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公开(公告)号：US08822606B2
公开(公告)日：2014-09-02
申请号：US13805952
申请日：2011-06-29
CPC分类号： C08G18/3893 , C08G18/10 , C08G18/289 , C08G18/4825 , C08G18/4829 , C08G18/5096 , C08G18/718 , C08G18/7621 , C08G18/809 , C08G18/837 , C08G77/46 , C08G18/48
摘要： Embodiment of the invention provide for compositions having at least one crosslinkable silyl group in each molecule. The crosslinkable silane-terminated polymer may include a reaction product of at least a polyol having a nominal functionality of at least 2 and a isocyanate capped hydrosilylated polymer. The isocyanate capped hydrosilylated polymer may include a reaction product of at least one isocyanate and a hydrosilylated polymer. The hydrosilylated polymer may include a reaction product of a the reaction of at least a) a polymer having at least one unsaturated group and at least one alcoholic hydroxyl group in each molecule and having a number average molecular weight of between about 100 and about 5000 and b) a compound having a hydrogen-silicon bond and a crosslinkable silyl group in each molecule.
摘要翻译： 本发明的实施方案提供了在每个分子中具有至少一个可交联甲硅烷基的组合物。 可交联硅烷封端的聚合物可以包括至少具有至少2的标称官能度的多元醇和异氰酸酯封端的氢化硅烷化聚合物的反应产物。 异氰酸酯封端的氢化硅烷化聚合物可以包括至少一种异氰酸酯和氢化硅烷化聚合物的反应产物。 氢化硅烷化聚合物可以包括至少一种在每个分子中具有至少一个不饱和基团和至少一个醇羟基的聚合物与数均分子量为约100至约5000的反应的反应产物和数均分子量为约100至约5000的反应产物，以及 b）在每个分子中具有氢 - 硅键和交联性甲硅烷基的化合物。
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公开(公告)号：US20130096274A1
公开(公告)日：2013-04-18
申请号：US13806962
申请日：2011-06-28
申请人： Kameswara R. Vyakaranam , Ling Zhang , William A. Koonce , Sara Arshad , Venkat S. Minnikanti , Dwight D. Latham , Phillip S. Athey
发明人： Kameswara R. Vyakaranam , Ling Zhang , William A. Koonce , Sara Arshad , Venkat S. Minnikanti , Dwight D. Latham , Phillip S. Athey
IPC分类号： C08G18/70
CPC分类号： C08G18/70 , C08G18/10 , C08G18/1875 , C08G18/289 , C08G18/4288 , C08G18/4866 , C08G18/5024 , C08G18/809 , C08G2190/00 , C08G18/48 , C08G18/42 , C08G18/50 , C08G18/44
摘要： Embodiments of the invention provide for compositions including a crosslinkable silane-terminated polymer having at least one crosslinkable silyl group in each molecule. The crosslinkable silane-terminated polymer comprises a reaction product of at least a isocyanate capped hydrosilylated polymer and a polyol having a nominal functionality of at least 2 which is at least one of a polycarbonate polyol, a natural oil based polyol, a polyoxyalkyleneamine, a difunctional aromatic amine, a polybutyloxide polyether polyol, and a polytetramethylene glycol.
摘要翻译： 本发明的实施方案提供了包含在每个分子中具有至少一个可交联甲硅烷基的可交联硅烷封端的聚合物的组合物。 可交联硅烷封端的聚合物包含至少异氰酸酯封端的硅烷化聚合物和标称官能度为至少为2的多元醇的反应产物，其为聚碳酸酯多元醇，天然油基多元醇，聚氧化烯胺，双官能团 芳香胺，聚四氢呋喃聚醚多元醇和聚四亚甲基二醇。
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公开(公告)号：US20130096251A1
公开(公告)日：2013-04-18
申请号：US13700961
申请日：2011-06-21
申请人： Paul J. Popa , Gary E. Spilman , Zenon Lysenko , William A. Koonce , David A. Bobb , Martin C. Beebe , Thomas C. Thyne
发明人： Paul J. Popa , Gary E. Spilman , Zenon Lysenko , William A. Koonce , David A. Bobb , Martin C. Beebe , Thomas C. Thyne
CPC分类号： C08G18/837 , C08G18/10 , C08G18/12 , C08G18/289 , C08G18/4891 , C08G18/7621 , C09D175/04 , C09J175/04
摘要： Embodiments of the invention relate to crosslinkable silyl group-containing polymers and methods of producing them. In one embodiment a method of producing a silyl polymer is provided. The method includes reacting at least one natural oil based polyol with at least one isocyanate to form at least one prepolymer having at least one NCO group. The at least one natural oil based polyol includes the reaction product of hydroxymethylated fatty acids or esters thereof and at least one polyol initiator. The prepolymer having at least one NCO group is reacted with at least one amino functional alkoxy silane to form the silyl polymer, such that the silyl polymer includes at least one crosslinkable silyl group, at least one urethane group, and at least one urea group in each molecule.
摘要翻译： 本发明的实施方案涉及可交联的含甲硅烷基的聚合物及其制备方法。 在一个实施方案中，提供了产生甲硅烷基聚合物的方法。 所述方法包括使至少一种天然油基多元醇与至少一种异氰酸酯反应以形成至少一种具有至少一个NCO基团的预聚物。 所述至少一种天然油基多元醇包括羟甲基化脂肪酸或其酯与至少一种多元醇引发剂的反应产物。 具有至少一个NCO基团的预聚物与至少一个氨基官能的烷氧基硅烷反应以形成甲硅烷基聚合物，使得甲硅烷基聚合物包括至少一个可交联甲硅烷基，至少一个氨基甲酸酯基和至少一个脲基 每个分子。
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4.发明授权Polyurethane films prepared by electrodeposition from polyurethane dispersions 失效通过聚氨酯分散体电沉积制备的聚氨酯薄膜公开(公告)号：US06514572B1
公开(公告)日：2003-02-04
申请号：US09548915
申请日：2000-04-13
IPC分类号： B05D104
CPC分类号： C09D5/4465 , C08G18/12 , C08G18/4808 , C08G18/4841 , C08G18/50 , C08G18/302
摘要： A process for preparing polyurethane films is disclosed, comprising electrodepositing the film onto a substrate from a polyurethane dispersion. One advantage of the electrodeposition process of the present invention is that there is no need for an additional step to remove coagulants from the films, as with conventional coagulation processes. Another advantage is that in using electrodeposition, the amount of water that must be removed during a dewatering step is minimized. A third advantage is that the resulting film demonstrates much greater uniformity in thickness as compare to films prepared by conventional coagulation techniques. The present invention has applicability in, for example, medical applications.
摘要翻译： 公开了一种制备聚氨酯膜的方法，包括将膜从聚氨酯分散体电沉积到基底上。 本发明的电沉积方法的一个优点是，与常规凝固方法一样，不需要额外的步骤从膜中除去凝结剂。 另一个优点是在使用电沉积时，在脱水步骤期间必须去除的水的量被最小化。 第三个优点是，与通过常规凝固技术制备的膜相比，所得到的膜在厚度方面表现出更大的均匀性。 本发明在例如医疗应用中具有适用性。
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5.发明授权Silane terminated polymer for coating, adhesives, sealant and elastomer applications 有权用于涂料，粘合剂，密封剂和弹性体应用的硅烷封端聚合物公开(公告)号：US08907014B2
公开(公告)日：2014-12-09
申请号：US14113318
申请日：2012-06-14
CPC分类号： C08G81/025 , C08G18/10 , C08G18/289 , C08G18/632 , C08G18/718 , C08G18/7621 , C08G18/63
摘要： A copolymer-filled crosslinkable silane-terminated polymer having at least one crosslinkable silyl group in each molecule is provided. The copolymer-filled crosslinkable silane-terminated polymer is the reaction product of a copolymer-filled polyol and an isocyanate capped hydrosilylated polymer. The isocyanate capped hydrosilylated polymer is the reaction product of at least one isocyanate and a hydrosilylated polymer. The hydrosilylated polymer is the reaction product of a polymer having at least one unsaturated group and at least one alcoholic group in each molecule and a compound having a hydrogen-silicon bond and a crosslinkable silyl group in each molecule. The copolymer-filled crosslinkable silane-terminated polymers exhibit improved modulus and tensile strength properties while maintaining elongation properties.
摘要翻译： 提供了在每个分子中具有至少一个可交联甲硅烷基的共聚物填充的可交联硅烷封端的聚合物。 共聚物填充的可交联硅烷封端的聚合物是共聚物填充的多元醇和异氰酸酯封端的氢化硅烷化聚合物的反应产物。 异氰酸酯封端的氢化硅烷化聚合物是至少一种异氰酸酯和氢化硅烷化聚合物的反应产物。 氢化硅烷化聚合物是每个分子中具有至少一个不饱和基团和至少一个醇基团的聚合物的反应产物和在每个分子中具有氢 - 硅键和交联性甲硅烷基的化合物。 共聚物填充的可交联硅烷封端的聚合物在保持伸长性能的同时表现出改善的模量和拉伸强度性能。
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公开(公告)号：US20140228515A1
公开(公告)日：2014-08-14
申请号：US14342652
申请日：2012-09-17
申请人： Kamesh R. Vyakaranam , Ling Zhang , Venkat S. Minnikanti , Dwight Latham , Sara Arshad , Rajat Duggal , William A. Koonce
发明人： Kamesh R. Vyakaranam , Ling Zhang , Venkat S. Minnikanti , Dwight Latham , Sara Arshad , Rajat Duggal , William A. Koonce
IPC分类号： C08L71/00
CPC分类号： C08L71/00 , C08G65/336 , C08K5/0025 , C08L71/02 , C08L75/04 , C08L75/08 , C08L83/00 , C08L83/06 , C08L101/10
摘要： Moisture curable compositions including silylated polymers and methods for producing the same are provided. A two component moisture curable system for producing a cured or cross-linked silylated polymer having improved compression set properties is provided. The two component system comprises a first formulation and a second formulation. The first formulation comprises a silylated polymer, water, and filler and the second formulation comprises the silylated polymer, a curing catalyst comprising at least one Brønsted acid, and a moisture scavenger. The final cured formulation may have a compression set, determined by ASTM D395 or ISO 815-1, of less than 100%, and in some examples less than 50% and in some examples less than 15%. This demonstrated improvement in compression set not only allows the silylated polymers to be used in applications where cyclic loads are applied but also enhances product durability.
摘要翻译： 提供了包含甲硅烷基化聚合物的水溶性组合物及其制备方法。 提供了用于制备具有改进的压缩永久变形特性的固化或交联的甲硅烷基化聚合物的双组分湿气可固化体系。 双组分体系包括第一制剂和第二制剂。 第一制剂包含甲硅烷基化聚合物，水和填料，第二制剂包含甲硅烷基化聚合物，包含至少一种布朗斯台德酸的固化催化剂和除湿剂。 最终固化的制剂可以具有通过ASTM D395或ISO 815-1测定的压缩永久变形小于100％，在一些实例中小于50％，在一些实例中小于15％。 这表明压缩变形的改进不仅允许将甲硅烷基化的聚合物用于应用循环载荷的应用中，而且可以提高产品的耐久性。
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公开(公告)号：US20110015292A1
公开(公告)日：2011-01-20
申请号：US12933284
申请日：2009-03-20
IPC分类号： C08G18/00 , C07C269/02 , C07F7/08 , C07D303/02 , C07C309/00 , C08J9/00
CPC分类号： C08G18/4891 , C08G18/12 , C08G18/4812 , C08G18/4841 , C08G18/7671 , C08G18/307
摘要： A prepolymer and products made from the preopolymer is described. The prepolymer includes the reaction product of at least one isocyanate and at least one natural oil based polyol. The natural oil based polyol includes at least two natural oil moieties separated by a molecular structure having an average of at least about 19 ether groups between any 2 of the natural oil moieties or by a polyether molecular structure having an equivalent weight of at least about 480.
摘要翻译： 描述了由预聚物制成的预聚物和产物。 预聚物包括至少一种异氰酸酯和至少一种天然油基多元醇的反应产物。 基于天然油的多元醇包括至少两个天然油部分，其分子结构在任何2个天然油部分之间平均具有至少约19个醚基团，或通过具有至少约480当量重量的聚醚分子结构 。
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公开(公告)号：US08486526B2
公开(公告)日：2013-07-16
申请号：US12597061
申请日：2008-04-10
申请人： Gary E. Spilman , John N. Argyropoulos , Debkumar Bhattacharjee , Paul J. Popa , William A. Koonce
发明人： Gary E. Spilman , John N. Argyropoulos , Debkumar Bhattacharjee , Paul J. Popa , William A. Koonce
CPC分类号： C08G18/4288 , C08G18/3851 , C08G18/4063 , C08G18/6229 , C08G18/755 , C08K5/1515 , C08K5/29 , C08K5/34922 , C09D175/04 , Y10T428/2852
摘要： A composition comprises (a) a binder component which comprises (1) 5 to 100 weight percent of at least one natural oil derived polyol having at least about 50 percent primary hydroxyl groups and (2) sufficient additional polyol different from a natural oil derived polyol to make 100 percent wherein the natural oil derived polyol has an average of from 1.5 to 3 hydroxyl groups per molecule and an equivalent weight of from 200 to 5000; and (b) a crosslinking component reactive with hydroxyl groups. Furthermore, a process for producing a coating, adhesive, binder or combination thereof on the surface of a substrate, comprises in any order: (a) admixing binder and crosslinking components of a composition to form an admixture, wherein a binder component comprises (1) 5 to 100 weight percent of at least one natural oil derived polyol having at least about 50 percent primary hydroxyl groups and (2) sufficient additional polyol different from a natural oil derived polyol to make 100 percent wherein the natural oil derived polyol has an average of from 1.5 to 3 hydroxyl groups per molecule and an equivalent weight of from 200 to 5000; and (b) applying a layer of said admixture on said surface. The invention includes coatings, adhesives, binders and combinations thereof prepared from any composition of the invention, substrates coated by the process of the invention or coated using a composition of the invention and articles, including laminates, comprising a coating, adhesive, binder or combination thereof of the invention.
摘要翻译： 组合物包含（a）粘合剂组分，其包含（1）5至100重量％的至少一种具有至少约50％伯羟基的天然油衍生的多元醇和（2）与天然油衍生的多元醇不同的足够的另外的多元醇 以制备100％，其中天然油衍生的多元醇的平均值为每分子1.5至3个羟基，当量为200至5000; 和（b）与羟基反应的交联组分。 此外，在基材表面上制备涂料，粘合剂，粘合剂或其组合的方法包括以下任意顺序：（a）混合粘合剂和组合物的交联组分以形成混合物，其中粘合剂组分包含（1 ）5至100重量％的至少一种具有至少约50％伯羟基的天然油衍生的多元醇，和（2）与天然油衍生的多元醇不同的足够额外的多元醇以制备100％，其中天然油衍生的多元醇具有平均值 每个分子为1.5至3个羟基，当量为200至5000; 和（b）在所述表面上施加一层所述混合物。 本发明包括由本发明的任何组合物制备的涂料，粘合剂，粘合剂及其组合，通过本发明的方法涂覆的基材或使用本发明的组合物涂覆的基材和包括层压材料的制品，其包括涂料，粘合剂，粘合剂或组合 的本发明。
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公开(公告)号：US20130090429A1
公开(公告)日：2013-04-11
申请号：US13805952
申请日：2011-06-29
IPC分类号： C08G18/38
CPC分类号： C08G18/3893 , C08G18/10 , C08G18/289 , C08G18/4825 , C08G18/4829 , C08G18/5096 , C08G18/718 , C08G18/7621 , C08G18/809 , C08G18/837 , C08G77/46 , C08G18/48
摘要： Embodiment of the invention provide for compositions having at least one crosslinkable silyl group in each molecule. The crosslinkable silane-terminated polymer may include a reaction product of at least a polyol having a nominal functionality of at least 2 and a isocyanate capped hydrosilylated polymer. The isocyanate capped hydrosilylated polymer may include a reaction product of at least one isocyanate and a hydrosilylated polymer. The hydrosilylated polymer may include a reaction product of a the reaction of at least a) a polymer having at least one unsaturated group and at least one alcoholic hydroxyl group in each molecule and having a number average molecular weight of between about 100 and about 5000 and b) a compound having a hydrogen-silicon bond and a crosslinkable silyl group in each molecule.
摘要翻译： 本发明的实施方案提供了在每个分子中具有至少一个可交联甲硅烷基的组合物。 可交联硅烷封端的聚合物可以包括至少具有至少2的标称官能度的多元醇和异氰酸酯封端的氢化硅烷化聚合物的反应产物。 异氰酸酯封端的氢化硅烷化聚合物可以包括至少一种异氰酸酯和氢化硅烷化聚合物的反应产物。 氢化硅烷化聚合物可以包括至少一种在每个分子中具有至少一个不饱和基团和至少一个醇羟基的聚合物与数均分子量为约100至约5000的反应的反应产物和数均分子量为约100至约5000的反应产物，以及 b）在每个分子中具有氢 - 硅键和交联性甲硅烷基的化合物。
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10.发明申请METHODS FOR PRODUCING CROSSLINKABLE SILYL GROUP-CONTAINING POLYOXYALKYLENE POLYMERS 有权生产可交联含硅烷基的聚氧乙烯聚合物的方法公开(公告)号：US20130060000A1
公开(公告)日：2013-03-07
申请号：US13696918
申请日：2011-05-26
CPC分类号： C08G65/336 , C08G18/289 , C08G18/7664 , C08G65/2663
摘要： Embodiments of the invention provide for a method of producing a silylated polyoxyalkylene polymer having at least one crosslinkable silyl group and at least one hydroxyl group in each molecule. The method comprises providing a polyoxyalkylene polymer having at least one unsaturated group and at least one alcoholic hydroxyl group in each molecule, wherein the polyoxyalkylene polymer includes an impurity double metal cyanide complex mixed therein, and wherein the polyoxyalkylene polymer has not been treated with a metal-coordinating compound; and adding to the polyoxyalkylene polymer a compound having a hydrogen-silicon bond and a crosslinkable silyl group in each molecule and a hydrosilylation catalyst to thereby carry out a hydrosilylation reaction, wherein the hydrosilyation reaction is performed in an absence of a metal-coordinating compound.
摘要翻译： 本发明的实施方案提供了在每个分子中具有至少一个交联性甲硅烷基和至少一个羟基的甲硅烷基化聚氧化烯聚合物的制备方法。 该方法包括提供在每个分子中具有至少一个不饱和基团和至少一个醇羟基的聚氧化烯聚合物，其中所述聚氧化烯聚合物包含混合在其中的杂质双金属氰化物络合物，并且其中所述聚氧化烯聚合物未被金属处理 配位化合物 并且在每个分子中加入具有氢硅键和交联性甲硅烷基的化合物和氢化硅烷化催化剂，从而进行氢化硅烷化反应，其中在没有金属配位化合物的情况下进行氢化反应。
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