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1.发明授权公开(公告)号：US06730708B2
公开(公告)日：2004-05-04
申请号：US09898287
申请日：2001-07-03
申请人： Ajoy P. Raje , Joe D. Allison , Kevin L. Coy
发明人： Ajoy P. Raje , Joe D. Allison , Kevin L. Coy
IPC分类号： C07C2700
CPC分类号： C10G2/33 , B01J21/02 , B01J23/75 , B01J23/8896 , C10G2/332
摘要： A process is disclosed for the hydrogenation of carbon monoxide. The process involves contacting a feed stream comprising hydrogen and carbon monoxide with a catalyst system in a reaction zone maintained at conversion-promoting conditions effective to produce an effluent stream, preferably comprising hydrocarbons. In accordance with this invention the catalyst system used in the process includes at least one catalytic material for Fischer-Tropsch reactions (e.g., iron, cobalt, nickel and/or ruthenium), preferably comprising cobalt, and a support comprising aluminum borate. The catalyst system can be prepared by impregnating alumina with a boron-containing composition to form an aluminum borate support and applying a Fischer-Tropsch catalytically active material to the aluminum borate to form a supported catalyst system.
摘要翻译： 公开了一氧化碳氢化的方法。 该方法包括将包含氢气和一氧化碳的进料流与催化剂体系接触，反应区保持在转化促进条件下，有效地产生优选包含烃的流出物流。 根据本发明，用于该方法的催化剂体系包括至少一种用于费 - 托反应的催化材料（例如铁，钴，镍和/或钌），优选包含钴，和包含硼酸铝的载体。 可以通过用含硼组合物浸渍氧化铝以形成硼酸铝载体并将费 - 托催化活性材料施加到硼酸铝上以形成负载型催化剂体系来制备催化剂体系。
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2.发明授权公开(公告)号：US07056955B2
公开(公告)日：2006-06-06
申请号：US10743856
申请日：2003-12-22
申请人： Rafael L. Espinoza , Kandaswamy Jothimurugesan , Ajoy P. Raje , Kevin L. Coy , Nithya Srinivasan
发明人： Rafael L. Espinoza , Kandaswamy Jothimurugesan , Ajoy P. Raje , Kevin L. Coy , Nithya Srinivasan
IPC分类号： C07C27/00
CPC分类号： B01J21/066 , B01J21/06 , B01J23/78 , B01J23/83 , B01J23/864 , B01J35/0013 , B01J35/006 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J37/0009 , B01J37/0045 , B01J37/03 , B01J37/031 , C10G2/332
摘要： According to a preferred embodiment, the present invention features a bulk catalyst that includes precipitated cobalt metal. The precipitated cobalt catalyst further includes a textural promoter, a binder and optionally a Group I metal. The method of making the catalyst is optimized so as to enhance attrition resistance and improve activity. According to some embodiments, the present catalyst is made by a method that includes one or a combination of: calcination under optimized temperature conditions; exposure to an acidic solution; and addition of a binder to a suspension of a precipitate. According to some embodiments, a Fischer-Tropsch process includes contacting the present catalyst with a feed stream containing carbon monoxide and hydrogen so as to produce hydrocarbons.
摘要翻译： 根据优选实施方案，本发明的特征在于包含沉淀的钴金属的本体催化剂。 沉淀的钴催化剂还包括结构促进剂，粘合剂和任选的第I族金属。 优化催化剂的制造方法，提高耐磨性，提高活性。 根据一些实施方案，本发明的催化剂通过包括以下组合的方法制备：在优化的温度条件下煅烧; 暴露于酸性溶液中; 并将粘合剂加入到沉淀物的悬浮液中。 根据一些实施方案，费 - 托法包括使本催化剂与含有一氧化碳和氢气的进料流接触以产生烃。
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公开(公告)号：US06727289B2
公开(公告)日：2004-04-27
申请号：US10047231
申请日：2002-01-14
申请人： Olga Ionkina , Wenchun Chao , Munirpallam A. Subramanian , Leo E. Manzer , Kamel M. Makar , Ajoy P. Raje
发明人： Olga Ionkina , Wenchun Chao , Munirpallam A. Subramanian , Leo E. Manzer , Kamel M. Makar , Ajoy P. Raje
IPC分类号： C07C2700
摘要： A process is disclosed for producing hydrocarbons. The process involves contacting a feed stream comprising hydrogen and carbon monoxide with a catalyst in a reaction zone maintained at conversion-promoting conditions effective to produce an effluent stream comprising hydrocarbons. In accordance with this invention, the catalyst used in the process includes at least a Fischer-Tropsch metal and boron. The Fischer-Tropsch metal preferably includes cobalt and optionally ruthenium or platinum. The catalyst may also comprise a support material selected from the group including silica, titania, titania/alumina, zirconia, alumina, aluminum fluoride, and fluorided aluminas.
摘要翻译： 公开了一种用于生产烃的方法。 该方法包括将包含氢气和一氧化碳的进料流与催化剂接触，所述反应区域保持在有效产生包含烃的流出物流的转化促进条件下。 根据本发明，用于该方法的催化剂至少包括费 - 托金属和硼。 费 - 托金属优选包括钴和任选的钌或铂。 催化剂还可以包含选自包括二氧化硅，二氧化钛，二氧化钛/氧化铝，氧化锆，氧化铝，氟化铝和氟化氧化铝的载体材料。
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4.发明授权Slurry activation of Fischer-Tropsch catalyst with carbon monoxide co-feed 失效用一氧化碳共同进料的费 - 托催化剂的浆料活化公开(公告)号：US07001928B2
公开(公告)日：2006-02-21
申请号：US10667637
申请日：2003-09-22
申请人： Ajoy P. Raje
发明人： Ajoy P. Raje
IPC分类号： C07C27/00
摘要： Methods and apparatus for improving the efficiency and effectiveness of in situ reduction of a Fischer-Tropsch catalyst slurry. The preferred embodiments of the present invention are characterized by a system that utilizes a co-feed of carbon monoxide along with the reducing gas into a reduction vessel maintained at an elevated temperature. As the metal oxide reduces to the active Fischer-Tropsch metal, the carbon monoxide acts as a poison to hydrogenolysis and reduces the loss of liquid from the slurry and the production of methane. The carbon monoxide is generally in parts-per-million quantities and will achieve the desired results in quantities less than 5,000 ppm, preferably less than 2,000 ppm.
摘要翻译： 提高费 - 托催化剂浆料原位还原效率和有效性的方法和装置。 本发明的优选实施方案的特征在于利用一氧化碳与还原气体共同进料到保持在高温下的还原容器的系统。 当金属氧化物还原成活性费 - 托金属时，一氧化碳作为毒液进行氢解并减少液体从浆料中的损失和甲烷的产生。 一氧化碳通常以百万分之一的量计，并且将以小于5,000ppm，优选小于2,000ppm的量获得期望的结果。
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5.发明授权公开(公告)号：US06878655B2
公开(公告)日：2005-04-12
申请号：US10251139
申请日：2002-09-20
摘要： The present invention is generally related towards the regeneration of hydrocarbon synthesis catalysts. In particular, the present invention is directed towards the regeneration of deactivated Fischer-Tropsch type catalysts using a two step process wherein the catalyst is first prepared using a dry gas and then regenerated using a hydrogen rich gas. The regeneration process is carried out at temperatures and pressures that are generally different than the operating temperatures and pressures for a typical hydrocarbon synthesis reaction.
摘要翻译： 本发明通常涉及烃合成催化剂的再生。 特别地，本发明涉及使用两步法再生失活的费 - 托型催化剂，其中首先使用干燥气体制备催化剂，然后使用富氢气体再生。 再生过程在通常不同于典型烃合成反应的操作温度和压力的温度和压力下进行。
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公开(公告)号：US06949488B2
公开(公告)日：2005-09-27
申请号：US10251928
申请日：2002-09-20
CPC分类号： C10G2/32 , B01J8/228 , B01J23/94 , B01J23/96 , B01J38/02 , B01J38/10 , B01J38/58 , B01J2208/003 , B01J2219/00006 , B01J2219/00029 , B01J2219/00031 , B01J2219/00033 , C10G2/332
摘要： Methods and apparatus for providing the heat required to maintain the desired temperature for catalyst regeneration. The catalyst is heated by contacting a reactant gas mixture with the catalyst in order to initiate an exothermic reaction and, once the desired temperature is achieved, exposing the catalyst to a regenerating gas. The temperature may also be maintained by heating the reactant gas mixture prior to contacting the catalyst and/or adding a liquid, which may be heated, to the catalyst. For heating a Fischer-Tropsch catalyst for regeneration, the reactant gas preferably contains less than 12 mole percent carbon monoxide and more preferably contains between 1 and 4 mole percent carbon monoxide.
摘要翻译： 提供维持催化剂再生所需温度所需热量的方法和装置。 通过使反应气体混合物与催化剂接触来加热催化剂，以引发放热反应，并且一旦达到所需温度，将催化剂暴露于再生气体。 温度也可以通过在催化剂接触之前加热反应气体混合物和/或加入可被加热的液体到催化剂来维持。 为了加热费 - 托催化剂用于再生，反应气体优选含有少于12摩尔％的一氧化碳，更优选含有1至4摩尔％的一氧化碳。
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公开(公告)号：US06897246B2
公开(公告)日：2005-05-24
申请号：US10293525
申请日：2002-11-12
申请人： Rafael L. Espinoza , Ajoy P. Raje , Doug S. Jack
发明人： Rafael L. Espinoza , Ajoy P. Raje , Doug S. Jack
CPC分类号： C10G2/33
摘要： A process for reducing C2-C9 olefin formation by recycling them to a Fischer-Tropsch hydrocarbon synthesis process and promoting recycled olefins chain growth comprises contacting a gas feed comprising a mixture of H2 and CO with a catalyst in a reactor system at conditions effective to produce a hydrocarbon product stream including C2-C9 olefins, separating a C2-C9 olefins-rich stream from the hydrocarbon product stream to form a light olefin recycle stream and recycling the light olefin recycle stream to the reactor system at a point in the reactor system where the H2:CO ratio is low relative to the H2:CO ratio in the rest of the reactor system. Depending on whether the initial H2:CO ratio is greater or less than the usage ratio of the selected catalyst, the recycled olefins can be returned to the system up- or downstream of the reactor system.
摘要翻译： 通过将其回收到费 - 托烃合成方法并促进再循环的烯烃链生长来减少C 2 -C 9 - 烯烃形成的方法包括使含有混合物 的H 2 CO和CO与反应器系统中的催化剂在有效产生包含C 2 -C 9烯烃的烃产物流的条件下反应， 从烃产物流中分离富C 2 -C 9烯烃的流，以形成轻烯烃再循环流，并将轻烯烃再循环流循环至反应器系统 在反应器系统中其中H 2 CO 2比率相对于反应器系统的其余部分中的H 2 CO 2比率较低。 取决于初始H 2 O 2：CO比率是否大于或小于所选择的催化剂的使用比例，回收的烯烃可以在反应器系统的上游或下游返回到系统。
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公开(公告)号：US07067562B2
公开(公告)日：2006-06-27
申请号：US10324419
申请日：2002-12-20
IPC分类号： C07C27/00
CPC分类号： B01J23/8946 , B01J23/8953 , B01J23/8986 , B01J37/031
摘要： The present invention presents an iron-based Fischer-Tropsch catalyst having a low water-gas shift activity and high selectivity and productivity toward a hydrocarbon wax wherein said catalyst comprises iron; silver; sodium, lithium, potassium, rubidium and/or cesium; optionally, calcium, magnesium, boron, and/or aluminum; and a silica structural promoter. The present invention further presents a method of making a precipitated iron-based Fischer-Tropsch catalyst. The present invention still further presents a process for producing hydrocarbons using the iron-based, precipitated Fischer-Tropsch catalyst of the present invention.
摘要翻译： 本发明提供了一种铁基费 - 托催化剂，其具有低水煤气变换活性和对烃蜡的高选择性和生产率，其中所述催化剂包含铁; 银; 钠，锂，钾，铷和/或铯; 任选地，钙，镁，硼和/或铝; 和二氧化硅结构促进剂。 本发明还提供一种制备沉淀的铁基费 - 托催化剂的方法。 本发明还提出了使用本发明的铁基，沉淀的费 - 托催化剂来生产烃的方法。
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9.发明授权Method for improved Fischer-Tropsch catalyst stability and higher stable syngas conversion 失效改善费 - 托催化剂稳定性和更稳定合成气转化的方法公开(公告)号：US07045554B2
公开(公告)日：2006-05-16
申请号：US10654087
申请日：2003-09-03
申请人： Ajoy P. Raje , Rafael Espinoza
发明人： Ajoy P. Raje , Rafael Espinoza
IPC分类号： C07C27/00
CPC分类号： C10G2/332 , B01J23/75 , B01J23/76 , B01J35/006 , B01J35/023 , C10G2/333
摘要： The present invention is generally related towards methods for preparing and using a more stable synthesis catalysts. In particular, the present invention is directed towards treating synthesis catalysts with low levels of oxygen to deactivate the smaller more unstable metal crystallites present in the catalyst matrix. The process can be carried out either prior to and/or simultaneously with the synthesis reaction.
摘要翻译： 本发明通常涉及制备和使用更稳定的合成催化剂的方法。 特别地，本发明涉及处理具有低水平氧的合成催化剂，以使催化剂基质中存在的更不稳定的更小的金属微晶失活。 该方法可以在合成反应之前和/或同时进行。
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公开(公告)号：US06962947B2
公开(公告)日：2005-11-08
申请号：US11035093
申请日：2005-01-13
IPC分类号： B01J23/889 , B01J23/89 , B01J23/94 , B01J38/02 , B01J38/06 , B01J38/10 , C07C1/04 , C10G2/00 , C07C27/00 , B01J20/34
CPC分类号： C10G2/32 , B01J23/8896 , B01J23/8913 , B01J23/94 , B01J38/02 , B01J38/06 , B01J38/10 , C07C1/045 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/46 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C07C2523/89 , C07C2527/125 , Y02P20/584
摘要： A process is disclosed for regenerating a catalyst used in a process for synthesizing hydrocarbons. The synthesis process involves contacting a feed stream comprising hydrogen and carbon monoxide with a catalyst in a reaction zone maintained at conversion-promoting conditions effective to produce an effluent stream comprising hydrocarbons. The regeneration process involves contacting a deactivated Fischer-Tropsch catalyst with a regeneration gas under regeneration-promoting conditions that include a pressure lower than the mean Fischer-Tropsch reaction pressure, for a period of time sufficient to reactivate the Fischer-Tropsch catalyst.
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