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    Dishwashing detergent compositions containing mixtures or crystallinity-disrupted surfactants
    6.
    发明授权
    Dishwashing detergent compositions containing mixtures or crystallinity-disrupted surfactants 失效
    含有混合物或结晶破坏的表面活性剂的餐具洗涤剂组合物

    公开(公告)号：US06774099B1

    公开(公告)日：2004-08-10

    申请号：US09889632

    申请日：2001-07-19

    申请人： Jeffrey John Scheibel ,  Thomas Anthony Cripe ,  Kevin Lee Kott ,  Daniel Stedman Connor ,  James Charles Theophile Roger Burckett-St. Laurent ,  Phillip Kyle Vinson ,  William Michael Scheper ,  Chandrika Kasturi

    发明人： Jeffrey John Scheibel ,  Thomas Anthony Cripe ,  Kevin Lee Kott ,  Daniel Stedman Connor ,  James Charles Theophile Roger Burckett-St. Laurent ,  Phillip Kyle Vinson ,  William Michael Scheper ,  Chandrika Kasturi

    IPC分类号： C11D1700

    CPC分类号： C11D3/0084 ,  C11D1/22 ,  C11D1/75 ,  C11D1/83 ,  C11D3/044 ,  C11D3/046 ,  C11D3/30 ,  C11D3/38618 ,  C11D3/38627

    摘要： A hand dishwashing compositions comprising; a) about 0.1% to about 99.9% by weight of said composition of an alkylarylsulfonate surfactant system comprising from about 10% to about 100% by weight of said surfactant system of two or more crystallinity-disrupted alkylarylsulfonate surfactants of formula (B—Ar—D)a(Mq+)b wherein D is SO3—, M is a cation or cation mixture, q is the valence of said cation, a and b are numbers selected such that said composition is electroneutral; Ar is selected from benzene, toluene, and combinations thereof; and B comprises the sum of at least one primary hydrocarbyl moiety containing from 5 to 20 carbon atoms and one or more crystallinity-disrupting moieties, wherein said crystallinity-disrupting moieties interrupt or branch from said hydrocarbyl moiety; and wherein said alkylarylsulfonate surfactant system has crystallinity disruption to the extent that its Sodium Critical Solubility Temperature, as measured by the CST Test, is no more than about 40° C.; and wherein further said alkylarylsulfonate surfactant system has at least one of the following properties: percentage biodegradation, as measured by the modified SCAS test, that exceeds tetrapropylene benzene sulfonate; and weight ratio of nonquaternary to quaternary carbon atoms in B of at least about 5:1; and b) from about 0.00001% to about 99.9% by weight of said composition of a conventional hand dishwashing adjunct; c) from about 0.01% to about 7% by weight of composition of a divalent ion selected from the group consisting of magnesium, calcium and mixtures thereof.

    摘要翻译： 一种手洗餐具组合物，其包含： a）约0.1重量％至约99.9重量％的所述组合物的烷基芳基磺酸盐表面活性剂体系，其包含约10重量％至约100重量％的所述表面活性剂体系的两种或更多种结晶度破坏的烷基芳基磺酸盐表面活性剂（B-Ar- D）a（M ）b其中D是SO 3 - ，M是阳离子或阳离子混合物，q是所述阳离子的化合价，a和b是选择的数字，使得所述组合物是电中性的; Ar选自苯，甲苯及其组合; 和B包含至少一个含有5至20个碳原子的一级烃基部分和一种或多种结晶破坏部分的总和，其中所述结晶破坏部分中断或从所述烃基部分分支; 并且其中所述烷基芳基磺酸盐表面活性剂体系具有结晶度破坏程度，其通过CST试验测量的其钠临界溶解度温度不超过约40℃; 并且其中所述烷基芳基磺酸盐表面活性剂体系具有以下特性中的至少一个：通过改性SCAS测试测量的超过四丙烯苯磺酸盐的百分比生物降解; 并且B中非季铵碳原子的重量比至少约为5：1; 和b）所述组合物的常规手洗餐具辅料的约0.00001重量％至约99.9重量％ c）约0.01重量％至约7重量％的组合物，选自镁，钙及其混合物的二价离子。

    Processes for making surfactants via adsorptive separation and products thereof
    7.
    发明授权
    Processes for making surfactants via adsorptive separation and products thereof 有权
    通过吸附分离制备表面活性剂的方法及其制品

    公开(公告)号：US07202205B1

    公开(公告)日：2007-04-10

    申请号：US09786078

    申请日：1999-09-01

    申请人： Daniel Stedman Connor ,  Jeffrey John Scheibel ,  James Charles Theophile Roger Burckett-St. Laurent ,  Thomas Anthony Cripe ,  Kevin Lee Kott ,  Phillip Kyle Vinson

    发明人： Daniel Stedman Connor ,  Jeffrey John Scheibel ,  James Charles Theophile Roger Burckett-St. Laurent ,  Thomas Anthony Cripe ,  Kevin Lee Kott ,  Phillip Kyle Vinson

    IPC分类号： C11D1/68 ,  C07C7/13 ,  C07C5/333 ,  C07C9/16

    CPC分类号： C11D1/22 ,  C11D1/146 ,  C11D1/29

    摘要： Processes for making particularly branched, especially monomethyl-branched or nongeminal dimethyl-branched surfactants used in cleaning products; preferred processes comprising particular combinations of two or more adsorptive separation steps and, more preferably, particular OXO and/or alkylation steps; products of such processes, including certain modified primary OXO alcohols and/or alkylbenzenes, modified primary OXO alcohol-derived alkoxylated alcohols, alkylsulfates and/or alkoxysulfates; alkylbenzensulfonate surfactants, and consumer cleaning products, especially laundry detergents, containing them. Preferred processes herein more specifically use specific, unconventional sequences of sorptive separation steps to secure certain branched hydrocarbon fractions which are used in further process steps to make olefins useful in OXO processes or as alkylating agents for arenes or for other useful surfactant-making purposes. Surprisingly, such fractions can even be derived from effluents from current linear alkylbenzene manufacture.

    摘要翻译： 用于制造特别是支链的，特别是用于清洁产品中的单甲基支链或非农业二甲基支链表面活性剂的方法; 优选的方法包括两个或更多个吸附分离步骤的特定组合，更优选地，特定的OXO和/或烷基化步骤; 这些方法的产物，包括某些改性的初级OXO醇和/或烷基苯，改性的初级OXO醇衍生的烷氧基化醇，烷基硫酸盐和/或烷氧基硫酸盐; 烷基苯磺酸盐表面活性剂和消费者清洁产品，特别是含有它们的衣物洗涤剂。 本文优选的方法更具体地使用吸附分离步骤的特定的非常规序列来确定某些支链烃馏分，其用于进一步的方法步骤以制备在OXO方法中有用的烯烃或作为芳烃的烷基化剂或用于其它有用的表面活性剂制备目的。 令人惊讶的是，这些馏分甚至可以从目前的直链烷基苯生产的流出物得到。

    Processes for making surfactants via absorptive separation and products thereof
    9.
    发明授权
    Processes for making surfactants via absorptive separation and products thereof 失效
    通过吸收分离制备表面活性剂的方法及其制品

    公开(公告)号：US06673961B2

    公开(公告)日：2004-01-06

    申请号：US10304920

    申请日：2002-11-26

    申请人： Daniel Stedman Connor ,  Jeffrey John Scheibel ,  James Charles Theophile Roger Burckett-St. Laurent ,  Thomas Anthony Cripe ,  Kevin Lee Kott ,  Phillip Kyle Vinson

    发明人： Daniel Stedman Connor ,  Jeffrey John Scheibel ,  James Charles Theophile Roger Burckett-St. Laurent ,  Thomas Anthony Cripe ,  Kevin Lee Kott ,  Phillip Kyle Vinson

    IPC分类号： C07C30901

    CPC分类号： C07C303/06 ,  C07C7/13 ,  C07C15/02 ,  C07C9/00 ,  C07C309/31

    摘要： Processes for making particularly branched, especially monomethyl-branched or nongeminal dimethyl-branched surfactants used in cleaning products; preferred processes comprising particular combinations of two or more adsorptive separation steps and, more preferably, particular alkylation steps; products of such processes, including certain modified alkylbenzenes, modified alkylbenzenesulfonate surfactants, and consumer cleaning products, especially laundry detergents, containing them. Preferred processes herein more specifically use specific, unconventional sequences of sorptive separation steps to secure certain branched hydrocarbon fractions which are used in further process steps as alkylating agents for arenes or for other useful surfactant-making purposes. Surprisingly, such fractions can even be derived from effluents from current linear alkylbenzene manufacture.

    摘要翻译： 用于制造特别是支链的，特别是用于清洁产品中的单甲基支链或非农业二甲基支链表面活性剂的方法; 优选的方法包括两个或多个吸附分离步骤的特定组合，更优选特定的烷基化步骤; 这些方法的产物，包括某些改性烷基苯，改性烷基苯磺酸盐表面活性剂，以及含有它们的消费者清洁产品，特别是衣物洗涤剂。 本文优选的方法更具体地使用吸附分离步骤的特定的非常规序列，以确保在进一步的工艺步骤中使用的某些支链烃馏分作为芳烃的烷基化剂或其它有用的表面活性剂制备目的。 令人惊讶的是，这些馏分甚至可以从目前的直链烷基苯生产的流出物得到。

    Detergent compositions containing mixtures of crystallinity-disrupted surfactants
    10.
    发明授权
    Detergent compositions containing mixtures of crystallinity-disrupted surfactants 失效
    含有结晶破坏表面活性剂混合物的洗涤剂组合物

    公开(公告)号：US06274540B1

    公开(公告)日：2001-08-14

    申请号：US09479369

    申请日：2000-01-07

    申请人： Jeffrey John Scheibel ,  Thomas Anthony Cripe ,  Kevin Lee Kott ,  Daniel Stedman Connor ,  James Charles Theophile Roger Burckett-St. Laurent ,  Phillip Kyle Vinson

    发明人： Jeffrey John Scheibel ,  Thomas Anthony Cripe ,  Kevin Lee Kott ,  Daniel Stedman Connor ,  James Charles Theophile Roger Burckett-St. Laurent ,  Phillip Kyle Vinson

    IPC分类号： C11D1700

    CPC分类号： C11D1/22

    摘要： A cleaning composition comprising: a) about 0.1% to about 99.9% by weight of said composition of an alkylarylsulfonate surfactant system comprising from about 10% to about 100% by weight of said surfactant system of two or more crystallinity-disrupted alkylarylsulfonate surfactants of formula (B-Ar-D)a(Mq+)b(Defined herein after); and b) from about 0.00001% to about 99.9% by weight of said composition of cleaning composition adjunct ingredients, at least one of which is selected from the group consisting of: i) detersive enzymes; ii) organic detergent builders; iii) oxygen bleaching agent; iv) bleach activators; v) transition metal bleach catalysts; vi) oxygen transfer agents and precursors; vii) polymeric soil release agents; viii) water-soluble ethoxylated amines having clay soil removal and antiredeposition properties; ix) polymeric dispersing agents; x) polymeric dye transfer inhibiting agents; xi) alkoxylated polycarboxylates; and xii) mixtures thereof.

    摘要翻译： 一种清洁组合物，其包含：a）约0.1％至约99.9％重量的所述组合物的烷基芳基磺酸盐表面活性剂体系，其包含约10％至约100％重量的所述表面活性剂体系，两种或更多种结晶度破坏的烷基芳基磺酸盐表面活性剂 ）为所述组合物的约0.00001％至约99.9％重量的清洁组合物辅助成分，其中至少一种选自：i）去污酶; ii）有机洗涤剂助剂; iii）氧漂剂; iv）漂白活化剂; v）过渡金属漂白剂催化剂; vi）氧传递剂和前体; vii）聚合物去污剂; viii）具有粘土去除和抗再沉积性质的水溶性乙氧基化胺; ix）聚合物分散剂; x）聚合染料转移抑制剂; xi）烷氧基化多羧酸盐; 和xii）其混合物。