公开(公告)号：US4724195A

公开(公告)日：1988-02-09

申请号：US742394

申请日：1985-06-07

申请人： Werner H. Muller ,  Arnold Schneller

发明人： Werner H. Muller ,  Arnold Schneller

IPC分类号： C08F20/00 ,  C08F20/10 ,  C08F20/22 ,  C08F20/26 ,  C08F212/00 ,  C08F212/14 ,  C08F220/24 ,  C08F220/30 ,  C08F220/34 ,  C08F220/40 ,  G03F7/004 ,  G03F7/023 ,  G03C1/60 ,  G03C1/68 ,  G03C1/71

CPC分类号： G03F7/0046 ,  C08F212/14 ,  C08F220/24 ,  C08F220/30 ,  G03F7/0233

摘要： Copolymers comprising perfluoroalkyl groups, reproduction layers containing these copolymers and use thereof for waterless offset printing. The novel perfluoroalkyl group-containing copolymers are prepared from at least two different monomers, monomer (a) comprising acryloyl or methacryloyl groups and phenolic OH groups and monomer (b) comprising acryloyloxy, methacryloyloxy or vinyl groups and a perfluoroalkyl group. Monomer component (a) can, for example, be prepared from a hydroxybenzoic acid by esterification with a hydroxyalkyl-acrylate. The novel copolymers are, in particular, used as binders in radiation-sensitive reproduction layers which additionally contain at least one radiation-sensitive compound. Reproduction layers of this kind are used as radiation-sensitive coatings of support materials for printing plates used in waterless offset printing.

摘要翻译： 包含全氟烷基的共聚物，含有这些共聚物的再生层及其用于无水胶版印刷的用途。 新型含全氟烷基的共聚物由至少两种不同的单体制备，包括丙烯酰基或甲基丙烯酰基的单体（a）和酚OH基团以及包含丙烯酰氧基，甲基丙烯酰氧基或乙烯基的全氟烷基和全氟烷基的单体（b）。 单体组分（a）可以例如通过用羟基烷基 - 丙烯酸酯酯化由羟基苯甲酸制备。 特别地，新型共聚物用作另外含有至少一种辐射敏感性化合物的辐射敏感性再生层中的结合剂。 这种复制层用作无水胶版印刷中使用的印版的支撑材料的辐射敏感涂层。

公开(公告)号：US4375560A

公开(公告)日：1983-03-01

申请号：US318115

申请日：1981-11-04

申请人： Werner H. Muller ,  Rudiger Berthold

发明人： Werner H. Muller ,  Rudiger Berthold

IPC分类号： C07B61/00 ,  B01J23/00 ,  C07C67/00 ,  C07C209/00 ,  C07C209/40 ,  C07C209/68 ,  C07C211/47 ,  C07C85/11

CPC分类号： C07C209/68

摘要： The invention provides a process for the preparation of 3,5-dimethylaniline by catalytically dehydrogenating 3,5-dimethyl-cyclohexenone oxime in the gaseous phase. The catalyst contains at least one noble metal of the 8th subgroup of the Periodic Table.

摘要翻译： 本发明提供了一种通过在气相中催化脱氢3,5-二甲基 - 环己烯酮肟来制备3,5-二甲基苯胺的方法。 该催化剂含有至少一种元素周期表第8族的贵金属。

公开(公告)号：US4332941A

公开(公告)日：1982-06-01

申请号：US195840

申请日：1980-10-10

申请人： Rudiger Berthold ,  Werner H. Muller

发明人： Rudiger Berthold ,  Werner H. Muller

IPC分类号： C07C311/16 ,  C07C45/67 ,  C07C67/00 ,  C07C213/00 ,  C07C219/12 ,  C07C231/00 ,  C07C231/12 ,  C07C235/82 ,  C07C253/00 ,  C07C255/56 ,  C07C301/00 ,  C07C303/40 ,  C07C311/17 ,  C07D295/088 ,  C07D401/12

CPC分类号： C07D295/088 ,  C07C45/673

摘要： Cyclohexanones and -hexenones ##STR1## R.sup.1 is hydrogen or--CO--O--C.sub.n H.sub.2n+1-m (--NR.sup.4 R.sup.5) (1c)R.sup.2 is a group 1c, R.sup.3 is C.sub.1 - to C.sub.10 -alkyl, phenyl or phenyl substituted by lower alkyl, lower alkoxy, trifluoromethyl, nitro, cyano, chloro, carbamoyl, lower-alkyl-carbamoyl, sulfamoyl or lower-alkyl-sulfamoyl, R.sup.4 and R.sup.5 are lower alkyl or --NR.sup.4 R.sup.5 is pyrrolidinyl, piperidyl or morpholyl, m is 1 or 2 and n is 2 to 6, are obtained by reacting 2 mols of an esterCH.sub.3 --CO--CH.sub.2 --CO--O--C.sub.n H.sub.2n+1-m (--NR.sup.4 R.sup.5).sub.m (2)with an aldehyde R.sup.3 --CHO (3). The compounds (1) easily saponify and decarboxylate without an added catalyst to form a cyclohexenones ##STR2## while setting free the alcoholHO--C.sub.n H.sub.2n+1-m (--NR.sup.4 R.sup.5).sub.m (5)which reacts without a catalyst with diketene to form the ester (2). Thus, in effect, 2 mols of diketene and 1 mol of aldehyde (3) form 1 mol of (4) and 2 mols of carbon dioxide as sole by-product. (4) can be transformed via the oxime to the correspondingly 5-substituted 3-methylaniline.

摘要翻译： 环己酮和己烯酮其中A为R 1为氢或-CO-O-C n H 2n + 1-m（-NR 4 R 5）（1c）R 2为基团C 1，R 3为C 1 -C 10 - 烷基，苯基或被低级烷基，低级烷氧基，三氟甲基，硝基，氰基，氯代，氨基甲酰基，低级烷基 - 氨基甲酰基，氨磺酰基或低级烷基 - 氨磺酰基取代的苯基，R4和R5是低级烷基或-NR4R5是吡咯烷基， 或吗啉基，m为1或2，n为2至6，通过使2摩尔的酯CH3-CO-CH2-CO-O-CnH2n + 1-m（-NR4R5）m（2）与醛 R3-CHO（3）。 化合物（1）容易地皂化和脱羧而不加入催化剂以形成环己烯酮（4），同时游离醇，其中HO-CnH2n + 1-m（-NR4R5）m（5），其中没有催化剂与双烯酮反应 形成酯（2）。 因此，实际上，2摩尔双烯酮和1摩尔醛（3）形成1摩尔（4）和2摩尔二氧化碳作为副产物。 （4）可以通过肟转化为相应的5-取代的3-甲基苯胺。

公开(公告)号：US4250336A

公开(公告)日：1981-02-10

申请号：US45941

申请日：1979-06-06

申请人： Werner H. Muller ,  Karl E. Mack ,  Hansjorg Hey

发明人： Werner H. Muller ,  Karl E. Mack ,  Hansjorg Hey

IPC分类号： C07C43/23 ,  B01J23/00 ,  C07C27/00 ,  C07C37/00 ,  C07C37/06 ,  C07C37/07 ,  C07C39/08 ,  C07C39/12 ,  C07C41/00 ,  C07C67/00

CPC分类号： C07C37/07 ,  Y02P20/584

摘要： Resorcinols are prepared by converting .delta.-ketocarboxylic acid esters in the gaseous phase at a temperature from 250.degree. to 500.degree. C. in the presence of hydrogen at a catalyst. The catalyst consists of two components which are prepared separately and combined thereafter. The first component contains at least one compound of a metal of group VIII and/or at least one compound of a metal of group I B supported on one or several carrier materials. The second component contains at least one compound of a metal of group II A and/or IV A and/or III B and/or IV B supported on one or several carrier materials. A particularly preferred catalyst consists of a mixture of equal volume parts of platinum/charcoal as first component and of thorium/charcoal as second component.

摘要翻译： 在氢气存在下，在催化剂存在下，在250〜500℃的温度下，将气态的α-酮羧酸酯转化成间苯二酚。 催化剂由两种组分组成，分别制备，然后合并。 第一组分含有至少一种第一族金属化合物和/或至少一种负载在一种或多种载体材料上的至少一种I B族金属化合物。 第二组分包含至少一种负载在一种或多种载体材料上的IIA族和/或IVA族和/或IIIB族和/或IVB族金属的化合物。 特别优选的催化剂由等体积份量的铂/炭作为第一组分和作为第二组分的钍/炭的混合物组成。

公开(公告)号：US4226997A

公开(公告)日：1980-10-07

申请号：US75240

申请日：1979-09-13

申请人： Helmut Meidert ,  Werner H. Muller ,  Wilfried Pressler

发明人： Helmut Meidert ,  Werner H. Muller ,  Wilfried Pressler

IPC分类号： C07D215/18 ,  C07D215/22 ,  C07D215/227 ,  C07D215/40 ,  C09B29/08 ,  C09B29/44

CPC分类号： C07D215/227 ,  C07D215/40 ,  C09B29/083

摘要： 8-Chloro-5,6,7,8-tetrahydro-2-quinolone and 8-bromo-5,6,7,8-tetrahydro-2-quinolone, the hydrochloride or hydrobromide thereof and their manufacture by reacting 3,4,5,6,7,8-hexahydro-2-quinolone with chlorine or bromine in an inert solvent at 10.degree. to 50.degree. C. with heating of the reaction mixture to 60.degree. to 80.degree. C. after the halogen addition.

摘要翻译： 8-氯-5,6,7,8-四氢-2-喹诺酮和8-溴-5,6,7,8-四氢-2-喹诺酮，其盐酸盐或氢溴酸盐，其制备方法是使3,4， 5,6,7,8-六氢-2-喹诺酮与氯或溴在惰性溶剂中在10至50℃下反应，加入反应混合物至60至80℃。

公开(公告)号：US4161615A

公开(公告)日：1979-07-17

申请号：US800915

申请日：1977-05-26

申请人： Werner H. Muller

发明人： Werner H. Muller

IPC分类号： C07C37/07 ,  C07C39/14

CPC分类号： C07C37/07

摘要： Preparation of 2-hydroxynaphthalenes optionally substituted by aliphatic or aromatic radicals from cycloalkenones or hydroxycycloalkanones by heating them in the presence of a dehydrogenation agent.

摘要翻译： 通过在脱氢剂的存在下加热，由环烯酮或羟基环烷酮制备任选被脂族或芳族基团取代的2-羟基萘。

公开(公告)号：US4160113A

公开(公告)日：1979-07-03

申请号：US850815

申请日：1977-11-11

申请人： Werner H. Muller ,  Knut Riedel ,  Hans Krekeler

发明人： Werner H. Muller ,  Knut Riedel ,  Hans Krekeler

IPC分类号： C07C37/07 ,  C07C39/08

CPC分类号： C07C37/07

摘要： The present invention is related to a process for the manufacture of resorcinols by catalytic dehydrogenation of cyclohexane diones-(1,3) in the liquid phase by means of a dehydrogenating mixture consisting of a solvent and of a catalyst containing a noble metal from Group VIII of the Periodic Table.

公开(公告)号：US4375561A

公开(公告)日：1983-03-01

申请号：US318117

申请日：1981-11-04

申请人： Rudiger Berthold ,  Werner H. Muller

发明人： Rudiger Berthold ,  Werner H. Muller

IPC分类号： C07B61/00 ,  B01J23/00 ,  C07C67/00 ,  C07C209/00 ,  C07C209/40 ,  C07C209/68 ,  C07C211/45 ,  C07C211/55 ,  C07C85/11

CPC分类号： C07C209/68

摘要： Aromatic amines are obtained from the corresponding cycloaliphatic oximes by heating the oxime to a temperature of from 150.degree. to 350.degree. C. in an ether group containing solvent in the presence of a catalyst containing a noble metal of the 8th auxiliary group of the Periodic Table of Elements. The solvent is preferably an aliphatic ether, especially a lower dialkyl ether of a polyethyleneglycol.

摘要翻译： 在含有第8族元素周期表的贵金属的催化剂存在下，通过将肟在含有醚基的溶剂中加热至150℃至350℃的温度，从相应的脂环族肟得到芳族胺 的元素。 溶剂优选为脂族醚，特别是聚乙二醇的低级二烷基醚。

公开(公告)号：US4277606A

公开(公告)日：1981-07-07

申请号：US127566

申请日：1980-03-06

申请人： Helmut Meidert ,  Wilfried Pressler ,  Werner H. Muller

发明人： Helmut Meidert ,  Wilfried Pressler ,  Werner H. Muller

IPC分类号： C07D215/24 ,  C07D215/26 ,  C09B29/44

CPC分类号： C09B29/3643 ,  C07D215/24 ,  C07D215/26

摘要： 8-Oxo-5,6,7,8-tetrahydro-2-quinolone is a novel compound which is prepared by hydrolyzing the hydrochloride of the corresponding 8-chloro compound or the hydrobromide of the corresponding 8-bromo compound to give the corresponding 8-hydroxy compound, and dehydrogenating the latter one.

摘要翻译： 8-氧代-5,6,7,8-四氢-2-喹诺酮是通过水解相应的8-氯化合物或相应的8-溴化合物的氢溴酸盐的盐酸盐制备的新化合物，得到相应的8 - 羟基化合物，并使后者脱氢。

公开(公告)号：US5104961A

公开(公告)日：1992-04-14

申请号：US630176

申请日：1990-12-19

申请人： Werner H. Muller

发明人： Werner H. Muller

IPC分类号： G03C1/72 ,  C08F8/18 ,  C08G8/00 ,  C08G8/02 ,  C08G8/04 ,  C08G8/12 ,  C08G8/28 ,  C08G8/36 ,  C08G61/00 ,  C08G61/02 ,  G03C1/00 ,  G03F7/00 ,  G03F7/004 ,  G03F7/039

CPC分类号： C08G61/02 ,  C08F8/18 ,  C08G8/04 ,  C08G8/28 ,  C08G8/36 ,  G03F7/0046 ,  Y10S430/106

摘要： Polymers comprising perfluoroalkyl groups, reproduction layers containing these polymers and use thereof for waterless offset printing. The novel perfluoroalkyl group-containing polymers comprise polymers or polycondensates and have, in each case as substituents on different carbon atoms of benzene rings, phenolic OH groups and perfluoroalkyl groups which are optionally attached through intermediate members. In particular, at least 10% of the polymer units carry perfluoroalkyl groups. These polymers are either formed by condensation of substituted phenols (e.g., 4-hydroxybenzoic acid-perfluoroalkyl ester) with an aldehyde, a ketone, or a reactive bismethylene compound or by reacting polymers containing phenolic OH groups (e.g., hydroxypolystyrene) or polycondensates containing reactive OH groups (e.g., phenol-formaldehyde resins) with a perfluoroalkyl group-containing compound (e.g., 2,2-dihydroperfluorodecanoic acid chloride). The novel polymers are particularly useful in radiation-sensitive reproduction layers which additionally contain at least one radiation-sensitive compound. Reproduction layers of this kind are applied as radiation-sensitive coatings to support materials for printing plates used in waterless offset printing.