Two-stage process for the production of polycarbonates based on special
dihydroxydiphenylalkanes
    2.
    发明授权
    Two-stage process for the production of polycarbonates based on special dihydroxydiphenylalkanes 失效
    基于特殊二羟基二苯基甲烷生产聚碳酸酯的两阶段工艺

    公开(公告)号:US5104963A

    公开(公告)日:1992-04-14

    申请号:US622058

    申请日:1990-12-04

    CPC分类号: C08G64/20 C08G64/04 C08G64/30

    摘要: A process for the preparation of a phenol and solvent free polycarbonate resin is disclosed comprising(i) forming an oligomeric polycarbonate comprising structural units based on a diphenol corresponding to ##STR1## wherein R.sup.1 and R.sup.2 independently of one another denote a member selected from the group consisting of a hydrogen atom, a halogen atom, C.sub.1-8 alkyl, C.sub.5-6 cycloalkyl, C.sub.6-10 aryl and C.sub.7-12 aralkyl radicals,m is an integer of from 4 to 7,X represents carbon andR.sup.3 and R.sup.4 are individually selected for each X and independently of one another represent a hydrogen atom or a C.sub.1-6 alkyl radical, with the proviso that for at least one X atom, both R.sup.3 and R.sup.4 are alkyl radicals, and(ii) condensing said oligomeric polycarbonate at a temperature in the range of of 140 to 350.degree. C.

    摘要翻译: 公开了一种制备苯酚和无溶剂聚碳酸酯树脂的方法,其包括(i)形成低聚聚碳酸酯,其包含基于对应于图像的二酚的结构单元,其中R 1和R 2彼此独立地表示选自以下的成员 由氢原子,卤素原子,C 1-8烷基,C 5-6环烷基,C 6-10芳基和C 7-12芳烷基组成,m为4-7的整数,X为碳,R3和R4分别为 对于每个X并且彼此独立地选择,表示氢原子或C 1-6烷基,条件是对于至少一个X原子,R 3和R 4都是烷基,和(ii)将所述低聚物聚碳酸酯在 温度范围为140〜350℃