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    Catalysts and processes for the polymerization of olefins
    6.
    发明授权
    Catalysts and processes for the polymerization of olefins 失效
    催化剂和烯烃聚合方法

    公开(公告)号：US5849653A

    公开(公告)日：1998-12-15

    申请号：US503948

    申请日：1995-07-19

    申请人： Tiziano Dall'Occo ,  Maurizio Galimberti ,  Luigi Resconi ,  Enrico Albizzati ,  Gianni Pennini

    发明人： Tiziano Dall'Occo ,  Maurizio Galimberti ,  Luigi Resconi ,  Enrico Albizzati ,  Gianni Pennini

    IPC分类号： C08F4/642 ,  C08F4/64 ,  C08F4/648 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/02 ,  C08F10/06 ,  C08F110/02 ,  C08F110/06 ,  C08F210/16

    CPC分类号： C08F10/00 ,  C08F10/02 ,  C08F10/06 ,  C08F110/02 ,  C08F110/06 ,  C08F210/16 ,  C08F4/65912 ,  C08F4/65922 ,  Y10S526/943

    摘要： Catalysts for the polymerization of olefins are disclosed, which comprise the reaction product of: (A) a bridged and/or substituted cyclopentadienyl compound of titanium, zirconium or hafnium; (B) an organometallic aluminum compound of the formula (II): Al(CH.sub.2 --CR.sup.4 R.sup.5 R.sup.6).sub.w R.sup.7.sub.y H.sub.z(II) wherein in the (CH.sub.2 --CR.sup.4 R.sup.5 R.sup.6) groups, which are the same or different, R.sup.4 is an alkyl, alkenyl or arylalkyl group having from 1 to 10 carbon atoms, R.sup.5 is an alkyl, alkenyl, aryl, arylalkyl or alkylaryl group having from 3 to 50 carbon atoms which is different from a straight alkyl or alkenyl group and, optionally, R.sup.4 and R.sup.5 fused together can form a ring having from 4 to 6 carbon atoms, R.sup.6 is hydrogen or an alkyl, alkenyl or arylalkyl group having from 1 to 10 carbon atoms, the R.sup.7 substituents, same or different, are alkyl, alkenyl, aryl, arylalkyl or alkylaryl radicals containing from 1 to 10 carbon atoms and, optionally, can contain Si or Ge atoms, w is 1, 2 or 3, z is 0 or 1, y=3-w-z; and (C) water. The molar ratio aluminum/water is comprised between 1:1 and 100:1. These catalysts show an improved activity with respect to known catalysts wherein an aluminum compound different from those of the above formula is used.

    摘要翻译： 公开了用于烯烃聚合的催化剂，其包含以下反应产物：（A）钛，锆或铪的桥连和/或取代的环戊二烯基化合物; （B）式（II）的有机金属铝化合物：Al（CH2-CR4R5R6）wR7yHz（Ⅱ）其中在相同或不同的（CH2-CR4R5R6）基团中，R4是烷基，烯基或芳基烷基 具有1至10个碳原子，R 5是具有3至50个碳原子的烷基，烯基，芳基，芳基烷基或烷基芳基，其不同于直链烷基或烯基，并且任选地，R 4和R 5稠合在一起可以形成 具有4至6个碳原子的环，R 6是氢或具有1至10个碳原子的烷基，链烯基或芳基烷基，相同或不同的R 7取代基是含1个碳原子的烷基，烯基，芳基，芳烷基或烷芳基 至10个碳原子，并且任选地可以含有Si或Ge原子，w是1,2或3，z是0或1，y = 3-wz; 和（C）水。 铝/水的摩尔比为1:1至100:1。 这些催化剂相对于已知的催化剂显示出改善的活性，其中使用与上式不同的铝化合物。

    Catalysts and processes for the polymerization of olefins
    7.
    发明授权
    Catalysts and processes for the polymerization of olefins 失效
    催化剂和烯烃聚合方法

    公开(公告)号：US6136932A

    公开(公告)日：2000-10-24

    申请号：US176188

    申请日：1998-10-21

    申请人： Tiziano Dall'occo ,  Maurizio Galimberti ,  Luigi Resconi ,  Enrico Albizzati ,  Gianni Pennini

    发明人： Tiziano Dall'occo ,  Maurizio Galimberti ,  Luigi Resconi ,  Enrico Albizzati ,  Gianni Pennini

    IPC分类号： C08F4/642 ,  C08F4/64 ,  C08F4/648 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/02 ,  C08F10/06 ,  C08F110/02 ,  C08F110/06 ,  C08F210/16 ,  C08F4/602

    CPC分类号： C08F10/00 ,  C08F10/02 ,  C08F10/06 ,  C08F110/02 ,  C08F110/06 ,  C08F210/16 ,  C08F4/65912 ,  C08F4/65922 ,  Y10S526/943

    摘要： Catalysts for the polymerization of olefins which comprise the reaction product of (a) a bridged and/or substituted cyclopentadienyl compound of titanium, zirconium, or hafnium; (b) an organometallic aluminum compound of formula Al(CH.sub.2 --CR.sup.4 R.sup.5 R.sup.6).sub.w R.sup.7.sub.y H.sub.z, wherein in the (CH.sub.2 --CR.sup.4 R.sup.5 R.sup.6) groups, which are the same or different, R.sup.4 is an alkyl, alkenyl or arylalkyl group having from 1 to 10 carbon atoms, R.sup.5 is an alkyl, alkenyl, aryl, arylalkyl or alkylaryl group having from 3 to 50 carbon atoms and, optionally, R.sup.4 and R.sup.5 can be fused together to form a ring having from 4-6 carbon atoms, R.sup.6 is hydrogen or an alkyl alkenyl or arylalkyl group having from 1 to 10 carbon atoms, the R.sup.7 substituents, the same or different, are alkyl, alkenyl, aryl, arylalkyl or alkylaryl radicals having from 1 to 10 carbon atoms and, optionally, can contain Si or Ge atoms, w is 1, 2 or 3, z is 0 or 1, and y=3-w-z; and (c) water. The molar ratio of aluminum to water is from 1:1 to 100:1. The catalysts show an improved activity with respect to known catalysts wherein an aluminum compound different from those of the invention are used.

    摘要翻译： 用于烯烃聚合的催化剂，其包含（a）钛，锆或铪的桥连和/或取代的环戊二烯基化合物的反应产物; （b）式A1（CH2-CR4R5R6）wR7yHz的有机金属铝化合物，其中在相同或不同的（CH2-CR4R5R6）基团中，R4是具有1至10个碳原子的烷基，烯基或芳基烷基 R 5是具有3至50个碳原子的烷基，烯基，芳基，芳基烷基或烷基芳基，并且任选地，R 4和R 5可以一起稠合形成具有4-6个碳原子的环，R 6是氢或烷基 具有1-10个碳原子的链烯基或芳基烷基，相同或不同的R 7取代基是具有1-10个碳原子的烷基，烯基，芳基，芳基烷基或烷基芳基，并且任选地可以含有Si或Ge原子， w为1,2或3，z为0或1，y = 3-wz; 和（c）水。 铝与水的摩尔比为1:1至100:1。 相对于已知的催化剂，催化剂显示出改善的活性，其中使用不同于本发明的铝化合物。