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1.
公开(公告)号:US09212270B2
公开(公告)日:2015-12-15
申请号:US13522031
申请日:2011-01-06
申请人: Andreas Füβl , Bangaru Sampath , Maximilian Hofmann , Ingo Bellin , Sameer Nalawade , Klaus Hahn , Andreas Künkel , Robert Loos
发明人: Andreas Füβl , Bangaru Sampath , Maximilian Hofmann , Ingo Bellin , Sameer Nalawade , Klaus Hahn , Andreas Künkel , Robert Loos
CPC分类号: C08J9/127 , C08J9/0061 , C08J9/16 , C08J9/18 , C08J2333/14 , C08J2367/02 , C08J2367/04 , C08J2463/00 , C08J2467/02 , C08L33/068 , C08L67/02 , C08L67/04 , C08L2666/02
摘要: The invention relates to a process for producing expandable pelletized material which comprises polylactic acid which comprises the following steps: a) melting and incorporation by mixing of the following components: i) from 50 to 99.9% by weight, based on the total weight of components i to iii), of polylactic acid, ii) from 0 to 49.9% by weight, based on the total weight of components i to iii), of one or more further polymers, iii) from 0.1 to 2% by weight, based on the total weight of components i to iii), of a diepoxide or polyepoxide, and iv) from 0 to 10% by weight of one or more additives, b) incorporation by mixing of v) from 3 to 7% by weight, based on the total weight of components i to iv), of an organic blowing agent into the polymer melt by means of a static or dynamic mixer at a temperature of at least 140° C., c) discharging through a die plate with holes, the diameter of which at the exit from the die is at most 1.5 mm, and d) pelletizing the melt comprising blowing agent directly downstream of the die plate, and under water, at a pressure in the range from 1 to 20 bar. The invention further relates to expandable pelletized material which comprises polylactic acid and which is obtainable by said process, and also to specific expandable pelletized material which comprises polylactic acid and which has a proportion of from 3 to 7% by weight of an organic blowing agent, preferably n-pentane and particularly preferably isopentane. The invention further relates to a preferred process for producing expandable pelletized material which comprises blowing agent and which comprises polylactic acid, and which has low bulk density.
摘要翻译: 本发明涉及一种生产可膨胀颗粒材料的方法,其包括聚乳酸,其包括以下步骤:a)通过混合以下组分熔融和掺入:i)基于组分的总重量为50至99.9重量% ii)0至49.9重量%,基于组分i至iii的总重量),一种或多种其它聚合物,iii)基于以下物质的0.1至2重量%,基于 组分i至iii),二环氧化物或聚环氧化物的总重量,和iv)0至10重量%的一种或多种添加剂,b)通过混合v)3至7重量%,基于 通过静态或动态混合器在至少140℃的温度下将有机发泡剂的总成分重量分配到聚合物熔体中,c)通过具有孔的模板排出,直径 其中在模具的出口处至多为1.5mm,以及d)将熔体造粒, 直接在模板的下游,并在水下,在1至20巴的压力范围内。 本发明还涉及包含聚乳酸并且可通过所述方法获得的可膨胀颗粒材料,还涉及包含聚乳酸并且具有3-7重量%的有机发泡剂的比例的特定的可膨胀颗粒状材料, 优选正戊烷,特别优选异戊烷。 本发明还涉及一种用于生产可膨胀颗粒材料的优选方法,其包括发泡剂,其包含聚乳酸,并且其堆积密度低。
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2.
公开(公告)号:US20130150468A1
公开(公告)日:2013-06-13
申请号:US13522031
申请日:2011-01-06
申请人: Andreas Füssi , Bangaru Sampath , Maximilian Hofmann , Ingo Bellin , Sameer Nalawade , Klaus Hahn , Andreas Künkel , Robert Loos
发明人: Andreas Füssi , Bangaru Sampath , Maximilian Hofmann , Ingo Bellin , Sameer Nalawade , Klaus Hahn , Andreas Künkel , Robert Loos
IPC分类号: C08J9/18
CPC分类号: C08J9/127 , C08J9/0061 , C08J9/16 , C08J9/18 , C08J2333/14 , C08J2367/02 , C08J2367/04 , C08J2463/00 , C08J2467/02 , C08L33/068 , C08L67/02 , C08L67/04 , C08L2666/02
摘要: The invention relates to a process for producing expandable pelletized material which comprises polylactic acid which comprises the following steps: a) melting and incorporation by mixing of the following components: i) from 50 to 99.9% by weight, based on the total weight of components i to iii), of polylactic acid, ii) from 0 to 49.9% by weight, based on the total weight of components i to iii), of one or more further polymers, iii) from 0.1 to 2% by weight, based on the total weight of components i to iii), of a diepoxide or polyepoxide, and iv) from 0 to 10% by weight of one or more additives, b) incorporation by mixing of v) from 3 to 7% by weight, based on the total weight of components i to iv), of an organic blowing agent into the polymer melt by means of a static or dynamic mixer at a temperature of at least 140° C., c) discharging through a die plate with holes, the diameter of which at the exit from the die is at most 1.5 mm, and d) pelletizing the melt comprising blowing agent directly downstream of the die plate, and under water, at a pressure in the range from 1 to 20 bar. The invention further relates to expandable pelletized material which comprises polylactic acid and which is obtainable by said process, and also to specific expandable pelletized material which comprises polylactic acid and which has a proportion of from 3 to 7% by weight of an organic blowing agent, preferably n-pentane and particularly preferably isopentane. The invention further relates to a preferred process for producing expandable pelletized material which comprises blowing agent and which comprises polylactic acid, and which has low bulk density.
摘要翻译: 本发明涉及一种生产可膨胀颗粒材料的方法,其包括聚乳酸,其包括以下步骤:a)通过混合以下组分熔融和掺入:i)基于组分的总重量为50至99.9重量% ii)0至49.9重量%,基于组分i至iii的总重量),一种或多种其它聚合物,iii)基于以下物质的0.1至2重量%,基于 组分i至iii),二环氧化物或聚环氧化物的总重量,和iv)0至10重量%的一种或多种添加剂,b)通过混合v)3至7重量%,基于 通过静态或动态混合器在至少140℃的温度下将有机发泡剂的总成分重量分配到聚合物熔体中,c)通过具有孔的模板排出,直径 其中在模具的出口处至多为1.5mm,以及d)将熔体造粒, 直接在模板的下游,并在水下,在1至20巴的压力范围内。 本发明还涉及包含聚乳酸并且可通过所述方法获得的可膨胀颗粒材料,还涉及包含聚乳酸并且具有3-7重量%的有机发泡剂的比例的特定的可膨胀颗粒状材料, 优选正戊烷,特别优选异戊烷。 本发明还涉及一种用于生产可膨胀颗粒材料的优选方法,其包括发泡剂,其包含聚乳酸,并且其堆积密度低。
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公开(公告)号:US20110196052A1
公开(公告)日:2011-08-11
申请号:US13022045
申请日:2011-02-07
申请人: Klaus Hahn , Olaf Kriha , Ingo Bellin , Patrick Spies , Sabine Fuchs , Peter Deglmann , Klemens Massonne , Hartmut Denecke , Christoph Fleckenstein , Geert Janssens , Maximilian Hofmann
发明人: Klaus Hahn , Olaf Kriha , Ingo Bellin , Patrick Spies , Sabine Fuchs , Peter Deglmann , Klemens Massonne , Hartmut Denecke , Christoph Fleckenstein , Geert Janssens , Maximilian Hofmann
IPC分类号: C08K5/5398 , C08L25/06 , C08J9/18 , C08J9/12
CPC分类号: C08J9/0038 , C08J9/16 , C08J2325/04 , C08K5/5398 , C08L25/06
摘要: Phosphine sulfide derivatives of the formula (I), S═PR1R2R3 (I) are suitable as flame retardants, in particular for polymers, where the definitions of the symbols in the formula (I) are as follows: R1 and R2 are identical or different, being C1-C12-alkyl, C3-C8-cycloalkyl, which may have no substitution or may have one or more C1-C4-alkyl groups as substituents, C2-C12-alkenyl, C2-C12-alkynyl, C6-C10-aryl, or C8-C10-aryl-C1-C4-alkyl; R3 is H, SH, SR4, OH, OR5 or a —(Y1)n—[P(═X1)R6—(Y2)n]m—P(═X2)R7R8 group; or two groups R1, R2, R3 form, together with the phosphorus atom bonded thereto, a ring system; X1 and X2 are identical or different, being O or S; Y1 and Y2 are identical or different, being O or S; R4, R5, R6, R7 and R8 are identical or different, being independently from one another C1-C12-alkyl, C3-C8-cycloalkyl, which may have no substitution or may have one or more C1-C4-alkyl groups as substituents, C2-C12-alkenyl, C2-C12-alkynyl, C6-C10-aryl, or C6-C10-aryl-C1-C4-alkyl; n is 1 if Y1 and, respectively, Y2 is O, and is 1, 2, 3, 4, 5, 6, 7, or 8 if Y1 and, respectively, Y2 is S, and m is an integer from 0 to 100.
摘要翻译: 式(I)的硫化膦衍生物,S = PR1R2R3(I)适用作阻燃剂,特别是用于聚合物的阻燃剂,其中式(I)中符号的定义如下:R1和R2相同或不同 可以不具有取代基或可以具有一个或多个C 1 -C 4烷基作为取代基的C 1 -C 12 - 烷基,C 3 -C 8 - 环烷基,C 2 -C 12 - 烯基,C 2 -C 12炔基,C 6 -C 10 - 芳基或C 8 -C 10 - 芳基-C 1 -C 4 - 烷基; R3是H,SH,SR4,OH,OR5或 - (Y1)n- [P(= X1)R6-(Y2)n] m-P(= X2)R7R8组; 或两个基团R 1,R 2,R 3与键合的磷原子一起形成环系; X1和X2相同或不同,为O或S; Y1和Y2相同或不同,为O或S; R 4,R 5,R 6,R 7和R 8相同或不同,彼此独立地为可以不具有取代基或可以具有一个或多个C 1 -C 4 - 烷基作为取代基的C 1 -C 12 - 烷基,C 3 -C 8 - 环烷基 ,C 2 -C 12 - 烯基,C 2 -C 12 - 炔基,C 6 -C 10 - 芳基或C 6 -C 10 - 芳基-C 1 -C 4 - 烷基; 如果Y1和Y1分别为0,则n为1,如果Y1分别为Y2,并且分别为1,2,3,4,5,6,7或8,并且m分别为0至100的整数。 。
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公开(公告)号:US08691896B2
公开(公告)日:2014-04-08
申请号:US13021843
申请日:2011-02-07
申请人: Klaus Hahn , Olaf Kriha , Ingo Bellin , Patrick Spies , Sabine Fuchs , Peter Deglmann , Klemens Massonne , Hartmut Denecke , Christoph Fleckenstein , Geert Janssens , Maximilian Hofmann , Manfred Döring , Ciesielski Michael , Jochen Wagner
发明人: Klaus Hahn , Olaf Kriha , Ingo Bellin , Patrick Spies , Sabine Fuchs , Peter Deglmann , Klemens Massonne , Hartmut Denecke , Christoph Fleckenstein , Geert Janssens , Maximilian Hofmann , Manfred Döring , Ciesielski Michael , Jochen Wagner
IPC分类号: C08J9/35 , C08J9/06 , C08K5/5397 , C08L25/06
CPC分类号: C08K5/5398 , C08J9/0033 , C08J9/0038 , C08J2201/028 , C08J2201/03 , C08J2325/06 , C08K3/06 , C08L25/06
摘要: Disclosed is a polymer foam with density in the range from 5 to 120 kg/m3 composed of a polymer component including at least one styrene polymer and from 0.1 to 5 parts by weight of a flame retardant mixture including at least one phosphorus compound of the formula PR1R2R3. A process for producing the polymer is also disclosed.
摘要翻译: 公开了一种密度为5至120kg / m 3的聚合物泡沫体,其由包含至少一种苯乙烯聚合物的聚合物组分和0.1至5重量份的阻燃混合物组成,所述阻燃剂混合物包含至少一种式 PR1R2R3。 还公开了聚合物的制造方法。
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公开(公告)号:US20120172467A1
公开(公告)日:2012-07-05
申请号:US13336677
申请日:2011-12-23
申请人: Ingo Bellin , Patrick Spies , Sabine Fuchs , Christoph Fleckenstein , Peter Deglmann , Maximilian Hofmann , Rainer Ostermann , Klaus Hahn , Hartmut Denecke , Klemens Massonne , Geert Janssens , Manfred Döring , Ciesielski Michael , Jochen Wagner
发明人: Ingo Bellin , Patrick Spies , Sabine Fuchs , Christoph Fleckenstein , Peter Deglmann , Maximilian Hofmann , Rainer Ostermann , Klaus Hahn , Hartmut Denecke , Klemens Massonne , Geert Janssens , Manfred Döring , Ciesielski Michael , Jochen Wagner
IPC分类号: C08K5/5398 , C08L81/04 , C08L85/02 , C08J9/06 , C08L25/06 , C08J9/20 , C08J9/228 , C08K5/521 , C08J9/04
CPC分类号: C08J9/0033 , C08J9/0038 , C08J9/0061 , C08J9/16 , C08J9/20 , C08J2201/03 , C08J2325/06 , C08J2481/02 , C08K5/372 , C08K5/521 , C08K5/5398 , C08L81/04
摘要: The invention relates to a flame retardant comprising a) at least one sulfur compound of the formula (I) b) at least one halogen-free organophosphorus compound with phosphorus content in the range from 0.5 to 40% by weight, based on the phosphorus compound.
摘要翻译: 本发明涉及一种阻燃剂,其包含a)至少一种式(I)的硫化合物,b)至少一种不含磷的有机磷化合物,其磷含量在0.5至40重量%的范围内,基于磷化合物 。
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公开(公告)号:US20110196053A1
公开(公告)日:2011-08-11
申请号:US13021843
申请日:2011-02-07
申请人: Klaus Hahn , Olaf Kriha , Ingo Bellin , Patrick Spies , Sabine Fuchs , Peter Deglmann , Klemens Massonne , Hartmut Denecke , Christoph Fleckenstein , Geert Janssens , Maximilian Hofmann , Manfred Döring , Ciesielski Michael , Jochen Wagner
发明人: Klaus Hahn , Olaf Kriha , Ingo Bellin , Patrick Spies , Sabine Fuchs , Peter Deglmann , Klemens Massonne , Hartmut Denecke , Christoph Fleckenstein , Geert Janssens , Maximilian Hofmann , Manfred Döring , Ciesielski Michael , Jochen Wagner
IPC分类号: C08J9/35 , C08L25/06 , C08K5/5398 , C08K5/5397 , C08J9/06
CPC分类号: C08K5/5398 , C08J9/0033 , C08J9/0038 , C08J2201/028 , C08J2201/03 , C08J2325/06 , C08K3/06 , C08L25/06
摘要: A polymer foam with density in the range from 5 to 120 kg/m3, comprising a) a polymer component, comprising at least one styrene polymer, b) from 0.1 to 5 parts by weight (based on 100 parts by weight of component a)) of a flame retardant mixture, comprising b1) at least one phosphorus compound of the formula (I) having phosphorus content in the range from 5 to 80% by weight, based on the phosphorus compound, (X1)s═PR1R2R3 (I) where the definitions of the symbols and indices in the formula (I) are as follows: R1 is C1-C16-alkyl, C1-C10-hydroxyalkyl, C1-C16-alkenyl, C1-C16-alkoxy, C1-C16-alkenoxy, C3-C10-cycloalkyl, C3-C10-cycloalkoxy, C6-C10-aryl, C6-C10-aryloxy, C6-C10-aryl-C1-C16-alkyl, C6-C10-aryl-C1-C16-alkoxy, SR9, COR10, COOR11, CONR12R13; R2 is C1-C16-alkyl, C1-C10-hydroxyalkyl, C1-C16-alkenyl, C1-C16-alkoxy, C1-C16-alkenoxy, C3-C10-cycloalkyl, C3-C10-cycloalkoxy, C6-C10-aryl, C6-C10-aryl-C1-C16-alkyl, C6-C10-aryl-C1-C16-alkoxy, SR9, COR10, COOR11, CONR12R13; R3 is H, SH, SR4, OH, OR5, or a —(Y1)n—[P(═X2)uR6—(Y2)n]m—P(═X3)tR7R8 group; or two groups R1, R2, R3 form, together with the phosphorus atom bonded thereto, a ring system; X1, X2 and X3 are identical or different and, independently of one another, O or S; Y1 and Y2 are identical or different, being O or S; R4, R5, R9, R10, R11, R12, and R13 are identical or different, being C1-C12-alkyl, C3-C8-cycloalkyl, which may either have no substitution or may have one or more C1-C4-alkyl groups as substituents, or being C2-C12-alkenyl, C2-C12-alkynyl, C6-C10-aryl, or C6-C10-aryl-C1-C4-alkyl; R6, R7, and R8 are identical or different and, independently of one another, C1-C16-alkyl, C1-C16-alkenyl, C1-C16-alkoxy, C1-C16-alkenoxy, C3-C10-cycloalkyl, C3-C10-cycloalkoxy, C6-C10-aryl, C6-C10-aryloxy, C6-C10-aryl-C1-C16-alkyl, C6-C10-aryl-C1-C16-alkoxy, SR9, COR10, COOR11, CONR12R13; n is 1 if Y1 and, respectively, Y2 is O, and is 1, 2, 3, 4, 5, 6, 7, or 8 if Y1 and, respectively, Y2 is S; m is an integer from 0 to 100; s, t, and u are, independently of one another, 0 or 1; and b2) elemental sulfur.
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公开(公告)号:US09234137B2
公开(公告)日:2016-01-12
申请号:US13516464
申请日:2010-12-15
申请人: Christoph Fleckenstein , Hartmut Denecke , Ingo Bellin , Olaf Kriha , Patrick Spies , Sabine Fuchs , Klemens Massonne , Klaus Hahn , Peter Deglmann , Maximilian Hofmann , Alois Kindler
发明人: Christoph Fleckenstein , Hartmut Denecke , Ingo Bellin , Olaf Kriha , Patrick Spies , Sabine Fuchs , Klemens Massonne , Klaus Hahn , Peter Deglmann , Maximilian Hofmann , Alois Kindler
IPC分类号: C08J9/16 , C08K5/1535 , C09K21/12 , C08J9/00 , C08J9/14 , C08J9/20 , C08K5/49 , C08K5/53 , C08K5/523 , C08K5/5313 , C08K5/5377 , C08K5/5398
CPC分类号: C09K21/12 , C08J9/0038 , C08J9/14 , C08J9/20 , C08J2325/04 , C08K5/49 , C08K5/523 , C08K5/53 , C08K5/5313 , C08K5/5377 , C08K5/5398 , C08L2201/02 , C08L2203/14 , C08L25/00 , C08L25/06
摘要: Use of a phosphorus compound of the formula (I) as flame retardant, where the definitions of the symbols in the formula (I) are as follows: A is one of the following groups: Y is —P(═X2)SR3R4, H, a straight-chain or branched C1-C12-alkyl group, C5-C6-cycloalkyl, C6-C12-aryl, or benzyl, where the four last-mentioned groups are unsubstituted or have substitution by one or more radicals from the group of C1-C4-alkyl or C1-C4-alkenyl; R1, R2, R3, and R4 are identical or different and are hydrogen, OH, C1-C16-alkyl, C1-C16-alkenyl, C1-C16-alkoxy, C1-C16-alkenoxy, C3-C10-cycloalkyl, C3-C10-cycloalkoxy, C6-C10-aryl, C6-C10-aryloxy, C6-C10-aryl-C1-C16-alkyl, C6-C10-aryl-C1-C16-alkoxy, SR9 COR10, COOR11, CONR12R13 or two radicals R1, R2, R3, or R4 form, together with the phosphorus atom to which they are bonded, or the P—O-A-O—P group, a ring system; R5, R6, R7, and R8 are identical or different and are H, C1-C16-alkyl, C1-C16-alkenyl, C1-C16-alkoxy, C1-C16-alkenoxy; R9, R10, R11, R12, R13 are identical or different and are H, C1-C16-alkyl, C1-C16-alkenyl, C6-C10-aryl, C6-C10-aryl-C1-C16-alkyl, C6-C10-aryl-C1-C16-alkoxy; X1 and X2 are identical or different and are S or O; r and s are identical or different and are 0 or 1; X3, X4, X5, and X6 are identical or different and are S or O, and n is a natural number from 1 to 50.
摘要翻译: 式(I)的磷化合物作为阻燃剂的用途,其中式(I)中的符号的定义如下:A是以下基团之一:Y是-P(= X 2)SR 3 R 4,H 直链或支链C 1 -C 12 - 烷基,C 5 -C 6 - 环烷基,C 6 -C 12 - 芳基或苄基,其中四个最后提到的基团是未取代的或具有一个或多个自由基 C 1 -C 4 - 烷基或C 1 -C 4 - 烯基; R1,R2,R3和R4相同或不同,为氢,OH,C1-C16 - 烷基,C1-C16 - 烯基,C1-C16 - 烷氧基,C1-C16 - 烯氧基,C3-C10-环烷基,C3- C 1 -C 10 - 芳基,C 6 -C 10 - 芳氧基,C 6 -C 10 - 芳基-C 1 -C 16 - 烷基,C 6 -C 10 - 芳基-C 1 -C 16 - 烷氧基,SR 9 COR 10,COOR 11,CONR 12 R 13或两个基团R 1 R 2,R 3或R 4与它们所键合的磷原子一起形成,或与P-OAO-P基团形成环系; R 5,R 6,R 7和R 8相同或不同,为H,C 1 -C 16 - 烷基,C 1 -C 16 - 烯基,C 1 -C 16 - 烷氧基,C 1 -C 16 - 烯氧基; R9,R10,R11,R12,R13相同或不同,为H,C1-C16 - 烷基,C1-C16 - 烯基,C6-C10-芳基,C6-C10-芳基-C1-C16 - 烷基,C6-C10 芳基-C 1 -C 16 - 烷氧基; X1和X2相同或不同,为S或O; r和s相同或不同,为0或1; X3,X4,X5和X6相同或不同,为S或O,n为1〜50的自然数。
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公开(公告)号:US09115312B2
公开(公告)日:2015-08-25
申请号:US13075518
申请日:2011-03-30
申请人: Klaus Hahn , Sabine Fuchs , Ingo Bellin , Patrick Spies , Maximilian Hofmann , Peter Deglmann , Klemens Massonne , Hartmut Denecke , Christoph Fleckenstein , Geert Janssens , Manfred Döring , Michael Ciesielski , Jochen Wagner
发明人: Klaus Hahn , Sabine Fuchs , Ingo Bellin , Patrick Spies , Maximilian Hofmann , Peter Deglmann , Klemens Massonne , Hartmut Denecke , Christoph Fleckenstein , Geert Janssens , Manfred Döring , Michael Ciesielski , Jochen Wagner
CPC分类号: C09K21/12 , C08J9/0033 , C08J2325/06 , C08K5/36 , C08K5/49
摘要: A flame retardant comprising a) at least one sulfur compound of the formula (I) A1-(Z1)m—(S)n—(Z2)p-A2 (I) where the definitions of the symbols and indices are as follows: A1 and A2 are identical or different, being C6-C12-aryl, cyclohexyl, Si(ORa)3, a saturated, partially unsaturated, or aromatic, mono- or bicyclic ring having from 3 to 12 ring members and comprising one or more heteroatoms from the group of N, O, and S, where the system is unsubstituted or has substitution by one or more substituents of the group of O, OH, S, SH, COORb, CONRcRd, C1-C18-alkyl, C1-C18-alkoxy, C1-C18-thioalkyl, C6-C12-aryl, C6-C12-aryloxy, C2-C18-alkenyl, C2-C18-alkenoxy, C2-C18-alkynyl, and C2-C18-alkinoxy; Z1 and Z2 are identical or different, being —CO— or —CS—; Ra is C1-C18-alkyl; Rb, Rc, and Rd are identical or different, being H, C1-C18-alkyl, C6-C12-aryl, or an aromatic, mono- or bicyclic ring having from 3 to 12 ring members and comprising one or more heteroatoms from the group of N, O, and S; m and p are identical or different, being 0 or 1, and n is a natural number from 2 to 10, and b) at least one halogen-free organophosphorus compound having phosphorus content in the range from 5 to 80% by weight, based on the phosphorus compound, is particularly suitable for protecting foams based on styrene polymers.
摘要翻译: 一种阻燃剂,其包含a)至少一种式(I)A1-(Z1)m-(S)n-(Z2)p-A2(I)的硫化合物,其中符号和指数的定义如下: A1和A2相同或不同,为具有3至12个环成员且包含一个或多个杂原子的饱和,部分不饱和或芳族单环或双环的C 6 -C 12 - 芳基,环己基,Si(OR a)3 由N,O和S的基团组成,其中体系未被取代或被一个或多个O,OH,S,SH,COORb,CONRcRd,C 1 -C 18烷基,C 1 -C 18 - 烷氧基,C 1 -C 18 - 硫代烷基,C 6 -C 12 - 芳基,C 6 -C 12 - 芳氧基,C 2 -C 18烯基,C 2 -C 18 - 烯氧基,C 2 -C 18炔基和C 2 -C 18 - 烷氧基; Z 1和Z 2相同或不同,为-CO-或-CS-; R a是C 1 -C 18 - 烷基; R b,R c和R d相同或不同,为H,C 1 -C 18 - 烷基,C 6 -C 12 - 芳基或具有3至12个环成员并且包含一个或多个来自 N,O,S组; m和p相同或不同,为0或1,n为2至10的自然数,b)至少一种磷含量为5-80重量%的无卤素有机磷化合物,基于 在磷化合物上,特别适用于保护基于苯乙烯聚合物的泡沫体。
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公开(公告)号:US20130030066A1
公开(公告)日:2013-01-31
申请号:US13559786
申请日:2012-07-27
申请人: Klaus Hahn , Sabine Fuchs , Ingo Bellin , Patrick Spies , Maximilian Hofmann , Peter Deglmann , Klemens Massonne , Hartmut Denecke , Christoph Fleckenstein , Geert Janssens , Anna Müller-Cristadoro , Bernd Bruchmann
发明人: Klaus Hahn , Sabine Fuchs , Ingo Bellin , Patrick Spies , Maximilian Hofmann , Peter Deglmann , Klemens Massonne , Hartmut Denecke , Christoph Fleckenstein , Geert Janssens , Anna Müller-Cristadoro , Bernd Bruchmann
CPC分类号: C07F9/34 , B29C48/0012 , B29C48/022 , B29C48/92 , B29C2948/92209 , B29C2948/92704 , B29K2105/04 , C07F9/12 , C07F9/304 , C07F9/46 , C08J9/0095 , C08J9/20 , C08J2325/04 , C08J2400/10 , C08J2469/00 , C08J2471/00 , C08K5/375 , C08K5/378 , C08K5/47 , C08K5/521 , C08K5/5398 , C08L69/00 , C08L101/02 , C08L2205/02 , C09J125/06 , C08L25/06
摘要: The invention relates to a polymer composition containing i) styrene polymer(s) and ii) phosphorylated polyether(s) with from 0.5 to 40% by weight phosphorus content, the main chain of which is formed exclusively from carbon atoms and from oxygen atoms, and which has at least three terminal and/or pendant OH groups, where these have been substituted with where ˜ indicates the bond to the polymer skeleton of the polyether; Y is O or S; t is 0 or 1; R1 and R2, being identical or different, are H, C1-C18-alkyl, C2-C18-alkenyl, C2-C18-alkynyl, C3-C10-cycloalkyl, C6-C10-aryl, furyl, C6-C10-aryl-C1-C10-alkyl, OR3, SR3, NR3R4, COR3, COOR3 or CONR3R4, or R1 and R2 form, together with the phosphorus atom P, a 4-8-membered ring system; R3 and R4, being identical or different, are H, C1-C16-alkyl, C2-C16-alkenyl, C3C16-alkynyl, C3-C10-cycloalkyl, C6-C10-aryl or C6-C10-aryl-C1-C10-alkyl, and/or polycarbonates containing phosphorus-containing group(s) of the general formula (I).
摘要翻译: 本发明涉及含有i)苯乙烯聚合物和ii)磷酸化聚醚的聚合物组合物,其具有0.5至40重量%的磷含量,其主链仅由碳原子和氧原子形成, 并且其具有至少三个末端和/或侧基OH基团,其中这些已被其中〜表示与聚醚的聚合物骨架的键的取代; Y为O或S; t为0或1; R 1和R 2相同或不同,为H,C 1 -C 18烷基,C 2 -C 18烯基,C 2 -C 18炔基,C 3 -C 10 - 环烷基,C 6 -C 10 - 芳基,呋喃基,C 6 -C 10 - 芳基 - C 1 -C 10烷基,OR 3,SR 3,NR 3 R 4,COR 3,COOR 3或CONR 3 R 4,或R 1和R 2与磷原子P一起形成4-8元环系; R 3和R 4相同或不同,为H,C 1 -C 16 - 烷基,C 2 -C 16 - 烯基,C 3 C 16 - 炔基,C 3 -C 10 - 环烷基,C 6 -C 10 - 芳基或C 6 -C 10 - 芳基-C 1 -C 10 - 烷基和/或含有通式(I)的含磷基团的聚碳酸酯。
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公开(公告)号:US20120252911A1
公开(公告)日:2012-10-04
申请号:US13516464
申请日:2010-12-15
申请人: Christoph Fleckenstein , Hartmut Denecke , Ingo Bellin , Olaf Kriha , Patrick Spies , Sabine Fuchs , Klemens Massonne , Klaus Hahn , Peter Deglmann , Maximilian Hofmann , Alois Kindler
发明人: Christoph Fleckenstein , Hartmut Denecke , Ingo Bellin , Olaf Kriha , Patrick Spies , Sabine Fuchs , Klemens Massonne , Klaus Hahn , Peter Deglmann , Maximilian Hofmann , Alois Kindler
IPC分类号: C07F9/655 , C07F9/6561 , C08K5/1535 , B29B9/06 , C08J9/16
CPC分类号: C09K21/12 , C08J9/0038 , C08J9/14 , C08J9/20 , C08J2325/04 , C08K5/49 , C08K5/523 , C08K5/53 , C08K5/5313 , C08K5/5377 , C08K5/5398 , C08L2201/02 , C08L2203/14 , C08L25/00 , C08L25/06
摘要: Use of a phosphorus compound of the formula (I) as flame retardant, where the definitions of the symbols in the formula (I) are as follows: A is one of the following groups: Y is —P(═X2)SR3R4, H, a straight-chain or branched C1-C12-alkyl group, C5-C6-cycloalkyl, C6-C12-aryl, or benzyl, where the four last-mentioned groups are unsubstituted or have substitution by one or more radicals from the group of C1-C4-alkyl or C1-C4-alkenyl; R1, R2, R3, and R4 are identical or different and are hydrogen, OH, C1-C16-alkyl, C1-C16-alkenyl, C1-C16-alkoxy, C1-C16-alkenoxy, C3-C10-cycloalkyl, C3-C10-cycloalkoxy, C6-C10-aryl, C6-C10-aryloxy, C6-C10-aryl-C1-C16-alkyl, C6-C10-aryl-C1-C16-alkoxy, SR9 COR10, COOR11, CONR12R13 or two radicals R1, R2, R3, or R4 form, together with the phosphorus atom to which they are bonded, or the P—O-A-O—P group, a ring system; R5, R6, R7, and R8 are identical or different and are H, C1-C16-alkyl, C1-C16-alkenyl, C1-C16-alkoxy, C1-C16-alkenoxy; R9, R10, R11, R12, R13 are identical or different and are H, C1-C16-alkyl, C1-C16-alkenyl, C6-C10-aryl, C6-C10-aryl-C1-C16-alkyl, C6-C10-aryl-C1-C16-alkoxy; X1 and X2 are identical or different and are S or O; r and s are identical or different and are 0 or 1; X3, X4, X5, and X6 are identical or different and are S or O, and n is a natural number from 1 to 50.
摘要翻译: 式(I)的磷化合物作为阻燃剂的用途,其中式(I)中的符号的定义如下:A是以下基团之一:Y是-P(= X 2)SR 3 R 4,H 直链或支链C 1 -C 12 - 烷基,C 5 -C 6 - 环烷基,C 6 -C 12 - 芳基或苄基,其中四个最后提到的基团是未取代的或具有一个或多个自由基 C 1 -C 4 - 烷基或C 1 -C 4 - 烯基; R1,R2,R3和R4相同或不同,为氢,OH,C1-C16 - 烷基,C1-C16 - 烯基,C1-C16 - 烷氧基,C1-C16 - 烯氧基,C3-C10-环烷基,C3- C 1 -C 10 - 芳基,C 6 -C 10 - 芳氧基,C 6 -C 10 - 芳基-C 1 -C 16 - 烷基,C 6 -C 10 - 芳基-C 1 -C 16 - 烷氧基,SR 9 COR 10,COOR 11,CONR 12 R 13或两个基团R 1 R 2,R 3或R 4与它们所键合的磷原子一起形成,或与P-OAO-P基团形成环系; R 5,R 6,R 7和R 8相同或不同,为H,C 1 -C 16 - 烷基,C 1 -C 16 - 烯基,C 1 -C 16 - 烷氧基,C 1 -C 16 - 烯氧基; R9,R10,R11,R12,R13相同或不同,为H,C1-C16 - 烷基,C1-C16 - 烯基,C6-C10-芳基,C6-C10-芳基-C1-C16 - 烷基,C6-C10 芳基-C 1 -C 16 - 烷氧基; X1和X2相同或不同,为S或O; r和s相同或不同,为0或1; X3,X4,X5和X6相同或不同,为S或O,n为1〜50的自然数。
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