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公开(公告)号：US20100326913A1
公开(公告)日：2010-12-30
申请号：US12879249
申请日：2010-09-10
申请人： Chunqing Liu , Raisa Minkov , Syed A. Faheem , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
发明人： Chunqing Liu , Raisa Minkov , Syed A. Faheem , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
CPC分类号： B01D53/228 , B01D61/025 , B01D61/362 , B01D71/62 , B01D2323/30 , B01D2323/345 , C02F1/441 , C02F2103/08 , C08G69/26 , C08G69/32 , C08G73/22 , C08L79/04 , H01M8/1018 , H01M8/1025 , H01M8/103 , H01M8/1032 , H01M8/1039 , H01M8/106 , H01M8/1069 , Y02A20/131 , Y02C20/20 , Y02P70/56
摘要： The present invention discloses high performance polybenzoxazole membranes prepared from aromatic poly(o-hydroxy amide) membranes by thermal cyclization and a method for using these membranes. The polybenzoxazole membranes were prepared by thermal treating aromatic poly(o-hydroxy amide) membranes in a temperature range of 200° to 550° C. under inert atmosphere. The aromatic poly(o-hydroxy amide) membranes used for making the polybenzoxazole membranes were prepared from aromatic poly(o-hydroxy amide) polymers comprising pendent phenolic hydroxyl groups ortho to the amide nitrogen in the polymer backbone. In some embodiments of the invention, the polybenzoxazole membranes may be subjected to an additional crosslinking step to increase the selectivity of the membranes. These polybenzoxazole membranes showed significantly improved permeability for gas separations compared to the precursor aromatic poly(o-hydroxy amide) membranes and are not only suitable for a variety of liquid, gas, and vapor separations, but also can be used in catalysis and fuel cells.
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公开(公告)号：US20100133188A1
公开(公告)日：2010-06-03
申请号：US12491473
申请日：2009-06-25
申请人： Chunqing Liu , Raisa Minkov , Syed A. Faheem , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
发明人： Chunqing Liu , Raisa Minkov , Syed A. Faheem , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
CPC分类号： B01D71/62 , B01D53/228 , B01D2323/30 , B01D2323/345 , C08G69/26 , C08G73/22 , H01M8/1027 , H01M8/103 , H01M2300/0082
摘要： The present invention discloses high performance polybenzoxazole membranes prepared from aromatic poly(o-hydroxy amide) membranes by thermal cyclization and a method for using these membranes. The polybenzoxazole membranes were prepared by thermal treating aromatic poly(o-hydroxy amide) membranes in a temperature range of 200° to 550° C. under inert atmosphere. The aromatic poly(o-hydroxy amide) membranes used for making the polybenzoxazole membranes were prepared from aromatic poly(o-hydroxy amide) polymers comprising pendent phenolic hydroxyl groups ortho to the amide nitrogen in the polymer backbone. In some embodiments of the invention, the polybenzoxazole membranes may be subjected to an additional crosslinking step to increase the selectivity of the membranes. These polybenzoxazole membranes showed significantly improved permeability for gas separations compared to the precursor aromatic poly(o-hydroxy amide) membranes and are not only suitable for a variety of liquid, gas, and vapor separations, but also can be used in catalysis and fuel cells.
摘要翻译： 本发明公开了通过热环化由芳族聚（邻羟基酰胺）膜制备的高性能聚苯并恶唑膜和使用这些膜的方法。 通过在惰性气氛下在200〜550℃的温度范围内热处理芳族聚（邻羟基酰胺）膜来制备聚苯并恶唑膜。 用于制备聚苯并恶唑膜的芳族聚（邻羟基酰胺）膜是由芳族聚（邻羟基酰胺）聚合物制备的，该聚合物包括聚合物骨架中酰胺氮原子邻位的酚羟基。 在本发明的一些实施方案中，聚苯并恶唑膜可以进行额外的交联步骤以增加膜的选择性。 与前体芳族聚（邻羟基酰胺）膜相比，这些聚苯并恶唑膜显示出显着改善气体分离的渗透性，并且不仅适用于各种液体，气体和蒸气分离，而且还可用于催化和燃料电池 。
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公开(公告)号：US08459469B2
公开(公告)日：2013-06-11
申请号：US12879244
申请日：2010-09-10
申请人： Chunqing Liu , Raisa Minkov , Syed A. Faheem , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
发明人： Chunqing Liu , Raisa Minkov , Syed A. Faheem , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
CPC分类号： B01D53/228 , B01D71/62 , B01D2323/30 , B01D2323/345 , C08G69/26 , C08G69/32 , C08G73/22 , C08L79/04 , H01M8/1027 , H01M8/103
摘要： The present invention discloses high performance polybenzoxazole membranes prepared from aromatic poly(o-hydroxy amide) membranes by thermal cyclization and a method for using these membranes. The polybenzoxazole membranes were prepared by thermal treating aromatic poly(o-hydroxy amide) membranes in a temperature range of 200° to 550° C. under inert atmosphere. The aromatic poly(o-hydroxy amide) membranes used for making the polybenzoxazole membranes were prepared from aromatic poly(o-hydroxy amide) polymers comprising pendent phenolic hydroxyl groups ortho to the amide nitrogen in the polymer backbone. In some embodiments of the invention, the polybenzoxazole membranes may be subjected to an additional crosslinking step to increase the selectivity of the membranes. These polybenzoxazole membranes showed significantly improved permeability for gas separations compared to the precursor aromatic poly(o-hydroxy amide) membranes and are not only suitable for a variety of liquid, gas, and vapor separations, but also can be used in catalysis and fuel cells.
摘要翻译： 本发明公开了通过热环化由芳族聚（邻羟基酰胺）膜制备的高性能聚苯并恶唑膜和使用这些膜的方法。 通过在惰性气氛下在200〜550℃的温度范围内热处理芳族聚（邻羟基酰胺）膜来制备聚苯并恶唑膜。 用于制备聚苯并恶唑膜的芳族聚（邻羟基酰胺）膜是由芳族聚（邻羟基酰胺）聚合物制备的，该聚合物包括聚合物骨架中酰胺氮原子邻位的酚羟基。 在本发明的一些实施方案中，聚苯并恶唑膜可以进行额外的交联步骤以增加膜的选择性。 与前体芳族聚（邻羟基酰胺）膜相比，这些聚苯并恶唑膜显示出显着改善气体分离的渗透性，并且不仅适用于各种液体，气体和蒸气分离，而且还可用于催化和燃料电池 。
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公开(公告)号：US20100331437A1
公开(公告)日：2010-12-30
申请号：US12879244
申请日：2010-09-10
申请人： Chunqing Liu , Raisa Minkov , Syed A. Faheem , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
发明人： Chunqing Liu , Raisa Minkov , Syed A. Faheem , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
IPC分类号： C08F24/00
CPC分类号： B01D53/228 , B01D71/62 , B01D2323/30 , B01D2323/345 , C08G69/26 , C08G69/32 , C08G73/22 , C08L79/04 , H01M8/1027 , H01M8/103
摘要： The present invention discloses high performance polybenzoxazole membranes prepared from aromatic poly(o-hydroxy amide) membranes by thermal cyclization and a method for using these membranes. The polybenzoxazole membranes were prepared by thermal treating aromatic poly(o-hydroxy amide) membranes in a temperature range of 200° to 550° C. under inert atmosphere. The aromatic poly(o-hydroxy amide) membranes used for making the polybenzoxazole membranes were prepared from aromatic poly(o-hydroxy amide) polymers comprising pendent phenolic hydroxyl groups ortho to the amide nitrogen in the polymer backbone. In some embodiments of the invention, the polybenzoxazole membranes may be subjected to an additional crosslinking step to increase the selectivity of the membranes. These polybenzoxazole membranes showed significantly improved permeability for gas separations compared to the precursor aromatic poly(o-hydroxy amide) membranes and are not only suitable for a variety of liquid, gas, and vapor separations, but also can be used in catalysis and fuel cells.
摘要翻译： 本发明公开了通过热环化由芳族聚（邻羟基酰胺）膜制备的高性能聚苯并恶唑膜和使用这些膜的方法。 通过在惰性气氛下在200〜550℃的温度范围内热处理芳族聚（邻羟基酰胺）膜来制备聚苯并恶唑膜。 用于制备聚苯并恶唑膜的芳族聚（邻羟基酰胺）膜是由芳族聚（邻羟基酰胺）聚合物制备的，该聚合物包括聚合物骨架中酰胺氮原子邻位的酚羟基。 在本发明的一些实施方案中，聚苯并恶唑膜可以进行额外的交联步骤以增加膜的选择性。 与前体芳族聚（邻羟基酰胺）膜相比，这些聚苯并恶唑膜显示出显着改善气体分离的渗透性，并且不仅适用于各种液体，气体和蒸气分离，而且还可用于催化和燃料电池 。
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公开(公告)号：US20110072973A1
公开(公告)日：2011-03-31
申请号：US12879208
申请日：2010-09-10
申请人： Chunqing Liu , Raisa Minkov , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
发明人： Chunqing Liu , Raisa Minkov , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
IPC分类号： B01D53/22
CPC分类号： B01D53/228 , B01D61/362 , B01D67/0011 , B01D71/62 , B01D71/82 , B01D2323/08
摘要： The present invention discloses a blends of an aromatic polyimide polymer and a polymer containing aromatic sulfonic acid groups that can be converted into polybenzoxazole (PBO) membranes for gas, vapor, and liquid separations. The PBO membranes that were prepared by thermal treating aromatic polyimide membranes containing between 0.05 and 20 wt-% of a poly(styrene sulfonic acid) polymer. These polymers showed up to 95% improvement in selectivity for CO2/CH4 and H2/CH4 separations compared to PBO membranes prepared from corresponding aromatic polyimide membranes without a poly(styrene sulfonic acid) polymer.
摘要翻译： 本发明公开了芳族聚酰亚胺聚合物和含有芳族磺酸基团的聚合物的混合物，其可以转化成用于气体，蒸气和液体分离的聚苯并恶唑（PBO）膜。 通过热处理含有0.05至20重量％聚（苯乙烯磺酸）聚合物的芳族聚酰亚胺膜制备的PBO膜。 与没有聚（苯乙烯磺酸）聚合物的相应芳族聚酰亚胺膜制备的PBO膜相比，这些聚合物显示出对CO 2 / CH 4和H 2 / CH 4分离的选择性提高高达95％。
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公开(公告)号：US08915379B2
公开(公告)日：2014-12-23
申请号：US12879193
申请日：2010-09-10
申请人： Chunqing Liu , Raisa Minkov , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
发明人： Chunqing Liu , Raisa Minkov , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
CPC分类号： B01D53/228 , B01D67/0011 , B01D71/62 , B01D71/82 , B01D2323/08
摘要： The present invention discloses a novel method to improve the selectivities of polybenzoxazole (PBO) membranes prepared from aromatic polyimide membranes for gas, vapor, and liquid separations. The PBO membranes that were prepared by thermal treating aromatic polyimide membranes containing between 0.05 and 20 wt-% of a poly(styrene sulfonic acid) polymer. These polymers showed up to 95% improvement in selectivity for CO2/CH4 and H2/CH4 separations compared to PBO membranes prepared from corresponding aromatic polyimide membranes without a poly(styrene sulfonic acid) polymer.
摘要翻译： 本发明公开了一种提高由芳族聚酰亚胺膜制备的用于气体，蒸汽和液体分离的聚苯并恶唑（PBO）膜的选择性的新方法。 通过热处理含有0.05至20重量％聚（苯乙烯磺酸）聚合物的芳族聚酰亚胺膜制备的PBO膜。 与没有聚（苯乙烯磺酸）聚合物的相应芳族聚酰亚胺膜制备的PBO膜相比，这些聚合物显示出对CO 2 / CH 4和H 2 / CH 4分离的选择性提高高达95％。
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公开(公告)号：US20100133190A1
公开(公告)日：2010-06-03
申请号：US12566834
申请日：2009-09-25
申请人： Chunqing Liu , Raisa Minkov , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
发明人： Chunqing Liu , Raisa Minkov , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
CPC分类号： B01D53/228 , B01D67/0093 , B01D71/62 , B01D2323/08
摘要： The present invention discloses a novel method to improve the selectivities of polybenzoxazole (PBO) membranes prepared from aromatic polyimide membranes for gas, vapor, and liquid separations. The PBO membranes that were prepared by thermal treating aromatic polyimide membranes containing between 0.05 and 20 wt-% of a poly(styrene sulfonic acid) polymer. These polymers showed up to 95% improvement in selectivity for CO2/CH4 and H2/CH4 separations compared to PBO membranes prepared from corresponding aromatic polyimide membranes without a poly(styrene sulfonic acid) polymer.
摘要翻译： 本发明公开了一种提高由芳族聚酰亚胺膜制备的用于气体，蒸汽和液体分离的聚苯并恶唑（PBO）膜的选择性的新方法。 通过热处理含有0.05至20重量％聚（苯乙烯磺酸）聚合物的芳族聚酰亚胺膜制备的PBO膜。 与没有聚（苯乙烯磺酸）聚合物的相应芳族聚酰亚胺膜制备的PBO膜相比，这些聚合物显示出对CO 2 / CH 4和H 2 / CH 4分离的选择性提高高达95％。
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公开(公告)号：US20110077312A1
公开(公告)日：2011-03-31
申请号：US12879193
申请日：2010-09-10
申请人： Chunqing Liu , Raisa Minkov , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
发明人： Chunqing Liu , Raisa Minkov , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
IPC分类号： C08J5/22
CPC分类号： B01D53/228 , B01D67/0011 , B01D71/62 , B01D71/82 , B01D2323/08
摘要： The present invention discloses a novel method to improve the selectivities of polybenzoxazole (PBO) membranes prepared from aromatic polyimide membranes for gas, vapor, and liquid separations. The PBO membranes that were prepared by thermal treating aromatic polyimide membranes containing between 0.05 and 20 wt-% of a poly(styrene sulfonic acid) polymer. These polymers showed up to 95% improvement in selectivity for CO2/CH4 and H2/CH4 separations compared to PBO membranes prepared from corresponding aromatic polyimide membranes without a poly(styrene sulfonic acid) polymer.
摘要翻译： 本发明公开了一种提高由芳族聚酰亚胺膜制备的用于气体，蒸汽和液体分离的聚苯并恶唑（PBO）膜的选择性的新方法。 通过热处理含有0.05至20重量％聚（苯乙烯磺酸）聚合物的芳族聚酰亚胺膜制备的PBO膜。 与没有聚（苯乙烯磺酸）聚合物的相应芳族聚酰亚胺膜制备的PBO膜相比，这些聚合物显示出对CO 2 / CH 4和H 2 / CH 4分离的选择性提高高达95％。
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公开(公告)号：US08931646B2
公开(公告)日：2015-01-13
申请号：US12879208
申请日：2010-09-10
申请人： Chunqing Liu , Raisa Minkov , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
发明人： Chunqing Liu , Raisa Minkov , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
IPC分类号： B01D71/64 , B01D71/28 , B01D53/22 , B01D67/00 , B01D71/62 , B01D71/82 , B01D69/00 , B01D61/36
CPC分类号： B01D53/228 , B01D61/362 , B01D67/0011 , B01D71/62 , B01D71/82 , B01D2323/08
摘要： The present invention discloses a blends of an aromatic polyimide polymer and a polymer containing aromatic sulfonic acid groups that can be converted into polybenzoxazole (PBO) membranes for gas, vapor, and liquid separations. The PBO membranes that were prepared by thermal treating aromatic polyimide membranes containing between 0.05 and 20 wt-% of a poly(styrene sulfonic acid) polymer. These polymers showed up to 95% improvement in selectivity for CO2/CH4 and H2/CH4 separations compared to PBO membranes prepared from corresponding aromatic polyimide membranes without a poly(styrene sulfonic acid) polymer.
摘要翻译： 本发明公开了芳族聚酰亚胺聚合物和含有芳族磺酸基团的聚合物的混合物，其可以转化成用于气体，蒸气和液体分离的聚苯并恶唑（PBO）膜。 通过热处理含有0.05至20重量％聚（苯乙烯磺酸）聚合物的芳族聚酰亚胺膜制备的PBO膜。 与没有聚（苯乙烯磺酸）聚合物的相应芳族聚酰亚胺膜制备的PBO膜相比，这些聚合物显示出对CO 2 / CH 4和H 2 / CH 4分离的选择性提高高达95％。
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公开(公告)号：US07810652B2
公开(公告)日：2010-10-12
申请号：US12566834
申请日：2009-09-25
申请人： Chunqing Liu , Raisa Minkov , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
发明人： Chunqing Liu , Raisa Minkov , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
CPC分类号： B01D53/228 , B01D67/0093 , B01D71/62 , B01D2323/08
摘要： The present invention discloses a novel method to improve the selectivities of polybenzoxazole (PBO) membranes prepared from aromatic polyimide membranes for gas, vapor, and liquid separations. The PBO membranes that were prepared by thermal treating aromatic polyimide membranes containing between 0.05 and 20 wt-% of a poly(styrene sulfonic acid) polymer. These polymers showed up to 95% improvement in selectivity for CO2/CH4 and H2/CH4 separations compared to PBO membranes prepared from corresponding aromatic polyimide membranes without a poly(styrene sulfonic acid) polymer.
摘要翻译： 本发明公开了一种提高由芳族聚酰亚胺膜制备的用于气体，蒸汽和液体分离的聚苯并恶唑（PBO）膜的选择性的新方法。 通过热处理含有0.05至20重量％聚（苯乙烯磺酸）聚合物的芳族聚酰亚胺膜制备的PBO膜。 与没有聚（苯乙烯磺酸）聚合物的相应芳族聚酰亚胺膜制备的PBO膜相比，这些聚合物显示出对CO 2 / CH 4和H 2 / CH 4分离的选择性提高高达95％。
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