公开(公告)号：USRE46374E1

公开(公告)日：2017-04-25

申请号：US15051391

申请日：2016-02-23

Applicant: BASF SE

Inventor： Thomas Schaub ,  Boris Buschhaus ,  Marion Kristina Da Silva ,  Mathias Schelwies ,  Rocco Paciello ,  Johann-Peter Melder ,  Martin Merger

IPC: C07C213/02 ,  C07D307/52 ,  C07C209/16 ,  C07C211/10 ,  C07C217/08 ,  C07C215/08 ,  C07C211/09 ,  C07C211/18 ,  C07C215/20 ,  C07C211/12 ,  C07D223/04 ,  C07D205/04 ,  C07D207/02 ,  C07D207/20 ,  C07D211/06 ,  C07D295/027

CPC classification number: C07C213/02 ,  C07C209/16 ,  C07C2601/14 ,  C07D205/04 ,  C07D207/02 ,  C07D207/20 ,  C07D211/06 ,  C07D223/04 ,  C07D295/027 ,  C07D307/52 ,  C07C217/08 ,  C07C215/08 ,  C07C211/09 ,  C07C211/10 ,  C07C211/18 ,  C07C215/20 ,  C07C211/12

Abstract: Process for preparing primary amines which have at least one functional group of the formula (—CH2—NH2) and at least one further primary amino group by alcohol amination of starting materials having at least one functional group of the formula (—CH2—OH) and at least one further functional group (—X), where (—X) is selected from among hydroxyl groups and primary amino groups, by means of ammonia with elimination of water, wherein the reaction is carried out homogeneously catalyzed in the presence of at least one complex catalyst comprising at least one element selected from groups 8, 9 and 10 of the Periodic Table and also at least one donor ligand.

公开(公告)号：US08853400B2

公开(公告)日：2014-10-07

申请号：US13948736

申请日：2013-07-23

Applicant: BASF SE

Inventor： Mathias Schelwies ,  Marion Brinks ,  Thomas Schaub ,  Johann-Peter Melder ,  Rocco Paciello ,  Martin Merger

IPC: C07F15/00 ,  C07C209/16

CPC classification number: C07D493/04 ,  C07F15/0046

Abstract: The invention relates to a process for preparing primary amines by alcohol amination of alcohols with ammonia with the elimination of water, where the alcohol amination is carried out under homogeneous catalysis in the presence of at least one complex catalyst which comprises ruthenium and at least one at least bidental donor ligand, but no anionic ligands.

Abstract translation: 本发明涉及通过醇与氨的醇胺化与消除水来制备伯胺的方法，其中醇胺化在均相催化下在至少一种包含钌和至少一种 最小二配体配体，但没有阴离子配体。

公开(公告)号：US20140024833A1

公开(公告)日：2014-01-23

申请号：US13948736

申请日：2013-07-23

Applicant: BASF SE

Inventor： Mathias SCHELWIES ,  Marion Brinks ,  Thomas Schaub ,  Johann-Peter Melder ,  Rocco Paciello ,  Martin Merger

IPC: C07D493/04 ,  C07F15/00

CPC classification number: C07D493/04 ,  C07F15/0046

Abstract: The invention relates to a process for preparing primary amines by alcohol amination of alcohols with ammonia with the elimination of water, where the alcohol amination is carried out under homogeneous catalysis in the presence of at least one complex catalyst which comprises ruthenium and at least one at least bidental donor ligand, but no anionic ligands.

Abstract translation: 本发明涉及通过醇与氨的醇胺化与消除水来制备伯胺的方法，其中醇胺化在均相催化下在至少一种包含钌和至少一种 最小二配体配体，但没有阴离子配体。