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1.发明申请Rhenium Catalyst on a Silanized Alumina Carrier and its Use in the Metathesis Reaction of Olefins 审中-公开铼催化剂在硅烷化氧化铝载体上的应用及其在烯烃复分解反应中的应用公开(公告)号：US20080132744A1
公开(公告)日：2008-06-05
申请号：US10580834
申请日：2004-10-26
CPC分类号： B01J37/0209 , B01J21/04 , B01J23/36 , B01J31/0231 , B01J31/0274 , B01J31/0275 , B01J31/122 , B01J31/2265 , B01J37/0203 , B01J2231/543 , B01J2531/74 , C07C6/04 , C07C6/06 , C07C2521/04 , C07C2523/36
摘要： A process is described for the preparation of a heterogeneous catalyst containing rhecnium as active component and C)an inert carrier medium. characterized in that said inert carrier is previously treated with a silanizing compound containing chlorine, before the laying of the active component on the carrier, and the activation of the heterogeneous catalyst takes place by means of thermal treatment followed by a rapid final cooling. The catalyst is particularly active in metathesis reactions of olefins.
摘要翻译： 描述了制备含有ium作为活性组分的多相催化剂和C）惰性载体介质的方法。 其特征在于，在将活性组分铺设在载体上之前，预先用含氯的硅烷化化合物处理所述惰性载体，并且通过热处理进行快速最终冷却来进行非均相催化剂的活化。 催化剂在烯烃的复分解反应中特别有活性。
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2.发明申请Rhenium Catalyst Supported on Modified Alumina and Use Thereof in the Metathesis Reaction of Olefins 审中-公开负载在改性氧化铝上的铼催化剂及其在烯烃复分解反应中的应用公开(公告)号：US20070225478A1
公开(公告)日：2007-09-27
申请号：US11579054
申请日：2005-03-08
CPC分类号： B01J23/36 , B01J21/04 , B01J23/8896 , B01J37/0207 , B01J37/0209 , C07C6/04 , C07C6/06 , C07C2521/04 , C07C2523/16 , C07C2527/10 , C07C11/02
摘要： A heterogeneous catalyst is described, active in the metathesis reaction of olefins comprising alumina as inert carrier and a rhenium compound as active component, characterized in that rhenium is present in an amount of less than 5% by weight with respect to the total preferably from 1 to 4% by weight, and the inert carrier is impregnated with at least one inorganic halide selected from FeCl3, CuCl2, TiCl4, RuCl3, ZnCl2 and NH4Cl, and/or the corresponding bromides or iodides and, subsequently, treated at a high temperature.
摘要翻译： 描述了非均相催化剂，其在包含氧化铝作为惰性载体的烯烃和作为活性组分的铼化合物的复分解反应中有活性，其特征在于铼的存在量相对于总计优选为1重量份小于5重量％ 至4重量％，惰性载体用至少一种选自FeCl 3 3，CuCl 2，TiCl 4， RuCl 3 3，ZnCl 2和NH 4 Cl，和/或相应的溴化物或碘化物，随后在高温下处理。
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3.发明授权Synthesis of diols, for use as intermediates for polymeric materials, by starting from terminal diolefins 失效通过从末端二烯烃开始合成二醇，用作聚合物材料的中间体
公开(公告)号：US5395992A
公开(公告)日：1995-03-07
申请号：US14528
申请日：1993-02-08
IPC分类号： C07C29/132 , C07C31/20 , C07D301/12 , C07D303/04 , C07C27/00
CPC分类号： C07C29/132 , C07D301/12
摘要： Disclosed is the synthesis of terminal diols, which are organic intermediates used in order to produce polymeric materials, by starting from terminal diolefins, which synthesis is based on the oxidation of diolefins to yield diepoxides, in a double-phase aqueous-organic system with hydrogen peroxide and in the presence of catalysts soluble in the organic phase, followed by a reaction of reduction of the resulting diepoxides.
摘要翻译： 公开了通过从具有氢的双相含水有机体系中的二烯烃的二氧化碳的氧化作用产生二环氧化物的末端二烯烃起始，合成末端二醇，其是用于生产聚合物材料的有机中间体 在可溶于有机相的催化剂存在下，然后还原所得的二环氧化物的反应。
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4.发明授权Relative permeability modifiers based on hydrophobically modified cationic copolymers 失效基于疏水改性阳离子共聚物的相对渗透性改性剂公开(公告)号：US08722824B2
公开(公告)日：2014-05-13
申请号：US13139737
申请日：2009-12-10
申请人： Cecilia Querci , Matteo Russo , Riccardo Po′ , Maria Anna Cardaci
发明人： Cecilia Querci , Matteo Russo , Riccardo Po′ , Maria Anna Cardaci
IPC分类号： C08F236/20 , C08F220/60 , C08F226/06
CPC分类号： C08F220/56
摘要： Copolymers of acrylamide or methacrylamide, suitably modified with appropriate percentages of units deriving from comonomers of a hydrophobic nature and comonomers containing a positively charged ionic group, which are capable of effectively reducing the water permeability of a porous medium.
摘要翻译： 丙烯酰胺或甲基丙烯酰胺的共聚物，适当地以衍生自疏水性的共聚单体的单元和含有带正电荷的离子基团的共聚单体适当地改性，能够有效降低多孔介质的透水性。
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5.发明申请RELATIVE PERMEABILITY MODIFIERS BASED ON HYDROPHOBICALLY MODIFIED CATIONIC COPOLYMERS 失效基于疏水性改性阳离子共聚物的相对渗透性改性剂公开(公告)号：US20120130037A1
公开(公告)日：2012-05-24
申请号：US13139737
申请日：2009-12-10
申请人： Cecilia Querci , Matteo Russo , Riccardo Po' , Maria Anna Cardaci
发明人： Cecilia Querci , Matteo Russo , Riccardo Po' , Maria Anna Cardaci
IPC分类号： C08F220/60 , C08F226/06 , C08F236/20
CPC分类号： C08F220/56
摘要： Copolymers of acrylamide or methacrylamide, suitably modified with appropriate percentages of units deriving from comonomers of a hydrophobic nature and comonomers containing a positively charged ionic group, which are capable of effectively reducing the water permeability of a porous medium.
摘要翻译： 丙烯酰胺或甲基丙烯酰胺的共聚物，适当地以衍生自疏水性的共聚单体的单元和含有带正电荷的离子基团的共聚单体适当地改性，能够有效降低多孔介质的透水性。
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公开(公告)号：US5500285A
公开(公告)日：1996-03-19
申请号：US373441
申请日：1995-01-17
申请人： Vittorio Carletti , Gianfranco Longhini , Riccardo Po' , Roberto Podesta' , Anna M. Romano , Cecilia Querci
发明人： Vittorio Carletti , Gianfranco Longhini , Riccardo Po' , Roberto Podesta' , Anna M. Romano , Cecilia Querci
IPC分类号： C07F9/53 , C07F9/655 , C07F9/6584 , C08K5/00 , C08K5/52 , C08K5/5397 , D02G3/00
CPC分类号： C07F9/65517 , C07F9/532 , C07F9/6584 , C08K5/0066 , C08K5/5397 , Y10T428/2913
摘要： Phosphino oxide group containing compounds useful as flame retardant additives, having the general formula (I): ##STR1## wherein: X and X.sub.1 represent a hydrogen atom or, when taken jointly, they represent an NR.sub.1 moiety in which R.sub.1 stands for a hydrogen atom; a linear or branched aliphatic C.sub.1 -C.sub.5 moiety; a linear or branched C.sub.2 -C.sub.6 acyl moiety; a phenyl moiety;R represents a cyclic or polycyclic C.sub.4 -C.sub.9 moiety containing two carboxy groups, possibly esterified with univalent alcohols or glycols, or transformed into anhydrides, or two hydroxy groups.
摘要翻译： 含有氧化膦基团的化合物，可用作阻燃添加剂，具有通式（I）：其中：X和X 1表示氢原子，或共同表示NR 1部分，其中R1代表 氢原子; 直链或支链脂族C 1 -C 5部分; 直链或支链C 2 -C 6酰基部分; 苯基部分; R表示含有两个羧基的环状或多环C4-C9部分，可能用一价醇或二醇酯化，或转化成酸酐或两个羟基。
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7.发明授权
公开(公告)号：US5936051A
公开(公告)日：1999-08-10
申请号：US802875
申请日：1997-02-19
CPC分类号： C07F17/00 , C08F10/00 , Y10S526/904 , Y10S526/943
摘要： Metallocene complexes of a metal M selected from titanium, zirconium and hafnium, comprising at least one anionic group A containing an .eta..sup.5 -cyclopentadienyl ring co-ordinated with the metal M, wherein the anionic group is substituted in at least one position of the cyclopentadienyl ring with a radical having the formula:Ph*--(CR.sup.6 R.sup.7).sub.nwherein: R.sup.6 and R.sup.7 are independently hydrogen, halogen or a C.sub.1 -C.sub.4 alkyl group, preferably hydrogen, "n" is 0 or 1, preferably 1, Ph* is a C.sub.6 -C.sub.14 group comprising an aromatic ring linked to --CR.sup.6 R.sup.7 -- or to A and substituted with at least one and up to a maximum of three electron-attractor groups, on the condition that, when A is an .eta..sup.5 -indenyl group and "n" is 0, at least one Ph group is linked to A in position 1 or 3 of indenyl.These complexes can be used in (co)polymerization processes of .alpha.-olefins, possibly in the presence of a suitable co-catalyst, for the production of polyolefins with a very high molecular weight.
摘要翻译： 选自钛，锆和铪的金属M的茂金属络合物，其包含至少一个阴离子基团A，其含有与金属M配位的η5-环戊二烯基环，其中阴离子基团在至少一个位置的环戊二烯基 具有下式的基团：Ph * - （CR 6 R 7）n其中R 6和R 7独立地是氢，卤素或C 1 -C 4烷基，优选氢，“n”是0或1，优选1，Ph *是 包含与-CR 6 R 7 - 或A连接的芳环的C 6 -C 14基团，并且被A至5个茚基取代，并且被至少一个和最多三个吸电子基团取代， n“为0，至少有一个Ph基与茚基的1位或3位的A连接。 这些络合物可用于α-烯烃的（共）聚合方法中，可能在合适的助催化剂存在下，用于生产具有非常高分子量的聚烯烃。
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