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1.发明授权Hetero diels-alder adducts of pentacene as soluble precursors of pentacene 有权并五苯作为并五苯的可溶性前体的异狄氏al醛加成物公开(公告)号：US07381585B2
公开(公告)日：2008-06-03
申请号：US11526943
申请日：2006-09-26
IPC分类号： H01L51/40
CPC分类号： C07D495/08 , C07D487/08 , C07D513/08 , H01L51/0003 , H01L51/0055 , H01L51/0545
摘要： The present invention describes organic solvent-soluble Diels-Alder adducts of polycyclic aromatic compounds, such as, oligothiophene, perylene, benzo[ghi]perylene, coronene and polyacenes, with variety of dienophiles containing at least one heteroatom and in some cases two heteroatoms bonded to aromatic moiety, such as, thioxomalonates, azodicarboxylates, thialdehyde, acylnitroso and N-sulfinylamides. The Diels-Alder adducts are prepared by a simple, one step cycloaddition reaction of the polycyclic aromatic compounds, such as, pentacene, or other fused aromatic compounds, with heterodienophiles. The Diels-Alder adducts according to the present invention all form soluble adducts with pentacene and can be converted back to pentacene by retro-Diels-Alder reaction at moderate (60-250° C.) temperatures both in bulk, in solution or as thin-films.
摘要翻译： 本发明描述了多环芳族化合物如低聚噻吩，苝，苯并[g]二萘嵌苯，苯并芘和多烯烃的有机溶剂可溶性狄尔斯 - 阿尔德加合物，其中含有至少一个杂原子的多种亲烯体，在一些情况下，两个杂原子键合 芳族部分，例如硫代孕酮，偶氮二羧酸酯，脯氨酸，酰基亚硝基和N-亚磺酰胺。 Diels-Alder加合物通过多环芳族化合物如并五苯或其它稠合芳族化合物与异源二烯体的简单的一步环加成反应来制备。 根据本发明的狄尔斯 - 阿尔德加合物全部形成与并五苯的可溶性加合物，并且可以在中等（60-250℃）温度下以体积，溶液或薄的方式通过逆狄尔斯 - 阿尔德反应转化回并五苯 薄膜
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2.发明授权Thin film transistors using solution processed pentacene precursor as organic semiconductor 有权使用溶液加工并五苯前体作为有机半导体的薄膜晶体管公开(公告)号：US06963080B2
公开(公告)日：2005-11-08
申请号：US10300630
申请日：2002-11-20
IPC分类号： C07D487/08 , C07D495/08 , C07D498/08 , C07D513/08 , H01L21/316 , H01L51/00 , H01L51/05 , H01L51/30 , H01L51/40
CPC分类号： H01L51/0055 , B82Y30/00 , C07D487/08 , C07D495/08 , C07D513/08 , H01L21/31691 , H01L51/0003 , H01L51/0036 , H01L51/0512 , H01L51/0516 , H01L51/0525 , H01L51/0545
摘要： The present invention describes thin film transistors in which the active channel layer is a thin film of a polycyclic aromatic compound, such as, pentacene, prepared by solution processing a soluble precursor of the polycyclic aromatic compound on a substrate followed by heating to a moderate temperature to convert the precursor back to the polycyclic aromatic compound. The soluble precursors of the polycyclic aromatic compounds are organic solvent-soluble Diels-Alder adducts of polycyclic aromatic compounds, such as, oligothiophene, perylene, benzo[ghi]perylene, coronene and a polyacene with a variety of dienophiles that contain at least one heteroatom. The Diels-Alder adducts can be converted back to pentacene by retro-Diels-Alder reaction at moderate (60-250° C.) temperatures both in bulk, in solution or as thin-films.
摘要翻译： 本发明描述了薄膜晶体管，其中有源沟道层是多基芳族化合物如并五苯的薄膜，其通过在基底上溶解处理多环芳族化合物的可溶性前体，然后加热至中等温度 以将前体转化为多环芳族化合物。 多环芳族化合物的可溶性前体是多环芳族化合物的有机溶剂可溶性狄尔斯 - 阿尔德加合物，例如低聚噻吩，苝，苯并[g]苝，假丝烯和具有多种亲核体的多并苯，其含有至少一个杂原子 。 Diels-Alder加合物可以在中等温度（60-250℃）的温度下以体积，溶液或薄膜的形式，通过逆狄尔斯 - 阿尔德反应转化回并五苯。
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公开(公告)号：US07125989B2
公开(公告)日：2006-10-24
申请号：US10300645
申请日：2002-11-20
IPC分类号： C07D417/04 , C07D413/04 , C07D403/04
CPC分类号： C07D495/08 , C07D487/08 , C07D513/08 , H01L51/0003 , H01L51/0055 , H01L51/0545
摘要： The present invention describes organic solvent-soluble Diels-Alder adducts of polycyclic aromatic compounds, such as, oligothiophene, perylene, benzo[ghi]perylene, coronene and polyacenes, with variety of dienophiles containing at least one heteroatom and in some cases two heteroatoms bonded to aromatic moiety, such as, thioxomalonates, azodicarboxylates, thialdehyde, acylnitroso and N-sulfinylamides. The Diels-Alder adducts are prepared by a simple, one step cycloaddition reaction of the polycyclic aromatic compounds, such as, pentacene, or other fused aromatic compounds, with heterodienophiles. The Diels-Alder adducts according to the present invention all form soluble adducts with pentacene and can be converted back to pentacene by retro-Diels-Alder reaction at moderate (60–250° C.) temperatures both in bulk, in solution or as thin-films.
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