Preparation of emulsifier-free aqueous polymer emulsions
    2.
    发明授权
    Preparation of emulsifier-free aqueous polymer emulsions 失效
    制备无乳化剂的聚合物乳液

    公开(公告)号:US5889101A

    公开(公告)日:1999-03-30

    申请号:US597134

    申请日:1996-02-06

    CPC分类号: C08F222/02 C08F220/06

    摘要: An aqueous polymer emulsion obtainable by free radical polymerization of monomers in aqueous emulsion in the presence of a polymeric protective colloid contains, as components,from 5 to 50% by weight of at least one ethylenically unsaturated monomer having at least one acid or acid anhydride group (monomers I),from 0.1 to 80% by weight of at least one (meth)acrylate of an aliphatic alcohol of at least 10 carbon atoms (monomers II),from 0 to 94.9% by weight of main monomers selected from the group consisting of C.sub.1 -C.sub.8 -alkyl (meth)acrylates, vinyl esters of carboxylic acids of up to 20 carbon atoms, vinyl aromatics of up to 20 carbon atoms, ethylenically unsaturated nitriles, vinyl halides and aliphatic hydrocarbons having 2 to 8 carbon atoms and 1 or 2 double bonds (monomers III) andfrom 0 to 60% by weight of further monomers (monomers IV),the stated weights being based on the polymeric protective colloid.

    摘要翻译: 通过在聚合物保护胶体存在下在水乳状液中单体的自由基聚合可获得的聚合物水乳液含有5至50重量%的至少一种具有至少一个酸或酸酐基团的烯属不饱和单体 (单体I),0.1至80重量%的至少一种至少10个碳原子的脂族醇(单体II)的(甲基)丙烯酸酯,0至94.9重量%的主要单体,所述主要单体选自 的(甲基)丙烯酸C 1 -C 8烷基酯,至多20个碳原子的羧酸的乙烯基酯,至多20个碳原子的乙烯基芳族化合物,烯键式不饱和腈,乙烯基卤化物和具有2至8个碳原子的脂族烃和1或 2双键(单体III)和0至60重量%的其它单体(单体IV),所述重量基于聚合物保护胶体。

    Anticorrosion binders comprising phosphate or phosphonate groups
    3.
    发明授权
    Anticorrosion binders comprising phosphate or phosphonate groups 失效
    在包含磷酸盐或膦酸酯基团的保护胶体存在下制备的防腐粘合剂

    公开(公告)号:US06218456B1

    公开(公告)日:2001-04-17

    申请号:US09321547

    申请日:1999-05-28

    IPC分类号: C08F224

    CPC分类号: C08F220/18 C08F230/02

    摘要: An aqueous polymer dispersion obtainable by emulsion polymerization of a monomer mixture A) comprising from 50 to 100% by weight of C1-C18 alkyl (meth)acrylates, vinyl esters, vinylaromatic compounds, or mixtures thereof, in the presence of a protective colloid B) composed of b1) from 2 to 40% by weight of ethylenically unsaturated copolymerizable compounds (monomers) having at least one phosphate or phosphonate group b2) from 0 to 98% by weight of C1-C18 alkyl (meth)acrylates, vinyl esters or vinylaromatic compounds b3) from 0 to 50% by weight of further monomers, the amounts by weight being based on the protective colloid.

    摘要翻译: 通过将单体混合物A)的乳液聚合得到的聚合物水分散体A)包含50至100重量%的(甲基)丙烯酸C 1 -C 18烷基酯,乙烯基酯,乙烯基芳族化合物或其混合物,在保护胶体B )bb)2〜40重量%的具有至少一个磷酸酯或膦酸酯基团的烯属不饱和可共聚化合物(单体)b2)0〜98重量%的(甲基)丙烯酸C 1 -C 18烷基酯,乙烯基酯或乙烯基芳族化合物b3 )0至50重量%的其它单体,其量以保护胶体为基准。