公开(公告)号：US20010053833A1

公开(公告)日：2001-12-20

申请号：US09861726

申请日：2001-05-22

申请人： CHISSO CORPORATION

发明人： Masato Nakano ,  Tsutomu Ushioda ,  Hiroshi Yamazaki ,  Toshihiro Uwai ,  Masami Kimura ,  Yoshiyuki Ohgi ,  Kiyomi Yamamoto

IPC分类号： C08F004/44

CPC分类号： C07F17/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  C08F4/65927 ,  C08F2500/03 ,  C08F2500/15 ,  C08F2500/12 ,  C08F210/16

摘要： The present invention provides a metallocene compound which produces an olefin polymer having a high molecular weight with a high stereoregularity. The metallocene compound has the following formula (1): Q(C5H4-mR1m)(C5H4-nR2n)MXYnullnull(1) wherein (C5H4-mR1m) and (C5H4-nR2n) each independently represent a cyclopentadienyl group; C5H4-m and C5H4-n each independently represent a cyclopentadienyl ring; m represents an integer of 1-3; n represents an integer of 2 or 3; R1 and R2 are each independently a substituent bonded respectively to C5H4-m and C5H4-n, and represent a hydrocarbon group of 1-20 carbon atoms, a silicon-containing hydrocarbon group of 1-20 carbon atoms or a heteroaromatic group; each R1m and each R2n may be the same or different; one pair of R2's in the R2n are bonded to each other to form at least one ring; Q represents a divalent group for cross-linking (C5H4-mR1m) and (C5H4-nR2n); M represents a titanium atom, a zirconium atom or a hafnium atom; and X and Y are the same or different and each a hydrogen atom, a halogen atom or a hydrocarbon group.

摘要翻译： 本发明提供茂金属化合物，其生产具有高立构规整性的具有高分子量的烯烃聚合物。 金属茂化合物具有下式（1）：其中，式（1）表示：式（1）其中， （C5H4-mR1m）和（C5H4-nR2n）各自独立地表示环戊二烯基; C5H4-m和C5H4-n各自独立地表示环戊二烯基环; m表示1-3的整数; n表示2或3的整数; R1和R2各自独立地是分别与C5H4-m和C5H4-n键合的取代基，代表1-20个碳原子的烃基，1-20个碳原子的含硅烃基或杂芳基; 每个R1m和每个R2n可以相同或不同; R2n中的一对R2相互键合形成至少一个环; Q表示用于交联的二价基团（C5H4-mR1m）和（C5H4-nR2n）; M表示钛原子，锆原子或铪原子; X和Y相同或不同，各自为氢原子，卤素原子或烃基。