公开(公告)号：US4504652A

公开(公告)日：1985-03-12

申请号：US603591

申请日：1984-04-25

申请人： Charles R. Widder ,  Don S. Wozniak

发明人： Charles R. Widder ,  Don S. Wozniak

IPC分类号： C08G18/42 ,  C08G63/20 ,  C08L27/06 ,  C08L67/00 ,  C08L75/08 ,  C08G63/70

CPC分类号： C08G63/20 ,  C08G18/4238 ,  C08L27/06 ,  C08L67/00 ,  C08L75/08

摘要： Disclosed is a method for reducing the odor and/or improving the performance of polyester plasticizers of the type made from a dibasic acid, a polyol, and a chain terminator wherein a molar excess of alcohol ingredients is used. Such improved polyester plasticizer is made by subjecting the polyester plasticizer to a second stage reaction with a treating agent reactive with hydroxyl groups to reduce the hydroxyl value to no more than about 4. Preferably, the low acid number of the initial polyester plasticizer is maintained. The treating agent can be monofunctional or poly-functional, though preferably a difunctional isocyanate is used. Conventional thermoplastic substrates, typified by polyvinyl chloride, can be plasticized with the novel polyester plasticizers of the present invention.

摘要翻译： 公开了一种降低由二元酸，多元醇和链终止剂制成的类型的聚酯增塑剂的气味和/或改进其中使用摩尔过量的醇成分的方法。 这种改进的聚酯增塑剂通过使聚酯增塑剂与与羟基反应的处理剂进行第二阶段反应来制备，以将羟基值降低至不大于约4.优选地，保持初始聚酯增塑剂的低酸值。 处理剂可以是单官能或多官能的，尽管优选使用双官能异氰酸酯。 用聚氯乙烯代表的常规热塑性基材可以用本发明的新型聚酯增塑剂增塑。

公开(公告)号：US4851464A

公开(公告)日：1989-07-25

申请号：US902936

申请日：1986-09-02

申请人： Don S. Wozniak

发明人： Don S. Wozniak

IPC分类号： C08K5/00 ,  C08J3/18 ,  C08L27/06 ,  C08L79/02 ,  C09D5/00 ,  C09D127/04 ,  C09D127/06 ,  C09J127/04

CPC分类号： C08J3/18 ,  C09D127/06 ,  C08J2327/06 ,  C08L79/02

摘要： Disclosed is an improved plastisol composition comprising a finely-divided vinyl chloride polymer, filler, a primary plasticizer, and a polyaminoamide-polyimidazoline adhesion promoter. The improvement for overcoating said plastisol with an acid catalyzed topcoat comprises a plasticizer/promoter phase which comprises said primary plasticizer, said adhesion promoter, and an effective amount of a secondary plasticizer non-ionic solvent effective in solvating the adhesion promoter in the plasticizer/promoter phase. The plasticizer/promoter phase is pre-formed for addition with the remaining ingredient for the plastisol composition.

摘要翻译： 公开了一种改进的增塑溶胶组合物，其包含细分氯乙烯聚合物，填料，主增塑剂和聚氨基酰胺 - 聚咪唑啉粘合促进剂。 用酸催化的面漆涂覆所述增塑溶胶的改进包括增塑剂/促进剂相，其包含所述主增塑剂，所述粘合促进剂和有效量的有助于溶剂化增塑剂/促进剂中的粘合促进剂的第二增塑剂非离子溶剂 相。 增塑剂/促进剂相被预先形成，用于添加用于增塑溶胶组合物的剩余成分。

公开(公告)号：US5071899A

公开(公告)日：1991-12-10

申请号：US474532

申请日：1990-02-02

申请人： Don S. Wozniak

发明人： Don S. Wozniak

IPC分类号： C08K5/06 ,  C08K5/11 ,  C08K5/12

CPC分类号： C08K5/11 ,  C08K5/06 ,  C08K5/12 ,  Y10S524/91 ,  Y10S524/911

摘要： Disclosed is an anti-stat which is effective in polyvinyl chloride polymeric parts to dissipate charge phenomena occurring at a surface thereof. The anti-stat comprises an ethoxylated fat-forming alcohol and a dibasic acid-capped fat-forming alcohol which is incorporated in an effective amount in the polyvinyl chloride polymeric material.

摘要翻译： 公开了一种在聚氯乙烯聚合物部件中有效消散其表面发生的电荷现象的抗静电。 抗静电剂包括乙氧基化脂肪形成醇和二元酸封端的成脂醇，其以有效量掺入聚氯乙烯聚合物材料中。

公开(公告)号：US4824700A

公开(公告)日：1989-04-25

申请号：US158568

申请日：1988-02-22

申请人： Don S. Wozniak

发明人： Don S. Wozniak

IPC分类号： C08J3/18 ,  C08L79/02 ,  C09D127/06 ,  B05D3/02

CPC分类号： C08J3/18 ,  C09D127/06 ,  C08J2327/06 ,  C08L79/02 ,  Y10T428/31681 ,  Y10T428/31699 ,  Y10T428/31725

摘要： Disclosed is an improved plastisol composition comprising a finely-divided vinyl chloride polymer, filler, a primary plasticizer, and a polyaminoamide-polyimidazoline adhesion promoter. The improvement for overcoating said plastisol with an acid catalyzed topcoat comprises a plasticizer/promoter phase which comprises said primary plasticizer, said adhesion promoter, and an effective amount of a secondary plasticizer non-ionic solvent effective in solvating the adhesion promoter in the plasticizer/promoter phase. The plasticizer/promoter phase is pre-formed for addition with the remaining ingredient for the plastisol composition.

公开(公告)号：US5021482A

公开(公告)日：1991-06-04

申请号：US570966

申请日：1990-08-21

申请人： Don S. Wozniak

发明人： Don S. Wozniak

IPC分类号： C08J5/12 ,  C08K5/20 ,  C08L27/06 ,  C09D127/06 ,  C09J127/04 ,  C09J127/06 ,  C08F5/30 ,  C08K8/34

CPC分类号： C09D127/06 ,  C08K5/20 ,  C09J127/06

摘要： The present invention provides a new vinyl chloride polymer coating material which can be top-coated with acid-catalyzed coating compositions at low curing temperatures without compromising the adhesion of the coating to the metal substrate and without inhibiting the cure of subsequently applied coating. In accordance with the present invention, a new plastisol coating composition comprises a finely-divided vinyl chloride polymer together with a plasticizer and from about 0.5 to about 5 percent by weight of a composition of an adhesion promoter which is a non-gelled condensation product ofa) a polymerized fatty acid; andb) a mixture of amines being present in a concentration to produce a final amine value that ranges up to about 225, said mixture being comprised of a polyalkylene polyamine and an N-aminoalkylpiperazine.In addition, the present invention provides a new and improved adhesion promoter for use in the aforesaid vinyl chloride polymer coating composition. This adhesion promoter is comprised of the condensation product of a polymeric fatty acid and an amine mixture of a polyalkylene polyamine and an N-aminoalkylpiperazine.

摘要翻译： 本发明提供了一种新的氯乙烯聚合物涂层材料，其可以在低固化温度下用酸催化的涂料组合物进行表面涂覆，而不会影响涂层与金属基材的粘合性，而不会阻碍随后涂覆的涂层的固化。 根据本发明，新的增塑溶胶涂料组合物包含细分的氯乙烯聚合物和增塑剂以及约0.5至约5重量％的粘合促进剂组合物，其为非胶凝的缩合产物 a）聚合脂肪酸; 和b）胺的混合物，其浓度以产生最高约225的最终胺值存在，所述混合物由聚亚烷基多胺和N-氨基烷基哌嗪组成。 此外，本发明提供了用于上述氯乙烯聚合物涂料组合物中的新的和改进的粘合促进剂。 该粘合促进剂由聚亚烷基多胺和N-氨基烷基哌嗪的聚合脂肪酸与胺混合物的缩合产物组成。

公开(公告)号：US4906681A

公开(公告)日：1990-03-06

申请号：US373717

申请日：1989-06-29

申请人： Don S. Wozniak

发明人： Don S. Wozniak

IPC分类号： C08K5/06 ,  C08K5/11 ,  C08K5/12

CPC分类号： C08K5/11 ,  C08K5/06 ,  C08K5/12 ,  Y10S524/91 ,  Y10S524/911

摘要： Disclosed is an anti-stat which is effective in polyvinyl chloride polymeric parts to dissipate charge phenomena occurring at a surface thereof. The anti-stat comprises an ethoxylated fat-forming alcohol and a dibasic acid-capped fat-forming alcohol which is incorporated in an effective amount in the polyvinyl chloride polymeric material.

摘要翻译： 公开了一种在聚氯乙烯聚合物部件中有效消散其表面发生的电荷现象的抗静电。 抗静电剂包括乙氧基化脂肪形成醇和二元酸封端的成脂醇，其以有效量掺入聚氯乙烯聚合物材料中。