公开(公告)号：US20110313188A1

公开(公告)日：2011-12-22

申请号：US13148595

申请日：2010-02-04

申请人： Christof Wilhelm Wigbers ,  Jochen Steiner ,  Martin Ernst ,  Bram Willem Hoffer ,  Ekkehard Schwab ,  Johann-Peter Melder

发明人： Christof Wilhelm Wigbers ,  Jochen Steiner ,  Martin Ernst ,  Bram Willem Hoffer ,  Ekkehard Schwab ,  Johann-Peter Melder

IPC分类号： C07C209/48 ,  B01J21/02 ,  B01J21/10 ,  B01J21/16 ,  B01J21/06 ,  B01J23/83 ,  C07C253/30 ,  B01J21/08

CPC分类号： B01J23/78 ,  B01J23/83 ,  B01J27/1817 ,  B01J27/1853 ,  B01J35/04 ,  B01J37/0201 ,  B01J37/0205 ,  B01J37/0215 ,  B01J37/0234 ,  B01J2523/00 ,  C07C209/48 ,  C07C253/30 ,  C07C2601/14 ,  C07C211/09 ,  C07C211/11 ,  C07C211/12 ,  C07C211/36 ,  C07C255/24 ,  B01J2523/12 ,  B01J2523/31 ,  B01J2523/51 ,  B01J2523/72 ,  B01J2523/845 ,  B01J2523/11 ,  B01J2523/48 ,  B01J2523/847

摘要： The present invention relates to a catalyst comprising one or more elements selected from the group consisting of cobalt, nickel and copper, said catalyst being present in the form of a structured monolith, wherein said catalyst comprises one or more elements selected from the group of the alkali metals, alkaline earth metals and rare earth metals. The invention further relates to processes for preparing the inventive catalyst and to the use of the inventive catalyst in a process for hydrogenating organic substances, especially for hydrogenating nitriles.

摘要翻译： 本发明涉及包含一种或多种选自钴，镍和铜的元素的催化剂，所述催化剂以结构化整料的形式存在，其中所述催化剂包括一种或多种选自以下的元素： 碱金属，碱土金属和稀土金属。 本发明还涉及用于制备本发明催化剂的方法和本发明催化剂在用于氢化有机物质，特别是用于氢化腈的方法中的用途。

公开(公告)号：US20110313187A1

公开(公告)日：2011-12-22

申请号：US13148586

申请日：2010-02-01

申请人： Christof Wilhelm Wigbers ,  Jochen Steiner ,  Martin Ernst ,  Bram Willem Hoffer ,  Ekkehard Schwab ,  Johann-Peter Melder

发明人： Christof Wilhelm Wigbers ,  Jochen Steiner ,  Martin Ernst ,  Bram Willem Hoffer ,  Ekkehard Schwab ,  Johann-Peter Melder

IPC分类号： C07C209/48 ,  C07C253/30

CPC分类号： B01J23/78 ,  B01J23/83 ,  B01J27/1853 ,  B01J35/04 ,  B01J37/0201 ,  B01J37/0205 ,  B01J37/0215 ,  B01J37/0234 ,  C07C209/48 ,  C07C253/30 ,  C07C2601/14 ,  C07C211/11 ,  C07C211/12 ,  C07C211/36 ,  C07C255/24

摘要： The present invention relates to a process for improving the catalytic properties of a catalyst comprising one or more elements selected from the group consisting of cobalt, nickel and copper, said catalyst being present in the form of a structured monolith, by contacting the catalyst with one or more basic compounds selected from the group of the alkali metals, alkaline earth metals and rare earth metals. The invention further relates to a process for hydrogenating compounds which comprise at least one unsaturated carbon-carbon, carbon-nitrogen or carbon-oxygen bond in the presence of a catalyst comprising one or more elements selected from the group consisting of cobalt, nickel and copper, said catalyst being present in the form of a structured monolith, by contacting the catalyst with one or more basic compounds selected from the group of the alkali metals, alkaline earth metals and rare earth metals. The present invention also relates to the use of a basic compound selected from the group of the alkali metals, alkaline earth metals and rare earth metals for improving the catalytic properties of a catalyst comprising cobalt and/or copper and/or nickel, said catalyst being present in the form of a structured monolith.

摘要翻译： 本发明涉及一种改进催化剂催化性能的方法，其包括选自钴，镍和铜的一种或多种元素，所述催化剂以结构化整料的形式存在，通过使催化剂与一种 或更多选自碱金属，碱土金属和稀土金属的碱性化合物。 本发明还涉及一种在包含一种或多种选自钴，镍和铜的元素的催化剂存在下，包含至少一种不饱和碳 - 碳，碳 - 氮或碳 - 氧键的化合物氢化的方法 所述催化剂以结构化整料的形式存在，通过使催化剂与一种或多种选自碱金属，碱土金属和稀土金属的碱性化合物接触。 本发明还涉及选自碱金属，碱土金属和稀土金属的碱性化合物用于改善包含钴和/或铜和/或镍的催化剂的催化性能的用途，所述催化剂是 以结构化整料的形式存在。

公开(公告)号：US20110313186A1

公开(公告)日：2011-12-22

申请号：US13148409

申请日：2010-02-01

申请人： Christof Wilhelm Wigbers ,  Jochen Steiner ,  Martin Ernst ,  Bram Willem Hoffer ,  Ekkehard Schwab ,  Johann-Peter Melder

发明人： Christof Wilhelm Wigbers ,  Jochen Steiner ,  Martin Ernst ,  Bram Willem Hoffer ,  Ekkehard Schwab ,  Johann-Peter Melder

IPC分类号： C07C209/00 ,  C07C253/00 ,  C07C209/48

CPC分类号： B01J37/0045 ,  B01J23/72 ,  B01J23/75 ,  B01J23/755 ,  B01J23/78 ,  B01J23/83 ,  B01J27/1817 ,  B01J27/1853 ,  B01J35/023 ,  B01J35/04 ,  B01J37/0211 ,  B01J2523/00 ,  C07C209/48 ,  C07C211/11 ,  C07C211/12 ,  C07C211/36 ,  C07C253/30 ,  C07C255/24 ,  B01J2523/12 ,  B01J2523/31 ,  B01J2523/48 ,  B01J2523/847 ,  B01J2523/11 ,  B01J2523/845 ,  B01J2523/51 ,  B01J2523/72

摘要： The present invention relates to catalysts and processes for preparation thereof, said catalysts being obtainable by contacting a monolithic catalyst support with a suspension which comprises one or more insoluble or sparingly soluble compounds of the elements selected from the group of the elements cobalt, nickel and copper. The invention further relates to the use of the inventive catalyst in a process for hydrogenating organic substances, especially for hydrogenating nitriles, and to a process for hydrogenating organic compounds, which comprises using an inventive catalyst in the process.

摘要翻译： 本发明涉及催化剂及其制备方法，所述催化剂可通过将整体式催化剂载体与悬浮液接触而获得，所述悬浮液包含选自钴，镍和铜元素组中的一种或多种不溶或微溶的化合物 。 本发明进一步涉及本发明的催化剂在有机物质的氢化，特别是用于氢化腈的方法中的用途，以及包括在该方法中使用本发明催化剂的有机化合物的氢化方法。

公开(公告)号：US08063252B2

公开(公告)日：2011-11-22

申请号：US12373825

申请日：2007-07-04

申请人： Petr Kubanek ,  Bram Willem Hoffer ,  Ekkehard Schwab ,  Johann-Peter Melder ,  Holger Evers ,  Till Gerlach

发明人： Petr Kubanek ,  Bram Willem Hoffer ,  Ekkehard Schwab ,  Johann-Peter Melder ,  Holger Evers ,  Till Gerlach

IPC分类号： C07C209/00

CPC分类号： C07C209/16 ,  B01J23/002 ,  B01J23/825 ,  B01J23/835 ,  B01J23/8435 ,  B01J23/8437 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/03 ,  B01J37/18 ,  B01J2523/00 ,  C07C209/26 ,  C07C213/02 ,  C07D295/023 ,  Y02P20/582 ,  B01J2523/17 ,  B01J2523/48 ,  B01J2523/54 ,  B01J2523/845 ,  B01J2523/847 ,  B01J2523/43 ,  B01J2523/53 ,  B01J2523/33 ,  C07C211/10 ,  C07C215/08 ,  C07C217/08

摘要： Processes comprising: (i) providing a reactant selected from the group consisting of primary alcohols, secondary alcohols, aldehydes, ketones and mixtures thereof; and (ii) reacting the reactant with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary amines, secondary amines and mixtures thereof, in the presence of a catalyst comprising a zirconium dioxide- and nickel-containing catalytically active composition, to form an amine; wherein the catalytically active composition, prior to reduction with hydrogen, comprises oxygen compounds of zirconium, copper, nickel and cobalt, and one or more oxygen compounds of one or more metals selected from the group consisting of Pb, Bi, Sn, Sb and In.

摘要翻译： 方法包括：（i）提供选自伯醇，仲醇，醛，酮及其混合物的反应物; 和（ii）在包含二氧化锆和含镍的催化活性组合物的催化剂存在下，使反应物与氢气和选自氨，伯胺，仲胺及其混合物的氮化合物反应， 形成胺; 其中所述催化活性组合物在用氢还原之前包括锆，铜，镍和钴的氧化合物，以及一种或多种选自Pb，Bi，Sn，Sb和In中的一种或多种金属的氧化合物 。

公开(公告)号：US20090275781A1

公开(公告)日：2009-11-05

申请号：US12373793

申请日：2007-07-04

申请人： Petr Kubanek ,  Bram Willem Hoffer ,  Ekkehard Schwab ,  Johann-Peter Melder ,  Holger Evers ,  Till Gerlach

发明人： Petr Kubanek ,  Bram Willem Hoffer ,  Ekkehard Schwab ,  Johann-Peter Melder ,  Holger Evers ,  Till Gerlach

IPC分类号： C07C209/68 ,  B01J23/28

CPC分类号： C07C213/02 ,  B01J23/002 ,  B01J23/885 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/03 ,  B01J37/18 ,  B01J2523/00 ,  C07C209/16 ,  C07C209/26 ,  C07D295/023 ,  C07C211/10 ,  C07C215/08 ,  C07C217/08

摘要： Processes comprising: (i) providing a reactant selected from the group consisting of primary alcohols, secondary alcohols, aldehydes, ketones and mixtures thereof, and (ii) reacting the reactant with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary amines, secondary amines and mixtures thereof, in the presence of a catalyst comprising a zirconium dioxide- and nickel-containing catalytically active composition, to form an amine; wherein the catalytically active composition, prior to reduction with hydrogen, comprises oxygen compounds of zirconium, copper, nickel and cobalt, and one or more oxygen compounds of molybdenum in an amount of 5.5 to 12% by weight, calculated as MoO3.

摘要翻译： 方法包括：（i）提供选自伯醇，仲醇，醛，酮及其混合物的反应物，和（ii）使反应物与氢和氮化合物反应，所述氮和化合物选自氨，伯 胺，仲胺及其混合物，在含有二氧化锆和镍的催化活性组合物的催化剂存在下，形成胺; 其中所述催化活性组合物在用氢还原之前包括锆，铜，镍和钴的氧化合物，以及以MoO 3计算的一种或多种重量百分比为5.5至12％的钼的氧化合物。

公开(公告)号：US20080255360A1

公开(公告)日：2008-10-16

申请号：US12088715

申请日：2006-09-25

申请人： Gunther van Cauwenberge ,  Johann-Peter Melder ,  Holger Evers ,  Till Gerlach ,  Frank Kiesslich ,  Ekkehard Schwab ,  Bram Willem Hoffer

发明人： Gunther van Cauwenberge ,  Johann-Peter Melder ,  Holger Evers ,  Till Gerlach ,  Frank Kiesslich ,  Ekkehard Schwab ,  Bram Willem Hoffer

IPC分类号： C07C209/14 ,  C07D295/023 ,  C07D241/04

CPC分类号： C07C209/16 ,  B01J21/04 ,  B01J23/755 ,  B01J35/023 ,  B01J37/0201 ,  B01J37/18 ,  C07D295/02 ,  C07D295/13 ,  C07C211/10 ,  C07C211/14

摘要： Processes comprising: providing a starting material comprising monoethanolamine; and reacting the starting material with ammonia in the presence of a heterogeneous transition metal catalyst to form a reaction product comprising one or more ethylene amines; wherein the catalyst comprises a catalytically active composition, which prior to treatment with hydrogen, comprises a mixture of oxygen-containing compounds of aluminum, copper, nickel and cobalt; and wherein the catalyst is present as one or more shaped catalyst particles selected from spheres, extrudates, pellets and other geometries, wherein the sphere or extrudate has a diameter of

摘要翻译： 方法包括：提供包含单乙醇胺的原料; 并在非均相过渡金属催化剂的存在下使原料与氨反应形成包含一种或多种亚乙基胺的反应产物; 其中所述催化剂包含催化活性组合物，其在用氢处理之前包括铝，铜，镍和钴的含氧化合物的混合物; 并且其中所述催化剂作为选自球体，挤出物，丸粒和其它几何形状的一种或多种成型催化剂颗粒存在，其中所述球体或挤出物的直径<3mm，所述颗粒具有<3mm的高度，而另一种 几何形状具有等效直径L = 1 / a'<0.70mm，其中a'是每单位体积的外表面积（mm×s×2 / 由 $ 定义的 3 MI> a = A / MSUB> V p 其中A < SUB>是催化剂颗粒的外表面积（mm 2），V p是催化剂颗粒的体积（mm 3） 3＆lt; 3＆gt; 3＆lt; 3＆gt;）。 7. 发明授权 Processes for preparing amines and zirconium dioxide- and nickel-containing catalysts for use therein 有权 标题翻译： 用于制备胺和二氧化锆和含镍催化剂的方法 公开(公告)号：US08765634B2 公开(公告)日：2014-07-01 申请号：US13271038 申请日：2011-10-11 申请人： Petr Kubanek ,  Bram Willem Hoffer ,  Ekkehard Schwab ,  Johann-Peter Melder ,  Holger Evers ,  Till Gerlach 发明人： Petr Kubanek ,  Bram Willem Hoffer ,  Ekkehard Schwab ,  Johann-Peter Melder ,  Holger Evers ,  Till Gerlach IPC分类号： B01J23/00 CPC分类号： C07C209/16 ,  B01J23/002 ,  B01J23/825 ,  B01J23/835 ,  B01J23/8435 ,  B01J23/8437 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/03 ,  B01J37/18 ,  B01J2523/00 ,  C07C209/26 ,  C07C213/02 ,  C07D295/023 ,  Y02P20/582 ,  B01J2523/17 ,  B01J2523/48 ,  B01J2523/54 ,  B01J2523/845 ,  B01J2523/847 ,  B01J2523/43 ,  B01J2523/53 ,  B01J2523/33 ,  C07C211/10 ,  C07C215/08 ,  C07C217/08 摘要： A catalytically active composition comprising, prior to reduction with hydrogen: 10 to 75% by weight of an oxygen compound of zirconium, calculated as ZrO2; 1 to 30% by weight of an oxygen compound of copper, calculated as CuO; 10 to 50% by weight of an oxygen compound of nickel, calculated as NiO; 10 to 50% by weight of an oxygen compound of cobalt, calculated as CoO; and 0.1 to 10% by weight of one or more oxygen compounds of one or more metals selected from the group consisting of Pb, Bi, Sn, Sb and In, calculated as PbO, Bi2O3, SnO, Sb2O3 or In2O3, respectively. 摘要翻译： 一种催化活性组合物，其在用氢还原之前包含：按ZrO 2计算的10至75重量％的锆氧化合物; 1至30重量％的以CuO计算的铜的氧化合物; 10至50重量％的以NiO计算的镍氧化合物; 10至50重量％的CoO氧化合物; 和0.1〜10重量％的一种或多种选自由PbO，Bi 2 O 3，SnO，Sb 2 O 3或In 2 O 3分别计算的Pb，Bi，Sn，Sb和In的一种或多种金属的氧化合物。 8. 发明申请 PROCESSES FOR PREPARING AMINES AND ZIRCONIUM DIOXIDE- AND NICKELCONTAINING CATALYSTS FOR USE THEREIN 有权 标题翻译： 用于制备氨基和二氧化锆和二硫化碳的催化剂的方法 公开(公告)号：US20120035049A1 公开(公告)日：2012-02-09 申请号：US13271038 申请日：2011-10-11 申请人： Petr Kubanek ,  Bram Willem Hoffer ,  Ekkehard Schwab ,  Johann-Peter Melder ,  Holger Evers ,  Till Gerlach 发明人： Petr Kubanek ,  Bram Willem Hoffer ,  Ekkehard Schwab ,  Johann-Peter Melder ,  Holger Evers ,  Till Gerlach IPC分类号： B01J21/06 CPC分类号： C07C209/16 ,  B01J23/002 ,  B01J23/825 ,  B01J23/835 ,  B01J23/8435 ,  B01J23/8437 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/03 ,  B01J37/18 ,  B01J2523/00 ,  C07C209/26 ,  C07C213/02 ,  C07D295/023 ,  Y02P20/582 ,  B01J2523/17 ,  B01J2523/48 ,  B01J2523/54 ,  B01J2523/845 ,  B01J2523/847 ,  B01J2523/43 ,  B01J2523/53 ,  B01J2523/33 ,  C07C211/10 ,  C07C215/08 ,  C07C217/08 摘要： A catalytically active composition comprising, prior to reduction with hydrogen: 10 to 75% by weight of an oxygen compound of zirconium, calculated as ZrO2; 1 to 30% by weight of an oxygen compound of copper, calculated as CuO; 10 to 50% by weight of an oxygen compound of nickel, calculated as NiO; 10 to 50% by weight of an oxygen compound of cobalt, calculated as CoO; and 0.1 to 10% by weight of one or more oxygen compounds of one or more metals selected from the group consisting of Pb, Bi, Sn, Sb and In, calculated as PbO, Bi2O3, SnO, Sb2O3 or In2O3, respectively. 摘要翻译： 一种催化活性组合物，其在用氢还原之前包含：按ZrO 2计算的10至75重量％的锆氧化合物; 1至30重量％的以CuO计算的铜的氧化合物; 10至50重量％的以NiO计算的镍氧化合物; 10至50重量％的CoO氧化合物; 和0.1〜10重量％的一种或多种选自由PbO，Bi 2 O 3，SnO，Sb 2 O 3或In 2 O 3分别计算的Pb，Bi，Sn，Sb和In的一种或多种金属的氧化合物。 9. 发明授权 Process for preparing an amine 有权 标题翻译： 制备胺的方法 公开(公告)号：US08017808B2 公开(公告)日：2011-09-13 申请号：US12293609 申请日：2007-03-13 申请人： Jan Eberhardt ,  Bram Willem Hoffer ,  Frank Haese ,  Johann-Peter Melder ,  Bernd Stein ,  Michael Stang ,  Thomas Hill ,  Ekkehard Schwab 发明人： Jan Eberhardt ,  Bram Willem Hoffer ,  Frank Haese ,  Johann-Peter Melder ,  Bernd Stein ,  Michael Stang ,  Thomas Hill ,  Ekkehard Schwab IPC分类号： C07C209/16 CPC分类号： C07C209/26 ,  C07C2601/14 ,  C07D295/023 ,  C07C211/35 ,  C07C211/08 摘要： A process for preparing an amine by reacting an aldehyde and/or ketone with hydrogen and a nitrogen compound selected from the group of primary and secondary amines in the presence of a heterogeneous catalyst, wherein the catalyst is a coated catalyst which comprises at least one metal of group VIII of the Periodic Table of the Elements as a hydrogenating metal and additionally a promoter on an oxidic support, at least 80% of the metal of group VIII of the Periodic Table of the Elements being present in a layer between the surface of the catalyst and a penetration depth which is not more than 80% of the radius of the catalyst, calculated from the surface of the catalyst. 摘要翻译： 一种通过在多相催化剂存在下使醛和/或酮与氢和选自伯胺和仲胺的氮化合物反应制备胺的方法，其中催化剂是包含至少一种金属 作为氢化金属的元素周期表第Ⅷ族，另外是氧化载体上的助催化剂，元素周期表第VIII族金属的至少80％存在于 催化剂和渗透深度不超过催化剂半径的80％，由催化剂的表面计算。 10. 发明授权 Method for producing an amine 失效 标题翻译： 胺的制备方法 公开(公告)号：US07919655B2 公开(公告)日：2011-04-05 申请号：US12373849 申请日：2007-07-04 申请人： Petr Kubanek ,  Bram Willem Hoffer ,  Ekkehard Schwab ,  Johann-Peter Melder ,  Holger Evers ,  Till Gerlach 发明人： Petr Kubanek ,  Bram Willem Hoffer ,  Ekkehard Schwab ,  Johann-Peter Melder ,  Holger Evers ,  Till Gerlach IPC分类号： C07C209/16 ,  C07C209/18 ,  C07C209/26 ,  B01J23/72 CPC分类号： C07C209/16 ,  B01J23/825 ,  B01J23/835 ,  B01J23/8435 ,  B01J23/8437 ,  B01J37/0009 ,  B01J37/03 ,  B01J37/14 ,  B01J37/18 ,  C07C209/26 ,  C07C213/02 ,  C07D295/02 ,  C07D295/023 ,  C07C211/10 ,  C07C215/08 ,  C07C217/08 摘要： Processes comprising: (i) providing a reactant selected from the group consisting of primary alcohols, secondary alcohols, aldehydes, ketones and mixtures thereof; and (ii) reacting the reactant with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary amines, secondary amines and mixtures thereof, in the presence of a catalyst comprising a zirconium dioxide- and nickel-containing catalytically active composition, to form an amine; wherein the catalytically active composition, prior to reduction with hydrogen, comprises oxygen compounds of zirconium, copper, and nickel, and one or more oxygen compounds of one or more metals selected from the group consisting of Sb, Pb, Bi, and In. 摘要翻译： 方法包括：（i）提供选自伯醇，仲醇，醛，酮及其混合物的反应物; 和（ii）在包含二氧化锆和含镍的催化活性组合物的催化剂存在下，使反应物与氢气和选自氨，伯胺，仲胺及其混合物的氮化合物反应， 形成胺; 其中所述催化活性组合物在用氢还原之前包含锆，铜和镍的氧化合物和一种或多种选自Sb，Pb，Bi和In的一种或多种金属的氧化合物。 $