公开(公告)号：US20110111657A1

公开(公告)日：2011-05-12

申请号：US13007702

申请日：2011-01-17

申请人： Jusong Xia ,  Zhaolin Zhou ,  Kirkland W. Vogt ,  Philip G. Harris

发明人： Jusong Xia ,  Zhaolin Zhou ,  Kirkland W. Vogt ,  Philip G. Harris

IPC分类号： B32B5/02 ,  B32B27/40 ,  C08L75/04

CPC分类号： D06N3/14 ,  C08G18/0823 ,  C08G18/12 ,  C08G18/3228 ,  C08G18/348 ,  C08G18/4277 ,  C08G18/664 ,  C08G18/758 ,  C08G18/7671 ,  C08G2150/60 ,  C09B67/0013 ,  C09B67/009 ,  C09B69/10 ,  D06N3/0056 ,  D06N3/0097 ,  D06N3/145 ,  D06N2209/0823 ,  D06N2211/28 ,  Y10T428/24512 ,  Y10T428/31551 ,  Y10T428/31558 ,  Y10T442/20 ,  C08G18/302

摘要： A coated substrate comprises a substrate and a coating on at least one surface of the substrate. The coating comprises a prepolymer, polymer, or resin produced, for example, by the reaction of (i) an isocyanate (e.g., a polyisocyanate), (ii) an active hydrogen-terminated colorant, and optionally (iii) at least one reactant selected from the group consisting of chain extenders, polyols, internal surfactants, and combinations thereof. Polymer dispersions suitable for use in making such coated substrates comprise such a prepolymer, polymer, or resin.

摘要翻译： 涂覆的基底包括基底和在基底的至少一个表面上的涂层。 涂层包含预聚物，聚合物或树脂，例如通过（i）异氰酸酯（例如多异氰酸酯），（ii）活性氢终端着色剂和任选地（iii）至少一种反应物 选自扩链剂，多元醇，内部表面活性剂及其组合。 适用于制造这种涂覆的基材的聚合物分散体包含这种预聚物，聚合物或树脂。

公开(公告)号：US20090253322A1

公开(公告)日：2009-10-08

申请号：US12486409

申请日：2009-06-17

申请人： Jusong Xia ,  Zhaolin ZhOU ,  Chenghua Chen

发明人： Jusong Xia ,  Zhaolin ZhOU ,  Chenghua Chen

IPC分类号： D06N3/00 ,  B32B5/02 ,  B32B37/14

CPC分类号： D06N3/14 ,  B32B7/12 ,  B32B27/12 ,  B32B27/40 ,  B32B2307/4026 ,  D06N3/0056 ,  D06N3/0097 ,  Y10S428/904 ,  Y10T428/24438 ,  Y10T428/24512 ,  Y10T428/24603 ,  Y10T428/31551 ,  Y10T442/20 ,  Y10T442/2762

摘要： Novel synthetic leather articles comprise a substrate and a coating applied to a surface of the substrate. The coating comprises a resin and a polymeric colorant. The polymeric colorant comprises a chromophore and an oligomeric constituent bound to the chromophore. Novel methods for producing synthetic leather articles using polymeric colorants are also provided.

摘要翻译： 新颖的合成革制品包括施加到基底表面的基底和涂层。 涂层包括树脂和聚合物着色剂。 聚合物着色剂包括发色团和与发色团结合的低聚物。 还提供了使用聚合物着色剂生产合成革制品的新方法。

公开(公告)号：US06586051B2

公开(公告)日：2003-07-01

申请号：US10131735

申请日：2002-04-24

申请人： Zhaolin Zhou ,  Rubin Cai

发明人： Zhaolin Zhou ,  Rubin Cai

IPC分类号： B05D302

CPC分类号： C08J7/047 ,  B29C37/0032 ,  B29K2075/00 ,  B29K2105/04 ,  B29K2995/002 ,  C08G18/38 ,  C08J5/00 ,  C08J2375/04 ,  C08J2475/00 ,  Y10T156/10 ,  Y10T428/31504 ,  Y10T428/31551 ,  Y10T428/31554

摘要： Improvements for in-mold polyurethane foam and/or resin products and the ability to provide surface coatings of such products exhibiting bright coloration and reduced colorant migration through utilization of easy-to-use polymeric colorants in simplified and environmentally friendly processing methods are disclosed. The inventive surface coating formulations include polyurethane-reactive polymeric colorants admixed with prepolymer and excess amounts of certain isocyanate compounds. Such a composition is applied (by spraying, for example) to a polyurethane prepolymer (for the production of the internal polyurethane article) which is then introduced within a mold in order to form a particularly shaped or configured polyurethane article with a colored surface coating. Upon curing through exposure to heat, the coating composition reacts with the introduced polyurethane prepolymer to form a surface over the target internal polyurethane. The excess isocyanate present within the surface coating has been found to provide surprisingly good non-migration and non-bleed properties to the polymeric colorant thereby permitting the addition of such a highly desired, high color space, and effective polyurethane colorant within such surface coatings. The specific method as well as colored polyurethane articles are also contemplated within this invention.

公开(公告)号：US07662461B2

公开(公告)日：2010-02-16

申请号：US11395665

申请日：2006-03-31

申请人： Jusong Xia ,  Zhaolin Zhou ,  Chenghua Chen

发明人： Jusong Xia ,  Zhaolin Zhou ,  Chenghua Chen

IPC分类号： B32B3/12 ,  A61F13/15 ,  B32B27/40

CPC分类号： D06N3/14 ,  B32B7/12 ,  B32B27/12 ,  B32B27/40 ,  B32B2307/4026 ,  D06N3/0056 ,  D06N3/0097 ,  Y10S428/904 ,  Y10T428/24438 ,  Y10T428/24512 ,  Y10T428/24603 ,  Y10T428/31551 ,  Y10T442/20 ,  Y10T442/2762

摘要： Novel synthetic leather articles comprise a substrate and a coating applied to a surface of the substrate. The coating comprises a resin and a polymeric colorant. The polymeric colorant comprises a chromophore and an oligomeric constituent bound to the chromophore. Novel methods for producing synthetic leather articles using polymeric colorants are also provided.

公开(公告)号：US20070231546A1

公开(公告)日：2007-10-04

申请号：US11395665

申请日：2006-03-31

申请人： Jusong Xia ,  Zhaolin Zhou ,  Chenghua Chen

发明人： Jusong Xia ,  Zhaolin Zhou ,  Chenghua Chen

IPC分类号： B32B5/02 ,  D06N3/00 ,  B32B3/00 ,  D06N7/04

CPC分类号： D06N3/14 ,  B32B7/12 ,  B32B27/12 ,  B32B27/40 ,  B32B2307/4026 ,  D06N3/0056 ,  D06N3/0097 ,  Y10S428/904 ,  Y10T428/24438 ,  Y10T428/24512 ,  Y10T428/24603 ,  Y10T428/31551 ,  Y10T442/20 ,  Y10T442/2762

摘要： Novel synthetic leather articles comprise a substrate and a coating applied to a surface of the substrate. The coating comprises a resin and a polymeric colorant. The polymeric colorant comprises a chromophore and an oligomeric constituent bound to the chromophore. Novel methods for producing synthetic leather articles using polymeric colorants are also provided.

摘要翻译： 新颖的合成革制品包括施加到基底表面的基底和涂层。 涂层包括树脂和聚合物着色剂。 聚合物着色剂包括发色团和与发色团结合的低聚物。 还提供了使用聚合物着色剂生产合成革制品的新方法。

公开(公告)号：US08431648B2

公开(公告)日：2013-04-30

申请号：US13007702

申请日：2011-01-17

申请人： Jusong Xia ,  Zhaolin Zhou ,  Kirkland W. Vogt ,  Philip G. Harris

发明人： Jusong Xia ,  Zhaolin Zhou ,  Kirkland W. Vogt ,  Philip G. Harris

IPC分类号： C08G18/08 ,  B32B3/12

CPC分类号： D06N3/14 ,  C08G18/0823 ,  C08G18/12 ,  C08G18/3228 ,  C08G18/348 ,  C08G18/4277 ,  C08G18/664 ,  C08G18/758 ,  C08G18/7671 ,  C08G2150/60 ,  C09B67/0013 ,  C09B67/009 ,  C09B69/10 ,  D06N3/0056 ,  D06N3/0097 ,  D06N3/145 ,  D06N2209/0823 ,  D06N2211/28 ,  Y10T428/24512 ,  Y10T428/31551 ,  Y10T428/31558 ,  Y10T442/20 ,  C08G18/302

摘要： A coated substrate comprises a substrate and a coating on at least one surface of the substrate. The coating comprises a prepolymer, polymer, or resin produced, for example, by the reaction of (i) an isocyanate (e.g., a polyisocyanate), (ii) an active hydrogen-terminated colorant, and optionally (iii) at least one reactant selected from the group consisting of chain extenders, polyols, internal surfactants, and combinations thereof. Polymer dispersions suitable for use in making such coated substrates comprise such a prepolymer, polymer, or resin.

摘要翻译： 涂覆的基底包括基底和在基底的至少一个表面上的涂层。 涂层包含预聚物，聚合物或树脂，例如通过（i）异氰酸酯（例如多异氰酸酯），（ii）活性氢终端着色剂和任选地（iii）至少一种反应物 选自扩链剂，多元醇，内部表面活性剂及其组合。 适用于制造这种涂覆的基材的聚合物分散体包含这种预聚物，聚合物或树脂。

公开(公告)号：US07872069B2

公开(公告)日：2011-01-18

申请号：US11689017

申请日：2007-03-21

申请人： Jusong Xia ,  Zhaolin Zhou ,  Kirkland W. Vogt ,  Philip G. Harris

发明人： Jusong Xia ,  Zhaolin Zhou ,  Kirkland W. Vogt ,  Philip G. Harris

IPC分类号： C08G18/08

CPC分类号： C08G18/664 ,  C08G18/0823 ,  C08G18/12 ,  C08G18/3228 ,  C08G18/329 ,  C08G18/348 ,  C08G18/3836 ,  C08G18/4277 ,  C08G18/758 ,  C08G18/7671 ,  C09D175/04 ,  C09D175/06 ,  D06N3/14 ,  Y10T428/31551 ,  Y10T428/31558 ,  C08G18/302 ,  C08L2666/20

摘要： A coated substrate comprises a substrate and a coating on at least one surface of the substrate. The coating comprises a prepolymer, polymer, or resin produced, for example, by the reaction of (i) an isocyanate (e.g., a polyisocyanate), (ii) an active hydrogen-terminated colorant, and optionally (iii) at least one reactant selected from the group consisting of chain extenders, polyols, internal surfactants, and combinations thereof. Polymer dispersions suitable for use in making such coated substrates comprise such a prepolymer, polymer, or resin.

摘要翻译： 涂覆的基底包括基底和在基底的至少一个表面上的涂层。 涂层包含预聚物，聚合物或树脂，例如通过（i）异氰酸酯（例如多异氰酸酯），（ii）活性氢终端着色剂和任选地（iii）至少一种反应物 选自扩链剂，多元醇，内部表面活性剂及其组合。 适用于制造这种涂覆的基材的聚合物分散体包含这种预聚物，聚合物或树脂。

公开(公告)号：US07824737B2

公开(公告)日：2010-11-02

申请号：US12486409

申请日：2009-06-17

申请人： Jusong Xia ,  Zhaolin Zhou ,  Chenghua Chen

发明人： Jusong Xia ,  Zhaolin Zhou ,  Chenghua Chen

IPC分类号： B05D3/02 ,  B29C47/00

CPC分类号： D06N3/14 ,  B32B7/12 ,  B32B27/12 ,  B32B27/40 ,  B32B2307/4026 ,  D06N3/0056 ,  D06N3/0097 ,  Y10S428/904 ,  Y10T428/24438 ,  Y10T428/24512 ,  Y10T428/24603 ,  Y10T428/31551 ,  Y10T442/20 ,  Y10T442/2762

摘要： Novel synthetic leather articles comprise a substrate and a coating applied to a surface of the substrate. The coating comprises a resin and a polymeric colorant. The polymeric colorant comprises a chromophore and an oligomeric constituent bound to the chromophore. Novel methods for producing synthetic leather articles using polymeric colorants are also provided.

摘要翻译： 新颖的合成革制品包括施加到基底表面的基底和涂层。 涂层包括树脂和聚合物着色剂。 聚合物着色剂包括发色团和与发色团结合的低聚物。 还提供了使用聚合物着色剂生产合成革制品的新方法。

公开(公告)号：US20080261052A1

公开(公告)日：2008-10-23

申请号：US11689017

申请日：2007-03-21

申请人： Jusong Xia ,  Zhaolin Zhou ,  Kirkland W. Vogt ,  Philip G. Harris

发明人： Jusong Xia ,  Zhaolin Zhou ,  Kirkland W. Vogt ,  Philip G. Harris

IPC分类号： B32B27/40 ,  B32B27/06 ,  C08K3/18

CPC分类号： C08G18/664 ,  C08G18/0823 ,  C08G18/12 ,  C08G18/3228 ,  C08G18/329 ,  C08G18/348 ,  C08G18/3836 ,  C08G18/4277 ,  C08G18/758 ,  C08G18/7671 ,  C09D175/04 ,  C09D175/06 ,  D06N3/14 ,  Y10T428/31551 ,  Y10T428/31558 ,  C08G18/302 ,  C08L2666/20

摘要： A coated substrate comprises a substrate and a coating on at least one surface of the substrate. The coating comprises a prepolymer, polymer, or resin produced, for example, by the reaction of (i) an isocyanate (e.g., a polyisocyanate), (ii) an active hydrogen-terminated colorant, and optionally (iii) at least one reactant selected from the group consisting of chain extenders, polyols, internal surfactants, and combinations thereof. Polymer dispersions suitable for use in making such coated substrates comprise such a prepolymer, polymer, or resin.

摘要翻译： 涂覆的基底包括基底和在基底的至少一个表面上的涂层。 涂层包含预聚物，聚合物或树脂，例如通过（i）异氰酸酯（例如多异氰酸酯），（ii）活性氢终端着色剂和任选地（iii）至少一种反应物 选自扩链剂，多元醇，内部表面活性剂及其组合。 适用于制造这种涂覆的基材的聚合物分散体包含这种预聚物，聚合物或树脂。

公开(公告)号：US06479561B1

公开(公告)日：2002-11-12

申请号：US09651327

申请日：2000-08-30

申请人： Zhaolin Zhou ,  Rubin Cai

发明人： Zhaolin Zhou ,  Rubin Cai

IPC分类号： C08G1800

CPC分类号： C08J7/047 ,  B29C37/0032 ,  B29K2075/00 ,  B29K2105/04 ,  B29K2995/002 ,  C08G18/38 ,  C08J5/00 ,  C08J2375/04 ,  C08J2475/00 ,  Y10T156/10 ,  Y10T428/31504 ,  Y10T428/31551 ,  Y10T428/31554

摘要： Improvements for in-mold polyurethane foam and/or resin products and the ability to provide surface coatings of such products exhibiting bright coloration and reduced colorant migration through utilization of easy-to-use polymeric colorants in simplified and environmentally friendly processing methods are disclosed. The inventive surface coating formulations include polyurethane-reactive polymeric colorants admixed with prepolymer and excess amounts of certain isocyanate compounds. Such a composition is applied (by spraying, for example) to a polyurethane prepolymer (for the production of the internal polyurethane article) which is then introduced within a mold in order to form a particularly shaped or configured polyurethane article with a colored surface coating. Upon curing through exposure to heat, the coating composition reacts with the introduced polyurethane prepolymer to form a surface over the target internal polyurethane. The excess isocyanate present within the surface coating has been found to provide surprisingly good non-migration and non-bleed properties to the polymeric colorant thereby permitting the addition of such a highly desired, high color space, and effective polyurethane colorant within such surface coatings. The specific method as well as colored polyurethane articles are also contemplated within this invention.