摘要:
The invention relates to new graft polymers based on elastomers as the graft base and grafted-on vinyl monomers, their preparation and blend thereof with polyamides.
摘要:
This invention relates to graft polymers produced from:(1) an elastomer component having glass transition temperatures below 0.degree. C. as the graft base; and(2) graft monomers corresponding to the following general formula: ##STR1## wherein R.sup.1 represents H or a C.sub.1 -C.sub.4 alkyl radical;R.sup.3 represents H, phenyl or a C.sub.1 -C.sub.8 alkyl radical;R.sup.2 represents H, a C.sub.1 -C.sub.10 alkyl or C.sub.6 -C.sub.12 aryl radical or --OR.sup.4 ; andR.sup.4 represents C.sub.1 -C.sub.8 alkyl or C.sub.6 -C.sub.12 aryl optionally substituted by alkyl groups, O-containing or N-containing groups;X represents a single bond, a C.sub.1 -C.sub.10 alkylene or C.sub.6 -C.sub.12 arylene radical, ##STR2## Y represents --O--Z--, --NH--Z--; and Z represents a C.sub.1 -C.sub.10 alkylene or C.sub.6 -C.sub.12 arylene radical; and, optionally, other olefinically unsaturated monomers.
摘要:
Readily processable moulding materials with improved impact strength of polyamides and graft products which have a particular chemical and physical structure.
摘要:
This invention relates to a process for the graft polymerization of (A) from 95 to 40 parts, by weight, of at least one ethylenically unsaturated monomer in the presence of (B) from 5 to 60 parts, by weight, of a partially or completely cross-linked rubber, in which the one or more than one monomer (A) and rubber (B) in the form of a latex or of a dispersion in an organic solvent are polymerized in an aliphatic hydrocarbon as reaction medium at from 30.degree. to 100.degree. C., using a radical forming initiator, and the graft polymerization product obtained as a sedimenting suspension of particles having an average diameter of from 5 to 1,000 .mu.m is isolated.
摘要:
Polyesters containing carbonate groups and consisting of repeating structural units corresponding to the general formula ##STR1## in which X is the residue of a reaction product of a polyhydric alcohol with a polybasic aliphatic carboxylic acid having a molecular weight of from 800 to 3500,X' has the same meaning as X or represents the residue of an aliphatic polyether having a molecular weight of from 800 to 3500,n=0 or 1 to 10 andm=is a number >20,the intrinsic viscosity in tetrahydrofuran being from 0.8 to 2.5 dl/g.
摘要:
The present invention relates to a process for the preparation of carbonic acid esters of polyester-polyols by transesterifying the polyols with carbonic acid aryl esters at elevated temperatures under vacuum in the presence of a catalyst. The reaction conditions are controlled to avoid the formation of by-products and the chain extension of the polyester-polyols. The present invention is also concerned with the polyester carbonic acid esters so formed, their use in producing polycarbonate block copolymers and the copolymers so produced. The copolymers may be produced by transesterifying the polyester carbonic acid esters with bisphenols and subjecting the bis-hydroxyaryl carbonates so formed to normal polycarbonate synthesis such as interfacial or melt polycondensation.
摘要:
The present invention relates to a process for the preparation of bis-carbonic acid aryl esters of polyester-diols, lengthened via --OCOO-- groups, characterized in that polyester-diols with molecular weights Mn (number-average) of over 250, preferably over 600, are heated with carbonic acid bis-aryl esters at temperatures between about 100.degree. C. and 200.degree. C., preferably between about 110.degree. C. and 180.degree. C., in vacuo below about 35 mm Hg, preferably between about 25 and 1 mm Hg, in the presence of catalysts, less than one mol of carbonic acid bis-aryl ester being employed per OH group of the polyester-diol and the hydroxyaryl compounds formed being distilled off.The invention further relates to the bis-carbonic acid aryl esters of polyester-diols lengthened via --OCOO-- groups obtained according to the instant invention and their use for the preparation of polyester diol bis-diphenol carbonates, lengthened via carbonate groups, characterized in that polyester-diol bis-aryl carbonates are reacted with a diphenol at a temperature of from about 100.degree. to about 200.degree. C. in vacuo below about 35 mm Hg in the presence of a catalyst, wherein more than 1 mol of diphenol is employed per mol of carbonic acid aryl ester groups of the polyester-diol bis-aryl carbonate, lengthened via carbonate groups, and the resulting hydroxyaryl compound is distilled off.The invention finally relates to the polyester-diol bis-diphenol carbonates, lengthened via carbonate groups obtained according to the instant invention and their use for the preparation of polyester/polycarbonates and the polycarbonate/polyesters so prepared.
摘要:
The present invention relates to the transesterification of the carbonic acid aryl esters obtainable according to German Published Patent Specification No. 2,650,533 with an excess of diphenol for the preparation of polyalkylene oxide-diol bis-diphenol carbonates lengthened via carbonate groups. The present invention also relates to the polyalkylene oxide-diol bis-diphenol carbonates, lengthened via carbonate groups, obtained according to the invention and their use for the preparation of polyether/polycarbonates. Finally, the present invention relates to the polyether/polycarbonates, obtained according to the invention, with an improved phase separation between the elastomeric segment and hard segment, which leads to better technological properties of the corresponding polycarbonate elastomers.
摘要:
The present invention relates to a process for the preparation of bis-carbonic acid monoaryl esters of polyester-diols, lengthened via --OCOO-- groups, characterized in that polyester-diols with molecular weights Mn (number-average) of over 250, preferably over 600, are heated with carbonic acid bis-aryl esters at temperatures between about 100.degree. C. and 200.degree. C., preferably between about 110.degree. C. and 180.degree. C., in vacuo below about 35 mm Hg, preferably between about 25 and 1 mm Hg, in the presence of catalysts, less than one mol of carbonic acid bis-aryl ester being employed per mol of OH group of the polyester-diol and the hydroxyaryl compounds formed being distilled off.The invention further relates to the bis-carbonic acid aryl esters of polyester-diols lengthened via --OCOO-- groups.
摘要:
Modified olefine polymers of 20 to 98 parts by weight of an olefine homopolymer or copolymer and 0.5 to 80 parts by weight of a polymer containing aliphatic polyester blocks, which polymers are chemically linked through 0.5 to 40 parts by weight of a polymer of a monomer containing olefinic double bonds, a method for their manufacture, and their employment as moulding compositions.