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公开(公告)号：US09598647B2
公开(公告)日：2017-03-21
申请号：US12876636
申请日：2010-09-07
IPC分类号： C10G27/04 , C10G21/20 , C10G53/08 , C10G53/14 , C10G21/00 , C10G21/06 , C10G21/12 , C10G21/16 , C10G21/22 , C10G21/28 , C10G25/00 , C10G27/12 , C10G53/04
CPC分类号： C10G27/04 , C10G21/003 , C10G21/06 , C10G21/12 , C10G21/16 , C10G21/22 , C10G21/28 , C10G25/003 , C10G27/12 , C10G53/04 , C10G53/08 , C10G53/14 , C10G2300/202 , C10G2300/206 , C10G2300/44
摘要： A method and apparatus for upgrading a hydrocarbon feedstock is provided. The method includes the steps of (a) supplying a hydrocarbon feedstock to an oxidation reactor, wherein the hydrocarbon feedstock is oxidized in the presence of a catalyst under conditions sufficient to selectively oxidize sulfur compounds present in the hydrocarbon feedstock; (c) separating the hydrocarbons and the oxidized sulfur compounds by solvent extraction; (d) collecting a residue stream that includes the oxidized sulfur compounds; and (e) supplying the residue stream to a deasphalting unit.
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2.发明授权Process for oxidative desulfurization and denitrogenation using a fluid catalytic cracking (FCC) unit 有权使用流化催化裂化（FCC）装置进行氧化脱硫脱氮的方法公开(公告)号：US09574144B2
公开(公告)日：2017-02-21
申请号：US12876702
申请日：2010-09-07
IPC分类号： C10G55/06 , C10G21/20 , C10G27/04 , C10G21/06 , C10G21/12 , C10G21/16 , C10G21/22 , C10G21/28 , C10G25/00 , C10G27/12 , C10G53/04 , C10G53/08 , C10G53/14
CPC分类号： C10G55/06 , C10G21/06 , C10G21/12 , C10G21/16 , C10G21/22 , C10G21/28 , C10G25/003 , C10G27/04 , C10G27/12 , C10G53/04 , C10G53/08 , C10G53/14 , C10G2300/1074 , C10G2300/202 , C10G2300/44
摘要： A method and apparatus for recovering components from a hydrocarbon feedstock is provided. The method includes the steps of (a) supplying a hydrocarbon feedstock to an oxidation reactor, wherein the hydrocarbon feedstock is oxidized in the presence of a catalyst under conditions sufficient to selectively oxidize sulfur compounds and nitrogen compounds present in the hydrocarbon feedstock; (b) separating the hydrocarbons, the oxidized sulfur compounds, and the oxidized nitrogen compounds by solvent extraction; (c) collecting a residue stream that includes the oxidized sulfur compounds and the oxidized nitrogen compounds; and (d) supplying the residue stream to a fluid catalytic cracking unit.
摘要翻译： 提供了一种从烃原料中回收组分的方法和装置。 该方法包括以下步骤：（a）将烃原料供应至氧化反应器，其中烃原料在催化剂存在下在足以选择性氧化存在于烃原料中的硫化合物和氮化合物的条件下被氧化; （b）通过溶剂萃取分离烃，氧化的硫化合物和氧化的氮化合物; （c）收集包含氧化的硫化合物和氧化的氮化合物的残余物流; 和（d）将残余物流供应到流化催化裂化装置。
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3.发明授权公开(公告)号：US09574142B2
公开(公告)日：2017-02-21
申请号：US12876822
申请日：2010-09-07
IPC分类号： C10G27/04 , C10G21/20 , C10G53/14 , C10G53/04 , C10G21/12 , C10G27/12 , C10G27/14 , C01B3/38
CPC分类号： C10G53/04 , C01B3/386 , C01B2203/0261 , C01B2203/127 , C01B2203/84 , C10G21/12 , C10G27/04 , C10G27/12 , C10G27/14 , C10G53/14 , C10G2300/1037 , C10G2300/1055 , C10G2300/202 , C10G2300/207 , C10G2300/44 , C10J2300/1665 , C10J2300/1807
摘要： A method and apparatus for upgrading a hydrocarbon feedstock is provided. The method includes the steps of (a) supplying a hydrocarbon feedstock to an oxidation reactor, wherein the hydrocarbon feedstock is oxidized in the presence of a catalyst under conditions sufficient to selectively oxidize sulfur compounds present in the hydrocarbon feedstock; (c) separating the hydrocarbons and the oxidized sulfur compounds by solvent extraction; (d) collecting a residue stream that includes the oxidized sulfur compounds; and (e) supplying the residue stream to a gasifier to produce a syngas stream and a hydrogen sulfide stream.
摘要翻译： 提供了一种用于升级烃原料的方法和装置。 该方法包括以下步骤：（a）向烃氧化反应器提供烃原料，其中烃原料在催化剂存在下在足以选择性氧化存在于烃原料中的硫化合物的条件下被氧化; （c）通过溶剂萃取分离烃和氧化的硫化合物; （d）收集包含氧化硫化合物的残余物流; 和（e）将残余物流供应到气化器以产生合成气流和硫化氢流。
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公开(公告)号：US20120055849A1
公开(公告)日：2012-03-08
申请号：US12876822
申请日：2010-09-07
CPC分类号： C10G53/04 , C01B3/386 , C01B2203/0261 , C01B2203/127 , C01B2203/84 , C10G21/12 , C10G27/04 , C10G27/12 , C10G27/14 , C10G53/14 , C10G2300/1037 , C10G2300/1055 , C10G2300/202 , C10G2300/207 , C10G2300/44 , C10J2300/1665 , C10J2300/1807
摘要： A method and apparatus for upgrading a hydrocarbon feedstock is provided. The method includes the steps of (a) supplying a hydrocarbon feedstock to an oxidation reactor, wherein the hydrocarbon feedstock is oxidized in the presence of a catalyst under conditions sufficient to selectively oxidize sulfur compounds present in the hydrocarbon feedstock; (c) separating the hydrocarbons and the oxidized sulfur compounds by solvent extraction; (d) collecting a residue stream that includes the oxidized sulfur compounds; and (e) supplying the residue stream to a gasifier to produce a syngas stream and a hydrogen sulfide stream.
摘要翻译： 提供了一种用于升级烃原料的方法和装置。 该方法包括以下步骤：（a）向烃氧化反应器供应烃原料，其中烃原料在催化剂存在下在足以选择性氧化存在于烃原料中的硫化合物的条件下被氧化; （c）通过溶剂萃取分离烃和氧化的硫化合物; （d）收集包含氧化硫化合物的残余物流; 和（e）将残余物流供应到气化器以产生合成气流和硫化氢流。
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公开(公告)号：US20120055845A1
公开(公告)日：2012-03-08
申请号：US12876781
申请日：2010-09-07
CPC分类号： C10G53/14 , C10B55/00 , C10B57/04 , C10G21/16 , C10G21/20 , C10G21/22 , C10G21/28 , C10G27/04 , C10G27/12 , C10G53/04 , C10G2300/202 , C10G2300/301 , C10G2300/44
摘要： A method and apparatus for upgrading a hydrocarbon feedstock is provided. The method includes the steps of (a) supplying a hydrocarbon feedstock to an oxidation reactor, wherein the hydrocarbon feedstock is oxidized in the presence of a catalyst under conditions sufficient to selectively oxidize sulfur compounds present in the hydrocarbon feedstock; (c) separating the hydrocarbons and the oxidized sulfur compounds by solvent extraction; (d) collecting a residue stream that includes the oxidized sulfur compounds; and (e) supplying the residue stream to a coker to produce coker gases and solid coke.
摘要翻译： 提供了一种用于升级烃原料的方法和装置。 该方法包括以下步骤：（a）向烃氧化反应器提供烃原料，其中烃原料在催化剂存在下在足以选择性氧化存在于烃原料中的硫化合物的条件下被氧化; （c）通过溶剂萃取分离烃和氧化的硫化合物; （d）收集包含氧化硫化合物的残余物流; 和（e）将残余物流供应到焦化器以产生焦化气体和固体焦炭。
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公开(公告)号：US09574143B2
公开(公告)日：2017-02-21
申请号：US12876781
申请日：2010-09-07
IPC分类号： C10G53/14 , C10G21/20 , C10G21/28 , C10B55/00 , C10B57/04 , C10G21/16 , C10G21/22 , C10G27/04 , C10G27/12 , C10G53/04
CPC分类号： C10G53/14 , C10B55/00 , C10B57/04 , C10G21/16 , C10G21/20 , C10G21/22 , C10G21/28 , C10G27/04 , C10G27/12 , C10G53/04 , C10G2300/202 , C10G2300/301 , C10G2300/44
摘要： A method and apparatus for upgrading a hydrocarbon feedstock is provided. The method includes the steps of (a) supplying a hydrocarbon feedstock to an oxidation reactor, wherein the hydrocarbon feedstock is oxidized in the presence of a catalyst under conditions sufficient to selectively oxidize sulfur compounds present in the hydrocarbon feedstock; (c) separating the hydrocarbons and the oxidized sulfur compounds by solvent extraction; (d) collecting a residue stream that includes the oxidized sulfur compounds; and (e) supplying the residue stream to a coker to produce coker gases and solid coke.
摘要翻译： 提供了一种用于升级烃原料的方法和装置。 该方法包括以下步骤：（a）向烃氧化反应器提供烃原料，其中烃原料在催化剂存在下在足以选择性氧化存在于烃原料中的硫化合物的条件下被氧化; （c）通过溶剂萃取分离烃和氧化的硫化合物; （d）收集包含氧化硫化合物的残余物流; 和（e）将残余物流供应到焦化器以产生焦化气体和固体焦炭。
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7.发明申请Process for Oxidative Desulfurization and Denitrogenation Using A Fluid Catalytic Cracking (FCC) Unit 有权使用流化催化裂化（FCC）单元进行氧化脱硫脱氮工艺公开(公告)号：US20120055844A1
公开(公告)日：2012-03-08
申请号：US12876702
申请日：2010-09-07
IPC分类号： C10G21/00
CPC分类号： C10G55/06 , C10G21/06 , C10G21/12 , C10G21/16 , C10G21/22 , C10G21/28 , C10G25/003 , C10G27/04 , C10G27/12 , C10G53/04 , C10G53/08 , C10G53/14 , C10G2300/1074 , C10G2300/202 , C10G2300/44
摘要： A method and apparatus for recovering components from a hydrocarbon feedstock is provided. The method includes the steps of (a) supplying a hydrocarbon feedstock to an oxidation reactor, wherein the hydrocarbon feedstock is oxidized in the presence of a catalyst under conditions sufficient to selectively oxidize sulfur compounds and nitrogen compounds present in the hydrocarbon feedstock; (b) separating the hydrocarbons, the oxidized sulfur compounds, and the oxidized nitrogen compounds by solvent extraction; (c) collecting a residue stream that includes the oxidized sulfur compounds and the oxidized nitrogen compounds; and (d) supplying the residue stream to a fluid catalytic cracking unit.
摘要翻译： 提供了一种从烃原料中回收组分的方法和装置。 该方法包括以下步骤：（a）将烃原料供应至氧化反应器，其中烃原料在催化剂存在下在足以选择性氧化存在于烃原料中的硫化合物和氮化合物的条件下被氧化; （b）通过溶剂萃取分离烃，氧化的硫化合物和氧化的氮化合物; （c）收集包含氧化的硫化合物和氧化的氮化合物的残余物流; 和（d）将残余物流供应到流化催化裂化装置。
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8.发明申请Process for Oxidative Desulfurization and Sulfone Disposal Using Solvent Deasphalting 有权使用溶剂脱沥青的氧化脱硫和砜处理方法公开(公告)号：US20120055843A1
公开(公告)日：2012-03-08
申请号：US12876636
申请日：2010-09-07
CPC分类号： C10G27/04 , C10G21/003 , C10G21/06 , C10G21/12 , C10G21/16 , C10G21/22 , C10G21/28 , C10G25/003 , C10G27/12 , C10G53/04 , C10G53/08 , C10G53/14 , C10G2300/202 , C10G2300/206 , C10G2300/44
摘要： A method and apparatus for upgrading a hydrocarbon feedstock is provided. The method includes the steps of (a) supplying a hydrocarbon feedstock to an oxidation reactor, wherein the hydrocarbon feedstock is oxidized in the presence of a catalyst under conditions sufficient to selectively oxidize sulfur compounds present in the hydrocarbon feedstock; (c) separating the hydrocarbons and the oxidized sulfur compounds by solvent extraction; (d) collecting a residue stream that includes the oxidized sulfur compounds; and (e) supplying the residue stream to a deasphalting unit.
摘要翻译： 提供了一种用于升级烃原料的方法和装置。 该方法包括以下步骤：（a）向烃氧化反应器提供烃原料，其中烃原料在催化剂存在下在足以选择性氧化存在于烃原料中的硫化合物的条件下被氧化; （c）通过溶剂萃取分离烃和氧化的硫化合物; （d）收集包含氧化硫化合物的残余物流; 和（e）将残余物流供应到脱沥青单元。
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9.发明授权System and process for integrated oxidative desulfurization, desalting and deasphalting of hydrocarbon feedstocks 有权碳氢化合物原料的综合氧化脱硫，脱盐和脱沥青的系统和工艺公开(公告)号：US08980080B2
公开(公告)日：2015-03-17
申请号：US13049305
申请日：2011-03-16
CPC分类号： C10G31/08 , C10G27/00 , C10G27/04 , C10G33/02 , C10G2300/202
摘要： A system and process for integrated desulfurizing, desalting and deasphalting of hydrocarbon feedstocks is provided. A hydrocarbon feedstock, a water soluble oxidant, and a water soluble catalyst can be introduced in a oxidation zone and retained for a period of time sufficient to achieve the desired degree of desulfurization, or introduced directly into the desalting zone along with wash water. Catalyst and dissolved salt are discharged along with the wastewater effluent from the desalting zone. A hydrocarbon stream including converted hydrocarbons and oxidation by-products is passed to a deasphalting zone. In the deasphalting zone, phase separation occurs, whereby a light phase including desulfurized hydrocarbons are produced, and a heavy phase including asphaltenes and oxidation by-products are discharged, e.g., passed to an asphalt pool.
摘要翻译： 提供了一种用于烃原料综合脱硫，脱盐和脱沥青的系统和方法。 可将烃原料，水溶性氧化剂和水溶性催化剂引入氧化区并保持足以达到所需程度的脱硫的时间段，或者与洗涤水一起直接引入脱盐区。 催化剂和溶解盐与脱盐区的废水一起排放。 包含转化烃和氧化副产物的烃流被送到脱沥青区。 在脱沥青区，发生相分离，由此产生包括脱硫烃的轻相，并且包括沥青质和氧化副产物的重相排出，例如通过沥青池。
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10.发明申请公开(公告)号：US20130199968A1
公开(公告)日：2013-08-08
申请号：US13741819
申请日：2013-01-15
申请人： Abdennour Bourane , Omer Refa Koseoglu , Zinfer Ismagilov , Svetlana Yashnik , Mikhail Kerzhentsev , Valentin Parmon
发明人： Abdennour Bourane , Omer Refa Koseoglu , Zinfer Ismagilov , Svetlana Yashnik , Mikhail Kerzhentsev , Valentin Parmon
IPC分类号： C10G67/12
CPC分类号： C10G67/12 , B01J23/002 , B01J23/005 , B01J23/80 , B01J23/83 , B01J35/0006 , B01J35/006 , B01J35/023 , B01J35/026 , B01J35/08 , B01J35/1014 , B01J35/1038 , B01J35/1061 , B01J37/009 , B01J37/031 , B01J2523/00 , C10G27/04 , C10G45/02 , B01J2523/17 , B01J2523/27 , B01J2523/31
摘要： Desulfurization of hydrocarbon feeds is achieved by first contacting the entire feed with a hydrodesulfurization catalyst in a hydrodesulfurization reaction zone operating under mild conditions; a flashing column downstream of the hydrodesulfurization reaction zone fractionates the effluent to obtain a first fraction which contains refractory organosulfur compounds and a second fraction that is substantially free of organosulfur compounds, since the organosulfur compounds boiling in the range of this fraction were the labile organosulfur compounds which were initially removed by mild hydrodesulfurization. The first fraction is contacted with a gaseous oxidizing agent over an oxidation catalyst having a formula CuxZn1-xAl2O4 in a gas phase catalytic oxidation reaction zone to convert the refractory organosulfur compounds to SOx and low sulfur hydrocarbons. The by-product SOx is subsequently removed, producing a stream containing a reduced level of organosulfur compounds.
摘要翻译： 通过在温和条件下操作的加氢脱硫反应区中首先使整个进料与加氢脱硫催化剂接触来实现烃进料的脱硫; 在加氢脱硫反应区下游的闪烁柱对流出物进行分馏，得到含有难熔有机硫化合物的第一馏分和基本上不含有机硫化合物的第二馏分，因为在该馏分范围内沸腾的有机硫化合物是不稳定的有机硫化合物 最初由轻度加氢脱硫除去。 在气相催化氧化反应区中，将第一级分与具有式CuxZn1-xAl2O4的氧化催化剂上的气态氧化剂接触，以将难熔有机硫化合物转化成SOx和低硫烃。 随后除去副产物SOx，产生含有降低水平的有机硫化合物的物流。
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