摘要:
A process for upgrading a Fischer-Tropsch feedstock which comprises (a) recovering from a Fischer-Tropsch reactor a Fischer-Tropsch wax fraction and a Fischer-Tropsch condensate fraction, wherein the Fischer-Tropsch condensate fraction contains alcohols boiling below about 370° C.; (b) contacting the Fischer-Tropsch condensate fraction with a dehydration catalyst in a dehydration zone under dehydration conditions pre-selected to convert at least some of the alcohols present in said fraction into olefins and recovering a first intermediate effluent from said dehydration zone; (c) pyrolyzing the paraffins in the Fischer-Tropsch wax fraction in a thermal cracking zone under thermal cracking conditions pre-selected to crack the Fischer-Tropsch wax molecules to form olefins and collecting a second intermediate effluent from the thermal cracking zone; (d) passing the first and second intermediate effluents recovered from steps (b) and (c) to an oligomerization zone containing an oligomerization catalyst under oligomerization conditions to form an oligomerization mixture having a higher molecular weight than either of said first and second intermediate effluent; (e) hydrofinishing the oligomerization mixture in a hydrofinishing zone; and (f) recovering from the hydrofinishing zone a C10 plus hydrocarbon product, most preferably a lubricating base oil.
摘要:
A process for increasing the yield of C10 plus hydrocarbon products from a Fischer-Tropsch plant which comprises the steps of (a) separating a Fischer-Tropsch product into a wax fraction and a condensate fraction; (b) dewaxing the wax fraction to produce a high boiling intermediate; (c) hydrofinishing the high boiling intermediate; (d) dehydrating the alcohols in the condensate fraction to convert them into olefins; (e) oligomerizing the olefins to form higher molecular weight hydrocarbons; (f) hydrofinishing the oligomerization mixture; and (g) and recovering a C10 plus hydrocarbon product from the hydrofinishing zone.
摘要:
A process for producing low pour point diesel and lubricating base oil products by bulk dewaxing a C5 plus Fischer-Tropsch syncrude, hydrofinishing the dewaxed intermediate, and recovering 120 degrees C. plus products having improved properties.
摘要:
The invention includes a process of making a lubricating composition including: contacting a heavy mineral oil feed in a hydrocracking zone with a hydrocracking catalyst at hydrocracking conditions, whereby at least a portion of the heavy mineral oil feed is cracked; recovering at least one gasoline-range fraction and one bottoms fraction from the hydrocracking zone; passing a first portion of the bottoms fraction including not more than about 67 wt. % of the bottoms fraction to a dewaxing zone; and passing a second portion of the bottoms fraction including at least about 33 wt. % of the bottoms fraction back to the fuels hydrocracker for additional processing; and where the bottoms fraction has a viscosity at 100° C. of less than about 4.0; contacting the first portion of the bottoms fraction with a dewaxing catalyst under catalytic dewaxing conditions, where at least a portion thereof is substantially dewaxed; contacting at least a portion of the substantially dewaxed bottoms fraction with a hydrofinishing catalyst under hydrofinishing conditions, thereby producing a hydrofinished, dewaxed bottoms fraction; and removing from the hydrofinished, dewaxed bottoms fraction at least one light fraction including diesel or jet fuel range material, thereby leaving a heavy fraction including the lubricating composition having a naphthenes content of at least about 33 wt. %.
摘要:
We provide a process to manufacture a base stock, comprising hydrocracking, separating, and dewaxing, wherein the base stock has a ratio of Noack volatility to CCS VIS at −25° C. multiplied by 100 from 0.15 to 0.40. We also provide a base stock made by a process, and a base oil manufacturing plant that produces the base stock.
摘要:
We provide a process to manufacture a base stock, comprising hydrocracking, separating, and dewaxing, wherein the base stock has a ratio of Noack volatility to CCS VIS at −25° C. multiplied by 100 from 0.15 to 0.40. We also provide a base stock made by a process, and a base oil manufacturing plant that produces the base stock.
摘要:
The present invention provides for a lubricating composition including: a hydrocracker-derived, highly naphthenic, low viscosity index mineral oil; from about 2 wt. % to about 14 wt. % of at least one polymethacrylate polymer; and from about 2 wt. % to about 14 wt. % of a performance additive package. The hydrocracker-derived, highly naphthenic, low viscosity index mineral oil is prepared by: (1) passing a first bottoms portion including not more than about 67 wt. % of a fuels hydrocracker bottoms recycle stream to a dewaxing zone; and (2) passing a second bottoms portion including at least about 33 wt. % of the recycle stream back to the fuels hydrocracker for additional processing; and where the recycle stream has a viscosity at 100.degree. C. of less than about 4.0; (3) contacting the first bottoms portion with a dewaxing catalyst under catalytic dewaxing conditions, where at least a portion of the hydrocracker bottoms is substantially dewaxed; and (4) contacting at least a portion of the substantially dewaxed hydrocracker bottoms with a hydrofinishing catalyst under hydrofinishing conditions, thereby producing a hydrofinished, dewaxed hydrocracker bottoms; and removing from the hydrofinished, dewaxed hydrocracker bottoms at least one light fraction including diesel or jet fuel range material, thereby leaving a heavy fraction including the hydrocracker-derived, highly naphthenic, viscosity index mineral oil having a naphthenes content of at least about 33 wt. %. The lubricating composition has an unsheared kinematic viscosity at 100.degree. C. of at least about 7.3 centistokes; a sheared kinematic viscosity at 100.degree. C. of at least about 6.8 centistokes, where shear is measured by the 20-hour KRL method; and a Brookfield viscosity at -40.degree. C. of no greater than about 10,000 centipoise.
摘要:
We provide a process to manufacture a base stock, comprising hydrocracking, separating, and dewaxing, wherein the base stock has a ratio of Noack volatility to CCS VIS at −25° C. multiplied by 100 from 0.15 to 0.40. We also provide a base stock made by a process, and a base oil manufacturing plant that produces the base stock.