公开(公告)号：US20010038092A1

公开(公告)日：2001-11-08

申请号：US09836317

申请日：2001-04-18

申请人： CHISSO CORPORATION

发明人： Tomoyuki Kondou ,  Shuichi Matsui ,  Kazutoshi Miyazawa ,  Hiroyuki Takeuchi ,  Yasuhiro Kubo ,  Fusayuki Takeshita ,  Etsuo Nakagawa

IPC分类号： C07C025/13 ,  C09K019/52 ,  C09K019/20

CPC分类号： C07C25/18 ,  C07C43/225 ,  C09K19/12 ,  Y10T428/10

摘要： The present invention provides liquid crystalline compounds having a high voltage holding ratio and a low threshold voltage, little variation of these properties with temperature change, high nulln, and good compatibility with other liquid crystal materials particularly under a low temperature; liquid crystal compositions containing these crystalline compounds; and liquid crystal display devices made using these liquid crystal compositions. The liquid crystalline compounds are terphenyl derivatives represented by general formula (1): 1 wherein R represents a straight or branched alkyl group of 1-20 carbon atoms, and any methylene groups (nullCH2null) not adjacent each other in each alkyl group may be replaced by oxygen atoms; X is a halogen atom, nullOCF3, nullOCF2H, nullCF3, nullCF2H or nullCFH2; Y1, Y2, Y3, Y4, Y5 and Y6 independently represents H or F, but at least two of Y1, Y2, Y3 and Y4 represent F; and any atom constituting these compounds may be substituted by its isotope.

摘要翻译： 本发明提供具有高电压保持率和低阈值电压的液晶化合物，这些性质与温度变化的变化小，DELTAn高，与其他液晶材料的相容性特别好，在低温下; 含有这些结晶化合物的液晶组合物; 以及使用这些液晶组合物制成的液晶显示装置。 液晶化合物是由通式（1）表示的三联苯衍生物：其中R表示1-20个碳原子的直链或支链烷基，每个烷基中不相邻的任何亚甲基（-CH 2 - ）可以是 被氧原子取代; X是卤素原子，-OCF 3，-OCF 2 H，-CF 3，-CF 2 H或-CFH 2; Y1，Y2，Y3，Y4，Y5和Y6独立地表示H或F，但Y1，Y2，Y3和Y4中的至少两个表示F; 并且构成这些化合物的任何原子可以被其同位素取代。

公开(公告)号：US20040065866A1

公开(公告)日：2004-04-08

申请号：US10650765

申请日：2003-08-29

申请人： CHISSO CORPORATION

发明人： Takashi Kato ,  Tomoyuki Kondo ,  Henry Bernhardt ,  Shuichi Matsui ,  Hiroyuki Takeuchi ,  Yasuhiro Kubo ,  Fusayuki Takeshita ,  Etsuo Nakagawa

IPC分类号： C09K019/12 ,  C07C025/13 ,  C09K019/34 ,  C09K019/30

CPC分类号： C09K19/3491 ,  C07C17/2635 ,  C07C25/18 ,  C07C25/24 ,  C07C45/515 ,  C07C45/60 ,  C07F7/0896 ,  C09K19/0403 ,  C09K19/12 ,  C09K19/3001 ,  C09K19/3003 ,  C09K19/3402 ,  C09K19/3444 ,  C09K19/3458 ,  C09K19/406 ,  C09K19/42 ,  C09K2019/0407 ,  C09K2019/0444 ,  C09K2019/3027 ,  C09K2019/3422 ,  Y10T428/10 ,  C07C49/753 ,  C07C47/277

摘要： There are provided a liquid crystalline compound having a large negative nullnull, low viscosity, a large K33/K11 value, a small nullnull/nullL and mutually excellent solubility even at extremely low temperature; a liquid crystal composition prepared from a liquid crystalline compound; and a liquid crystal display device fabricated from such a liquid crystal composition. The liquid crystalline compound of the present invention is a liquid crystalline compound represented by the following general formula (1): 1 where, R1 represents hydrogen, fluorine, an alkyl group having 1 to 15 carbon atoms, or an alkenyl group having 2 to 15 carbon atoms; each of rings A1, A2, and A3 independently represents trans-1,4-cyclohexylene group, 1,4-cyclohexenylene group, trans-1,4-silacyclohexylene group, 1,4-phenylenegroup, 2,3-difluoro-1,4-phenylene group, 2-fluoro-1,4-phenylene group, 3-fluoro-1,4-phenylene group, pyrimidine-2,5-diyl group, pyridine-2,5-diyl group, 1,3-dioxane-2,5-diyl group, tetrahydropyrane-2,5-diyl group, 1,3-dithiane-2,5-diyl group, or tetrahydrothiopyrane-2,5-diyl group; X1 represents hydrogen or fluorine; Y1 represents hydrogen or an alkyl group having 1 to 15 carbon atoms; 1 represents an integer from 1 to 10; and each of m and n independently represents 0 or 1.

摘要翻译： 提供了具有大的负三角锥，低粘度，大的K33 / K11值，小的三角/ epsilonL的液晶化合物，即使在极低的温度下也具有相互优异的溶解性; 由液晶化合物制备的液晶组合物; 以及由这种液晶组合物制造的液晶显示装置。 本发明的液晶性化合物是由以下通式（1）表示的液晶性化合物：其中，R 1表示氢，氟，碳原子数1〜15的烷基或具有2个 15个碳原子; 环A 1，A 2和A 3各自独立地表示反式-1,4-亚环己基，1,4-亚环己烯基，反-1,4-硅亚环己基，1,4-亚苯基 ，2,3-二氟-1,4-亚苯基，2-氟-1,4-亚苯基，3-氟-1,4-亚苯基，嘧啶-2,5-二基，吡啶-2,5 - 二基，1,3-二恶烷-2,5-二基，四氢吡喃-2,5-二基，1,3-二噻烷-2,5-二基或四氢噻喃-2,5-二基; X 1表示氢或氟; Y 1表示氢或碳原子数1〜15的烷基。 1表示1〜10的整数， m和n各自独立地表示0或1。

公开(公告)号：US20010038891A1

公开(公告)日：2001-11-08

申请号：US09836315

申请日：2001-04-18

申请人： CHISSO CORPORATION

发明人： Tomoyuki Kondou ,  Shuichi Matsui ,  Kazutoshi Miyazawa ,  Hiroyuki Takeuchi ,  Yasuhiro Kubo ,  Fusayuki Takeshita ,  Etsuo Nakagawa

IPC分类号： C09K019/20 ,  C07C025/13 ,  G02F001/13 ,  C09K019/52

CPC分类号： C07C25/18 ,  C07C43/225 ,  C09K19/12 ,  Y10T428/10

摘要： The present invention provides liquid crystalline compounds having a high voltage holding ratio and a low threshold voltage, little variation of these properties with temperature change, high An, and good compatibility with other liquid crystal materials particularly under a low temperature; liquid crystal compositions containing these crystalline compounds; and liquid crystal display devices made using these liquid crystal compositions. The liquid crystalline compounds are terphenyl derivatives represented by general formula (1): 1 wherein R represents a straight or branched alkyl group of 1-20 carbon atoms, and any methylene groups (nullCH2null) not adjacent each other in each alkyl group may be replaced by oxygen atoms; X is a halogen atom, nullOCF3, nullOCF2H, nullCF3, nullCF2H or nullCFH2; Y1, Y2, Y3, Y4, Y5 and Y6 independently represents H or F, but at least two of Y1, Y2, Y3 and Y4 represent F; and any atom constituting these compounds may be substituted by its isotope.

摘要翻译： 本发明提供了具有高电压保持率和低阈值电压的液晶化合物，这些性质与温度变化的变化很小，高的An，以及与其他液晶材料的相容性，特别是在低温下; 含有这些结晶化合物的液晶组合物; 以及使用这些液晶组合物制成的液晶显示装置。 液晶化合物是由通式（1）表示的三联苯衍生物：其中R表示1-20个碳原子的直链或支链烷基，每个烷基中不相邻的任何亚甲基（-CH 2 - ）可以是 被氧原子取代; X是卤素原子，-OCF 3，-OCF 2 H，-CF 3，-CF 2 H或-CFH 2; Y1，Y2，Y3，Y4，Y5和Y6独立地表示H或F，但Y1，Y2，Y3和Y4中的至少两个表示F; 并且构成这些化合物的任何原子可以被其同位素取代。

公开(公告)号：US20020033472A1

公开(公告)日：2002-03-21

申请号：US09899169

申请日：2001-07-06

申请人： CHISSO CORPORATION

发明人： Takashi Kato ,  Shuichi Matsui ,  Hiroyuki Takeuchi ,  Yasuhiro Kubo ,  Etsuo Nakagawa

IPC分类号： C09K019/34 ,  C09K019/30 ,  C07C025/13 ,  C09K019/52

CPC分类号： C07C49/753 ,  C07C49/687 ,  C07C49/693 ,  C07C49/697 ,  C07D319/06 ,  C09K19/04 ,  C09K19/3402 ,  C09K19/42 ,  C09K19/44 ,  C09K19/46 ,  C09K2019/0448 ,  C09K2019/0451 ,  C09K2019/3422 ,  Y10T428/10

摘要： Provided are a liquid crystalline compound having a wide liquid crystal phase temperature range, low viscosity, a large elastic constant ratio K33/K11 and excellent solubility at low temperature, a liquid crystal composition using the same and a liquid crystal display. Provided is a novel difluorovinyl compound is represented by Formula (1): 1 wherein Y1 represents H or a straight chain or branched alkyl group having 1 to 10 carbon atoms, and optional nullC2null in the above alkyl group may be replaced by nullOnull or nullCnullCHnull, but nullOnull is not adjacent to each other, and at least one H in Y1 may be substituted with halogen or a cyano group; A1, A2, A3 and A4 each independently represent 1,4-cyclohexenylene in which optional nullC2null which is not adjacent to each other may be replaced by nullOnull, 1,4-phenylene in which optional H may be substituted with halogen, and a single bond, in which at least two of A1, A2, A3 and A4 have the ring structure described above, and at least one of them is 1,4-cyclohexenylene in which nullC2null is replaced by nullOnull; Z1, Z2 and Z3 each independently represent a single bond, null(CH2)2null, nullCnullCHnull, null(CH2)4null, nullO(CH2)3null or null(CH2)3Onull; n represents 0 or an integer of 1 to 10, provided that when any of A1, A2, A3 and A4 is 1,4-phenylene, Z1, Z2 and Z3 are single bonds, and among them, when A1 is 1,3-dioxane-2,5-diyl and A2 is 1,4-phenylene and when A3 is 1,4-cyclohexylene and A4 is a single bond, Y1 is H, and n is not 0.

摘要翻译： 本发明提供具有宽的液晶相温度范围，低粘度，大的弹性常数比K33 / K11和低温溶解度的液晶化合物，使用该溶液的液晶组合物和液晶显示器。 提供一种新的二氟乙烯基化合物由式（1）表示：其中Y 1表示H或具有1至10个碳原子的直链或支链烷基，并且上述烷基中任选的-C 2-可以被-O- 或-C = CH-，但-O-不彼此相邻，并且Y1中的至少一个H可以被卤素或氰基取代; A1，A2，A3和A4各自独立地表示1,4-亚环己烯，其中不相邻的任选的C 2-可以被-O-，1,4-亚苯基代替，其中任选的H可以被卤素 和单键，其中A1，A2，A3和A4中的至少两个具有上述环结构，并且其中至少一个是其中-C2-被-O-取代的1,4-亚环己烯基; Z 1，Z 2和Z 3各自独立地表示单键， - （CH 2）2 - ， - C = CH - ， - （CH 2）4 - ， - O（CH 2）3 - 或 - （CH 2） n表示0或1〜10的整数，条件是当A1，A2，A3和A4中的任一个为1,4-亚苯基时，Z1，Z2和Z3为单键，其中，当A1为1,3- 二恶烷-2,5-二基，A2为1,4-亚苯基，当A3为1,4-亚环己基且A4为单键时，Y1为H，n为0。