摘要:
The present invention relates to a composition which comprises at least one hydroxyalkyl(meth)acrylate and has been stabilized for a purification, which comprises hydroquinone monomethyl ether and 4-hydroxy-2,2,6,6-tetramethylpiperidine N-oxyl. The present invention additionally describes processes for purifying and for preparing hydroxyalkyl(meth)acrylates. A further aspect of the present invention is a composition which is obtainable by the processes mentioned.
摘要:
The present invention relates to a process for purifying monomers, by evaporating at least a portion of the monomers present in a starting composition and then condensing it, which is characterized in that at least a portion of the starting composition is evaporated in a short-path evaporator, the mass flow density of the vapors {dot over (m)} being selected according to the relation (I) m . ≤ 1800 kg · K mbar · m 2 · h · kg kmol · p i · ( M ~ T ) 0.5 ( I ) in which {tilde over (M)} is the average molar mass of the vapors in the short-path evaporator in kg/kmol T is the temperature of the vapors in K pi is the pressure in the short-path evaporator in mbar {dot over (m)} is the mass flow density of the vapors in kg/(m2·h). A further aspect of the present invention is a plant for performing the process.
摘要:
The present invention relates to a process for purifying monomers, by evaporating at least a portion of the monomers present in a starting composition and then condensing it, which is characterized in that at least a portion of the starting composition is evaporated in a short-path evaporator, the mass flow density of the vapours {dot over (m)} being selected according to the relation (I) m . ≤ 1800 kg · K mbar · m 2 · h · kg kmol · p i · ( M ~ T ) 0.5 ( I ) in which {tilde over (M)} is the average molar mass of the vapours in the short-path evaporator in kg/kmol T is the temperature of the vapours in K pi is the pressure in the short-path evaporator in mbar {dot over (m)} is the mass flow density of the vapours in kg/(m2·h). A further aspect of the present invention is a plant for performing the process.
摘要:
The present invention relates to a process for purifying unsaturated compounds, said purification being performed in a plant which comprises at least two evaporators which are connected in such a way that a portion of the unsaturated compound is circulated, the vapours condensed in the first evaporator being isolated and the vapours condensed in the second evaporator being introduced into the first evaporator, which is characterized in that the mass flow with which the condensed vapours are isolated from the mixture to be purified in the first evaporator is less than the mass flow with which the condensed vapours from the second evaporator are introduced into the first evaporator.The present invention further describes a plant for performing the process, which comprises at least three evaporators which are connected to one another such that the residue of the first evaporator remaining in the liquid phase can be passed into the second evaporator, the condensed vapours of the second evaporator can be passed into the first evaporator and the residue of the second evaporator remaining in the liquid phase can be passed into the third evaporator, and the condensed vapours of the third evaporator can be passed into the second evaporator.
摘要:
A circuit arrangement, especially for supplying an electromagnetic holding brake with a clocked supply voltage, includes a module for controlled provision of a clocked supply voltage for free-wheeling operation of the holding brake. The module has a switching unit for switching off the supply voltage for braking operation. A free-wheeling diode and a suppressor diode are connected in parallel to an inductance of the holding brake, with the free-wheeling diode being effective in free-wheeling operation only and the suppressor diode being effective in braking operation only.
摘要:
The present invention relates to a process for preparing allyl methacrylate, comprising the reaction of allyl alcohol with an ester of methacrylic acid, wherein the reaction is catalysed by zirconium acetylacetonate. The process according to the invention enables particularly favourable preparation of allyl methacrylate with a very high purity.
摘要:
The present invention relates to a process for preparing allyl methacrylate, comprising the reaction of allyl alcohol with an ester of methacrylic acid, wherein the reaction is catalyzed by zirconium acetylacetonate. The process according to the invention enables particularly favorable preparation of allyl methacrylate with a very high purity.