摘要:
An electrophotographic imaging member includingat least one photographic imaging layer anda partially electrically conductive overcoat layer includingfinely divided charge injection enabling particles dispersed ina charge transporting continuous matrix including a cross linked polyamide, charge transport molecules and oxidized charge transport molecules, the continuous matrix being formed from a solution selected from the group includinga first solution includingcrosslinkable alcohol soluble polyamide containing methoxy methyl groups attached to amide nitrogen atoms,an acid having a pK.sub.a of less than about 3,a cross linking agent selected from the group comprising a formaldehyde generating cross linking agent, an alkoxylated cross linking agent, a methylolamine cross linking agent and mixtures thereof,a dihydroxy arylamine, anda liquid selected from the group including alcohol solvents, diluent and mixtures thereof,a second solution includingcrosslinkable alcohol soluble polyamide free of methoxy methyl groups attached to amide nitrogen atoms,an acid having a pK.sub.a of less than about 3,an alkoxylated cross linking agent, a methylolamine cross linking agent and mixtures thereof,a dihydroxy arylamine, anda liquid selected from the group including alcohol solvents, diluent and mixtures thereof.The electrophotographic imaging process is also disclosed.
摘要:
A flexible electrophotographic imaging member including a supporting substrate coated with at least one imaging layer comprising charge transport material free of long chain alkyl carboxylate groups and a small amount of a different second hole transporting material containing at least two long chain alkyl carboxylate groups dissolved or molecularly dispersed in a film forming binder and coated from a mixture of solvents containing low boiling component and a small concentration of high boiling solvent. Preferably, the flexible electrophotographic imaging member is free of an anticurl backing layer, the imaging member comprising a supporting substrate uncoated on one side and coated on the opposite side with at least a charge generating layer and a charge transport layer containing comprising a first charge transport material and a small amount of a different second hole transporting material containing at least two long chain alkyl carboxylate groups dissolved or molecularly dispersed in a film forming binder and coated from a mixture of solvents containing low boiling component and a small concentration of high boiling solvent.
摘要:
A photoconductive imaging member comprised of an optional supporting substrate, a hole blocking layer thereover, a photogenerating layer, and a charge transport layer, and wherein the hole blocking layer is comprised of a pyrolyzed polyacrylonitrile.
摘要:
A photoconductive imaging member comprised of an optional supporting substrate, a hole blocking layer thereover, a photogenerating layer, and a charge transport layer, and wherein the hole blocking layer is comprised of a pyrolyzed polyacrylonitrile.
摘要:
A conductive composition including a mixture of a reaction product ofa hole transporting hydroxy functionalized aryl amine,a hydroxy functionalized arylamine that is different from the hole transporting hydroxy functionalized aryl amine,a cross linkable polyamide, andand an acid capable of simultaneously cross linking the polyamide and oxidizing a portion of the hydroxy functionalized arylamine,the mixture of a reaction product includinga hole transporting hydroxy functionalized aryl amine andan oxidized hydroxy functionalized aryl amine in aa crosslinked polyamide matrix.Other embodiments including processes for applying the aforementioned composition and processes for using devices containing the compositions in high speed laser printing and related printing systems are also disclosed.
摘要:
A charge transport layer for an imaging member comprising a first and second charge transport layer wherein the second charge transport layer comprises a charge transport component, a hindered phenol covalently bonded to a polymer, and an additional polymer binder other than the polymer containing the hindered phenol. The charge transport layer exhibits excellent wear resistance, excellent electrical performance, and excellent print quality.
摘要:
A charge transport layer for an imaging member comprising a charge transport layer wherein the charge transport layer is coated in two passes and wherein the second pass comprises the application of a charge transport component and a hindered phenol covalently bonded to a polymer. The charge transport layer exhibits excellent wear resistance, excellent electrical performance, and excellent print quality.
摘要:
An electrophotographic imaging member including a substrate, a charge generating layer, a charge transport layer, and an overcoat layer including a polyvinyl butyral film forming binder, a cross linked polyamide film forming binder, and a hole transport material. A process for forming an overcoated imaging member is also disclosed.
摘要:
An electrophotographic imaging member including a supporting substrate coated with at least photoconductive layer, a charge transport layer and an overcoating layer, the overcoating layer includinga hydroxy functionalized aromatic diamine anda hydroxy functionalized triarylamine dissolved or molecularly dispersed ina crosslinked polyamide matrix, the crosslinked polyamide prior to crosslinking being selected from the group consisting of materials represented by the following Formulae I and II: ##STR1## wherein: n is a positive integer sufficient to achieve a weight average molecular weight between about 5000 and about 100,000,R is an alkylene unit containing from 1 to 10 carbon atoms,between 1 and 99 percent of the R.sub.2 sites are --H, andthe remainder of the R.sub.2 sites are --CH.sub.2 --O--CH.sub.3, and ##STR2## wherein: m is a positive integer sufficient to achieve a weight average molecular weight between about 5000 and about 100000,R.sub.1 and R are independently selected from the group consisting of alkylene units containing from 1 to 10 carbon atoms, andbetween 1 and 99 percent of the R.sub.3 and R.sub.4 sites are --H, andthe remainder of the R.sub.3 and R.sub.4 sites are --CH.sub.2 --O--CH.sub.3.Coating compositions for the overcoating layer of this invention as well as methods of making and using the overcoated photoreceptor are also disclosed.
摘要:
An electrophotographic imaging member includinga supporting substrate coated withat least one photoconductive layer, andan overcoating layer, the overcoating layer including aa hydroxy functionalized aromatic diamine anda hydroxy functionalized triarylamine dissolved or molecularly dispersed ina crosslinked acrylated polyamide matrix, the hydroxy functionalized triarylamine being a compound different from the polyhydroxy functionalized aromatic diamine, the crosslinked polyamide prior to crosslinking being selected from the group consisting of materials represented by the following Formulae I and II: ##STR1## wherein: n is a positive integer sufficient to achieve a weight average molecular weight between about 5000 and about 100,000,R is an alkylene group containing from 1 to 10 carbon atoms,between 1 and 99 percent of the R.sub.2 sites are ##STR2## wherein X is selected from the group consisting of --H (acrylate), --CH.sub.3 (methacrylate), alkyl and aryl, andthe remainder of the R.sub.2 sites are selected from the group consisting of --H, --CH.sub.2 OCH.sub.3, and --CH.sub.2 OH, and ##STR3## wherein: m is a positive integer sufficient to achieve a weight average molecular weight between about 5000 and about 100000,R and R.sub.1 are independently selected from the group consisting of alkylene units containing from 1 to 10 carbon atoms;between 1 and 99 percent of R.sub.3 and R.sub.4 are independently selected from the group consisting of ##STR4## wherein X is selected from the group consisting of hydrogen, alkyl, aryl and alkylaryl, wherein the alkyl groups contain 1 to 10 carbon atoms and the aryl groups contain 1 to 3 alkyl groups, y is an integer between 1 and 10, andthe remainder of the R.sub.3 and R.sub.4 groups are selected from the group consisting of --H, --CH.sub.2 OH, --CH.sub.2 OCH.sub.3, and --CH.sub.2 OC(O)--C(X).dbd.CH.sub.2.The overcoating layer is formed by coating. The electrophotographic imaging member may be imaged in a process.