摘要:
The invention describes a process for preparing acetone starting from acetyl-coenzyme A comprising process steps A. enzymatic conversion of acetyl-CoA into acetoacetyl-CoA B. enzymatic conversion of acetoacetyl-CoA into acetoacetate and CoA and C. decarboxylation of acetoacetate to acetone and CO2, which is characterized in that the coenzyme A is not transferred in process step B to an acceptor molecule. In addition, process step B is surprisingly catalysed by enzymes of the classes of acyl-CoA thioesterase, acyl-CoA synthetase or acyl-CoA thiokinase.A completely novel metabolic pathway is concerned, because the enzymatic hydrolysis of acetoacetyl-CoA without simultaneous transfer of CoA to a receptor molecule has never previously been described for any microbial enzyme.
摘要翻译:本发明描述了从乙酰辅酶A开始制备丙酮的方法,包括方法步骤A.将乙酰辅酶A酶促转化为乙酰乙酰辅酶A.将乙酰乙酰辅酶A酶促转化为乙酰乙酸酯,并将乙酰乙酸酯脱羧至丙酮, CO 2,其特征在于辅酶A在工艺步骤B中不转移到受体分子。 此外,工艺步骤B由酰基-CoA硫酯酶,酰基辅酶A合成酶或酰基辅酶A硫代激酶类的催化剂惊人地催化。 关注一个完全新颖的代谢途径,因为乙酰乙酰辅酶A的酶水解而不会同时转移CoA到受体分子,从未以前没有描述任何微生物酶。
摘要:
The invention describes a process for preparing acetone starting from acetyl-coenzyme A comprising process steps A. enzymatic conversion of acetyl-CoA into acetoacetyl-CoA B. enzymatic conversion of acetoacetyl-CoA into acetoacetate and CoA and C. decarboxylation of acetoacetate to acetone and CO2, which is characterized in that the coenzyme A is not transferred in process step B to an acceptor molecule. In addition, process step B is surprisingly catalyzed by enzymes of the classes of acyl-CoA thioesterase, acyl-CoA synthetase or acyl-CoA thiokinase.A completely novel metabolic pathway is concerned, because the enzymatic hydrolysis of acetoacetyl-CoA without simultaneous transfer of CoA to a receptor molecule has never previously been described for any microbial enzyme.
摘要翻译:本发明描述了从乙酰辅酶A开始制备丙酮的方法,包括方法步骤A.将乙酰辅酶A酶促转化为乙酰乙酰辅酶A.将乙酰乙酰辅酶A酶促转化为乙酰乙酸酯,并将乙酰乙酸酯脱羧至丙酮, CO 2,其特征在于辅酶A在工艺步骤B中不转移到受体分子。 此外,方法步骤B令人惊奇地由酰基-CoA硫酯酶,酰基辅酶A合成酶或酰基辅酶A硫代激酶类的酶催化。 关注一个完全新颖的代谢途径,因为乙酰乙酰辅酶A的酶水解而不会同时转移CoA到受体分子,从未以前没有描述任何微生物酶。
摘要:
A water-soluble or water-dispersible binder based on polybutadienes which is modified with at least 5% by weight of maleic anhydride and wherein at least 30% of the anhydride groups are present as imide groups from reaction with an amino carboxylic acid.
摘要:
A hyperbranched polyurethane which is obtainable by reacting a diisocyante or polyisocyanate with a triol of the formula (1) where R and R″ each independently of one another are hydrogen or an alkyl group having 1 to 4 carbon atoms and where n is an integer greater than 2 and which has a numerical average of at least 4 repeating units of the formula (2) per molecule.
摘要:
An epoxidized polyalkenylene is prepared reacting a polyalkenylene, an aqueous solution of 15 to 90% by volume of hydrogen peroxide and a carboxylic acid having from 1 to 3 carbon atoms in the presence of a catalyst which is phosphonic acid, a derivative of phosphonic acid or a mixture thereof, without addition of an organic solvent or water, to obtain the epoxidized polyalkenylene. The epoxidized polyalkenylene has a number-average molar mass of between 500 and 50 000 g/mol and an epoxide oxygen content of between 1 and 25 percent by mass.
摘要:
Ketone-aldehyde resins with wide compatibility, process for their preparation, and their use. The invention relates to ketone-aldehyde resins with wide compatibility comprising cycloaliphatic ketones and, in particular, formaldehyde and, if desired, further monomers, to a process for their preparation and to their use as hard resin in paints, printing inks and other coatings, especially in pigment preparations.
摘要:
Non-aqueous ball point pen inks, which contain dyes, resins, solvents and additives which demonstrate improved rheological behavior under the most varied climatic conditions. Leaking and spotting are reliably avoided, and ink production is simplified. Alcohol-soluble cellulose derivatives are used as additives.
摘要:
A water-soluble or water-dispersible binder based on polybutadienes which is modified with at least 5% by weight of maleic anhydride and wherein at least 30% of the anhydride groups are present as imide groups from reaction with an amino carboxylic acid.