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公开(公告)号:US5668186A
公开(公告)日:1997-09-16
申请号:US618742
申请日:1996-03-20
CPC分类号: C08J11/18 , C08J2367/02 , Y02W30/706
摘要: The invention relates to a novel process for depolymerizing polyesters by subjecting the polyesters to catalysts and organic solvents which are substantially free of oxygen and water in order to produce macrocyclic polyester oligomers substantially free of hydroxybutyl terminated linear impurities.
摘要翻译: 本发明涉及通过使聚酯经受基本上不含氧和水的催化剂和有机溶剂来解聚聚酯的新方法,以便制备基本上不含羟基丁基封端的线性杂质的大环聚酯低聚物。
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公开(公告)号:USRE38995E1
公开(公告)日:2006-02-28
申请号:US10642007
申请日:2003-08-15
申请人: Patrick Joseph McCloskey , Timothy Brydon Burnell , Daniel Joseph Brunelle , Elliott West Shanklin , Paul Michael Smigelski, Jr. , Ganesh Kailasam
发明人: Patrick Joseph McCloskey , Timothy Brydon Burnell , Daniel Joseph Brunelle , Elliott West Shanklin , Paul Michael Smigelski, Jr. , Ganesh Kailasam
IPC分类号: C07C69/96
摘要: High yields of ester-substituted diary carbonates such as bis-methyl salicyl carbonate were obtained by the condensation of methyl salicylate with phosgene in the presence of a phase transfer catalyst (PTC) in an interfacial reaction system in which the pH of the aqueous phase was greater than 9.3. Using the method of the present invention conversions of greater than 99% were obtained whereas under standard conditions using triethylamine as the catalyst conversions were limited to 70-75% of the methyl salicylate starting material even with a 20 mole % excess of added phosgene. The optimized conditions of the of the present invention use only a slight excess of phosgene and represent an attractive route for the manufacture of bis methyl salicyl carbonate and ester-substituted diaryl carbonates generally.
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公开(公告)号:US06790934B2
公开(公告)日:2004-09-14
申请号:US10034866
申请日:2001-12-21
申请人: Norman Enoch Johnson , Raul Eduardo Ayala , Thomas Joseph Fyvie , Amy Rene Freshour , David Winfield Woodruff , Peter David Phelps , Ganesh Kailasam , Paul Edward Howson , Elliott West Shanklin , Lioba Maria Kloppenburg , David Bruce Hall , Pradeep Jeevaji Nadkarni , Daniel Joseph Brunelle
发明人: Norman Enoch Johnson , Raul Eduardo Ayala , Thomas Joseph Fyvie , Amy Rene Freshour , David Winfield Woodruff , Peter David Phelps , Ganesh Kailasam , Paul Edward Howson , Elliott West Shanklin , Lioba Maria Kloppenburg , David Bruce Hall , Pradeep Jeevaji Nadkarni , Daniel Joseph Brunelle
IPC分类号: C08G606
CPC分类号: C08G73/12 , C08G65/48 , C08G73/1046 , C08G75/23
摘要: Aromatic polyethers are prepared by displacement polymerization reaction in the presence of a water-immiscible solvent with boiling point at atmospheric pressure of greater than 110° C. and a density ratio to water of greater than 1.1:1 at 20-25° C. The polyethers are purified by processes comprising aqueous extraction, or filtration, or a combination thereof.
摘要翻译: 在大气压大于110℃的沸点和水分密度比大于1.1:1的水不混溶溶剂存在下,通过置换聚合反应制备芳族聚醚。 聚醚通过包括水提取或过滤或其组合的方法纯化。
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公开(公告)号:US06548623B2
公开(公告)日:2003-04-15
申请号:US09911443
申请日:2001-07-24
申请人: Daniel Joseph Brunelle , Patrick Joseph McCloskey , Paul Michael Smigelski, Jr. , Timothy Brydon Burnell , Ganesh Kailasam
发明人: Daniel Joseph Brunelle , Patrick Joseph McCloskey , Paul Michael Smigelski, Jr. , Timothy Brydon Burnell , Ganesh Kailasam
IPC分类号: C08G6400
CPC分类号: C08G64/06 , C08G64/04 , C08G64/14 , C08G64/307
摘要: Polycarbonates containing low or undetectable levels of Fries rearrangement product may be prepared by the melt reaction of a dihydroxy aromatic compound such as bisphenol A with an ester-substituted diaryl carbonate such as the diaryl carbonate of methyl salicylate, bis-methyl salicyl carbonate. Low levels of Fries product are obtained as the combined result of a highly effective catalyst system which suppresses the Fries reaction and the use of lower melt polymerization temperatures relative to temperatures required for the analogous polymerization reaction using diphenyl carbonate.
摘要翻译: 含有低或不可检测水平的Fries重排产物的聚碳酸酯可以通过二羟基芳族化合物如双酚A与酯取代的二芳基碳酸酯例如水杨酸甲酯的碳酸二芳基酯,碳酸双甲基酯的熔融反应来制备。 通过抑制Fries反应的高效催化剂体系和相对于使用碳酸二苯酯的类似聚合反应所需的温度使用较低熔融聚合温度的综合结果,可以获得低水平的油炸产品。
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公开(公告)号:US06420588B1
公开(公告)日:2002-07-16
申请号:US09911440
申请日:2001-07-24
申请人: Patrick Joseph McCloskey , Timothy Brydon Burnell , Daniel Joseph Brunelle , Elliott West Shanklin , Paul Michael Smigelski, Jr. , Ganesh Kailasam
发明人: Patrick Joseph McCloskey , Timothy Brydon Burnell , Daniel Joseph Brunelle , Elliott West Shanklin , Paul Michael Smigelski, Jr. , Ganesh Kailasam
IPC分类号: C07C6996
摘要: High yields of ester-substituted diary carbonates such as bis-methyl salicyl carbonate were obtained by the condensation of methyl salicylate with phosgene in the presence of a phase transfer catalyst (PTC) in an interfacial reaction system in which the pH of the aqueous phase was greater than 9.3. Using the method of the present invention conversions of greater than 99% were obtained whereas under standard conditions using triethylamine as the catalyst conversions were limited to 70-75% of the methyl salicylate starting material even with a 20 mole % excess of added phosgene. The optimized conditions of the of the present invention use only a slight excess of phosgene and represent an attractive route for the manufacture of bis methyl salicyl carbonate and ester-substituted diaryl carbonates generally.
摘要翻译: 通过在界面反应体系中存在相转移催化剂(PTC)的情况下,通过水杨酸甲酯与光气的缩合得到高产率的酯取代的二元碳酸酯,其中水相的pH为 大于9.3。 使用本发明的方法获得大于99%的转化率,而在使用三乙胺的标准条件下,即使使用20摩尔%过量的加入的光气,催化剂转化率也限于水杨酸甲酯起始原料的70-75%。 本发明的优化条件仅使用轻微过量的光气,并且代表通常用于制造碳酸双甲基水杨酸酯和酯取代的二芳基碳酸酯的有吸引力的途径。
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公开(公告)号:US06489372B1
公开(公告)日:2002-12-03
申请号:US09690596
申请日:2000-10-17
申请人: Qiwei He , Paul Russell Wilson , Paul William Buckley , Allen Wai Yee Ko , Larry Allen Divins , William Lee Gately , Ganesh Kailasam
发明人: Qiwei He , Paul Russell Wilson , Paul William Buckley , Allen Wai Yee Ko , Larry Allen Divins , William Lee Gately , Ganesh Kailasam
IPC分类号: C08J1104
CPC分类号: C08G64/403 , C08G63/89 , C08J3/14
摘要: Polymer are removed from organic solvent-polymer mixtures by preparing a liquid-liquid dispersion of finely dispersed solvent droplets containing polymer in water, adding this liquid-liquid dispersion to a stirred vessel containing water or other suitable liquid and rapidly evaporating the solvent to produce a slurry of the polymer in a liquid from which the solid polymer particles are recovered.
摘要翻译: 通过制备含有聚合物在水中的精细分散的溶剂液滴的液 - 液分散体,将该液 - 液分散体加入到含有水或其它合适液体的搅拌容器中并快速蒸发溶剂以产生聚合物,从而从有机溶剂 - 聚合物混合物中除去聚合物 聚合物在从其中回收固体聚合物颗粒的液体中的淤浆。
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公开(公告)号:US08877885B2
公开(公告)日:2014-11-04
申请号:US13704162
申请日:2011-06-29
申请人: Kamesh R. Vyakaranam , Ling Zhang , William A. Koonce , Juan Carlos Medina , Ganesh Kailasam , Rajat Duggal , Nathan Wilmot
发明人: Kamesh R. Vyakaranam , Ling Zhang , William A. Koonce , Juan Carlos Medina , Ganesh Kailasam , Rajat Duggal , Nathan Wilmot
IPC分类号: C08G18/20
CPC分类号: C08G18/222 , C08G18/18 , C08G18/20 , C08G18/289 , C08G18/3893 , C08G18/4825 , C08G18/718 , C08G18/7621 , C08G18/7671 , C08G18/837
摘要: Embodiments of the invention provide for methods of producing a composition comprising a crosslinkable silane-terminated polymer having at least one crosslinkable silyl group in each molecule. The method comprises providing a polymer having at least one unsaturated group and at least one alcoholic hydroxyl group in each molecule, adding to the polymer a compound having a hydrogen-silicon bond and a crosslinkable silyl group in each molecule and a hydrosilylation catalyst to thereby carry out a hydrosilylation reaction to form a composition comprising hydrosilylated polyoxyalkylene polymers, reacting the hydrosilylated polyoxyalkylene polymers with at least one isocyanate in the presence of a first tin-free catalyst to form an isocyanate reacted hydrosilylated polymer, and optionally reacting the isocyanate reacted hydrosilylated polymer with a polyol having a nominal functionality of at least 2 to form a polyol reacted crosslinkable silane-terminated polymer.
摘要翻译: 本发明的实施方案提供了制备包含在每个分子中具有至少一个可交联甲硅烷基的可交联的硅烷端基聚合物的组合物的方法。 该方法包括在每个分子中提供具有至少一个不饱和基团和至少一个醇羟基的聚合物,向该聚合物中加入每个分子中具有氢 - 硅键和交联性甲硅烷基的化合物和氢化硅烷化催化剂从而携带 进行氢化硅烷化反应以形成包含氢化硅烷化聚氧化烯聚合物的组合物,在第一无锡催化剂存在下使氢化硅烷化聚氧化烯聚合物与至少一种异氰酸酯反应,以形成异氰酸酯反应的氢化硅烷化聚合物,以及任选地使异氰酸酯反应的硅烷化聚合物与 具有至少2的标称官能度的多元醇以形成多元醇反应的可交联的硅烷封端的聚合物。
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公开(公告)号:US20130096252A1
公开(公告)日:2013-04-18
申请号:US13704162
申请日:2011-06-29
申请人: Kamesh R. Vyakaranam , Ling Zhang , William A. Koonce , Juan Carlos Medina , Ganesh Kailasam , Rajat Duggal , Nathan Wilmot
发明人: Kamesh R. Vyakaranam , Ling Zhang , William A. Koonce , Juan Carlos Medina , Ganesh Kailasam , Rajat Duggal , Nathan Wilmot
CPC分类号: C08G18/222 , C08G18/18 , C08G18/20 , C08G18/289 , C08G18/3893 , C08G18/4825 , C08G18/718 , C08G18/7621 , C08G18/7671 , C08G18/837
摘要: Embodiments of the invention provide for methods of producing a composition comprising a crosslinkable silane-terminated polymer having at least one crosslinkable silyl group in each molecule. The method comprises providing a polymer having at least one unsaturated group and at least one alcoholic hydroxyl group in each molecule, adding to the polymer a compound having a hydrogen-silicon bond and a crosslinkable silyl group in each molecule and a hydrosilylation catalyst to thereby carry out a hydrosilylation reaction to form a composition comprising hydrosilylated polyoxyalkylene polymers, reacting the hydrosilylated polyoxyalkylene polymers with at least one isocyanate in the presence of a first tin-free catalyst to form an isocyanate reacted hydrosilylated polymer, and optionally reacting the isocyanate reacted hydrosilylated polymer with a polyol having a nominal functionality of at least 2 to form a polyol reacted crosslinkable silane-terminated polymer.
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公开(公告)号:US08034857B2
公开(公告)日:2011-10-11
申请号:US11853357
申请日:2007-09-11
CPC分类号: C08L79/08 , C08L81/06 , C08L81/10 , C08L81/00 , C08L2666/14
摘要: Compositions comprise phase separated polyetherimide/polyphenylene ether sulfone blends. The dispersed phase has an average cross sectional size of 0.1 to 10 micrometers. The composition retains has good hydrolytic stability and is capable of withstanding steam autoclaving at temperatures of 130 to 138° C.
摘要翻译: 组合物包括相分离的聚醚酰亚胺/聚苯醚砜共混物。 分散相的平均横截面尺寸为0.1至10微米。 保留的组合物具有良好的水解稳定性,并且能够在130至138℃的温度下耐受蒸汽高压灭菌。
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公开(公告)号:US20090018242A1
公开(公告)日:2009-01-15
申请号:US11776658
申请日:2007-07-12
IPC分类号: C08L81/06 , C08F283/04 , C08K5/51
CPC分类号: C08L53/00 , C08F283/04 , C08G75/23 , C08G75/30 , C08K5/09 , C08K5/20 , C08L79/08 , C08L81/06 , C08L81/10 , C08L2205/05 , C08L2666/02 , C08L2666/14 , C08L81/00
摘要: Compositions comprise phase separated polyetherimide/polyphenylene ether sulfone blends. The dispersed phase has an average cross sectional size of 0.1 to 10 micrometers. The composition retains has good hydrolytic stability and is capable of withstanding steam autoclaving at temperatures of 130 to 138° C.
摘要翻译: 组合物包括相分离的聚醚酰亚胺/聚苯醚砜共混物。 分散相的平均横截面尺寸为0.1至10微米。 保留的组合物具有良好的水解稳定性,并且能够在130至138℃的温度下耐受蒸汽高压灭菌。
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