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公开(公告)号：US07319180B2
公开(公告)日：2008-01-15
申请号：US10973746
申请日：2004-10-26
IPC分类号： C07C2/54
CPC分类号： C07C2/62 , C07C11/02 , C07C2527/054 , C10G29/205 , C10G2300/1081 , C10G2300/1088
摘要： A process for the alkylation of alkane with olefin or olefin precursor such as an oligomer of tertiary olefin comprising contacting a liquid system comprising acid catalyst, isoparaffin and olefin in concurrent downflow into contact in a reaction zone with a disperser mesh under conditions of temperature and pressure to react said isoparaffin and said olefin to produce an alkylate product is disclosed. Preferably, the liquid system is maintained at about its boiling point in the reaction zone. Unexpectedly, the olefin oligomers have been found to function as olefin precursors and not as olefins in the reaction. Thus, for example, a cold acid alkylation using an oligomer of isobutene (principally dimer and trimer) with isobutane produces isooctane with the isobutane reacting with the constituent isobutene units of the oligomers on a molar basis. The product isooctane is essentially the same as that produced in the conventional cold acid process.
摘要翻译： 一种烷烃与烯烃或烯烃前体烷基化的方法，例如叔烯烃的低聚物，包括使含有酸催化剂，异链烷烃和烯烃的液体体系同时向下流动，在温度和压力条件下在分散网中与反应区接触 使所述异链烷烃和所述烯烃反应生成烷基化物产物。 优选地，液体系统保持在反应区域的大约沸点。 出乎意料地，已经发现烯烃低聚物作为烯烃前体而不是反应中的烯烃。 因此，例如，使用异丁烯（主要是二聚体和三聚体）的低聚物与异丁烷的冷酸烷基化产生异辛烷，异丁烷与摩尔的低聚物的组分异丁烯单元反应。 产物异辛烷基本上与常规冷酸法中产生的相同。
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公开(公告)号：US07250542B2
公开(公告)日：2007-07-31
申请号：US10793028
申请日：2004-03-04
CPC分类号： C07C2/62 , C07C11/02 , C07C2527/054 , C10G29/205 , C10G2300/1081 , C10G2300/1088
摘要： A process for the alkylation of alkane with olefin or olefin precursor such as an oligomer of tertiary olefin comprising contacting a liquid system comprising acid catalyst, isoparaffin and olefin in concurrent downflow into contact in a reaction zone with a disperser mesh under conditions of temperature and pressure to react said isoparaffin and said olefin to produce an alkylate product is disclosed. Preferably, the liquid system is maintained at about its boiling point in the reaction zone. Unexpectedly, the olefin oligomers have been found to function as olefin precursors and not as olefins in the reaction. Thus, for example, a cold acid alkylation using an oligomer of isobutene (principally dimer and trimer) with isobutane produces isooctane with the isobutane reacting with the constituent isobutene units of the oligomers on a molar basis. The product isooctane is essentially the same as that produced in the conventional cold acid process.
摘要翻译： 一种烷烃与烯烃或烯烃前体烷基化的方法，例如叔烯烃的低聚物，包括使含有酸催化剂，异链烷烃和烯烃的液体体系同时向下流动，在温度和压力条件下在分散网中与反应区接触 使所述异链烷烃和所述烯烃反应生成烷基化物产物。 优选地，液体系统保持在反应区域的大约沸点。 出乎意料地，已经发现烯烃低聚物作为烯烃前体而不是反应中的烯烃。 因此，例如，使用异丁烯（主要是二聚体和三聚体）的低聚物与异丁烷的冷酸烷基化产生异辛烷，异丁烷与摩尔的低聚物的组分异丁烯单元反应。 产物异辛烷基本上与常规冷酸法中产生的相同。
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公开(公告)号：US06995296B2
公开(公告)日：2006-02-07
申请号：US10870104
申请日：2004-06-17
IPC分类号： C07C2/62
CPC分类号： C07C2/62 , C07C11/02 , C07C2527/054 , C10G29/205 , C10G2300/1081 , C10G2300/1088
摘要： A process for the alkylation of alkane with olefin or olefin precursor such as an oligomer of tertiary olefin comprising contacting a liquid system comprising acid catalyst, isoparaffin and olefin in concurrent downflow into contact in a reaction zone with a disperser mesh under conditions of temperature and pressure to react said isoparaffin and said olefin to produce an alkylate product is disclosed. Preferably, the liquid system is maintained at about its boiling point in the reaction zone. Unexpectedly, the olefin oligomers have been found to function as olefin precursors and not as olefins in the reaction. Thus, for example, a cold acid alkylation using an oligomer of isobutene (principally dimer and trimer) with isobutane produces isooctane with the isobutane reacting with the constituent isobutene units of the oligomers on a molar basis. The product isooctane is essentially the same as that produced in the conventional cold acid process.
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4.发明授权Method of operating downflow boiling point reactors in the selective hydrogenation of acetylenes and dienes 有权在乙炔和二烯的选择性氢化中操作下流沸点反应器的方法公开(公告)号：US07408090B2
公开(公告)日：2008-08-05
申请号：US11101098
申请日：2005-04-07
IPC分类号： C07C5/03
CPC分类号： C07C7/167 , C07C7/163 , C10G45/34 , C10G49/002
摘要： Acetylenes and dienes in a stream containing hydrogen, methane, C2-C6 olefins and paraffins, C2-C6 acetylenes and dienes, benzene, toluene, xylenes, and other C6+ components are hydrogenated in a downflow boiling point reactor wherein the heat of reaction is absorbed by the liquid in the reactor which produces a vapor. Besides the feed to the reactor there is a recirculating stream which is fed at a rate sufficient to ensure that the catalyst particles within the reactor are wetted. A third stream, which is provided from a second downstream liquid/vapor separator from partially condensed vapor from the first downstream liquid/vapor separator corresponding to the mass evaporated in the reactor, is fed to the reactor. The composition of the third stream controls the steady state composition of the liquid flowing through the reactor.
摘要翻译： 含有氢，甲烷，C 2 -C 6烯烃和链烷烃，C 2 -C 6烯烃的物流中的乙炔和二烯， 乙炔和二烯，苯，甲苯，二甲苯和其它C 6+组分在下流沸点反应器中氢化，其中反应热被反应器中的液体吸收，产生 汽。 除了进料到反应器之外还有一个再循环流，其进料量足以确保反应器内的催化剂颗粒被润湿。 从第二下游液体/蒸汽分离器提供的第三流体，其与来自在反应器中蒸发的物质相对应的来自第一下游液体/蒸气分离器的部分冷凝的蒸气供给到反应器。 第三流的组成控制流过反应器的液体的稳态组成。
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5.发明授权公开(公告)号：US06867338B2
公开(公告)日：2005-03-15
申请号：US10385677
申请日：2003-03-12
CPC分类号： C07C5/09 , C07C5/05 , C07C7/163 , C07C7/167 , C07C2523/44
摘要： Acetylenes and dienes in a stream containing hydrogen, methane, C2-C6 olefins and paraffins, C2-C6 acetylenes and dienes, benzene, toluene, xylenes, and other C6+ components are hydrogenated in a downflow boiling point reactor wherein the heat of reaction is absorbed by the liquid in the reactor which produces a vapor. Besides the feed to the reactor there is a recirculating stream which is fed at a rate sufficient to ensure that the catalyst particles within the reactor are wetted. A third stream, which is taken from a downstream distillation column, is fed to provide the make up mass corresponding to the mass evaporated in the reactor. The composition of the this third stream controls the steady state composition of the liquid flowing through the reactor.
摘要翻译： 在含有氢气，甲烷，C 2 -C 6烯烃和链烷烃，C 2 -C 6炔烃和二烯，苯，甲苯，二甲苯和其它C 6+组分的物流中的乙炔和二烯在反应热被吸收的下流沸点反应器中氢化 通过反应器中产生蒸汽的液体。 除了进料到反应器之外还有一个再循环流，其进料量足以确保反应器内的催化剂颗粒被润湿。 进料从下游蒸馏塔获得的第三料流，以提供与在反应器中蒸发的物质相应的补充质量。 该第三流的组成控制流过反应器的液体的稳态组成。
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公开(公告)号：US06858770B2
公开(公告)日：2005-02-22
申请号：US10219877
申请日：2002-08-15
IPC分类号： B01J27/053 , B01J35/12 , C07C2/06 , C07C2/54 , C07C2/56 , C07C2/58 , C07C2/62 , C10G35/04 , C10G50/00 , C10G63/02
CPC分类号： C07C2/62 , C07C11/02 , C07C2527/054 , C10G29/205 , C10G2300/1081 , C10G2300/1088
摘要： A process for the alkylation of alkane with olefin or olefin precursor such as an oligomer of tertiary olefin comprising contacting a liquid system comprising acid catalyst, isoparaffin and olefin in concurrent downflow into contact in a reaction zone with a disperser mesh under conditions of temperature and pressure to react said isoparaffin and said olefin to produce an alkylate product is disclosed. Preferably, the liquid system is maintained at about its boiling point in the reaction zone. Unexpectedly, the olefin oligomers have been found to function as olefin precursors and not as olefins in the reaction. Thus, for example, a cold acid alkylation using an oligomer of isobutene (principally dimer and trimer) with isobutane produces isooctane with the isobutane reacting with the constituent isobutene units of the oligomers on a molar basis. The product isooctane is essentially the same as that produced in the conventional cold acid process.
摘要翻译： 一种烷烃与烯烃或烯烃前体烷基化的方法，例如叔烯烃的低聚物，包括使含有酸催化剂，异链烷烃和烯烃的液体体系同时向下流动，在温度和压力条件下在分散网中与反应区接触 使所述异链烷烃和所述烯烃反应生成烷基化物产物。 优选地，液体系统保持在反应区域的大约沸点。 出乎意料地，已经发现烯烃低聚物作为烯烃前体而不是反应中的烯烃。 因此，例如，使用异丁烯（主要是二聚体和三聚体）的低聚物与异丁烷的冷酸烷基化产生异辛烷，异丁烷与摩尔的低聚物的组分异丁烯单元反应。 产物异辛烷基本上与常规冷酸法中产生的相同。
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公开(公告)号：US09139503B2
公开(公告)日：2015-09-22
申请号：US11852923
申请日：2007-09-10
CPC分类号： C07C41/09 , Y02P20/127 , C07C43/043
摘要： A process for the production of dialkyl ether, the process including: feeding a stream comprising an alkyl alcohol to a distillation column reactor system; concurrently in the distillation column reactor system: i) contacting the alkyl alcohol with a catalytic distillation structure in a distillation reaction zone thereby catalytically reacting at least a portion of the alkyl alcohol to form a corresponding dialkyl ether and water; and ii) fractionating the resulting dialkyl ether from the water; operating the distillation column reactor system to obtain substantially complete conversion of the alkyl alcohol to form the corresponding dialkyl ether and water; recovering the dialkyl ether from the distillation column reactor as an overheads fraction; recovering the water from the distillation column reactor as a bottoms fraction.
摘要翻译： 一种制备二烷基醚的方法，该方法包括：将包含烷基醇的物流进料到蒸馏塔反应器系统; 在蒸馏塔反应器系统中同时进行：i）在蒸馏反应区中使烷基醇与催化蒸馏结构接触，从而使至少一部分烷基醇催化反应形成相应的二烷基醚和水; 和ii）从水中分馏得到的二烷基醚; 操作蒸馏塔反应器系统以获得烷基醇的基本上完全转化以形成相应的二烷基醚和水; 从塔顶反应器中回收二烷基醚作为塔顶馏分; 从蒸馏塔反应器中回收水作为塔底馏分。
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公开(公告)号：US08153854B2
公开(公告)日：2012-04-10
申请号：US12134652
申请日：2008-06-06
IPC分类号： C07C2/02
摘要： A process for producing an alkylate having a low Reid vapor pressure, the process including: contacting a C6+-containing hydrocarbon stream with a mixture of isopentane and isobutane in the presence of an acid catalyst in an alkylation reactor to form a dilute alkylate product, wherein the C6+-containing hydrocarbon stream includes at least one of oligomers of C3 to C5 olefins and a dilute alkylate produced by contacting an isoparaffin with at least one of C3 to C5 olefins and oligomers of C3 to C5 olefins; fractionating the dilute alkylate product to form an isobutane-rich fraction, a n-butane-rich fraction, a fraction containing isopentane, and an alkylate product having a Reid vapor pressure less than 0.35 bar (5 psi); recycling at least a portion of the fraction containing isopentane to the alkylation reactor.
摘要翻译： 一种制备具有低Reid蒸气压的烷基化物的方法，该方法包括：在烷基化反应器中，在酸催化剂存在下，将含C 6+的烃物流与异戊烷和异丁烷的混合物接触以形成稀烷基化物产物，其中 含有C 6 +的烃物流包括C 3 -C 5烯烃的低聚物和通过使异链烷烃与C 3至C 5烯烃中的至少一种和C 3至C 5烯烃的低聚物接触而产生的稀烷基化物中的至少一种; 分馏稀烷基化产物以形成富含异丁烷的馏分，富含正丁烷的级分，含有异戊烷的级分和具有Reid蒸汽压小于0.35巴（5psi）的烷基化物产物; 将至少一部分含有异戊烷的级分再循环至烷基化反应器。
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9.发明授权公开(公告)号：US07368617B2
公开(公告)日：2008-05-06
申请号：US10983433
申请日：2004-11-08
IPC分类号： C07C5/03
CPC分类号： C07C5/09 , C07C5/05 , C07C7/163 , C07C7/167 , C07C2523/44
摘要： Acetylenes and dienes in a stream containing hydrogen, methane, C2-C6 olefins and paraffins, C2-C6 acetylenes and dienes, benzene, toluene, xylenes, and other C6+ components are hydrogenated in a downflow boiling point reactor wherein the heat of reaction is absorbed by the liquid in the reactor which produces a vapor. Besides the feed to the reactor there is a recirculating stream which is fed at a rate sufficient to ensure that the catalyst particles within the reactor are wetted. A third stream, which is taken from a downstream distillation column, is fed to provide the make up mass corresponding to the mass evaporated in the reactor. The composition of the this third stream controls the steady state composition of the liquid flowing through the reactor.
摘要翻译： 含有氢，甲烷，C 2 -C 6烯烃和链烷烃，C 2 -C 6烯烃的物流中的乙炔和二烯， 乙炔和二烯，苯，甲苯，二甲苯和其它C 6+组分在下流沸点反应器中氢化，其中反应热被反应器中的液体吸收，产生 汽。 除了进料到反应器之外还有一个再循环流，其进料量足以确保反应器内的催化剂颗粒被润湿。 进料从下游蒸馏塔获得的第三料流，以提供与在反应器中蒸发的物质相应的补充质量。 该第三流的组成控制流过反应器的液体的稳态组成。
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10.发明授权H2SO4 alkylation by conversion of olefin feed to oligomers and sulfate esters 有权通过将烯烃进料转化为低聚物和硫酸酯来进行H 2 SO 4烷基化公开(公告)号：US07977525B2
公开(公告)日：2011-07-12
申请号：US12023390
申请日：2008-01-31
IPC分类号： C07C2/62
CPC分类号： C07C2/08 , C07C2/58 , C07C7/17 , C07C7/171 , C07C17/08 , C07C303/24 , C10G29/205 , C07C9/16 , C07C19/08 , C07C305/06
摘要： A process for treating an alkylation feedstock comprising olefins, n-alkanes, and iso-alkanes, the process including: contacting at least a portion of the alkylation feedstock with sulfuric acid in a reaction zone under conditions to form sulfate esters of the olefins; separating the n-alkanes and the iso-alkanes from the sulfuric acid and the sulfate esters; recovering the n-alkanes and the iso-alkanes in a first product stream; and recovering the sulfate esters in a second product stream; wherein the sulfuric acid has a strength titrating as below 75 weight percent H2SO4/water mixtures.
摘要翻译： 一种用于处理包含烯烃，正烷烃和异烷烃的烷基化原料的方法，该方法包括：在形成烯烃的硫酸酯的条件下，使反应区中至少一部分烷基化原料与硫酸接触; 从硫酸和硫酸酯分离正烷烃和异烷烃; 在第一产物流中回收正烷烃和异烷烃; 并在第二产物流中回收硫酸酯; 其中硫酸的浓度滴定低于75重量％的H 2 SO 4 /水混合物。
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