公开(公告)号：US07808242B2

公开(公告)日：2010-10-05

申请号：US12270996

申请日：2008-11-14

申请人： Hiroyuki Yamamoto ,  Kazuo Saitoh ,  Kenji Kawasaki ,  Yuzo Fukuda ,  Michiya Okada

发明人： Hiroyuki Yamamoto ,  Kazuo Saitoh ,  Kenji Kawasaki ,  Yuzo Fukuda ,  Michiya Okada

IPC分类号： G01V3/00

CPC分类号： G01R33/3635 ,  G01R33/34053 ,  G01R33/34069 ,  G01R33/3806

摘要： A probe for nuclear magnetic resonance (NMR) measurement provided with a multiple resonant circuit for detecting signals of two or more nuclides with high detection efficiency for nuclide at low resonant frequency comprises a multiple resonance radio frequency (RF) coil circuit that, with multiple lead lines connected to the RF coil, causes a part of the RF coil, separated by the connection points of the lead lines, to function as the inductor of a trap circuit that cuts off a signal at the frequency F1 for a signal at the resonant frequency F1 of a first nuclide and, at the same time, to function as an RF coil that detects a signal at the frequency F2 for a signal at the resonant frequency F2 of a second nuclide, thus increasing the signal detection efficiency for the nuclide at the frequency F2.

摘要翻译： 具有用于以低谐振频率检测核素的具有高检测效率的两个或多个核素的信号的多谐振电路的核磁共振（NMR）测量探针包括多谐振射频（RF）线圈电路，其具有多引线 连接到RF线圈的线路使得由引线的连接点分开的RF线圈的一部分用作陷波电路的电感器，该陷波电路以频率F1切断谐振频率处的信号的信号 F1，并且同时用作检测频率为F2的信号的RF线圈，用于在第二核素的共振频率F2处的信号，从而提高在第二核素处的核素的信号检测效率 频率F2。

公开(公告)号：US20090121718A1

公开(公告)日：2009-05-14

申请号：US12270996

申请日：2008-11-14

申请人： Hiroyuki YAMAMOTO ,  Kazuo Saitoh ,  Kenji Kawasaki ,  Yuzo Fukuda ,  Michiya Okada

发明人： Hiroyuki YAMAMOTO ,  Kazuo Saitoh ,  Kenji Kawasaki ,  Yuzo Fukuda ,  Michiya Okada

IPC分类号： G01R33/32

CPC分类号： G01R33/3635 ,  G01R33/34053 ,  G01R33/34069 ,  G01R33/3806

摘要： A probe for nuclear magnetic resonance (NMR) measurement provided with a multiple resonant circuit for detecting signals of two or more nuclides with high detection efficiency for nuclide at low resonant frequency comprises a multiple resonance radio frequency (RF) coil circuit that, with multiple lead lines connected to the RF coil, causes a part of the RF coil, separated by the connection points of the lead lines, to function as the inductor of a trap circuit that cuts off a signal at the frequency F1 for a signal at the resonant frequency F1 of a first nuclide and, at the same time, to function as an RF coil that detects a signal at the frequency F2 for a signal at the resonant frequency F2 of a second nuclide, thus increasing the signal detection efficiency for the nuclide at the frequency F2.

摘要翻译： 具有用于以低谐振频率检测核素的具有高检测效率的两个或多个核素的信号的多谐振电路的核磁共振（NMR）测量探针包括多谐振射频（RF）线圈电路，其具有多引线 连接到RF线圈的线路使得由引线的连接点分开的RF线圈的一部分用作陷波电路的电感器，该陷波电路以频率F1切断谐振频率处的信号的信号 F1，并且同时用作检测频率为F2的信号的RF线圈，用于在第二核素的共振频率F2处的信号，从而提高在第二核素处的核素的信号检测效率 频率F2。

公开(公告)号：US20070096741A1

公开(公告)日：2007-05-03

申请号：US11588368

申请日：2006-10-27

申请人： Yuzo Fukuda ,  Kazuo Saitoh

发明人： Yuzo Fukuda ,  Kazuo Saitoh

IPC分类号： G01V3/00

CPC分类号： G01R33/34069 ,  G01R33/34023 ,  G01R33/34053 ,  G01R33/34092

摘要： A NMR probe which causes only a minimum disturbance to magnetic-field uniformity, and which acquires a high resonant Q value. A detection coil 1 for detecting a nuclear magnetic resonance signal emitted from a sample 3 measured, and a compensation coil 4 composed of a superconducting material for compensating for inductance of the detection coil 1 are electrically connected in series with each other. Moreover, a tuning-dedicated variable capacitor 6 is connected to the detection coil 1 in series therewith, and a matching-dedicated variable capacitor 5 is connected to the compensation coil 4 in series therewith. Furthermore, a coaxial cable 9 is connected to both ends of the matching-dedicated variable capacitor 5. This configuration allows detection of the signal.

摘要翻译： 一种仅对磁场均匀性产生最小干扰的NMR探针，其获得高谐振Q值。 用于检测从测量的样品3发射的核磁共振信号的检测线圈1和用于补偿检测线圈1的电感的超导材料构成的补偿线圈4彼此串联电连接。 此外，调谐专用可变电容器6与检测线圈1串联连接，匹配专用可变电容器5与补偿线圈4串联连接。 此外，同轴电缆9连接到匹配专用可变电容器5的两端。该配置允许检测信号。

公开(公告)号：US20070096740A1

公开(公告)日：2007-05-03

申请号：US11493819

申请日：2006-07-27

申请人： Yuzo Fukuda ,  Hiromitsu Seino ,  Kazuo Saitoh ,  Hiroyuki Tanaka ,  Tsuyoshi Wakuda ,  Norihide Saho ,  Michiya Okada

发明人： Yuzo Fukuda ,  Hiromitsu Seino ,  Kazuo Saitoh ,  Hiroyuki Tanaka ,  Tsuyoshi Wakuda ,  Norihide Saho ,  Michiya Okada

IPC分类号： G01V3/00

CPC分类号： G01R33/30

摘要： The invention provides a low temperature probe having a high sensitivity by reducing a heat intrusion into a receive coil. A heat making an intrusion into a coil is suppressed by inserting a heat radiation shield in which a temperature is controlled at about 100 K to a portion between an outer container of a probe and a coil portion. A heat radiation shield bore sleeve is provided in a heat radiation bore, is connected to the heat radiation shield, and is cooled by a second heat exchanger. Further, the coil portion is cooled by a first heat exchanger. In preparation for a contraction at a time of being cooled, the outer container, the heat radiation shield and the coil portion are connected by using a fixing portion, and a heat relieving mechanism or a contraction relieving mechanism is provided in a root side (an opposite side to the fixing portion) of the heat radiation shield and the coil portion. The fixing portion is formed in a shape and made of a material having a small heat intrusion amount and having a small heat contraction.

摘要翻译： 本发明通过减少对接收线圈的热侵入来提供具有高灵敏度的低温探针。 通过将温度控制在约100K的热辐射屏蔽物插入到探针的外部容器与线圈部分之间的部分来抑制进入线圈的热量。 热辐射屏蔽孔套筒设置在散热孔中，连接到散热屏蔽，并由第二热交换器冷却。 此外，线圈部分由第一热交换器冷却。 为了准备冷却时的收缩，通过使用固定部连接外容器，散热屏蔽体和线圈部，并且在根侧设置有放热机构或收缩解除机构 热辐射屏蔽体和线圈部分相对于固定部分的相对侧）。 固定部形成为由热侵入量小且热收缩小的材料构成。

公开(公告)号：US07701212B2

公开(公告)日：2010-04-20

申请号：US11877978

申请日：2007-10-24

申请人： Yuzo Fukuda ,  Hiroyuki Tanaka

发明人： Yuzo Fukuda ,  Hiroyuki Tanaka

IPC分类号： G01V3/00

CPC分类号： G01R33/34069 ,  F25B9/10 ,  F25B25/005 ,  G01R33/34023 ,  G01R33/3403 ,  G01R33/34053

摘要： A low temperature probe having a coil used in an NMR apparatus includes an opposed heat exchanger cooling a cooling medium, and a cooling apparatus having a first cooling stage capable of cooling to no more than 10K and a second cooling stage capable of cooling to at least 10K in series cooling the cooling medium from the opposed heat exchanger. A probe portion has a first heat exchanging portion executing heat exchange between the cooling medium and the coil, a circulation structure which circulates the cooling medium into the opposed heat exchanger, a second heat exchanging portion executing heat exchange between the cooling medium and a heat radiation shield. The heat radiation shield has a heat capacity greater than the heat capacity of the cooling medium.

摘要翻译： 具有在NMR装置中使用的线圈的低温探针包括冷却冷却介质的相对的热交换器和具有能够冷却至不超过10K的第一冷却阶段的冷却装置和能够至少冷却的第二冷却阶段 10K从相对的热交换器串联冷却冷却介质。 探针部分具有在冷却介质和线圈之间执行热交换的第一热交换部分，将冷却介质循环到相对的热交换器中的循环结构，在冷却介质和热辐射之间执行热交换的第二热交换部分 屏蔽。 热辐射屏蔽体的热容量大于冷却介质的热容量。

公开(公告)号：US07560932B2

公开(公告)日：2009-07-14

申请号：US11943731

申请日：2007-11-21

申请人： Yuzo Fukuda ,  Shuya Hagiwara ,  Kenji Kawasaki

发明人： Yuzo Fukuda ,  Shuya Hagiwara ,  Kenji Kawasaki

IPC分类号： G01V3/00

CPC分类号： G01R33/3621 ,  G01R33/34061 ,  G01R33/34092 ,  G01R33/3664

摘要： There is provided a nuclear magnetic resonance probe in which the loss caused by a high frequency cable between a probe coil and a preamplifier is reduced and the sensitivity of an NMR signal is improved. A changeover switch for NMR probe is divided into a switch part including switch elements and a filter part for filtering a switch control signal and an RF transmission signal. The switch part is disposed in a probe body inserted in a magnet of the probe. The filter part is disposed near a measurement apparatus located outside the probe. As for the switch part, a section structure of thickness and width is reduced in conformity with a narrow and slender shape of the probe body. The length of a high frequency cable between the probe coil and the preamplifier is shortened remarkably, and consequently the loss can be reduced.

摘要翻译： 提供了一种核磁共振探针，其中由探头线圈和前置放大器之间的高频电缆引起的损耗降低，并且提高了NMR信号的灵敏度。 用于NMR探针的转换开关被分为包括开关元件的开关部分和用于滤波开关控制信号和RF发送信号的滤波器部分。 开关部设置在插入探针的磁体中的探针体内。 过滤器部件设置在位于探头外部的测量装置附近。 对于开关部件，厚度和宽度的截面结构根据探头主体的窄而细长的形状而减小。 探针线圈和前置放大器之间的高频电缆的长度显着缩短，从而可以减少损耗。

公开(公告)号：US20080122442A1

公开(公告)日：2008-05-29

申请号：US11877978

申请日：2007-10-24

申请人： Yuzo FUKUDA ,  Hiroyuki Tanaka

发明人： Yuzo FUKUDA ,  Hiroyuki Tanaka

IPC分类号： G01V3/00

CPC分类号： G01R33/34069 ,  F25B9/10 ,  F25B25/005 ,  G01R33/34023 ,  G01R33/3403 ,  G01R33/34053

摘要： A low temperature probe having a coil used in an NMR apparatus includes an opposed heat exchanger cooling a cooling medium, and a cooling apparatus having a first cooling stage capable of cooling to no more than 10K and a second cooling stage capable of cooling to at least 10K in series cooling the cooling medium from the opposed heat exchanger. A probe portion has a first heat exchanging portion executing heat exchange between the cooling medium and the coil, a circulation structure which circulates the cooling medium into the opposed heat exchanger, a second heat exchanging portion executing heat exchange between the cooling medium and a heat radiation shield. The heat radiation shield has a heat capacity greater than the heat capacity of the cooling medium.

摘要翻译： 具有在NMR装置中使用的线圈的低温探针包括冷却冷却介质的相对的热交换器和具有能够冷却至不超过10K的第一冷却阶段的冷却装置和能够至少冷却的第二冷却阶段 10K从相对的热交换器串联冷却冷却介质。 探针部分具有在冷却介质和线圈之间执行热交换的第一热交换部分，将冷却介质循环到相对的热交换器中的循环结构，在冷却介质和热辐射之间执行热交换的第二热交换部分 屏蔽。 热辐射屏蔽体的热容量大于冷却介质的热容量。

公开(公告)号：US20080061786A1

公开(公告)日：2008-03-13

申请号：US11757453

申请日：2007-06-04

申请人： YUZO FUKUDA ,  Kazuo Saitoh ,  Hiroyuki Yamamoto ,  Michiya Okada

发明人： YUZO FUKUDA ,  Kazuo Saitoh ,  Hiroyuki Yamamoto ,  Michiya Okada

IPC分类号： G01R33/32

CPC分类号： G01R33/3657 ,  G01R33/34023 ,  G01R33/34053 ,  G01R33/34069

摘要： A probe for a nuclear magnetic resonance apparatus comprises: a transmission coil for irradiating a sample with a high-frequency electromagnetic wave; and a receiving coil for detecting a nuclear magnetic resonance signal emitted by the sample, wherein a selector switch is disposed to the transmission coil to reduce the deterioration of sensitivity of the receiving coil by switching the resonance state of the transmission circuit between during irradiation and during detection, even if an electromagnetic coupling remains between transmission and reception.

摘要翻译： 核磁共振装置的探针包括：用高频电磁波照射样品的发射线圈; 以及用于检测样品发射的核磁共振信号的接收线圈，其中选择器开关设置在传输线圈上，以通过在照射期间和之前切换传输电路的谐振状态来减少接收线圈的灵敏度的劣化 检测，即使电磁耦合保持在发送和接收之间。

公开(公告)号：US20120168649A1

公开(公告)日：2012-07-05

申请号：US13376869

申请日：2010-06-09

申请人： Yoichi Ishibai ,  Akihito Sakai ,  Takashi Nishikawa ,  Kenji Kataoka ,  Kiyoyuki Hotta ,  Hideyo Ando ,  Yuzo Fukuda ,  Yorisuke Kondo ,  Kazuya Suzuki

发明人： Yoichi Ishibai ,  Akihito Sakai ,  Takashi Nishikawa ,  Kenji Kataoka ,  Kiyoyuki Hotta ,  Hideyo Ando ,  Yuzo Fukuda ,  Yorisuke Kondo ,  Kazuya Suzuki

IPC分类号： G02B5/20 ,  B05D5/06 ,  B05D3/00 ,  C09D5/32

CPC分类号： C09D5/32 ,  C03C17/3417 ,  C03C2217/71 ,  C08K3/22 ,  C08K5/5419 ,  C08K5/5435 ,  C08K5/5455 ,  C09D7/61

摘要： Provided is a near-infrared shielding coating agent containing: (1) an inorganic near-infrared absorbing agent; (2) a tetrafunctional silicon compound represented by general formula Si(OR1)4, a hydrolysate thereof, and/or a condensation polymerization product thereof; (3) a trifunctional silicon compound represented by general formula R2Si(OR3)3, a hydrolysate thereof, and/or a condensation polymerization product thereof; (4) a silane coupling agent represented by one of the general formulas Si(X)3-Y or R4Si(X)2-Y, a hydrolysate thereof, and/or a condensation polymerization product thereof; and (5) a solvent. This coating agent allows the formation, at an ordinary temperature between 5° C. and 40° C., of a near-infrared shielding film that has a high film hardness and is not prone to cracks.

摘要翻译： 本发明提供一种近红外屏蔽涂层剂，其包含：（1）无机近红外吸收剂; （2）由通式Si（OR 1）4表示的四官能硅化合物，其水解产物和/或其缩聚产物; （3）由通式R 2 Si（OR 3）3表示的三官能硅化合物，其水解物和/或其缩聚产物; （4）由通式Si（X）3-Y或R 4 Si（X）2-Y之一表示的硅烷偶联剂，其水解产物和/或其缩聚产物; 和（5）溶剂。 该涂布剂允许在常温5℃至40℃之间形成具有高膜硬度并且不易发生裂纹的近红外屏蔽膜。

公开(公告)号：US20080258730A1

公开(公告)日：2008-10-23

申请号：US11943731

申请日：2007-11-21

申请人： Yuzo Fukuda ,  Shuya Hagiwara ,  Kenji Kawasaki

发明人： Yuzo Fukuda ,  Shuya Hagiwara ,  Kenji Kawasaki

IPC分类号： G01R33/34

CPC分类号： G01R33/3621 ,  G01R33/34061 ,  G01R33/34092 ,  G01R33/3664

摘要： There is provided a nuclear magnetic resonance probe in which the loss caused by a high frequency cable between a probe coil and a preamplifier is reduced and the sensitivity of an NMR signal is improved. A changeover switch for NMR probe is divided into a switch part including switch elements and a filter part for filtering a switch control signal and an RF transmission signal. The switch part is disposed in a probe body inserted in a magnet of the probe. The filter part is disposed near a measurement apparatus located outside the probe. As for the switch part, a section structure of thickness and width is reduced in conformity with a narrow and slender shape of the probe body. The length of a high frequency cable between the probe coil and the preamplifier is shortened remarkably, and consequently the loss can be reduced.

摘要翻译： 提供了一种核磁共振探针，其中由探头线圈和前置放大器之间的高频电缆引起的损耗降低，并且提高了NMR信号的灵敏度。 用于NMR探针的转换开关被分为包括开关元件的开关部分和用于滤波开关控制信号和RF发送信号的滤波器部分。 开关部设置在插入探针的磁体中的探针体内。 过滤器部件设置在位于探头外部的测量装置附近。 对于开关部件，厚度和宽度的截面结构根据探头主体的窄而细长的形状而减小。 探针线圈和前置放大器之间的高频电缆的长度显着缩短，从而可以减少损耗。