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    PROCESS FOR THE ALKOXYLATION OF AMINO GROUP CONTAINING POLYMERS
    1.
    发明申请
    PROCESS FOR THE ALKOXYLATION OF AMINO GROUP CONTAINING POLYMERS 有权
    含氨基聚合物的烷氧基化方法

    公开(公告)号：US20100286342A1

    公开(公告)日：2010-11-11

    申请号：US12743754

    申请日：2008-11-17

    申请人： Dieter Boeckh ,  Stefan Frenzel ,  Christian Bittner ,  Andrea Misske ,  Ulrich Annen ,  Wilfried Sager ,  Sophia Ebert ,  Andreas Eichhorn

    发明人： Dieter Boeckh ,  Stefan Frenzel ,  Christian Bittner ,  Andrea Misske ,  Ulrich Annen ,  Wilfried Sager ,  Sophia Ebert ,  Andreas Eichhorn

    IPC分类号： C08F8/00

    CPC分类号： C08G65/2618 ,  C08G65/2633 ,  C08G65/2648 ,  C08L71/02 ,  C08L77/00 ,  C08L79/00 ,  C08L2666/20

    摘要： The present invention relates to a process for the alkoxylation of a first polymer comprising at least one monomer unit having NH groups and optionally NH2 groups, wherein the first polymer has a molecular weight Mw of at least 500 g/mol, comprising the steps of (a) reacting the first polymer with alkylene oxide in a reaction mixture comprising a solvent until the average degree of alkoxylation of each NH group and each optional NH2 group, calculated as two NH groups, is from 0.75 to 1.25; (b) adding a second polymer of formula (I), wherein R is a linear or branched alkyl group having from 1 to 20 carbon atoms, each R′ is independently a linear or branched alkyl group having from 1 to 20 carbon atoms or hydrogen, each n is independently from 1 to 5 and m is from 5 to 40, to the reaction mixture of step (a); (c) at least partially removing the solvent from the reaction mixture of step (b); and (d) further reacting the reaction mixture of step (c) with alkylene oxide at a given temperature until the average degree of alkoxylation of each NH group and each optional NH2 group, calculated as two NH groups, of the first polymer is from 2 to 40. The present invention also relates to a polymer composition obtainable from that process and the use of such a polymer composition.

    摘要翻译： 本发明涉及第一聚合物的烷氧基化方法，其包括至少一个具有NH基团和任选的NH 2基团的单体单元，其中第一聚合物的分子量Mw至少为500g / mol，包括步骤（ a）在包含溶剂的反应混合物中使第一聚合物与烯化氧反应，直到每个NH基团和每个任选的NH 2基团的平均烷氧基化程度计算为两个NH基团为0.75至1.25; （b）添加式（I）的第二聚合物，其中R是具有1至20个碳原子的直链或支链烷基，每个R'独立地是具有1至20个碳原子的直链或支链烷基或氢 相对于步骤（a）的反应混合物，每个n独立地为1至5，m为5至40。 （c）至少部分地从步骤（b）的反应混合物中除去溶剂; 和（d）在给定温度下使步骤（c）的反应混合物与烯化氧进一步反应，直到第一聚合物的两个NH基团计算的每个NH基团和每个任选的NH 2基团的平均烷氧基化程度为2 本发明还涉及可从该方法获得的聚合物组合物和这种聚合物组合物的用途。

    Process for the alkoxylation of amino group containing polymers
    2.
    发明授权
    Process for the alkoxylation of amino group containing polymers 有权
    含氨基聚合物的烷氧基化方法

    公开(公告)号：US08507613B2

    公开(公告)日：2013-08-13

    申请号：US12743754

    申请日：2008-11-17

    申请人： Dieter Boeckh ,  Stefan Frenzel ,  Christian Bittner ,  Andrea Misske ,  Ulrich Annen ,  Wilfried Sager ,  Sophia Ebert ,  Andreas Eichhorn

    发明人： Dieter Boeckh ,  Stefan Frenzel ,  Christian Bittner ,  Andrea Misske ,  Ulrich Annen ,  Wilfried Sager ,  Sophia Ebert ,  Andreas Eichhorn

    IPC分类号： C08G65/00 ,  C08G65/30

    CPC分类号： C08G65/2618 ,  C08G65/2633 ,  C08G65/2648 ,  C08L71/02 ,  C08L77/00 ,  C08L79/00 ,  C08L2666/20

    摘要： The present invention relates to a process for the alkoxylation of a first polymer comprising at least one monomer unit having NH groups and optionally NH2 groups, wherein the first polymer has a molecular weight Mw of at least 500 g/mol, comprising the steps of (a) reacting the first polymer with alkylene oxide in a reaction mixture comprising a solvent until the average degree of alkoxylation of each NH group and each optional NH2 group, calculated as two NH groups, is from 0.75 to 1.25; (b) adding a second polymer of formula (I), wherein R is a linear or branched alkyl group having from 1 to 20 carbon atoms, each R′ is independently a linear or branched alkyl group having from 1 to 20 carbon atoms or hydrogen, each n is independently from 1 to 5 and m is from 5 to 40, to the reaction mixture of step (a); (c) at least partially removing the solvent from the reaction mixture of step (b); and (d) further reacting the reaction mixture of step (c) with alkylene oxide at a given temperature until the average degree of alkoxylation of each NH group and each optional NH2 group, calculated as two NH groups, of the first polymer is from 2 to 40. The present invention also relates to a polymer composition obtainable from that process and the use of such a polymer composition.

    摘要翻译： 本发明涉及第一聚合物的烷氧基化方法，其包含至少一个具有NH基团和任选的NH 2基团的单体单元，其中第一聚合物的分子量Mw至少为500g / mol，包括步骤（ a）在包含溶剂的反应混合物中使第一聚合物与烯化氧反应，直到每个NH基团和每个任选的NH 2基团的平均烷氧基化程度计算为两个NH基团为0.75至1.25; （b）添加式（I）的第二聚合物，其中R是具有1至20个碳原子的直链或支链烷基，每个R'独立地是具有1至20个碳原子的直链或支链烷基或氢 相对于步骤（a）的反应混合物，每个n独立地为1至5，m为5至40。 （c）至少部分地从步骤（b）的反应混合物中除去溶剂; 和（d）在给定温度下使步骤（c）的反应混合物与烯化氧进一步反应，直到第一聚合物的NH基团和每个任选的NH 2基团的平均烷氧基化程度计算为两个NH基团为2 本发明还涉及可从该方法获得的聚合物组合物和这种聚合物组合物的用途。

    Amphiphilic water-soluble alkoxylated polyalkyleneimines having an inner polyethylene oxide block and an outer polypropylene oxide block
    3.
    发明授权
    Amphiphilic water-soluble alkoxylated polyalkyleneimines having an inner polyethylene oxide block and an outer polypropylene oxide block 有权
    具有内部聚环氧乙烷嵌段和外部聚环氧丙烷嵌段的两亲性水溶性烷氧基化聚亚烷基亚胺

    公开(公告)号：US08318653B2

    公开(公告)日：2012-11-27

    申请号：US12739747

    申请日：2008-11-07

    申请人： Andrea Misske ,  Sophia Ebert ,  Stefan Frenzel ,  Dieter Boeckh ,  Frank Huelskoetter ,  James Danziger

    发明人： Andrea Misske ,  Sophia Ebert ,  Stefan Frenzel ,  Dieter Boeckh ,  Frank Huelskoetter ,  James Danziger

    IPC分类号： C11D3/37 ,  C11D1/722 ,  C11D3/30 ,  C08G73/02

    CPC分类号： C08L79/02 ,  C08G73/0206 ,  C08G73/024

    摘要： The present invention relates to amphiphilic water-soluble alkoxylated polyalkyleneimines having an inner polyethylene oxide block comprising 20 to 50 polyethylene oxide units and an outer polypropylene oxide block comprising 10 to 50 polyethylene oxide units and especially to such alkoxylated polyalkyleneimines wherein the ratio of polyethylene oxide units and polypropylene oxide units is proportionally related to the square root of the number of polyalkyleneimine units present in the backbone. The present invention further relates to the use of these alkoxylated polyalkyleneimines as a soil detachment promoting additive to laundry detergents and cleaning compositions and to laundry detergents and cleaning compositions which comprise these alkoxylated mono- or polyalkyleneimines.

    摘要翻译： 本发明涉及具有包含20-50个聚环氧乙烷单元的内部聚环氧乙烷嵌段的两亲性水溶性烷氧基化聚亚烷基亚胺和包含10-50个聚环氧乙烷单元的外部聚环氧丙烷嵌段，特别涉及这样的烷氧基化聚亚烷基亚胺，其中聚环氧乙烷单元 和聚丙烯氧化物单元与存在于主链中的聚亚烷基亚胺单元的数量的平方根成比例地相关。 本发明还涉及这些烷氧基化聚亚烷基亚胺作为洗涤剂和清洁组合物的促进添加剂的土壤剥离剂以及包含这些烷氧基化单 - 或聚亚烷基亚胺的衣物洗涤剂和清洁组合物的用途。

    Alkoxylated polyalkanolamines
    4.
    发明授权
    Alkoxylated polyalkanolamines 有权
    烷氧基化聚链烷醇胺

    公开(公告)号：US08129326B2

    公开(公告)日：2012-03-06

    申请号：US12740050

    申请日：2008-11-07

    申请人： Andrea Misske ,  Sophia Ebert ,  Stefan Frenzel ,  Dieter Boeckh ,  Frank Huelskoetter ,  James Danziger

    发明人： Andrea Misske ,  Sophia Ebert ,  Stefan Frenzel ,  Dieter Boeckh ,  Frank Huelskoetter ,  James Danziger

    IPC分类号： C11D3/30

    CPC分类号： C08G73/024

    摘要： The present invention relates to polymers obtainable by condensation of N-(hydroxy-alkyl)amines and reacting the remaining hydroxy and/or secondary amino groups of the condensation product with alkylene oxides and to derivatives obtainable by quaternization, protonation, sulphation and/or phosphation of said polymers, as well as to a process for preparing said polymers and a process for preparing said derivatives.

    摘要翻译： 本发明涉及通过N-（羟基 - 烷基）胺的缩合和使缩合产物的剩余羟基和/或仲氨基与环氧烷反应得到的聚合物和通过季铵化，质子化，硫酸化和/或磷酸化得到的衍生物 的所述聚合物，以及制备所述聚合物的方法和制备所述衍生物的方法。

    AMPHIPHILIC WATER-SOLUBLE ALKOXYLATED POLYALKYLENEIMINES HAVING AN INNER POLYETHYLENE OXIDE BLOCK AND AN OUTER POLYPROPYLENE OXIDE BLOCK
    8.
    发明申请
    AMPHIPHILIC WATER-SOLUBLE ALKOXYLATED POLYALKYLENEIMINES HAVING AN INNER POLYETHYLENE OXIDE BLOCK AND AN OUTER POLYPROPYLENE OXIDE BLOCK 有权
    具有内部聚乙烯氧化物块和外部聚丙烯氧化物块的水溶性可溶性烷氧基聚亚烷基

    公开(公告)号：US20100261634A1

    公开(公告)日：2010-10-14

    申请号：US12739747

    申请日：2008-11-07

    申请人： Andrea Misske ,  Sophia Ebert ,  Stefan Frenzel ,  Dieter Boeckh ,  Frank Huelskoetter ,  James Danziger

    发明人： Andrea Misske ,  Sophia Ebert ,  Stefan Frenzel ,  Dieter Boeckh ,  Frank Huelskoetter ,  James Danziger

    IPC分类号： C11D3/26 ,  C07C249/02 ,  C08G73/00

    CPC分类号： C08L79/02 ,  C08G73/0206 ,  C08G73/024

    摘要： The present invention relates to amphiphilic water-soluble alkoxylated polyalkyleneimines having an inner polyethylene oxide block comprising 20 to 50 polyethylene oxide units and an outer polypropylene oxide block comprising 10 to 50 polyethylene oxide units and especially to such alkoxylated polyalkyleneimines wherein the ratio of polyethylene oxide units and polypropylene oxide units is proportionally related to the square root of the number of polyalkyleneimine units present in the backbone. The present invention further relates to the use of these alkoxylated polyalkyleneimines as a soil detachment promoting additive to laundry detergents and cleaning compositions and to laundry detergents and cleaning compositions which comprise these alkoxylated mono- or polyalkyleneimines.

    摘要翻译： 本发明涉及具有包含20-50个聚环氧乙烷单元的内部聚环氧乙烷嵌段的两亲性水溶性烷氧基化聚亚烷基亚胺和包含10-50个聚环氧乙烷单元的外部聚环氧丙烷嵌段，特别涉及这样的烷氧基化聚亚烷基亚胺，其中聚环氧乙烷单元 和聚丙烯氧化物单元与存在于主链中的聚亚烷基亚胺单元的数量的平方根成比例地相关。 本发明还涉及这些烷氧基化聚亚烷基亚胺作为洗涤剂和清洁组合物的促进添加剂的土壤剥离剂以及包含这些烷氧基化单 - 或聚亚烷基亚胺的衣物洗涤剂和清洁组合物的用途。