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1.发明授权Alkenyl-functional siloxane copolymers as antimisting additives for silicone coating compositions 失效烯基官能硅氧烷共聚物作为有机硅涂料组合物的防霉添加剂公开(公告)号：US06956096B2
公开(公告)日：2005-10-18
申请号：US10797987
申请日：2004-03-11
IPC分类号： B05D7/24 , C08G77/50 , C09D183/04 , C09D183/05 , C09D183/07 , C09K3/18 , C08G77/04
CPC分类号： C08G77/50 , C09D183/04 , Y10T428/31663 , C08L83/00
摘要： Antimisting additives are used in crosslinkable silicone coating compositions for reducing aerosol formation, the antimisting additives being alkenyl-functional siloxane copolymers prepared by reacting a hydrocarbon containing at least three aliphatic double bonds, and with an organosiloxane (2) having terminal Si-bonded hydrogen atoms in the presence of a hydrosilylation catalyst (3) at a ratio of Si-bonded hydrogen to aliphatic double bonds of from 1.3 to 10, and subsequently reacting the resulting SiH-containing hydrocarbon-siloxane copolymer with an α,ω-dialkenylsiloxane polymer (4) in the presence of a hydrosilylation catalyst (3) at a ratio of aliphatic double bonds to Si-bonded hydrogen of from 1.2 to 10, and optionally, in another step, equilibrating the resulting alkenyl-functional siloxane copolymers with an organopolysiloxane (5).
摘要翻译： 抗变性添加剂用于可还原气溶胶形成的可交联硅氧烷涂料组合物中，抗反应添加剂是通过使含有至少三个脂族双键的烃反应制备的烯基官能硅氧烷共聚物和与具有末端Si键合的氢原子的有机硅氧烷（2） 在硅键合氢与脂族双键的比例为1.3至10的情况下，在氢化硅烷化催化剂（3）存在下，随后使所得含SiH的烃 - 硅氧烷共聚物与α，ω-二烯基硅氧烷聚合物（4 ）在氢化硅烷化催化剂（3）存在下，脂族双键与Si键合氢的比例为1.2至10，并且任选地，在另一步骤中，使所得烯基官能硅氧烷共聚物与有机聚硅氧烷（5）平衡， 。
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2.发明授权公开(公告)号：US06764717B2
公开(公告)日：2004-07-20
申请号：US10298715
申请日：2002-11-18
IPC分类号： B05D102
CPC分类号： C08G77/50 , C09D183/04 , Y10T428/31663 , C08L83/00
摘要： Antimisting additives are used in crosslinkable silicone coating compositions for reducing aerosol formation, the antimisting additives being alkenyl-functional siloxane copolymers prepared by reacting a hydrocarbon containing at least three aliphatic double bonds, and with an organosiloxane (2) having terminal Si-bonded hydrogen atoms in the presence of a hydrosilylation catalyst (3) at a ratio of Si-bonded hydrogen to aliphatic double bonds of from 1.3 to 10, and subsequently reacting the resulting SiH-containing hydrocarbon-siloxane copolymer with an &agr;,&ohgr;-dialkenylsiloxane polymer (4) in the presence of a hydrosilylation catalyst (3) at a ratio of aliphatic double bonds to Si-bonded hydrogen of from 1.2 to 10, and optionally, in another step, equilibrating the resulting alkenyl-functional siloxane copolymers with an organopolysiloxane (5).
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3.发明授权Alkenyl ether-siloxane compositions which can be crosslinked by free radicals 失效可以通过自由基交联的烯基醚 - 硅氧烷组合物
公开(公告)号：US5621057A
公开(公告)日：1997-04-15
申请号：US455489
申请日：1995-05-31
IPC分类号： C08F283/12 , C08F290/00 , C08L83/04 , C08L83/07 , C09D4/00 , C08F26/00
CPC分类号： C08F283/124
摘要： Alkenyl ether-siloxane compositions comprising(A) an oligomeric or polymeric organosilicon compound having on average more than one alkenyloxy group of the formulaR.sup.2 --CH.dbd.CH--O-- (VI)(B) a monomeric maleic and/or fumaric acid compound of the formula ##STR1## in which R.sup.2 is a hydrogen atom or the methyl radical,R.sup.3 is identical or different and is a hydrogen atom, a hydrocarbon radical having 1 to 16 carbon atoms, which can be interrupted by oxygen, sulfur or oxygen- or silicon-containing units, a substituted hydrocarbon radical having 1 to 6 carbon atoms, a silyl radical or a siloxanyl radical,R.sup.4 is identical or different and is a hydrogen atom, chlorine, bromine, fluorine or an optionally substituted alkyl radical andZ is an oxygen atom or a radical --NR.sup.5 --, where R.sup.5 has one of the meanings given for R.sup.3,optionally(C) initiators which form free radicals and optionally(D) inhibitors for regulating the pot life.
摘要翻译： 烯基醚 - 硅氧烷组合物，其包含（A）具有平均多于一个式R 2 -CH = CH-O-（VI）的烯氧基的低聚或聚合有机硅化合物（B）（B）单体马来酸和/或富马酸化合物 该式为氢原子或甲基，R3相同或不同，为氢原子，可被氧，硫或含氧或含硅单元中断的碳原子数为1〜16的烃基， 具有1至6个碳原子的取代烃基，甲硅烷基或硅氧烷基，R4相同或不同，为氢原子，氯，溴，氟或任选取代的烷基，Z为氧原子或基团 - NR5-，其中R5具有R3给出的含义之一，任选的（C）引发剂，其形成自由基和任选的（D）抑制剂以调节适用期。
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公开(公告)号：US5693734A
公开(公告)日：1997-12-02
申请号：US495009
申请日：1995-06-27
IPC分类号： C07F7/04 , C07F7/08 , C07F7/18 , C08G77/14 , C08G77/22 , C08G77/38 , C08L83/04 , C09D183/00 , C09D183/04 , C09D183/06 , C08G77/04
CPC分类号： C08G77/38 , C07F7/0852 , C09D183/06
摘要： Organosilicon compounds containing furanyl groups which contain units of the formula ##EQU1## in which R is identical or different and is a hydrogen atom or monovalent, SiC-bonded, aliphatically saturated, optionally substituted hydrocarbon radical, which can be interrupted by oxygen atoms, R.sup.1 is identical or different and is an optionally substituted hydrocarbon radical having 1 to 8 carbon atoms, which can be interrupted by 1 to 3 oxygen atoms. A is identical or different and is an SiC-bonded furanyl radical of the formula ##STR1## where R.sup.2 has the meaning given above for the radical R and R.sup.3 is a divalent hydrocarbon radical having 2 to 30 carbon atoms, which can contain one or more groups, chosen from the group consisting of ##STR2## a is 0, 1, 2 or 3, b is 0, 1 or 2 and c is 0, 1 or 2, with the proviso that the sum a+b+c is less than or equal to 3 and the organosilicon compound contains at least one radical A per molecule.
摘要翻译： 含有呋喃基的有机硅化合物，其含有式（I）的单元，其中R相同或不同，并且是氢原子或可被氧中断的一价，SiC键合，脂族饱和，任选取代的烃基 原子，R 1相同或不同，并且是可以被1至3个氧原子间隔的具有1至8个碳原子的任选取代的烃基。 A是相同或不同的，并且是具有下式（II）的SiC键合的呋喃基，其中R2具有上述对于基团R的含义，且R 3是具有2至30个碳原子的二价烃基，其可以含有 选自由
a组成的组中的一个或多个基团是0,1,2或3，b是0,1或2，c是0,1或2，条件是和a + b + c小于或等于3，有机硅化合物每分子含有至少一个基团A. -
公开(公告)号：US5691435A
公开(公告)日：1997-11-25
申请号：US782871
申请日：1997-01-14
IPC分类号： C08L83/05 , C07F7/08 , C08G77/12 , C08G77/48 , C08K5/5419 , C08L83/07 , C09D183/04 , C09D183/05 , C09D183/07 , C09J183/07 , C08G77/08
CPC分类号： C08K5/5419 , C07F7/0896 , C08G77/12 , C08G77/485 , C09D183/04
摘要： The present invention provides crosslinkable compositions comprising (A) an organosilicon compound having radicals containing aliphatic carbon-carbon multiple bonds, (B) an organosilicon compound having Si-bonded hydrogen atoms, (C) a catalyst which promotes the addition of Si-bonded hydrogen onto aliphatic multiple bond, and optionally (D) an agent which retards the addition of Si-bonded hydrogen onto aliphatic multiple bond at room temperature and to the use of the crosslinkable compositions for producing coatings which repel tacky substances. The present invention also relates to organosilicon compounds having Si-bonded hydrogen atoms, and to a process for their preparation.
摘要翻译： 本发明提供可交联组合物，其包含（A）具有含有脂族碳 - 碳多重键的基团的有机硅化合物，（B）具有Si键合氢原子的有机硅化合物，（C）促进加入Si键合氢的催化剂 和任选的（D）在室温下将Si键合的氢加成到脂肪族多键上的试剂，以及使用可交联组合物来制造排斥粘性物质的涂层。 本发明还涉及具有Si键合的氢原子的有机硅化合物及其制备方法。
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公开(公告)号：US5446119A
公开(公告)日：1995-08-29
申请号：US279382
申请日：1994-07-25
IPC分类号： B01J31/02 , B01J31/04 , C08G63/68 , C08G63/695 , C08G77/20 , C08G77/38 , C08G77/42 , C08G77/445 , C08G77/46 , C08G81/00 , C08G77/16
摘要： Organopolysiloxanes which contain ester groups and comprise units of the formula ##EQU1## in which R may be an identical or different monovalent, SiC-bonded hydrocarbon radical having 1 to 18 carbon atoms,A may be an identical or different radical of the formula ##STR1## in which R.sup.1, R.sup.2, R.sup.3, c, v, w, s, t,is 0 or an integer, the sum of s and tbeing an integer from 1 to 20,x is 0 or 1,y is 0 or 1, the sum of x and y being 1 or 2,a is 0, 1, 2 or 3, andb is 0, 1 or 2,with the proviso that the sum of a and b is less than or equal to 3 and the organopolysiloxane contains at least one radical A per molecule.
摘要翻译： 含有酯基并且包含式（I）的单元的有机聚硅氧烷，其中R可以是具有1至18个碳原子的相同或不同的一价SiC键合烃基，A可以是相同或不同的 式中，R1，R2，R3，c，v，w，s，t为0或整数，s和t之和为1〜20的整数，x为0或1 ，y为0或1，x和y之和为1或2，a为0,1,2或3，b为0,1或2，条件是a和b的和小于 或等于3，有机聚硅氧烷每分子含有至少一个基团A.
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公开(公告)号：US20090156755A1
公开(公告)日：2009-06-18
申请号：US12328795
申请日：2008-12-05
CPC分类号： C08G77/50 , C08L83/04 , C08L83/14 , C09D183/04 , C09D183/14 , C08L83/00
摘要： Crosslinkable silicone coating compositions are prepared from (1) organopolysiloxanes containing alkenyl groups and containing per molecule at least one unit O3-n/2RnSi—Y(SiRnO3-n/2)a (I), at least 2 units R1RbSiO(3-b)/2 (II), and units RcSiO(4-c)/2 (III), where R is a monovalent, SiC-bonded organic radical having 1 to 30 C atoms free from aliphatic carbon-carbon multiple bonds, R1 is an alkenyl radical having 2 to 4 C atoms, and Y is a divalent or trivalent organic radical having 1 to 30 C atoms, with the proviso that the organopolysiloxanes (1) contain units (II) in amounts wherein the concentration of alkenyl radicals R1 is less than 2 meq/g, (2) organopolysiloxanes containing Si-bonded hydrogen atoms, (3) a hydrosilylation catalyst, and (4) optionally, inhibitors. The compositions cure rapidly with few extractables and are very useful in preparing release coatings.
摘要翻译： 可交联的硅氧烷涂料组合物由（1）含烯基的有机聚硅氧烷制备，每分子含有至少一个单位<？在线式描述=“在线式”末端=“铅”→O 3 -n / Y（SiRnO3-n / 2）a（I），<？in-line-formula description =“In-line formula”end =“tail”？>至少2个单位<？in-line-formula description =“In 线性公式“end =”lead“？> R1RbSiO（3-b）/ 2（II），<？in-line-formula description =”In-line Formulas“end =”tail“？> and units < -line-formula description =“In-line Formulas”end =“lead”？> RcSiO（4-c）/ 2（III），<？in-line-formula description =“In-line Formulas”end =“tail 其中R是不含脂肪碳 - 碳多重键的1至30个碳原子的一价SiC键合有机基团，R 1是具有2至4个C原子的烯基，Y是二价或三价有机基团 具有1至30个C原子，条件是有机聚硅氧烷（1）含有单元（II），其中烯基的浓度 R1小于2meq / g，（2）含有Si键合氢原子的有机聚硅氧烷，（3）氢化硅烷化催化剂和（4）任选的抑制剂。 组合物用很少的可萃取物快速固化，并且在制备脱模涂层中非常有用。
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公开(公告)号：US20100137544A1
公开(公告)日：2010-06-03
申请号：US12063312
申请日：2006-08-09
CPC分类号： C08G77/50
摘要： The invention relates to organopolysiloxane compounds containing per-molecule at least one structural unit of general formula (I) O3-a/2RaSi—Y(SiRaO3-a/2)b, wherein R can be identical or different and represents an organic monovalent SiC-bonded group which comprises from 1 to 30 carbon atoms and can contain one or several O atoms, a is 0 or 1 and b is an integer number ranging from 1 to 11.
摘要翻译： 本发明涉及含有每分子至少一个通式（I）O 3-a / 2RaSi-Y（SiRaO 3-a / 2）b的结构单元的有机聚硅氧烷化合物，其中R可以相同或不同，表示有机单价SiC 包含1至30个碳原子并且可以含有一个或几个O原子的键合基团，a是0或1，b是1至11的整数。
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公开(公告)号：US07888446B2
公开(公告)日：2011-02-15
申请号：US12063312
申请日：2006-08-09
IPC分类号： C08G77/00
CPC分类号： C08G77/50
摘要： An organopolysiloxane compound containing per molecule at least one structural unit of the general formula O3-a/2RaSi—Y(SiRaO3-a/2)b (I) where R can be identical or different and denotes a monovalent SiC-bonded organic radical which has 1 to 30 C atoms and may contain one or more N and/or O atoms, Y is a divalent to dodecavalent organic radical which has 1 to 30 C atoms and may contain one or more O atoms, a is 0 or 1, and b is an integer from 1 to 11.
摘要翻译： 每分子含有至少一个通式O 3-a / 2RaSi-Y（SiRaO 3 -a / 2）b（I）的结构单元的有机聚硅氧烷化合物，其中R可以相同或不同，表示一价SiC键合的有机基团， 具有1至30个C原子并且可以含有一个或多个N和/或O原子，Y是具有1至30个C原子并且可以含有一个或多个O原子的二价至十价有机基团，a为0或1，以及 b为1〜11的整数。
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10.发明授权Branched organosilicon compounds as antimisting additives for silicone coating compositions 失效支链有机硅化合物作为有机硅涂料组合物的防霉添加剂公开(公告)号：US07135513B2
公开(公告)日：2006-11-14
申请号：US10506656
申请日：2003-02-20
IPC分类号： C08K5/5419
CPC分类号： C09D183/14 , Y10T428/31663
摘要： Branched organosilicon compounds bearing aliphatic multiple bonds, prepared by reacting a branched organosilicon compound having Si-bonded hydrogen atoms with an organosiloxane or organopolysiloxane having terminal aliphatic multiple bonds and optionally equilibrating with further organopolysiloxanes are useful as antimisting additives in the high speed coating of substrates with crosslinkable silicone compositions.
摘要翻译： 通过使具有Si键合氢原子的支链有机硅化合物与具有末端脂族多重键的有机硅氧烷或有机聚硅氧烷进一步与其它有机聚硅氧烷平衡而制备的带有脂肪族多键的支链有机硅化合物可用作基材高速涂层中的抗吸附添加剂， 可交联硅氧烷组合物。
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