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公开(公告)号：US20130079262A1
公开(公告)日：2013-03-28
申请号：US13247717
申请日：2011-09-28
Applicant: Vilas G. POL , Michael M. THACKERAY , Kuldeep MISTRY , Ali ERDEMIR
Inventor： Vilas G. POL , Michael M. THACKERAY , Kuldeep MISTRY , Ali ERDEMIR
IPC: C10M129/72 , C10M125/10 , C10M125/26 , C10M125/24 , C10M125/02 , C10M125/22 , B82Y30/00
CPC classification number: C10M125/02 , B01J31/2239 , B01J2531/845 , B82Y30/00 , B82Y40/00 , C10M129/72 , C10M169/04 , C10M177/00 , C10M2201/041 , C10M2201/0413 , C10M2201/061 , C10M2201/065 , C10M2201/085 , C10M2205/0285 , C10M2207/12 , C10M2207/28 , C10M2207/283 , C10M2207/289 , C10N2210/01 , C10N2210/04 , C10N2210/05 , C10N2210/06 , C10N2210/08 , C10N2220/08 , C10N2220/082 , C10N2230/06 , C10N2240/10 , C10N2250/10 , C10N2250/16 , C10N2270/00
Abstract: This invention relates to carbon-based materials as anti-friction and anti-wear additives for advanced lubrication purposes. The materials have various shapes, sizes, and structures and are synthesized by autogenic reactions under extreme conditions of high temperature and pressure. The lubricant compositions comprise carbon-based particles suspended in a liquid hydrocarbon carrier. Optionally, the compositions further comprise a surfactant (e.g., to aid in dispersion of the carbon particles). Specifically, the novel lubricants have the ability to significantly lower friction and wear, which translates into improved fuel economies and longer durability of mechanical devices and engines.
Abstract translation: 本发明涉及碳基材料作为用于高级润滑目的的抗摩擦和耐磨添加剂。 该材料具有各种形状，大小和结构，并在高温高压条件下通过自发反应合成。 润滑剂组合物包含悬浮在液体烃载体中的碳基颗粒。 任选地，组合物还包含表面活性剂（例如，以帮助碳颗粒的分散）。 具体来说，新型润滑剂具有显着降低摩擦和磨损的能力，这转化为改进的燃料经济性和机械装置和发动机的更长的耐久性。
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公开(公告)号：US20110104576A1
公开(公告)日：2011-05-05
申请号：US12915580
申请日：2010-10-29
Applicant: Christopher S. JOHNSON , Vilas G. POL , Zhengcheng ZHANG
Inventor： Christopher S. JOHNSON , Vilas G. POL , Zhengcheng ZHANG
CPC classification number: H01M4/587 , B82Y30/00 , H01M4/131 , H01M4/133 , H01M4/136 , H01M4/366 , H01M4/485 , H01M4/5825 , H01M4/625
Abstract: A lithium-oxygen electrochemical cell of the invention comprises a lithium-containing anode, an oxygen-permeable cathode, a non-aqueous electrolyte comprising a lithium salt in a non-aqueous liquid between the anode and the cathode, and a source of gaseous oxygen in fluid communication with the cathode; the cathode comprising an oxygen-permeable support bearing carbon nanotubes having at least one open end. In some embodiments, the cell is rechargeable and the cathode includes a nanoparticulate catalyst in contact with the carbon nanotubes; wherein the catalyst is adapted to facilitate the reversible interconversion between oxygen gas and an oxygen anion e.g., oxide ion, peroxide ion, or a combination thereof, during charge and discharge of the cell.
Abstract translation: 本发明的锂 - 氧电化学电池包括含锂阳极，透氧阴极，在阳极和阴极之间的非水液体中包含锂盐的非水电解质和气态氧源 与阴极流体连通; 所述阴极包括具有至少一个开口端的具有碳纳米管的氧气可渗透支撑体。 在一些实施方案中，电池是可再充电的，阴极包括与碳纳米管接触的纳米颗粒催化剂; 其中所述催化剂适于在所述电池的充电和放电期间促进氧气和氧阴离子之间的可逆相互转换，例如氧化物离子，过氧化物离子或其组合。
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公开(公告)号：US08153094B2
公开(公告)日：2012-04-10
申请号：US12507300
申请日：2009-07-22
Applicant: Vilas G. Pol , Pappannan Thiyagarajan
Inventor： Vilas G. Pol , Pappannan Thiyagarajan
CPC classification number: B82Y40/00 , B82Y30/00 , C01B32/05 , C01B32/16 , C01B32/162 , C01B32/20 , C01B2202/06
Abstract: A single step process for degrading plastic waste by converting the plastic waste into carbonaceous products via thermal decomposition of the plastic waste by placing the plastic waste into a reactor, heating the plastic waste under an inert or air atmosphere until the temperature of 700° C. is achieved, allowing the reactor to cool down, and recovering the resulting decomposition products therefrom. The decomposition products that this process yields are carbonaceous materials, and more specifically egg-shaped and spherical-shaped solid carbons. Additionally, in the presence of a transition metal compound, this thermal decomposition process produces multi-walled carbon nanotubes.
Abstract translation: 通过将塑料废物放入反应器中，将塑料废物通过热分解将塑料废物转化为碳质产品，在惰性或空气气氛下加热废塑料直到700°C ，使反应器冷却，并从中回收所得到的分解产物。 该方法产生的分解产物是碳质材料，更特别是卵形和球形固体碳。 此外，在过渡金属化合物的存在下，该热分解过程产生多壁碳纳米管。
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公开(公告)号：US20110104553A1
公开(公告)日：2011-05-05
申请号：US12915395
申请日：2010-10-29
Applicant: Vilas G. POL , Swati V. POL , Michael M. THACKERAY
Inventor： Vilas G. POL , Swati V. POL , Michael M. THACKERAY
CPC classification number: H01M4/587 , B82Y30/00 , H01M4/131 , H01M4/133 , H01M4/136 , H01M4/366 , H01M4/485 , H01M4/5825 , H01M4/625
Abstract: A lithium- or lithium-ion electrochemical cell of the present invention comprises a lithium-containing cathode, an anode, and a non-aqueous lithium-containing electrolyte therebetween; wherein one or more of the anode and the cathode comprises at least one particulate carbon-containing material selected from the group consisting of one or more carbon-coated metal oxide or metal phosphate particles, carbon-containing metals that alloy with Li, carbon-containing metalloids that alloy with Li, or rounded carbon particles such as carbon spheres, prolate-shaped spheroids, oblate-shaped spheroids, and carbon nanotubes. In a preferred embodiment, the particulate carbon material is prepared by reacting one or more solid, solvent-free chemical precursor materials comprising the elements making up the material in an enclosed autogenic pressure reactor in which the precursor materials are dissociated and reacted at elevated temperature, thereby creating self-generated pressure within the reactor.
Abstract translation: 本发明的锂离子电池或锂离子电化学电池包含含锂阴极，阳极和其中的非水性含锂电解质; 其中阳极和阴极中的一个或多个包括至少一种选自一种或多种碳涂覆的金属氧化物或金属磷酸盐颗粒的含碳物质，与Li合金的含碳金属，含碳的 与Li合金的准金属，或碳球，扁圆形球体，扁圆形球体和碳纳米管等圆形碳颗粒。 在优选的实施方案中，颗粒状碳材料通过使一种或多种不含固体的无溶剂的化学前体材料制成，所述化学前体材料包含构成材料的元件在封闭的自生压力反应器中，其中前体材料在升高的温度下解离和反应， 从而在反应器内产生自产生的压力。
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公开(公告)号：US20100178232A1
公开(公告)日：2010-07-15
申请号：US12507300
申请日：2009-07-22
Applicant: Vilas G. Pol , Pappannan Thiyagarajan
Inventor： Vilas G. Pol , Pappannan Thiyagarajan
IPC: C01B31/02
CPC classification number: B82Y40/00 , B82Y30/00 , C01B32/05 , C01B32/16 , C01B32/162 , C01B32/20 , C01B2202/06
Abstract: A single step process for degrading plastic waste by converting the plastic waste into carbonaceous products via thermal decomposition of the plastic waste by placing the plastic waste into a reactor, heating the plastic waste under an inert or air atmosphere until the temperature of 700° C. is achieved, allowing the reactor to cool down, and recovering the resulting decomposition products therefrom. The decomposition products that this process yields are carbonaceous materials, and more specifically egg-shaped and spherical-shaped solid carbons. Additionally, in the presence of a transition metal compound, this thermal decomposition process produces multi-walled carbon nanotubes.
Abstract translation: 通过将塑料废物放入反应器中，将塑料废物通过热分解将塑料废物转化为碳质产品，在惰性或空气气氛下加热废塑料直到700°C ，使反应器冷却，并从中回收所得到的分解产物。 该方法产生的分解产物是碳质材料，更特别是卵形和球形固体碳。 此外，在过渡金属化合物的存在下，该热分解过程产生多壁碳纳米管。
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公开(公告)号：US08648019B2
公开(公告)日：2014-02-11
申请号：US13247717
申请日：2011-09-28
Applicant: Vilas G. Pol , Michael M. Thackeray , Kuldeep Mistry , Ali Erdemir
Inventor： Vilas G. Pol , Michael M. Thackeray , Kuldeep Mistry , Ali Erdemir
IPC: C10M169/04
CPC classification number: C10M125/02 , B01J31/2239 , B01J2531/845 , B82Y30/00 , B82Y40/00 , C10M129/72 , C10M169/04 , C10M177/00 , C10M2201/041 , C10M2201/0413 , C10M2201/061 , C10M2201/065 , C10M2201/085 , C10M2205/0285 , C10M2207/12 , C10M2207/28 , C10M2207/283 , C10M2207/289 , C10N2210/01 , C10N2210/04 , C10N2210/05 , C10N2210/06 , C10N2210/08 , C10N2220/08 , C10N2220/082 , C10N2230/06 , C10N2240/10 , C10N2250/10 , C10N2250/16 , C10N2270/00
Abstract: This invention relates to carbon-based materials as anti-friction and anti-wear additives for advanced lubrication purposes. The materials have various shapes, sizes, and structures and are synthesized by autogenic reactions under extreme conditions of high temperature and pressure. The lubricant compositions comprise carbon-based particles suspended in a liquid hydrocarbon carrier. Optionally, the compositions further comprise a surfactant (e.g., to aid in dispersion of the carbon particles). Specifically, the novel lubricants have the ability to significantly lower friction and wear, which translates into improved fuel economies and longer durability of mechanical devices and engines.
Abstract translation: 本发明涉及碳基材料作为用于高级润滑目的的抗摩擦和耐磨添加剂。 该材料具有各种形状，大小和结构，并在高温高压条件下通过自发反应合成。 润滑剂组合物包括悬浮在液体烃载体中的碳基颗粒。 任选地，组合物还包含表面活性剂（例如，以帮助碳颗粒的分散）。 具体来说，新型润滑剂具有显着降低摩擦和磨损的能力，这转化为改进的燃料经济性和机械装置和发动机的更长的耐久性。
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公开(公告)号：US08580222B2
公开(公告)日：2013-11-12
申请号：US13422811
申请日：2012-03-16
Applicant: Vilas G. Pol , Pappannan Thiyagarajan
Inventor： Vilas G. Pol , Pappannan Thiyagarajan
CPC classification number: B82Y40/00 , B82Y30/00 , C01B32/16 , C01B32/162 , C01B2202/06 , C08L25/08
Abstract: A single step process for degrading plastic waste by converting the plastic waste into carbonaceous products via thermal decomposition of the plastic waste by placing the plastic waste into a reactor, heating the plastic waste under an inert or air atmosphere until the temperature of about 700° C. is achieved, allowing the reactor to cool down, and recovering the resulting decomposition products therefrom. The decomposition products that this process yields are carbonaceous materials, and more specifically carbon nanotubes having a partially filled core (encapsulated) adjacent to one end of the nanotube. Additionally, in the presence of a transition metal compound, this thermal decomposition process produces multi-walled carbon nanotubes.
Abstract translation: 通过将塑料废物放入反应器中，通过将塑料废物热分解，将塑料废物转化成碳质产品，将塑料废物转化为碳质产品，在惰性或空气氛围下加热塑料废物直至温度达到约700°C ，使反应器冷却，并从中回收所得到的分解产物。 该方法产生的分解产物是碳质材料，更具体地，具有与纳米管的一端相邻的部分填充芯（封装）的碳纳米管。 此外，在过渡金属化合物的存在下，该热分解过程产生多壁碳纳米管。
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8.发明授权
公开(公告)号：US09314770B2
公开(公告)日：2016-04-19
申请号：US13247759
申请日：2011-09-28
Applicant: Brian J. Ingram , Vilas G. Pol , Donald C. Cronauer , Muruganathan Ramanathan
Inventor： Brian J. Ingram , Vilas G. Pol , Donald C. Cronauer , Muruganathan Ramanathan
IPC: C07C1/20 , B01J21/06 , C01G19/02 , C01G23/047 , B82Y30/00 , C07C1/12 , C01F17/00 , B01J37/08 , B01J37/14 , B01J23/06 , B01J23/10 , B01J23/14 , B01J23/745 , B01J35/00
CPC classification number: B01J21/063 , B01J23/06 , B01J23/10 , B01J23/14 , B01J23/745 , B01J35/0013 , B01J35/004 , B01J37/08 , B01J37/084 , B01J37/14 , B82Y30/00 , C01F17/0043 , C01G19/02 , C01G23/047 , C01P2002/54 , C01P2002/72 , C01P2002/82 , C01P2002/85 , C01P2004/04 , C01P2004/64 , C01P2006/80 , C07C1/12 , C07C2521/06 , C07C2523/06 , C07C2523/10 , C07C2523/14 , C07C2523/745 , Y02P20/52 , C07C9/04
Abstract: In one preferred embodiment, a photocatalyst for conversion of carbon dioxide and water to a hydrocarbon and oxygen comprises at least one nanoparticulate metal or metal oxide material that is substantially free of a carbon coating, prepared by heating a metal-containing precursor compound in a sealed reactor under a pressure autogenically generated by dissociation of the precursor material in the sealed reactor at a temperature of at least about 600° C. to form a nanoparticulate carbon-coated metal or metal oxide material, and subsequently substantially removing the carbon coating. The precursor material comprises a solid, solvent-free salt comprising a metal ion and at least one thermally decomposable carbon- and oxygen-containing counter-ion, and the metal of the salt is selected from the group consisting of Mn, Ti, Sn, V, Fe, Zn, Zr, Mo, Nb, W, Eu, La, Ce, In, and Si.
Abstract translation: 在一个优选实施方案中，用于将二氧化碳和水转化为烃和氧的光催化剂包括至少一种基本上不含碳涂层的纳米颗粒金属或金属氧化物材料，其通过将密封的含金属的前体化合物 反应器在压力下通过在密封的反应器中在至少约600℃的温度下解离前体材料而产生的压力，以形成纳米颗粒碳涂覆的金属或金属氧化物材料，随后基本上除去碳涂层。 前体材料包含固体的无溶剂盐，其包含金属离子和至少一种可热分解的含碳和氧的反离子，并且所述盐的金属选自Mn，Ti，Sn， V，Fe，Zn，Zr，Mo，Nb，W，Eu，La，Ce，In和Si。
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公开(公告)号：US08568914B2
公开(公告)日：2013-10-29
申请号：US12915395
申请日：2010-10-29
Applicant: Vilas G. Pol , Swati V. Pol , Michael M. Thackeray
Inventor： Vilas G. Pol , Swati V. Pol , Michael M. Thackeray
CPC classification number: H01M4/587 , B82Y30/00 , H01M4/131 , H01M4/133 , H01M4/136 , H01M4/366 , H01M4/485 , H01M4/5825 , H01M4/625
Abstract: A lithium- or lithium-ion electrochemical cell of the present invention comprises a lithium-containing cathode, an anode, and a non-aqueous lithium-containing electrolyte therebetween; wherein one or more of the anode and the cathode comprises at least one particulate carbon-containing material selected from the group consisting of one or more carbon-coated metal oxide or metal phosphate particles, carbon-containing metals that alloy with Li, carbon-containing metalloids that alloy with Li, or rounded carbon particles such as carbon spheres, prolate-shaped spheroids, oblate-shaped spheroids, and carbon nanotubes. In a preferred embodiment, the particulate carbon material is prepared by reacting one or more solid, solvent-free chemical precursor materials comprising the elements making up the material in an enclosed autogenic pressure reactor in which the precursor materials are dissociated and reacted at elevated temperature, thereby creating self-generated pressure within the reactor.
Abstract translation: 本发明的锂离子电池或锂离子电化学电池包含含锂阴极，阳极和其中的非水性含锂电解质; 其中阳极和阴极中的一个或多个包括至少一种选自一种或多种碳涂覆的金属氧化物或金属磷酸盐颗粒的含碳物质，与Li合金的含碳金属，含碳的 与Li合金的准金属，或碳球，扁圆形球体，扁圆形球体和碳纳米管等圆形碳颗粒。 在优选的实施方案中，颗粒状碳材料通过使一种或多种不含固体的无溶剂的化学前体材料制成，所述化学前体材料包含构成材料的元件在封闭的自生压力反应器中，其中前体材料在升高的温度下解离和反应， 从而在反应器内产生自产生的压力。
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10.发明申请
公开(公告)号：US20130079577A1
公开(公告)日：2013-03-28
申请号：US13247759
申请日：2011-09-28
Applicant: Brian J. INGRAM , Vilas G. POL , Donald C. CRONAUER , Muruganathan RAMANATHAN
Inventor： Brian J. INGRAM , Vilas G. POL , Donald C. CRONAUER , Muruganathan RAMANATHAN
CPC classification number: B01J21/063 , B01J23/06 , B01J23/10 , B01J23/14 , B01J23/745 , B01J35/0013 , B01J35/004 , B01J37/08 , B01J37/084 , B01J37/14 , B82Y30/00 , C01F17/0043 , C01G19/02 , C01G23/047 , C01P2002/54 , C01P2002/72 , C01P2002/82 , C01P2002/85 , C01P2004/04 , C01P2004/64 , C01P2006/80 , C07C1/12 , C07C2521/06 , C07C2523/06 , C07C2523/10 , C07C2523/14 , C07C2523/745 , Y02P20/52 , C07C9/04
Abstract: In one preferred embodiment, a photocatalyst for conversion of carbon dioxide and water to a hydrocarbon and oxygen comprises at least one nanoparticulate metal or metal oxide material that is substantially free of a carbon coating, prepared by heating a metal-containing precursor compound in a sealed reactor under a pressure autogenically generated by dissociation of the precursor material in the sealed reactor at a temperature of at least about 600° C. to form a nanoparticulate carbon-coated metal or metal oxide material, and subsequently substantially removing the carbon coating. The precursor material comprises a solid, solvent-free salt comprising a metal ion and at least one thermally decomposable carbon- and oxygen-containing counter-ion, and the metal of the salt is selected from the group consisting of Mn, Ti, Sn, V, Fe, Zn, Zr, Mo, Nb, W, Eu, La, Ce, In, and Si.
Abstract translation: 在一个优选实施方案中，用于将二氧化碳和水转化为烃和氧的光催化剂包括至少一种基本上不含碳涂层的纳米颗粒金属或金属氧化物材料，其通过将密封的含金属的前体化合物 反应器在压力下通过在密封的反应器中在至少约600℃的温度下解离前体材料而产生的压力，以形成纳米颗粒碳涂覆的金属或金属氧化物材料，随后基本上除去碳涂层。 前体材料包含固体的无溶剂盐，其包含金属离子和至少一种可热分解的含碳和氧的反离子，并且所述盐的金属选自Mn，Ti，Sn， V，Fe，Zn，Zr，Mo，Nb，W，Eu，La，Ce，In和Si。
