Aqueous polyurethane dispersions
    5.
    发明申请

    公开(公告)号:US20050222368A1

    公开(公告)日:2005-10-06

    申请号:US11093158

    申请日:2005-03-29

    摘要: Polyurethane which is obtainable by reacting a) an NCO-containing prepolymer composed of a1) at least one polyesterpolyol, preferably polycarbonatepolyol, carbonate group-free polyesterpolyol, polyestercarbonatepolyol, polyesteramidepolyol, in particular polyesterdiol, having an average molecular weight, determined as the number average, greater than or equal to 500 g/mol, preferably from 500 to 6000 g/mol, in particular from 500 to 4000 g/mol, very particularly preferably from 800 to 4000 g/mol, and a2) at least one polyetherpolyol which differs from a1) and is preferably polyalkylene glycol, such as polyethylene glycol, polypropylene glycol, polytetramethylene glycol, polyhexamethylene glycol and copolyethers, in particular those containing building blocks from the group consisting of ethyleneoxy, propyleneoxy, tetramethyleneoxy and/or hexamethyleneoxy, having a molecular weight, determined as the number average, greater than or equal to 500, preferably from 500 to 10 000 g/mol, in particular from 500 to 4000, particularly preferably from 800 to 4000, g/mol, preferably a polyetherdiol, and a3) at least one polyol, in particular diol, having a molecular weight of less than 500 g/mol, which carries one or more ionic groups and/or one or more potentially ionic groups, preferably carries one or more carboxylate groups, and a4) at least one aliphatic polyisocyanate, preferably diisocyanate, preferably having a molecular weight of less than 500 g/mol, in particular from 112 to 400 g/mol, particularly preferably from 168 to 262 g/mol, and a5) optionally a nonionic polyol, preferably diol having a molecular weight of less than 500 g/mol, preferably from 61 to 499 g/mol, and a6) optionally a monoalcohol with b) at least one polysiloxane reactive towards NCO groups and having a molecular weight, determined as the number average, of less than 1500 g/mol, preferably having 1 to 6, in particular 1 to 3, amino and/or hydroxyl groups reactive towards NCO groups, in particular amino groups, and c) at least one amine reactive towards NCO groups and having an average amino functionality of from 1 to 6 and a molecular weight of less than 500 g/mol (molecular weight determined as the number average), which may be substituted by hydroxyl groups and/or sulpho groups and/or carboxyl groups, and d) water, the molar ratio of the hydroxy-functional compounds used for the preparation of the prepolymer a) to the polyisocyanate being from 1: 1.1 to 1: 2.5, preferably from 1.1:1 to 1: 1.7.

    Anionically modified polyurethane ureas having reduced tackiness for the
coating of leather
    6.
    发明授权
    Anionically modified polyurethane ureas having reduced tackiness for the coating of leather 失效
    具有降低皮革涂层粘性的阴离子改性聚氨酯脲

    公开(公告)号:US5770264A

    公开(公告)日:1998-06-23

    申请号:US711423

    申请日:1996-09-05

    摘要: This invention relates to a method for coating leather with an anionically modified polyurethane urea prepared by (1) reacting (A) an aromatic diisocyanate, (B) a polyether polyol having a number average molecular weight greater than 1500, (C) at least one compound containing 1 to 2 isocyanate-reactive groups and at least one ionic group, and (D) a polyamine having a number average molecular weight of at least 32, wherein the average total functionality of compounds (B), (C), and (D) is 1.85 to 2.2 and the molar ratio between the NCO groups of component (A) and the NCO-reactive groups of components (B), (C), and (D) is greater than 1, thereby forming an intermediate having residual NCO groups, and (2) mixing the intermediate product with water to form an aqueous dispersion of an anionically modified polyurethane urea having 800 to 1500 mmol of urethane groups and 800 to 1800 mmol of urethane plus urea groups per kilogram of the polyurethane urea.

    摘要翻译: 本发明涉及一种用阴离子改性聚氨酯脲涂覆皮革的方法,该方法是(1)使(A)芳族二异氰酸酯,(B)数均分子量大于1500的聚醚多元醇,(C)至少一种 含有1至2个异氰酸酯反应性基团和至少一个离子基团的化合物,和(D)数均分子量至少为32的多胺,其中化合物(B),(C)和(C) D)为1.85〜2.2,组分(A)的NCO基与组分(B),(C)和(D)的NCO-反应性基团之间的摩尔比大于1,从而形成具有残余 NCO基团,和(2)将中间产物与水混合以形成每千克聚氨酯脲具有800至1500mmol氨基甲酸酯基团和800至1800mmol氨基甲酸酯加脲基团的阴离子改性聚氨酯脲的水分散体。

    Water-dispersible polyisocyanate mixtures, a process for their
preparation and their use in two-component aqueous compositions
    8.
    发明授权
    Water-dispersible polyisocyanate mixtures, a process for their preparation and their use in two-component aqueous compositions 失效
    水分散性多异氰酸酯混合物,其制备方法及其在双组分含水组合物中的应用

    公开(公告)号:US5252696A

    公开(公告)日:1993-10-12

    申请号:US971491

    申请日:1992-11-04

    摘要: The present invention relates to water-dispersible polyisocyanate mixtures whicha) have an average isocyanate functionality of 1.8 to 4.2,b) contain 12.0 to 21.5% by weight of (cyclo)aliphatically bound isocyanate groups (calculated as NCO, molecular weight=42) andc) contain 2 to 20% by weight of ethylene oxide units (calculated as C.sub.2 H.sub.4 O, molecular weight=44) arranged within polyether chains, the polyether chains containing an average of 5.0 to 9.9 ethylene oxide units.The present invention also relates to the preparation of these polyisocyanate mixtures by reacting at an NCO/OH equivalent ratio of 4:1 to 120:1A) a polyisocyanate component having an average isocyanate functionality of 2.1 to 4.4 and containing one or more polyisocyanates in which all the isocyanate groups are (cyclo)aliphatically bound withB) a monovalent polyalkylene oxide polyether alcohol containing an average of 5.0 to 9.9 ethylene oxide units.Finally, the present invention also relates to aqueous two-component compositions containing these polyisocyanate mixtures and aqueous resins having isocyanate-reactive groups.

    摘要翻译: 本发明涉及a)具有1.8-4.2的平均异氰酸酯官能度的水分散性多异氰酸酯混合物,b)含有12.0至21.5重量%(环)脂族结合的异氰酸酯基团(按NCO计算,分子量= 42) 和c)包含2至20重量%的排列在聚醚链内的环氧乙烷单元(按C 2 H 4 O计算,分子量= 44),所述聚醚链平均含有5.0至9.9个环氧乙烷单元。 本发明还涉及这些多异氰酸酯混合物的制备,其反应为NCO / OH当量比为4:1至120:1,A)异氰酸酯官能度平均值为2.1至4.4的多异氰酸酯组分,并含有一种或多种多异氰酸酯 其中所有异氰酸酯基团(B)与B)一种含有平均5.0-9.9个环氧乙烷单元的一价聚环氧烷聚醚醇。 最后,本发明还涉及含有这些多异氰酸酯混合物和具有异氰酸酯反应性基团的水性树脂的水性双组分组合物。