Processing asphaltene-containing tailings
    1.
    发明授权
    Processing asphaltene-containing tailings 有权
    加工含沥青质的尾矿

    公开(公告)号:US08679325B2

    公开(公告)日:2014-03-25

    申请号:US12404150

    申请日:2009-03-13

    IPC分类号: C10G1/04 C10G21/14 C10G21/28

    CPC分类号: C10G1/047 C10G1/045

    摘要: Embodiments of a method and a system for recovering energy, materials or both from asphaltene-containing tailings are disclosed. The asphaltene-containing tailings can be generated, for example, from a process for recovering hydrocarbons from oil sand. Embodiments of the method can include a flotation separation and a hydrophobic agglomeration separation. Flotation can be used to separate the asphaltene-containing tailings into an asphaltene-rich froth and an asphaltene-depleted aqueous phase. The asphaltene-rich froth, or an asphaltene-rich slurry formed from the asphaltene-rich froth, then can be separated into a heavy mineral concentrate and a light tailings. Hydrophobic agglomeration can be used to recover an asphaltene concentrate from the light tailings. Another flotation separation can be included to remove sulfur-containing minerals from the heavy mineral concentrate. Oxygen-containing minerals also can be recovered from the heavy mineral concentrate. Water removed by the various separation steps can be recycled and its heat energy recovered.

    摘要翻译: 公开了用于从含沥青质的尾矿中回收能量,材料或二者的方法和系统的实施例。 含沥青烯的尾矿可以例如从用于从油砂中回收烃的方法产生。 该方法的实施方案可以包括浮选分离和疏水性聚集分离。 浮选可用于将含沥青质的尾矿分离成富含沥青质的泡沫和不含沥青质的水相。 富含沥青质的泡沫或富含沥青质的泡沫形成的富含沥青质的浆料然后可以分离成重矿物浓缩物和轻质尾矿。 疏水聚集可用于从轻尾矿中回收沥青质浓缩物。 可以包括另一种浮选分离以从重矿物质浓缩物中除去含硫矿物。 含氧矿物也可从重矿物精矿中回收。 通过各种分离步骤除去的水可以回收并回收其热能。

    Oxidation of asphaltenes
    2.
    发明授权
    Oxidation of asphaltenes 失效
    沥青质氧化

    公开(公告)号:US08529687B2

    公开(公告)日:2013-09-10

    申请号:US12869264

    申请日:2010-08-26

    IPC分类号: C08L95/00

    摘要: A method for processing asphaltenes is disclosed. The method can include separating asphaltenes from an asphaltene-containing composition and oxidizing the separated asphaltenes to form oxidation products. Alternatively, the method can include oxidizing asphaltenes within an asphaltene-containing composition without first separating the asphaltenes. Once formed, the oxidation products can be combined with other hydrocarbons. The amount of oxidation can be limited to an amount sufficient to produce a mixture suitable for the desired application. This method can be used to upgrade asphaltenes from a variety of sources, including oil sands. The oxidation step can be performed, for example, by introducing an oxidizing agent and, in some cases, a catalyst into the asphaltenes. A solvent or miscibility agent also can be introduced to improve mixing between the oxidizing agent and the asphaltenes.

    摘要翻译: 公开了一种处理沥青质的方法。 该方法可以包括从含沥青烯的组合物中分离沥青质并氧化分离的沥青质以形成氧化产物。 或者,该方法可以包括在含沥青质的组合物中氧化沥青质而不首先分离沥青质。 一旦形成,氧化产物可与其它烃结合。 氧化的量可以限制为足以产生适合于所需应用的混合物的量。 该方法可用于从各种来源(包括油砂)升级沥青质。 氧化步骤可以例如通过将氧化剂和一些催化剂引入沥青质中进行。 还可以引入溶剂或混溶剂以改善氧化剂和沥青质之间的混合。

    Nozzle reactor and method of use
    3.
    发明授权
    Nozzle reactor and method of use 失效
    喷嘴反应器及使用方法

    公开(公告)号:US08435402B2

    公开(公告)日:2013-05-07

    申请号:US12749068

    申请日:2010-03-29

    IPC分类号: C10G9/26

    摘要: A method of cracking hydrocarbon material in a nozzle reactor. The method includes a step of providing a nozzle reactor, a step of injecting a stream of cracking material into the reactor body of the nozzle reactor, and a step of injecting hydrocarbon material into the reactor body of the nozzle reactor, wherein the cracking material is methanol, ethanol, ethane, propane, biodiesel, carbon monoxide, nitrogen, or combinations thereof. The cracking material can also include steam. The hydrocarbon material can be injected into the reactor body at a direction transverse to the direction the cracking material is injected into the reactor body.

    摘要翻译: 在喷嘴反应器中裂化烃材料的方法。 该方法包括提供喷嘴反应器的步骤,将裂解材料流注入喷嘴反应器的反应器主体的步骤,以及将烃材料注入喷嘴反应器的反应器主体的步骤,其中裂化材料为 甲醇,乙醇,乙烷,丙烷,生物柴油,一氧化碳,氮气或其组合。 裂解材料还可以包括蒸汽。 烃材料可以在横向于将裂化材料注入反应器主体的方向的方向上注入反应器主体。

    System and Method For Recovering Boron Values From Plant Tailings
    4.
    发明申请
    System and Method For Recovering Boron Values From Plant Tailings 审中-公开
    从植物尾矿中回收硼值的系统和方法

    公开(公告)号:US20120263637A1

    公开(公告)日:2012-10-18

    申请号:US13087986

    申请日:2011-04-15

    IPC分类号: C01B35/10

    CPC分类号: C01B35/1054

    摘要: A method is provided for recovering boric acid from a solution containing boric acid and at least one lithium compound. The method comprises (a) passing the solution through an ion exchange resin such that boric acid accumulates on the resin; (b) removing the boric acid from the resin with an aqueous alcohol solution, thus obtaining a first solution comprising an alcohol, boric acid, and water; (c) converting at least a portion of the boric acid to trimethyl borate, thereby obtaining a second solution; (d) distilling an azeotrope from the second solution, wherein the azeotrope contains trimethyl borate; and (e) recovering boric acid from the azeotrope.

    摘要翻译: 提供了从含有硼酸和至少一种锂化合物的溶液中回收硼酸的方法。 该方法包括(a)使溶液通过离子交换树脂,使硼酸积聚在树脂上; (b)用醇水溶液从树脂中除去硼酸,从而得到包含醇,硼酸和水的第一溶液; (c)将至少一部分硼酸转化为硼酸三甲酯,从而得到第二溶液; (d)从第二溶液中蒸馏出共沸物,其中共沸物含有硼酸三甲酯; 和(e)从共沸物中回收硼酸。

    Nozzle reactor and method of use
    5.
    发明授权
    Nozzle reactor and method of use 失效
    喷嘴反应器及使用方法

    公开(公告)号:US07927565B2

    公开(公告)日:2011-04-19

    申请号:US12466923

    申请日:2009-05-15

    IPC分类号: B01J10/00 B01J8/08 B01J8/02

    摘要: A nozzle reactor system for increasing the conversion rate of material feed injected into the nozzle reactor system. The system includes two or more nozzle reactors aligned in series, such that material exiting a first nozzle reactor may be injected into a second nozzle reactor. Each nozzle reactor includes an interior reactor chamber and an injection passage and a material feed passage that are each in material injecting communication with the interior reactor chamber. Furthermore, the injection passage is aligned transversely to the injection passage. The injection passage is configured to accelerate cracking material passed therethrough to a supersonic speed. A method of increasing the conversion rate of material feed utilizing multiple cracking steps is also described.

    摘要翻译: 喷嘴反应器系统,用于提高注入喷嘴反应器系统的原料进料的转化率。 该系统包括串联排列的两个或更多个喷嘴反应器,使得离开第一喷嘴反应器的材料可以被注入到第二喷嘴反应器中。 每个喷嘴反应器包括内部反应器室和注入通道和材料供给通道,每个注射通道和材料供给通道各自与内部反应器室注入连通。 此外,注射通道横向于注射通道排列。 喷射通道构造成将通过其的裂化材料加速至超音速。 还描述了利用多个裂解步骤提高材料进料的转化率的方法。

    Electrogalvanizing utilizing primary and secondary zinc sources
    6.
    发明授权
    Electrogalvanizing utilizing primary and secondary zinc sources 失效
    使用一次和二次锌源进行电解

    公开(公告)号:US4552629A

    公开(公告)日:1985-11-12

    申请号:US696985

    申请日:1985-01-31

    摘要: A hydrometallurgical process is provided to electrogalvanize steel, utilizing primary and secondary zinc sources. The process consists of leaching the feed in a mildly acidic solution. The zinc is selectively recovered from the leach liquor in a solvent extraction system and thereafter stripped from the solvent using a stronger acidic solution to provide a strip solution which is fed to an electrogalvanizing bath for electrogalvanizing steel products, e.g., sheet steel, using insoluble anodes. Acidic solutions and organic solvent are recycled in the process.

    摘要翻译: 提供了一种湿法冶金工艺,用于使用一次和二次锌源电镀锌钢。 该过程包括将饲料浸入温和酸性溶液中。 在溶剂萃取系统中从浸出液中选择性地回收锌,然后使用较强的酸性溶液从溶剂中汽提,从而提供条状溶液,其被加入到电镀锌浴中,以使用不溶性阳极电镀锌钢产品(例如钢板) 。 酸性溶液和有机溶剂在此过程中循环使用。

    Nozzle reactor and method of use
    7.
    发明授权
    Nozzle reactor and method of use 失效
    喷嘴反应器及使用方法

    公开(公告)号:US08449763B2

    公开(公告)日:2013-05-28

    申请号:US12761204

    申请日:2010-04-15

    IPC分类号: C10G9/38

    摘要: Embodiments of a nozzle reactor of the type useable to inject a first material feed stock and a second material feed stock to cause interaction between the first material feed stock and second material feed stock are described herein. According to some embodiments, the nozzle reactor may crack residual oil produced by other processing units in a refinery process. Furthermore, nozzle reactors may replace traditional processing units of a refinery process, such as cokers, hydrocrackers and deasphalting units.

    摘要翻译: 本文描述了可用于注入第一材料原料和第二材料原料以引起第一原料原料和第二原料原料之间相互作用的类型的喷嘴反应器的实施方案。 根据一些实施例,喷嘴反应器可以在炼油过程中裂开由其它处理单元产生的残余油。 此外,喷嘴反应器可以替代炼油工艺的传统加工单元,例如焦化器,加氢裂化器和脱沥青装置。

    Oxidation of asphaltenes
    8.
    发明授权
    Oxidation of asphaltenes 失效
    沥青质氧化

    公开(公告)号:US07811444B2

    公开(公告)日:2010-10-12

    申请号:US11450591

    申请日:2006-06-08

    摘要: A method for processing asphaltenes is disclosed. The method can include separating asphaltenes from an asphaltene-containing composition and oxidizing the separated asphaltenes to form oxidation products. Alternatively, the method can include oxidizing asphaltenes within an asphaltene-containing composition without first separating the asphaltenes. Once formed, the oxidation products can be combined with other hydrocarbons. The amount of oxidation can be limited to an amount sufficient to produce a mixture suitable for the desired application. This method can be used to upgrade asphaltenes from a variety of sources, including oil sands. The oxidation step can be performed, for example, by introducing an oxidizing agent and, in some cases, a catalyst into the asphaltenes. A solvent or miscibility agent also can be introduced to improve mixing between the oxidizing agent and the asphaltenes.

    摘要翻译: 公开了一种处理沥青质的方法。 该方法可以包括从含沥青烯的组合物中分离沥青质并氧化分离的沥青质以形成氧化产物。 或者,该方法可以包括在含沥青质的组合物中氧化沥青质而不首先分离沥青质。 一旦形成,氧化产物可与其它烃结合。 氧化的量可以限制为足以产生适合于所需应用的混合物的量。 该方法可用于从各种来源(包括油砂)升级沥青质。 氧化步骤可以例如通过将氧化剂和一些催化剂引入沥青质中进行。 还可以引入溶剂或混溶剂以改善氧化剂和沥青质之间的混合。

    Biodiesel production and use in oil sands processing
    9.
    发明申请
    Biodiesel production and use in oil sands processing 有权
    生物柴油生产用于油砂加工

    公开(公告)号:US20080060257A1

    公开(公告)日:2008-03-13

    申请号:US11517730

    申请日:2006-09-08

    IPC分类号: C10M101/02

    摘要: A method for obtaining heavy oil is disclosed. The method includes mixing a material including heavy oil (e.g., oil sand) with a solvent including biodiesel to form a mixture and separating the mixture into a oil-enriched solvent phase and a residual sand phase. The method also can include introducing a solvent including biodiesel into an in-situ geological formation including heavy oil and collecting a mixture including biodiesel and heavy oil from the formation. For example, the mixture can be collected after the solvent travels through at least a portion of the formation by gravity. A method for producing biodiesel also is disclosed. The method includes microbially digesting asphaltenes to form a liquor including a fatty acid and reacting the fatty acid with an alcohol to produce biodiesel. This method can be used to convert petroleum asphaltenes and/or coal asphaltenes into biodiesel.

    摘要翻译: 公开了一种获得重油的方法。 该方法包括将包含重油(例如油砂)的材料与包括生物柴油在内的溶剂混合以形成混合物,并将该混合物分离成富油溶剂相和残余砂相。 该方法还可以包括将包括生物柴油在内的溶剂引入包括重油的原位地层,并从地层中收集包括生物柴油和重油的混合物。 例如,可以在溶剂通过重力穿过地层的至少一部分之后收集混合物。 公开了生产生物柴油的方法。 该方法包括将沥青质微生物消化以形成包含脂肪酸的液体,并使脂肪酸与醇反应生成生物柴油。 该方法可用于将石油沥青质和/或煤沥青质转化为生物柴油。

    Biochemical treatment of bitumen froth tailings
    10.
    发明授权
    Biochemical treatment of bitumen froth tailings 失效
    沥青尾矿生化处理

    公开(公告)号:US6074558A

    公开(公告)日:2000-06-13

    申请号:US193332

    申请日:1998-11-16

    CPC分类号: C10G32/00 C10G1/045

    摘要: A process for the biological treatment of bitumen froth tailings produced from a tar sands treatment and bitumen froth extraction process is disclosed. In this process bitumen froth tailings, containing native hydrocarbon metabolizing microorganisms, are mixed with a growth media to form an inoculum which is then incubated under isothermal conditions for an amount of time to produce a mixed bacterial culture containing bioliquor and a water product containing a reduced amount of asphaltenes as well as solids such as clays and sands. The bioliquor produced in this process is then utilized in the initial tar sands conditioning process from which bitumen froth is produced as well as in the initial tar sands mining process via bioliquor injection directly into the tar sands formation. Because the mixed bacterial culture is made up of a number of hydrocarbon metabolizing microorganisms, the bioliquor is also used in the degradation of the asphaltenes. The treatment results in a process for decreasing the amount of waste produced in bitumen extraction processes. Furthermore, because the invention utilizes a biosurfactant containing bioliquor in the initial tar sands conditioning process, bitumen froth can be produced at lower temperatures and without requiring the use of caustic soda, as is conventionally practiced. Thus, the present invention advantageously avoids the production of tailings sludges caused by clay dispersion.

    摘要翻译: 公开了一种由焦油砂处理和沥青泡沫提取方法生产的沥青泡沫尾矿的生物处理方法。 在这个过程中,将含有天然烃代谢微生物的沥青尾矿与生长培养基混合以形成接种物,然后在等温条件下孵育一段时间以产生含有生物分解液的混合细菌培养物和含有还原 沥青质量以及固体,如粘土和沙子。 然后在该过程中生产的生物分子被用于生产沥青泡沫的初始焦油砂调节过程中,以及在初始焦油砂矿开采过程中,通过直接注入沥青砂组合中的生物混合物注入。 因为混合的细菌培养物由许多烃代谢微生物组成,所以生物分子也用于沥青质的降解。 该处理产生了减少在沥青提取过程中产生的废物量的过程。 此外,由于本发明在初始焦油砂调理过程中利用含有生物分子的生物表面活性剂,所以可以在较低温度下生产沥青泡沫,而不需要使用苛性钠,如常规实践的那样。 因此,本发明有利地避免了由粘土分散体引起的尾渣污泥的产生。