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公开(公告)号：US07169937B2
公开(公告)日：2007-01-30
申请号：US10662902
申请日：2003-09-15
申请人： Dirk Achten , Michael Klimpel , Emilie Barriau , Lothar Reif , Renke Mottweiler , Heinrich Berg , Zsolt Szentivanyi , Stefan Glander
发明人： Dirk Achten , Michael Klimpel , Emilie Barriau , Lothar Reif , Renke Mottweiler , Heinrich Berg , Zsolt Szentivanyi , Stefan Glander
IPC分类号： C07D207/30
CPC分类号： C07D207/325 , C07C333/24 , C07D231/12 , C07D233/54 , C07D233/56 , C07D249/08 , C08F2/38 , C08F36/18
摘要： The present invention relates to dithiocarbamic esters, their preparation and their use for regulating the degree of polymerization during the polymerization of monomers, such as during the polymerization of chloroprene to give polychloroprene, and during the polymerization of 2,3-dichlorobutadiene to give poly-2,3-dichlorobutadiene, and during the copolymerization of chloroprene with 2,3-dichlorobutadiene. The present invention further relates to polymers which are obtainable via the polymerization of monomers in the presence of the dithiocarbamic esters of the invention. The present invention also relates to polymers which contain end groups derived from the dithiocarbamic esters of the present invention.
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公开(公告)号：US20070078229A1
公开(公告)日：2007-04-05
申请号：US11607535
申请日：2006-12-01
申请人： Dirk Achten , Michael Klimpel , Emilie Barriau , Lothar Reif , Renke Mottweiler , Heinrich Berg , Zsolt Szentivanyi , Stefan Glander
发明人： Dirk Achten , Michael Klimpel , Emilie Barriau , Lothar Reif , Renke Mottweiler , Heinrich Berg , Zsolt Szentivanyi , Stefan Glander
IPC分类号： C08F291/00 , C08F253/00 , C07D207/34
CPC分类号： C07D207/325 , C07C333/24 , C07D231/12 , C07D233/54 , C07D233/56 , C07D249/08 , C08F2/38 , C08F36/18
摘要： The present invention relates to dithiocarbamic esters, their preparation and their use for regulating the degree of polymerization during the polymerization of monomers, such as during the polymerization of chloroprene to give polychloroprene, and during the polymerization of 2,3-dichlorobutadiene to give poly-2,3-dichlorobutadiene, and during the copolymerization of chloroprene with 2,3-dichlorobutadiene. The present invention further relates to polymers which are obtainable via the polymerization of monomers in the presence of the dithiocarbamic esters of the invention. The present invention also relates to polymers which contain end groups derived from the dithiocarbamic esters of the present invention.
摘要翻译： 本发明涉及二硫代氨基甲酸酯，它们的制备及其用于调节单体聚合过程中聚合反应的程度，例如在氯丁二烯聚合反应得到聚氯丁二烯期间，以及在2,3-二氯丁二烯聚合过程中， 在氯丁二烯与2,3-二氯丁二烯的共聚过程中。 本发明还涉及在本发明的二硫代氨基甲酸酯存在下通过单体的聚合获得的聚合物。 本发明还涉及含有源自本发明的二硫代氨基甲酸酯的端基的聚合物。
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公开(公告)号：US20110015360A1
公开(公告)日：2011-01-20
申请号：US12888461
申请日：2010-09-23
申请人： Dirk Achten , Michael Klimpel , Emilie Barriau , Lothar Reif , Renke Mottweiler , Heinrich Berg , Zsolt Szentivanyi , Stefan Glander
发明人： Dirk Achten , Michael Klimpel , Emilie Barriau , Lothar Reif , Renke Mottweiler , Heinrich Berg , Zsolt Szentivanyi , Stefan Glander
IPC分类号： C08F226/00
CPC分类号： C07D207/325 , C07C333/24 , C07D231/12 , C07D233/54 , C07D233/56 , C07D249/08 , C08F2/38 , C08F36/18
摘要： The present invention relates to dithiocarbamic esters, their preparation and their use for regulating the degree of polymerization during the polymerization of monomers, such as during the polymerization of chloroprene to give polychloroprene, and during the polymerization of 2,3-dichlorobutadiene to give poly-2,3-dichlorobutadiene, and during the copolymerization of chloroprene with 2,3-dichlorobutadiene. The present invention further relates to polymers which are obtainable via the polymerization of monomers in the presence of the dithiocarbamic esters of the invention. The present invention also relates to polymers which contain end groups derived from the dithiocarbamic esters of the present invention.
摘要翻译： 本发明涉及二硫代氨基甲酸酯，它们的制备及其用于调节单体聚合过程中聚合反应的程度，例如在氯丁二烯聚合反应得到聚氯丁二烯期间，以及在2,3-二氯丁二烯聚合过程中， 在氯丁二烯与2,3-二氯丁二烯的共聚过程中。 本发明还涉及在本发明的二硫代氨基甲酸酯存在下通过单体的聚合获得的聚合物。 本发明还涉及含有源自本发明的二硫代氨基甲酸酯的端基的聚合物。
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公开(公告)号：US07977431B2
公开(公告)日：2011-07-12
申请号：US12888461
申请日：2010-09-23
申请人： Dirk Achten , Michael Klimpel , Emilie Barriau , Lothar Reif , Renke Mottweiler , Heinrich Berg , Zsolt Szentivanyi , Stefan Glander
发明人： Dirk Achten , Michael Klimpel , Emilie Barriau , Lothar Reif , Renke Mottweiler , Heinrich Berg , Zsolt Szentivanyi , Stefan Glander
IPC分类号： C08F236/06 , C08F236/08 , C08F236/10
CPC分类号： C07D207/325 , C07C333/24 , C07D231/12 , C07D233/54 , C07D233/56 , C07D249/08 , C08F2/38 , C08F36/18
摘要： The present invention relates to dithiocarbamic esters, their preparation and their use for regulating the degree of polymerization during the polymerization of monomers, such as during the polymerization of chloroprene to give polychloroprene, and during the polymerization of 2,3-dichlorobutadiene to give poly-2,3-dichlorobutadiene, and during the copolymerization of chloroprene with 2,3-dichlorobutadiene. The present invention further relates to polymers which are obtainable via the polymerization of monomers in the presence of the dithiocarbamic esters of the invention. The present invention also relates to polymers which contain end groups derived from the dithiocarbamic esters of the present invention.
摘要翻译： 本发明涉及二硫代氨基甲酸酯，它们的制备及其用于调节单体聚合过程中聚合反应的程度，例如在氯丁二烯聚合反应得到聚氯丁二烯期间，以及在2,3-二氯丁二烯聚合过程中， 在氯丁二烯与2,3-二氯丁二烯的共聚过程中。 本发明还涉及在本发明的二硫代氨基甲酸酯存在下通过单体的聚合获得的聚合物。 本发明还涉及含有源自本发明的二硫代氨基甲酸酯的端基的聚合物。
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公开(公告)号：US07825193B2
公开(公告)日：2010-11-02
申请号：US11607535
申请日：2006-12-01
申请人： Dirk Achten , Michael Klimpel , Emilie Barriau , Lothar Reif , Renke Mottweiler , Heinrich Berg , Zsolt Szentivanyi , Ste{acute over (f)}an Glander
发明人： Dirk Achten , Michael Klimpel , Emilie Barriau , Lothar Reif , Renke Mottweiler , Heinrich Berg , Zsolt Szentivanyi , Ste{acute over (f)}an Glander
IPC分类号： C08F236/06 , C08F236/08 , C08F236/10
CPC分类号： C07D207/325 , C07C333/24 , C07D231/12 , C07D233/54 , C07D233/56 , C07D249/08 , C08F2/38 , C08F36/18
摘要： The present invention relates to dithiocarbamic esters, their preparation and their use for regulating the degree of polymerization during the polymerization of monomers, such as during the polymerization of chloroprene to give polychloroprene, and during the polymerization of 2,3-dichlorobutadiene to give poly-2,3-dichlorobutadiene, and during the copolymerization of chloroprene with 2,3-dichlorobutadiene. The present invention further relates to polymers which are obtainable via the polymerization of monomers in the presence of the dithiocarbamic esters of the invention. The present invention also relates to polymers which contain end groups derived from the dithiocarbamic esters of the present invention.
摘要翻译： 本发明涉及二硫代氨基甲酸酯，它们的制备及其用于调节单体聚合过程中聚合反应的程度，例如在氯丁二烯聚合反应得到聚氯丁二烯期间，以及在2,3-二氯丁二烯聚合过程中， 在氯丁二烯与2,3-二氯丁二烯的共聚过程中。 本发明还涉及在本发明的二硫代氨基甲酸酯存在下通过单体的聚合获得的聚合物。 本发明还涉及含有源自本发明的二硫代氨基甲酸酯的端基的聚合物。
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公开(公告)号：US20120283351A1
公开(公告)日：2012-11-08
申请号：US13395950
申请日：2010-08-31
CPC分类号： C08L15/005 , C08C19/02 , C08C19/20 , C08L19/006 , C08L35/00
摘要： A new process is provided for preparing nitrile rubbers by free-radical polymerization in an organic solvent and in the presence of specific modifier substances. This polymerization may be followed by hydrogenation to give likewise new hydrogenated nitrile rubbers, the hydrogenation advantageously taking place likewise in organic solvent. The optionally hydrogenated nitrile rubbers obtained are notable for having fragments of the employed modifier substances in the main polymer chain and/or as end groups. They can he prepared with a wide diversity of molecular weights and polydispersity indices, especially with very low polydispersity indices.
摘要翻译： 提供了一种通过在有机溶剂中和在特定改性剂物质存在下通过自由基聚合来制备丁腈橡胶的新方法。 该聚合之后可以进行氢化，同样提供新的氢化丁腈橡胶，氢化有利地同样存在于有机溶剂中。 所得到的任选氢化的丁腈橡胶在主聚合物链和/或端基中具有使用的改性物质的片段是显着的。 他们可以准备多种多样的分子量和多分散指数，特别是具有非常低的多分散指数。
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公开(公告)号：US20100029857A1
公开(公告)日：2010-02-04
申请号：US12496953
申请日：2009-07-02
IPC分类号： C08F214/18 , C08F236/02
CPC分类号： C08K5/3465 , C08F236/12 , C08K5/17 , C08L9/02 , C08L13/00 , C08L15/005 , C08L101/08
摘要： A novel vulcanizable polymer composition is provided which is characterized by a specific combination of a polyamine crosslinking agent and a particular crosslinking accelerator. Furtheron polymer vulcanizates on the basis of such polymer compositions as well as method for preparing such polymer vulcanizate is provided, in particular in the form of mouldings or shaped parts.
摘要翻译： 提供了一种新型的可硫化聚合物组合物，其特征在于多胺交联剂和特定交联促进剂的特定组合。 基于这种聚合物组合物以及制备这种聚合物硫化橡胶的方法，特别是以模制品或成形部件的形式提供聚合物硫化橡胶。
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8.发明授权Process for preparing aromatic olefins by using palladaphosphacyclobutanes as catalysts 失效通过使用缓磷磷脂环丁烷作为催化剂制备芳族烯烃的方法公开(公告)号：US06194627B1
公开(公告)日：2001-02-27
申请号：US09308189
申请日：1999-08-20
申请人： Holger Geissler , Peter Gross , Bianca Guckes , Michael Klimpel
发明人： Holger Geissler , Peter Gross , Bianca Guckes , Michael Klimpel
IPC分类号： C07C1207
CPC分类号： B01J31/26 , B01J31/24 , B01J31/2409 , B01J31/2423 , B01J31/2447 , B01J2231/4261 , B01J2531/0205 , B01J2531/824 , B01J2540/225 , C07B37/04 , C07C67/343 , C07C69/734
摘要： The invention relates to a process for preparing monofunctional, bifunctional and polyfunctional aromatic olefins of the formula (I) by reacting haloaromatics of the formula (II) with olefins of the formula (III) wherein a palladium compound of the formula (IV) is used as catalyst.
摘要翻译： 本发明涉及通过使式（II）的卤代芳族化合物与式（III）的烯烃与式（Ⅳ）的钯化合物反应来制备式（I）的单官能，双官能和多官能的芳族烯烃的方法， 作为催化剂。
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公开(公告)号：US10597467B2
公开(公告)日：2020-03-24
申请号：US13640775
申请日：2011-04-15
申请人： Sven Brandau , Michael Klimpel , Hans Magg
发明人： Sven Brandau , Michael Klimpel , Hans Magg
摘要： By the use of special cross-linkers that contain at least two isocyanate groups, hydroxyl group-containing optionally hydrogenated nitrile rubber polymers can be successfully cross-linked. Preferred cross-linkers contain allophanate, biuret, uretdione, uretonimine, bridged carbamate, carbodiimide, isocyanurate, iminooxadiazinedione or oxadiazinetrione structural elements.
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公开(公告)号：US09650452B2
公开(公告)日：2017-05-16
申请号：US13995268
申请日：2011-12-29
申请人： Sven Brandau , Michael Klimpel , Hans Magg , Achim Welle
发明人： Sven Brandau , Michael Klimpel , Hans Magg , Achim Welle
CPC分类号： C08F24/00 , C08K5/0091 , C08K5/19 , C08L15/005 , C08L9/02
摘要： There are provided novel vulcanizable compositions based on optionally fully or partly hydrogenated nitrile rubbers containing epoxy groups, and specific crosslinkers, which no longer require use of conventional crosslinkers, more particularly sulphur. The vulcanizates producible therefrom possess very good compression sets at room temperature, 100° C. and 150° C., and additionally exhibit high tensile strength combined with good elongation at break.
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