt of any thereof, and a mixture of any thereof; (2) providing a trimerisation catalyst system comprising; (a) an substituted iminium cation; and (b) an isocyanate-trimer inducing anion; (c) wherein said trimerisation catalyst system has a trimerisation activation temperature in the range of equal to or less than 73° C.; (3) trimerising said one or more monomers in the presence of said trimerisation catalyst; (4) thereby forming an isocyanurate ring. The process for making the PIR foam comprises the steps of: (1) providing one or more monomers selected from the group consisting of an isocyanate, a diisocyanate, a triisocyanate, oligomeric isocyanate, a salt of any thereof, and a mixture of any thereof; (2) providing polyol; (3) providing a trimerisation catalyst system comprising; (a) a substituted iminium cation; and (b) an isocyanate-trimer inducing anion; wherein said trimerisation catalyst system has a trimerisation activation temperature in the range of equal to or less than 73° C.; and (4) optionally providing one or more surfactants, one or more flame retardants, water, one or more antioxidants, one or more auxiliary blowing agents, one or more urethane catalysts, one or more auxiliary trimerisation catalysts, or combinations thereof; (5) contacting said one or more monomers, and said polyol, and optionally said one or more surfactants, and optionally said one or more flame retardants, and optionally said water, and optionally said one or more antioxidants, and optionally said one or more auxiliary blowing agents in the presence of said trimerisation catalyst system and optionally said one or more urethane catalysts, and optionally said one or more auxiliary trimerisation catalysts; (6) thereby forming said polyisocyanurate/polyurethane rigid foam. The PIR foam comprises the reaction product of one or more monomers selected from the group consisting of an isocyanate, a diisocyanate, a triisocyanate, oligomeric isocyanate, a salt of any thereof, and a mixture of any thereof with polyol in the presence of a trimerisation catalyst system comprising a substituted iminium cation, and an isocyanate-trimer inducing anion, and optionally one or more surfactants, optionally one or more flame retardants, optionally water, optionally one or more antioxidants, optionally one or more auxiliary blowing agents, optionally one or more additional urethane catalysts, and optionally one or more auxiliary trimerisation catalysts, or optionally combinations thereof, wherein the trimerisation catalyst system has a trimerisation activation temperature in the range of equal to or less than 73° C. The PIR foam comprises the reaction product of one or more monomers selected from the group consisting of an isocyanate, a diisocyanate, a triisocyanate, oligomeric isocyanate, a salt of any thereof, and a mixture of any thereof with polyol in the presence of a trimerisation catalyst system comprising a substituted iminium cation, and an isocyanate-trimer inducing anion, and optionally one or more surfactants, optionally one or more flame retardants, optionally water, optionally one or more antioxidants, optionally one or more auxiliary blowing agents, optionally one or more additional polyurethane catalysts, and optionally one or more auxiliary trimerisation catalysts, or optionally combinations thereof, wherein the PIR foam has a polyisocyanurate trimer ratio (Abs1410/Abs1595) of at least 5 at a depth of 12 mm from the rising surface of the rigid foam, measured via ATR-FTIR spectroscopy.